Herbicidally active 3-phenylisoxazoline-5-carboxamides of cyclopentenylcarboxylic acid derivatives

ABSTRACT

Herbicidally active 3-phenylisoxazoline-5-carboxamides of cyclopentenylcarboxylic acid derivatives 
     The invention relates to 3-phenylisoxazoline-5-carboxamides of cyclopentenylcarboxylic acid derivatives of the general formula (I) and their agrochemically acceptable salts 
     
       
         
         
             
             
         
       
     
     and to their use in the crop protection sector.

The invention relates to the technical field of the herbicides,especially that of the herbicides for selective control of weeds andweed grasses in crops of useful plants.

Specifically, it relates to substituted3-phenylisoxazoline-5-carboxamides and -5-thioamides ofcyclopentenylcarboxylic acid derivatives, to processes for theirpreparation and to their use as herbicides.

WO1995/014681 A1, WO1995/014680 A1, WO 2008/035315 A1, WO2005/051931 A1and WO2005/021515 A1 each describe, inter alia,3-phenylisoxazoline-5-carboxamides which are substituted at the phenylring in the 3- and 4-positions by alkoxy radicals. WO1998/057937 A1describes, inter alia, compounds which are substituted at the phenylring in the 4-position by an alkoxy radical. WO2006/016237 A1 describes,inter alia, in each case those compounds which are substituted at thephenyl ring by an amido radical. The compounds described in thedocuments mentioned above are disclosed in these documents as beingpharmacologically active.

WO2005/021516 A1 discloses3-(([3-(3-tert-butylphenyl)-5-ethyl-4,5-dihydro-1,2-oxazol-5-yl]carbonyl)amino)-5-fluoro-4-oxopentanoicacid and3-(([3-(3-tert-butylphenyl)-5-isopropyl-4,5-dihydro-1,2-oxazol-5-yl]carbonyl)amino)-5-fluoro-4-oxopentanoicacid as pharmacologically active compounds.

DE 4026018 A1, EP 0 520 371 A2 and DE 4017665 disclose3-phenylisoxazoline-5-carboxamides bearing a hydrogen atom in the 5position of the isoxazoline ring. These compounds are described thereinas agrochemically active safeners, i.e. as compounds which eliminate theunwanted herbicidal action of herbicides on crop plants. No herbicidalaction of these compounds is disclosed. European patent application No.10170238, which has an earlier priority date but was yet to be publishedat the priority date of the present application, discloses herbicidallyand fungicidally active 3-phenylisoxazoline-5-carboxamides and3-phenylisoxazoline-5-thioamides bearing a hydrogen atom in the 5position of the isoxazoline ring. Monatshefte Chemie (2010) 141, 461 andLetters in Organic Chemistry (2010), 7, 502 also disclose3-phenylisoxazoline-5-carboxamides bearing a hydrogen atom in the 5position of the isoxazoline ring. Fungicidal action, but not herbicidalaction, is disclosed for some of the compounds mentioned.

WO 2014/048827 describes the herbicidal action of3-phenylisoxazoline-5-carboxylic acids, -5-carboxylic esters,-5-carbaldehydes and -5-nitriles.

WO 2014/048853 discloses isoxazoline-5-carboxamides and -5-thioamideshaving heterocycles in the 3-position (herbicidal and fungicidal),

WO 2014/048940 having quinoline as specific heterocycle in the3-position (fungicidal), WO 2014/048882 having alkoxy as specificradical in the 5-position.

WO 2014/048882 discloses isoxazolinecarboxamides having alkoxy asspecific radical in the 5-position.

WO 2012/130798 describes herbicidally and fungicidally active3-phenylisoxazoline-5-carboxamides and -5-thioamides of substitutedheterocycles.

The herbicidal activity of these known compounds, in particular at lowapplication rates, and/or their compatibility with crop plants remain inneed of improvement.

For the reasons stated, there is still a need for potent herbicidesand/or plant growth regulators for the selective use in crop plants orthe use on non-crop land, where these active ingredients preferablyshould have further advantageous properties in application, for examplean improved compatibility with crop plants.

Accordingly, it is an object of the present invention to providecompounds having herbicidal activity (herbicides) which are highlyeffective against economically important harmful plants even atrelatively low application rates and can be used selectively in cropplants, preferably with good activity against harmful plants, and at thesame time preferably have good compatibility with crop plants.Preferably, these herbicidal compounds should be particularly effectiveand efficient against a broad spectrum of weed grasses and preferablyalso have good activity against a large number of weeds.

In addition to a herbicidal action, numerous compounds of the formula(I) also have fungicidal action which, however, is not very pronounced.

Surprisingly it has now been found that the3-phenylisoxazoline-5-carboxamides of cyclopentenylcarboxylic acidderivatives of the formula (I) defined below and their salts haveexcellent herbicidal activity against a broad spectrum of economicallyimportant mono- and dicotyledonous annual harmful plants.

The present invention therefore provides compounds of the generalformula (I)

-   or an agrochemically acceptable salt thereof, in which-   G represents a group of the formula OR⁴ or NR¹¹R¹²;-   G¹ and R² independently of one another represent hydrogen, halogen    or cyano,    -   or    -   represent (C₁-C₄)-alkyl or (C₁-C₄)-alkoxy, each of which is        substituted by m radicals from the group consisting of halogen        and cyano;    -   R³ represents cyano or fluorine,    -   or    -   represents (C₁-C₅)-alkyl, (C₃-C₆)-cycloalkyl, (C₂-C₅)-alkenyl,        (C₂-C₅)-alkynyl or (C₁-C₅)-alkoxy, each of which is substituted        by m radicals from the group consisting of halogen, cyano,        (C₁-C₅)-alkoxy and hydroxy;-   R⁴ represents hydrogen,    -   or    -   represents (C₁-C₁₂)-alkyl, (C₃-C₇)-cycloalkyl,        (C₃-C₇)-cycloalkyl-(C₁-C₈)-alkyl, (C₂-C₈)-alkenyl,        (C₅-C₆)-cycloalkenyl or (C₂-C₈)-alkynyl, each of which is        substituted by m radicals from the group consisting of halogen,        cyano, (C₁-C₆)-alkoxy, hydroxy and aryl;-   Y represents oxygen or sulfur;-   W represents oxygen or sulfur;-   Z represents a monounsaturated cyclopentane ring which is    substituted by k radicals from the group R¹⁰,

-   -   where the arrow in each case denotes a bond to the group C═W of        the formula (I);

-   R¹⁰ represents halogen, cyano or CO₂R⁷,    -   or    -   represents (C₁-C₂)-alkyl or (C₁-C₂)-alkoxy, each of which is        substituted by m radicals from the group consisting of fluorine        and chlorine;    -   R¹¹, R¹² independently of one another each represent hydrogen,        cyano, S(O)_(n)R⁵, SO₂NR⁶R⁷, CO₂R⁸, CONR⁶R⁸, COR⁶, NR⁶R⁸,        NR⁶COR⁸, NR⁶CONR⁸R⁸, NR⁶CO₂R⁸, NR⁶SO₂R⁸, NR⁶SO₂NR⁶R⁸,        C(R⁶)═NOR⁸, optionally substituted aryl, optionally substituted        heteroaryl or optionally substituted heterocyclyl,    -   or    -   represent (C₁-C₁₂)-alkyl, (C₃-C₈)-cycloalkyl,        (C₃-C₇)-cycloalkyl-(C₁-C₇)-alkyl, (C₂-C₁₂)-alkenyl,        (C₅-C₇)-cycloalkenyl or (C₂-C₁₂)-alkynyl, each of which is        substituted by m radicals from the group consisting of halogen,        cyano, nitro, OR⁷, S(O)_(n)R⁵, SO₂NR⁶R⁷, CO₂R⁸, CONR⁶R⁸, COR⁶,        NR⁶R⁸, NR⁶COR⁸, NR⁶CONR⁸R⁸, NR⁶CO₂R⁸, NR⁶SO₂R⁸, NR⁶SO₂NR⁶R⁸,        C(R⁶)═NOR⁸, optionally substituted aryl, optionally substituted        heteroaryl and optionally substituted heterocyclyl,    -   or

-   R¹¹ and R¹² together with the nitrogen atom to which they are    attached form a saturated, partially or fully unsaturated five-,    six- or seven-membered ring which is optionally mono- to    hexasubstituted by radicals from the group consisting of halogen,    cyano, nitro, (C₁-C₆)-alkyl, halo-(C₁-C₆)-alkyl, oxo, OR⁷, S(O). R⁵,    SO₂NR⁶R⁷, CO₂R⁸, CONR⁶R⁸, COR⁶, NR⁶R⁸, NR⁶COR⁸, NR⁶CONR⁸R⁸,    NR⁶CO₂R⁸, NR⁶SO₂R⁸, NR⁶SO₂NR⁶R⁸ and C(R⁶)═NOR⁸ and which, in    addition to this nitrogen atom, contains r carbon atoms, o oxygen    atoms, p sulfur atoms and q elements from the group consisting of    NR′ and NCOR⁷ as ring atoms;

-   X², X⁴ and X⁶ independently of one another each represent hydrogen,    halogen or cyano,    -   or    -   represent (C₁-C₂)-alkyl, in each case substituted by m radicals        from the group consisting of fluorine, chlorine, bromine and        (C₁-C₂)-alkoxy;

-   X³ and X⁵ independently of one another each represent hydrogen,    fluorine, chlorine, bromine, iodine, hydroxy, cyano, nitro,    S(O)_(n)R⁶ or CO₂R⁷,    -   or    -   represent (C₁-C₃)-alkyl, (C₁-C₃)-alkoxy, (C₃-C₄)-cycloalkyl,        (C₂-C₃)-alkenyl or (C₂-C₃)-alkynyl, each of which is substituted        by m radicals from the group consisting of fluorine, chlorine        and bromine;

-   R⁵ represents (C₁-C₈)-alkyl, (C₃-C₆)-cycloalkyl or aryl, each of    which is substituted by m radicals from the group consisting of    halogen, cyano and hydroxy;

-   R⁶ represents hydrogen or R⁵;

-   R⁷ represents hydrogen,    -   or    -   represents (C₁-C₆)-alkyl, (C₃-C₆)-cycloalkyl, (C₃-C₄)-alkenyl or        (C₃-C₄)-alkynyl, each of which is substituted by m radicals from        the group consisting of halogen, cyano and (C₁-C₂)-alkoxy;

-   R⁸ represents hydrogen,    -   or    -   represents (C₁-C₈)-alkyl, (C₃-C₆)-cycloalkyl, (C₃-C₈)-alkenyl or        (C₃-C₈)-alkynyl, each of which is substituted by m radicals from        the group consisting of halogen, cyano and (C₁-C₂)-alkoxy;

-   k represents the running number 0, 1 or 2; where for k>1 R¹⁰    independently of the others may be identical or different;

-   m represents the running number 0, 1, 2, 3, 4 or 5;

-   n represents the running number 0, 1 or 2;

-   o represents the running number 0, 1 or 2;

-   p represents the running number 0 or 1;

-   q represents the running number 0 or 1; and

-   r represents the running number 3, 4, 5 or 6.

Alkyl means saturated straight-chain or branched hydrocarbyl radicalshaving the number of carbon atoms specified in each case, e.g.C₁-C₆-alkyl such as methyl, ethyl, propyl, 1-methylethyl, butyl,1-methylpropyl, 2-methylpropyl, 1,1-dimethylethyl, pentyl,1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 2,2-dimethylpropyl,1-ethylpropyl, hexyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl,1-methylpentyl, 2-methylpentyl, 3-methylpentyl, 4-methylpentyl,1,1-dimethylbutyl, 1,2-dimethylbutyl, 1,3-dimethylbutyl,2,2-dimethylbutyl, 2,3-dimethylbutyl, 3,3-dimethylbutyl, 1-ethylbutyl,2-ethylbutyl, 1,1,2-trimethylpropyl, 1,2,2-trimethylpropyl,1-ethyl-1-methylpropyl and 1-ethyl-2-methylpropyl.

Halogen-substituted alkyl means straight-chain or branched alkyl groupswhere some or all of the hydrogen atoms in these groups may be replacedby halogen atoms, e.g. C₁-C₂-haloalkyl such as chloromethyl,bromomethyl, dichloromethyl, trichloromethyl, fluoromethyl,difluoromethyl, trifluoromethyl, chlorofluoromethyl,dichlorofluoromethyl, chlorodifluoromethyl, 1-chloroethyl, 1-bromoethyl,1-fluoroethyl, 2-fluoroethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl,2-chloro-2-fluoroethyl, 2-chloro-2-difluoroethyl,2,2-dichloro-2-fluoroethyl, 2,2,2-trichloroethyl, pentafluoroethyl and1,1,1-trifluoroprop-2-yl.

Alkenyl represents unsaturated straight-chain or branched hydrocarbylradicals having the number of carbon atoms stated in each case and onedouble bond in any position, for example C₂-C₆-alkenyl such as ethenyl,1-propenyl, 2-propenyl, 1-methylethenyl, 1-butenyl, 2-butenyl,3-butenyl, 1-methyl-1-propenyl, 2-methyl-1-propenyl,1-methyl-2-propenyl, 2-methyl-2-propenyl, 1-pentenyl, 2-pentenyl,3-pentenyl, 4-pentenyl, 1-methyl-1-butenyl, 2-methyl-1-butenyl,3-methyl-1-butenyl, 1-methyl-2-butenyl, 2-methyl-2-butenyl,3-methyl-2-butenyl, 1-methyl-3-butenyl, 2-methyl-3-butenyl,3-methyl-3-butenyl, 1,1-dimethyl-2-propenyl, 1,2-dimethyl-1-propenyl,1,2-dimethyl-2-propenyl, 1-ethyl-1-propenyl, 1-ethyl-2-propenyl,1-hexenyl, 2-hexenyl, 3-hexenyl, 4-hexenyl, 5-hexenyl,1-methyl-1-pentenyl, 2-methyl-1-pentenyl, 3-methyl-1-pentenyl,4-methyl-1-pentenyl, 1-methyl-2-pentenyl, 2-methyl-2-pentenyl,3-methyl-2-pentenyl, 4-methyl-2-pentenyl, 1-methyl-3-pentenyl,2-methyl-3-pentenyl, 3-methyl-3-pentenyl, 4-methyl-3-pentenyl,1-methyl-4-pentenyl, 2-methyl-4-pentenyl, 3-methyl-4-pentenyl,4-methyl-4-pentenyl, 1,1-dimethyl-2-butenyl, 1,1-dimethyl-3-butenyl,1,2-dimethyl-1-butenyl, 1,2-dimethyl-2-butenyl, 1,2-dimethyl-3-butenyl,1,3-dimethyl-1-butenyl, 1,3-dimethyl-2-butenyl, 1,3-dimethyl-3-butenyl,2,2-dimethyl-3-butenyl, 2,3-dimethyl-1-butenyl, 2,3-dimethyl-2-butenyl,2,3-dimethyl-3-butenyl, 3,3-dimethyl-1-butenyl, 3,3-dimethyl-2-butenyl,1-ethyl-1-butenyl, 1-ethyl-2-butenyl, 1-ethyl-3-butenyl,2-ethyl-1-butenyl, 2-ethyl-2-butenyl, 2-ethyl-3-butenyl,1,1,2-trimethyl-2-propenyl, 1-ethyl-1-methyl-2-propenyl,1-ethyl-2-methyl-1-propenyl and 1-ethyl-2-methyl-2-propenyl.

Alkynyl means straight-chain or branched hydrocarbyl radicals having thenumber of carbon atoms specified in each case and one triple bond in anyposition, e.g. C₂-C₆-alkynyl such as ethynyl, 1-propynyl, 2-propynyl (orpropargyl), 1-butynyl, 2-butynyl, 3-butynyl, 1-methyl-2-propynyl,1-pentynyl, 2-pentynyl, 3-pentynyl, 4-pentynyl, 3-methyl-1-butynyl,1-methyl-2-butynyl, 1-methyl-3-butynyl, 2-methyl-3-butynyl,1,1-dimethyl-2-propynyl, 1-ethyl-2-propynyl, 1-hexynyl, 2-hexynyl,3-hexynyl, 4-hexynyl, 5-hexynyl, 3-methyl-1-pentynyl,4-methyl-1-pentynyl, 1-methyl-2-pentynyl, 4-methyl-2-pentynyl,1-methyl-3-pentynyl, 2-methyl-3-pentynyl, 1-methyl-4-pentynyl,2-methyl-4-pentynyl, 3-methyl-4-pentynyl, 1,1-dimethyl-2-butynyl,1,1-dimethyl-3-butynyl, 1,2-dimethyl-3-butynyl, 2,2-dimethyl-3-butynyl,3,3-dimethyl-1-butynyl, 1-ethyl-2-butynyl, 1-ethyl-3-butynyl,2-ethyl-3-butynyl and 1-ethyl-1-methyl-2-propynyl.

Cycloalkyl means a carbocyclic saturated ring system having preferably3-8 ring carbon atoms, for example cyclopropyl, cyclobutyl, cyclopentylor cyclohexyl. In the case of optionally substituted cycloalkyl, cyclicsystems with substituents are included, also including substituents witha double bond on the cycloalkyl radical, for example an alkylidene groupsuch as methylidene.

In the case of optionally substituted cycloalkyl, polycyclic aliphaticsystems are also included, for example bicyclo[1.1.0]butan-1-yl,bicyclo[1.1.0]butan-2-yl, bicyclo[2.1.0]pentan-1-yl,bicyclo[2.1.0]pentan-2-yl, bicyclo[2.1.0]pentan-5-yl,bicyclo[2.2.1]hept-2-yl (norbornyl), adamantan-1-yl and adamantan-2-yl.

In the case of substituted cycloalkyl, spirocyclic aliphatic systems arealso included, for example spiro[2.2]pent-1-yl, spiro[2.3]hex-1-yl,spiro[2.3]hex-4-yl, 3-spiro[2.3]hex-5-yl.

Cycloalkenyl means a carbocyclic, nonaromatic, partially unsaturatedring system having preferably 4-8 carbon atoms, e.g. 1-cyclobutenyl,2-cyclobutenyl, 1-cyclopentenyl, 2-cyclopentenyl, 3-cyclopentenyl, or1-cyclohexenyl, 2-cyclohexenyl, 3-cyclohexenyl, 1,3-cyclohexadienyl or1,4-cyclohexadienyl, also including substituents with a double bond onthe cycloalkenyl radical, for example an alkylidene group such asmethylidene. In the case of optionally substituted cycloalkenyl, theelucidations for substituted cycloalkyl apply correspondingly.

Alkoxy means saturated straight-chain or branched alkoxy radicals havingthe number of carbon atoms specified in each case, for exampleC₁-C₆-alkoxy such as methoxy, ethoxy, propoxy, 1-methylethoxy, butoxy,1-methylpropoxy, 2-methylpropoxy, 1,1-dimethylethoxy, pentoxy,1-methylbutoxy, 2-methylbutoxy, 3-methylbutoxy, 2,2-dimethylpropoxy,1-ethylpropoxy, hexoxy, 1,1-dimethylpropoxy, 1,2-dimethylpropoxy,1-methylpentoxy, 2-methylpentoxy, 3-methylpentoxy, 4-methylpentoxy,1,1-dimethylbutoxy, 1,2-dimethylbutoxy, 1,3-dimethylbutoxy,2,2-dimethylbutoxy, 2,3-dimethylbutoxy, 3,3-dimethylbutoxy,1-ethylbutoxy, 2-ethylbutoxy, 1,1,2-trimethylpropoxy,1,2,2-trimethylpropoxy, 1-ethyl-1-methylpropoxy and1-ethyl-2-methylpropoxy. Halogen-substituted alkoxy means straight-chainor branched alkoxy radicals having the number of carbon atoms specifiedin each case, where some or all of the hydrogen atoms in these groupsmay be replaced by halogen atoms as specified above, e.g.C₁-C₂-haloalkoxy such as chloromethoxy, bromomethoxy, dichloromethoxy,trichloromethoxy, fluoromethoxy, difluoromethoxy, trifluoromethoxy,chlorofluoromethoxy, dichlorofluoromethoxy, chlorodifluoromethoxy,1-chloroethoxy, 1-bromoethoxy, 1-fluoroethoxy, 2-fluoroethoxy,2,2-difluoroethoxy, 2,2,2-trifluoroethoxy, 2-chloro-2-fluoroethoxy,2-chloro-1,2-difluoroethoxy, 2,2-dichloro-2-fluoroethoxy,2,2,2-trichloroethoxy, pentafluoroethoxy and 1,1,1-trifluoroprop-2-oxy.

The term “aryl” denotes an optionally substituted mono-, bi- orpolycyclic aromatic system having preferably 6 to 14, especially 6 to10, ring carbon atoms, for example phenyl, naphthyl, anthryl,phenanthrenyl and the like, preferably phenyl.

The term “optionally substituted aryl” also includes polycyclic systems,such as tetrahydronaphthyl, indenyl, indanyl, fluorenyl, biphenylyl,where the bonding site is on the aromatic system. In systematic terms,“aryl” is generally also encompassed by the term “optionally substitutedphenyl”.

Independently of one another, the aryls listed above are preferablymono- to pentasubstituted, for example, by hydrogen, halogen, alkyl,haloalkyl, hydroxyl, alkoxy, cycloalkoxy, aryloxy, alkoxyalkyl,alkoxyalkoxy, cycloalkyl, halocycloalkyl, aryl, arylalkyl, heteroaryl,heterocyclyl, alkenyl, alkylcarbonyl, cycloalkylcarbonyl, arylcarbonyl,heteroarylcarbonyl, alkoxycarbonyl, hydroxy carbonyl,cycloalkoxycarbonyl, cycloalkylalkoxycarbonyl, alkoxycarbonylalkyl,arylalkoxycarbonyl, arylalkoxycarbonylalkyl, alkynyl, alkynylalkyl,alkylalkynyl, trisalkylsilylalkynyl, nitro, amino, cyano, haloalkoxy,haloalkylthio, alkylthio, hydrothio, hydroxyalkyl, heteroarylalkoxy,arylalkoxy, heterocyclylalkoxy, heterocyclylalkylthio, heterocyclyloxy,heterocyclylthio, heteroaryloxy, bisalkylamino, alkylamino,cycloalkylamino, hydroxycarbonylalkylamino, alkoxycarbonylalkylamino,arylalkoxycarbonylalkylamino, alkoxycarbonylalkyl(alkyl)amino,aminocarbonyl, alkylaminocarbonyl, bisalkylaminocarbonyl,cycloalkylaminocarbonyl, hydroxycarbonylalkylaminocarbonyl,alkoxycarbonylalkylaminocarbonyl, arylalkoxycarbonylalkylaminocarbonyl.

A heterocyclic radical (heterocyclyl) contains at least one heterocyclicring (=carbocyclic ring in which at least one carbon atom has beenreplaced by a heteroatom, preferably by a heteroatom from the group ofN, O, S, P) which is saturated, unsaturated, partially saturated orheteroaromatic and may be unsubstituted or substituted, in which casethe bonding site is localized on a ring atom. If the heterocyclylradical or the heterocyclic ring is optionally substituted, it may befused to other carbocyclic or heterocyclic rings. In the case ofoptionally substituted heterocyclyl, polycyclic systems are alsoincluded, for example 8-azabicyclo[3.2.1]octanyl,8-azabicyclo[2.2.2]octanyl or 1-azabicyclo[2.2.1]heptyl. In the case ofoptionally substituted heterocyclyl, spirocyclic systems are alsoincluded, for example 1-oxa-5-azaspiro[2.3]hexyl. Unless defineddifferently, the heterocyclic ring preferably contains 3 to 9 ringatoms, especially 3 to 6 ring atoms, and one or more, preferably 1 to 4,especially 1, 2 or 3, heteroatoms in the heterocyclic ring, preferablyfrom the group of N, O and S, but no two oxygen atoms should be directlyadjacent, for example with one heteroatom from the group of N, O and S:1- or 2- or 3-pyrrolidinyl, 3,4-dihydro-2H-pyrrol-2- or 3-yl,2,3-dihydro-1H-pyrrol-1- or 2- or 3- or 4- or 5-yl;2,5-dihydro-1H-pyrrol-1- or 2- or 3-yl, 1- or 2- or 3- or 4-piperidinyl;2,3,4,5-tetrahydropyridin-2- or 3- or 4- or 5-yl or 6-yl;1,2,3,6-tetrahydropyridin-1- or 2- or 3- or 4- or 5- or 6-yl;1,2,3,4-tetrahydropyridin-1- or 2- or 3- or 4- or 5- or 6-yl;1,4-dihydropyridin-1- or 2- or 3- or 4-yl; 2,3-dihydropyridin-2- or 3-or 4- or 5- or 6-yl; 2,5-dihydropyridin-2- or 3- or 4- or 5- or 6-yl, 1-or 2- or 3- or 4-azepanyl; 2,3,4,5-tetrahydro-1H-azepin-1- or 2- or 3-or 4- or 5- or 6- or 7-yl; 2,3,4,7-tetrahydro-1H-azepin-1- or 2- or 3-or 4- or 5- or 6- or 7-yl; 2,3,6,7-tetrahydro-1H-azepin-1- or 2- or 3-or 4-yl; 3,4,5,6-tetrahydro-2H-azepin-2- or 3- or 4- or 5- or 6- or7-yl; 4,5-dihydro-1H-azepin-1- or 2- or 3- or 4-yl;2,5-dihydro-1H-azepin-1- or -2- or 3- or 4- or 5- or 6- or 7-yl;2,7-dihydro-1H-azepin-1- or -2- or 3- or 4-yl; 2,3-dihydro-1H-azepin-1-or -2- or 3- or 4- or 5- or 6- or 7-yl; 3,4-dihydro-2H-azepin-2- or 3-or 4- or 5- or 6- or 7-yl; 3,6-dihydro-2H-azepin-2- or 3- or 4- or 5- or6- or 7-yl; 5,6-dihydro-2H-azepin-2- or 3- or 4- or 5- or 6- or 7-yl;4,5-dihydro-3H-azepin-2- or 3- or 4- or 5- or 6- or 7-yl; 1H-azepin-1-or -2- or 3- or 4- or 5- or 6- or 7-yl; 2H-azepin-2- or 3- or 4- or 5-or 6- or 7-yl; 3H-azepin-2- or 3- or 4- or 5- or 6- or 7-yl;4H-azepin-2- or 3- or 4- or 5- or 6- or 7-yl, 2- or 3-oxolanyl (=2- or3-tetrahydrofuranyl); 2,3-dihydrofuran-2- or 3- or 4- or 5-yl;2,5-dihydrofuran-2- or 3-yl, 2- or 3- or 4-oxanyl (=2- or 3- or4-tetrahydropyranyl); 3,4-dihydro-2H-pyran-2- or 3- or 4- or 5- or 6-yl;3,6-dihydro-2H-pyran-2- or 3- or 4- or 5- or 6-yl; 2H-pyran-2- or 3- or4- or 5- or 6-yl; 4H-pyran-2- or 3- or 4-yl, 2- or 3- or 4-oxepanyl;2,3,4,5-tetrahydrooxepin-2- or 3- or 4- or 5- or 6- or 7-yl;2,3,4,7-tetrahydrooxepin-2- or 3- or 4- or 5- or 6- or 7-yl;2,3,6,7-tetrahydrooxepin-2- or 3- or 4-yl; 2,3-dihydrooxepin-2- or 3- or4- or 5- or 6- or 7-yl; 4,5-dihydrooxepin-2- or 3- or 4-yl;2,5-dihydrooxepin-2- or 3- or 4- or 5- or 6- or 7-yl; oxepin-2- or 3- or4- or 5- or 6- or 7-yl; 2- or 3-tetrahydrothiophenyl;2,3-dihydrothiophen-2- or 3- or 4- or 5-yl; 2,5-dihydrothiophen-2- or3-yl; tetrahydro-2H-thiopyran-2- or 3- or 4-yl;3,4-dihydro-2H-thiopyran-2- or 3- or 4- or 5- or 6-yl;3,6-dihydro-2H-thiopyran-2- or 3- or 4- or 5- or 6-yl; 2H-thiopyran-2-or 3- or 4- or 5- or 6-yl; 4H-thiopyran-2- or 3- or 4-yl. Preferred3-membered and 4-membered heterocycles are, for example, 1- or2-aziridinyl, oxiranyl, thiiranyl, 1- or 2- or 3-azetidinyl, 2- or3-oxetanyl, 2- or 3-thietanyl, 1,3-dioxetan-2-yl. Further examples of“heterocyclyl” are a partially or fully hydrogenated heterocyclicradical having two heteroatoms from the group consisting of N, O and S,such as, for example, 1- or 2- or 3- or 4-pyrazolidinyl;4,5-dihydro-3H-pyrazol-3- or -4- or -5-yl; 4,5-dihydro-1H-pyrazol-1- or-3- or -4- or -5-yl; 2,3-dihydro-1H-pyrazol-1- or -2- or -3- or -4- or-5-yl; 1- or 2- or 3- or 4-imidazolidinyl; 2,3-dihydro-1H-imidazol-1- or-2- or -3- or -4-yl; 2,5-dihydro-1H-imidazol-1- or -2- or -4- or -5-yl;4,5-dihydro-1H-imidazol-1- or -2- or -4- or -5-yl; hexahydropyridazin-1-or -2- or -3- or -4-yl; 1,2,3,4-tetrahydropyridazin-1- or -2- or -3- or-4- or -5- or -6-yl; 1,2,3,6-tetrahydropyridazin-1- or -2- or -3- or -4-or -5- or -6-yl; 1,4,5,6-tetrahydropyridazin-1- or -3- or -4- or -5- or-6-yl; 3,4,5,6-tetrahydropyridazin-3- or -4- or -5-yl;4,5-dihydropyridazin-3- or -4-yl; 3,4-dihydropyridazin-3- or -4- or -5-or -6-yl; 3,6-dihydropyridazin-3- or -4-yl; 1,6-dihydropyriazin-1- or-3- or -4- or -5- or -6-yl; hexahydropyrimidin-1- or -2- or -3- or-4-yl; 1,4,5,6-tetrahydropyrimidin-1- or -2- or -4- or -5- or -6-yl;1,2,5,6-tetrahydropyrimidin-1- or -2- or -4- or -5- or -6-yl;1,2,3,4-tetrahydropyrimidin-1- or -2- or -3- or -4- or -5- or -6-yl;1,6-dihydropyrimidin-1- or -2- or -4- or -5- or -6-yl;1,2-dihydropyrimidin-1- or -2- or -4- or -5- or -6-yl;2,5-dihydropyrimidin-2- or -4- or -5-yl; 4,5-dihydropyrimidin-4- or -5-or -6-yl; 1,4-dihydropyrimidin-1- or -2- or -4- or -5- or -6-yl; 1- or2- or 3-piperazinyl; 1,2,3,6-tetrahydropyrazin-1- or -2- or -3- or -5-or -6-yl; 1,2,3,4-tetrahydropyrazin-1- or -2- or -3- or -4- or -5- or-6-yl; 1,2-dihydropyrazin-1- or -2- or -3- or -5- or -6-yl;1,4-dihydropyrazin-1- or -2- or -3-yl; 2,3-dihydropyrazin-2- or -3- or-5- or -6-yl; 2,5-dihydropyrazin-2- or -3-yl; 1,3-dioxolan-2- or -4- or-5-yl; 1,3-dioxol-2- or -4-yl; 1,3-dioxan-2- or -4- or -5-yl;4H-1,3-dioxin-2- or -4- or -5- or -6-yl; 1,4-dioxan-2- or -3- or -5- or-6-yl; 2,3-dihydro-1,4-dioxin-2- or -3- or -5- or -6-yl; 1,4-dioxin-2-or -3-yl; 1,2-dithiolan-3- or -4-yl; 3H-1,2-dithiol-3- or -4- or -5-yl;1,3-dithiolan-2- or -4-yl; 1,3-dithiol-2- or -4-yl; 1,2-dithian-3- or-4-yl; 3,4-dihydro-1,2-dithiin-3- or -4- or -5- or -6-yl;3,6-dihydro-1,2-dithiin-3- or -4-yl; 1,2-dithiin-3- or -4-yl;1,3-dithian-2- or -4- or -5-yl; 4H-1,3-dithiin-2- or -4- or -5- or-6-yl; isoxazolidin-2- or -3- or -4- or -5-yl; 2,3-dihydroisoxazol-2- or-3- or -4- or -5-yl; 2,5-dihydroisoxazol-2- or -3- or -4- or -5-yl;4,5-dihydroisoxazol-3- or -4- or -5-yl; 1,3-oxazolidin-2- or -3- or -4-or -5-yl; 2,3-dihydro-1,3-oxazol-2- or -3- or -4- or -5-yl;2,5-dihydro-1,3-oxazol-2- or -4- or -5-yl; 4,5-dihydro-1,3-oxazol-2- or-4- or -5-yl; 1,2-oxazinan-2- or -3- or -4- or -5- or -6-yl;3,4-dihydro-2H-1,2-oxazin-2- or -3- or -4- or -5- or -6-yl;3,6-dihydro-2H-1,2-oxazin-2- or -3- or -4- or -5- or -6-yl;5,6-dihydro-2H-1,2-oxazin-2- or -3- or -4- or -5- or -6-yl;5,6-dihydro-4H-1,2-oxazin-3- or -4- or -5- or -6-yl; 2H-1,2-oxazin-2- or-3- or -4- or -5- or -6-yl; 6H-1,2-oxazin-3- or -4- or -5- or -6-yl;4H-1,2-oxazin-3- or -4- or -5- or -6-yl; 1,3-oxazinan-2- or -3- or -4-or -5- or -6-yl; 3,4-dihydro-2H-1,3-oxazin-2- or -3- or -4- or -5- or-6-yl; 3,6-dihydro-2H-1,3-oxazin-2- or -3- or -4- or -5- or -6-yl;5,6-dihydro-2H-1,3-oxazin-2- or -4- or -5- or -6-yl;5,6-dihydro-4H-1,3-oxazin-2- or -4- or -5- or -6-yl; 2H-1,3-oxazin-2- or-4- or -5- or -6-yl; 6H-1,3-oxazin-2- or -4- or -5- or -6-yl;4H-1,3-oxazin-2- or -4- or -5- or -6-yl; morpholin-2- or -3- or -4-yl;3,4-dihydro-2H-1,4-oxazin-2- or -3- or -4- or -5- or -6-yl;3,6-dihydro-2H-1,4-oxazin-2- or -3- or -5- or -6-yl; 2H-1,4-oxazin-2- or-3- or -5- or -6-yl; 4H-1,4-oxazin-2- or -3-yl; 1,2-oxazepan-2- or -3-or -4- or -5- or -6- or -7-yl; 2,3,4,5-tetrahydro-1,2-oxazepin-2- or -3-or -4- or -5- or -6- or -7-yl; 2,3,4,7-tetrahydro-1,2-oxazepin-2- or -3-or -4- or -5- or -6- or -7-yl; 2,3,6,7-tetrahydro-1,2-oxazepin-2- or -3-or -4- or -5- or -6- or -7-yl; 2,5,6,7-tetrahydro-1,2-oxazepin-2- or -3-or -4- or -5- or -6- or -7-yl; 4,5,6,7-tetrahydro-1,2-oxazepin-3- or -4-or -5- or -6- or -7-yl; 2,3-dihydro-1,2-oxazepin-2- or -3- or -4- or -5-or -6- or -7-yl; 2,5-dihydro-1,2-oxazepin-2- or -3- or -4- or -5- or -6-or -7-yl; 2,7-dihydro-1,2-oxazepin-2- or -3- or -4- or -5- or -6- or-7-yl; 4,5-dihydro-1,2-oxazepin-3- or -4- or -5- or -6- or -7-yl;4,7-dihydro-1,2-oxazepin-3- or -4- or -5- or -6- or -7-yl;6,7-dihydro-1,2-oxazepin-3- or -4- or -5- or -6- or -7-yl;1,2-oxazepin-3- or -4- or -5- or -6- or -7-yl; 1,3-oxazepan-2- or -3- or-4- or -5- or -6- or -7-yl; 2,3,4,5-tetrahydro-1,3-oxazepin-2- or -3- or-4- or -5- or -6- or -7-yl; 2,3,4,7-tetrahydro-1,3-oxazepin-2- or -3- or-4- or -5- or -6- or -7-yl; 2,3,6,7-tetrahydro-1,3-oxazepin-2- or -3- or-4- or -5- or -6- or -7-yl; 2,5,6,7-tetrahydro-1,3-oxazepin-2- or -4- or-5- or -6- or -7-yl; 4,5,6,7-tetrahydro-1,3-oxazepin-2- or -4- or -5- or-6- or -7-yl; 2,3-dihydro-1,3-oxazepin-2- or -3- or -4- or -5- or -6- or-7-yl; 2,5-dihydro-1,3-oxazepin-2- or -4- or -5- or -6- or -7-yl;2,7-dihydro-1,3-oxazepin-2- or -4- or -5- or -6- or -7-yl;4,5-dihydro-1,3-oxazepin-2- or -4- or -5- or -6- or -7-yl;4,7-dihydro-1,3-oxazepin-2- or -4- or -5- or -6- or -7-yl;6,7-dihydro-1,3-oxazepin-2- or -4- or -5- or -6- or -7-yl;1,3-oxazepin-2- or -4- or -5- or -6- or -7-yl; 1,4-oxazepan-2- or -3- or-5- or -6- or -7-yl; 2,3,4,5-tetrahydro-1,4-oxazepin-2- or -3- or -4- or-5- or -6- or -7-yl; 2,3,4,7-tetrahydro-1,4-oxazepin-2- or -3- or -4- or-5- or -6- or -7-yl; 2,3,6,7-tetrahydro-1,4-oxazepin-2- or -3- or -5- or-6- or -7-yl; 2,5,6,7-tetrahydro-1,4-oxazepin-2- or -3- or -5- or -6- or-7-yl; 4,5,6,7-tetrahydro-1,4-oxazepin-2- or -3- or -4- or -5- or -6- or-7-yl; 2,3-dihydro-1,4-oxazepin-2- or -3- or -5- or -6- or -7-yl;2,5-dihydro-1,4-oxazepin-2- or -3- or -5- or -6- or -7-yl;2,7-dihydro-1,4-oxazepin-2- or -3- or -5- or -6- or -7-yl;4,5-dihydro-1,4-oxazepin-2- or -3- or -4- or -5- or -6- or -7-yl;4,7-dihydro-1,4-oxazepin-2- or -3- or -4- or -5- or -6- or -7-yl;6,7-dihydro-1,4-oxazepin-2- or -3- or -5- or -6- or -7-yl;1,4-oxazepin-2- or -3- or -5- or -6- or -7-yl; isothiazolidin-2- or -3-or -4- or -5-yl; 2,3-dihydroisothiazol-2- or -3- or -4- or -5-yl;2,5-dihydroisothiazol-2- or -3- or -4- or -5-yl;4,5-dihydroisothiazol-3- or -4- or -5-yl; 1,3-thiazolidin-2- or -3- or-4- or -5-yl; 2,3-dihydro-1,3-thiazol-2- or -3- or -4- or -5-yl;2,5-dihydro-1,3-thiazol-2- or -4- or -5-yl; 4,5-dihydro-1,3-thiazol-2-or -4- or -5-yl; 1,3-thiazinan-2- or -3- or -4- or -5- or -6-yl;3,4-dihydro-2H-1,3-thiazin-2- or -3- or -4- or -5- or -6-yl;3,6-dihydro-2H-1,3-thiazin-2- or -3- or -4- or -5- or -6-yl;5,6-dihydro-2H-1,3-thiazin-2- or -4- or -5- or -6-yl;5,6-dihydro-4H-1,3-thiazin-2- or -4- or -5- or -6-yl; 2H-1,3-thiazin-2-or -4- or -5- or -6-yl; 6H-1,3-thiazin-2- or -4- or -5- or -6-yl;4H-1,3-thiazin-2- or -4- or -5- or -6-yl. Further examples of“heterocyclyl” are a partially or fully hydrogenated heterocyclicradical having 3 heteroatoms from the group of N, O and S, for example1,4,2-dioxazolidin-2- or -3- or -5-yl; 1,4,2-dioxazol-3- or -5-yl;1,4,2-dioxazinan-2- or -3- or -5- or -6-yl;5,6-dihydro-1,4,2-dioxazin-3- or -5- or -6-yl; 1,4,2-dioxazin-3- or -5-or -6-yl; 1,4,2-dioxazepan-2- or -3- or -5- or -6- or -7-yl;6,7-dihydro-5H-1,4,2-dioxazepin-3- or -5- or -6- or -7-yl;2,3-dihydro-7H-1,4,2-dioxazepin-2- or -3- or -5- or -6- or -7-yl;2,3-dihydro-5H-1,4,2-dioxazepin-2- or -3- or -5- or -6- or -7-yl;5H-1,4,2-dioxazepin-3- or -5- or -6- or -7-yl; 7H-1,4,2-dioxazepin-3- or-5- or -6- or -7-yl.

Independently of one another, the heterocycles listed above arepreferably mono- to hexasubstituted, for example, by hydrogen, halogen,alkyl, haloalkyl, hydroxyl, alkoxy, cycloalkoxy, aryloxy, alkoxyalkyl,alkoxyalkoxy, cycloalkyl, halocycloalkyl, aryl, arylalkyl, heteroaryl,heterocyclyl, alkenyl, alkylcarbonyl, cycloalkylcarbonyl, arylcarbonyl,heteroarylcarbonyl, alkoxycarbonyl, hydroxycarbonyl,cycloalkoxycarbonyl, cycloalkylalkoxycarbonyl, alkoxycarbonylalkyl,arylalkoxycarbonyl, arylalkoxycarbonylalkyl, alkynyl, alkynylalkyl,alkylalkynyl, trisalkylsilylalkynyl, nitro, amino, cyano, haloalkoxy,haloalkylthio, alkylthio, hydrothio, hydroxyalkyl, oxo,heteroarylalkoxy, arylalkoxy, heterocyclylalkoxy, heterocyclylalkylthio,heterocyclyloxy, heterocyclylthio, heteroaryloxy, bisalkylamino,alkylamino, cycloalkylamino, hydroxycarbonylalkylamino,alkoxycarbonylalkylamino, arylalkoxycarbonylalkylamino,alkoxycarbonylalkyl(alkyl)amino, aminocarbonyl, alkylaminocarbonyl,bisalkylaminocarbonyl, cycloalkylaminocarbonyl,hydroxycarbonylalkylaminocarbonyl, alkoxycarbonylalkylaminocarbonyl,arylalkoxycarbonylalkylaminocarbonyl.

When a base structure is substituted “by one or more radicals” from alist of radicals (=group) or a generically defined group of radicals,this in each case includes simultaneous substitution by a plurality ofidentical and/or structurally different radicals.

In the case of a partially or fully saturated nitrogen heterocycle, thismay be joined to the remainder of the molecule either via carbon or viathe nitrogen.

Suitable substituents for a substituted heterocyclic radical are thesubstituents specified further down, and additionally also oxo andthioxo. The oxo group as a substituent on a ring carbon atom is then,for example, a carbonyl group in the heterocyclic ring. As a result,lactones and lactams are preferably also included. The oxo group mayalso occur on the ring heteroatoms, which may exist in differentoxidation states, for example in the case of N and S, and in that caseform, for example, the divalent —N(O)—, —S(O)— (also SO for short) andS(O)₂ (also SO₂ for short) groups in the heterocyclic ring. In the caseof —N(O)— and —S(O)— groups, both enantiomers in each case are included.

According to the invention, the expression “heteroaryl” refers toheteroaromatic compounds, i.e. fully unsaturated aromatic heterocycliccompounds, preferably 5- to 7-membered rings having 1 to 4, preferably 1or 2, identical or different heteroatoms, preferably 0, S or N.Inventive heteroaryls are, for example, 1H-pyrrol-1-yl; 1H-pyrrol-2-yl;1H-pyrrol-3-yl; furan-2-yl; furan-3-yl; thien-2-yl; thien-3-yl,1H-imidazol-1-yl; 1H-imidazol-2-yl; 1H-imidazol-4-yl; 1H-imidazol-5-yl;1H-pyrazol-1-yl; 1H-pyrazol-3-yl; 1H-pyrazol-4-yl; 1H-pyrazol-5-yl,1H-1,2,3-triazol-1-yl, 1H-1,2,3-triazol-4-yl, 1H-1,2,3-triazol-5-yl,2H-1,2,3-triazol-2-yl, 2H-1,2,3-triazol-4-yl, 1H-1,2,4-triazol-1-yl,1H-1,2,4-triazol-3-yl, 4H-1,2,4-triazol-4-yl, 1,2,4-oxadiazol-3-yl,1,2,4-oxadiazol-5-yl, 1,3,4-oxadiazol-2-yl, 1,2,3-oxadiazol-4-yl,1,2,3-oxadiazol-5-yl, 1,2,5-oxadiazol-3-yl, azepinyl, pyridin-2-yl,pyridin-3-yl, pyridin-4-yl, pyrazin-2-yl, pyrazin-3-yl, pyrimidin-2-yl,pyrimidin-4-yl, pyrimidin-5-yl, pyridazin-3-yl, pyridazin-4-yl,1,3,5-triazin-2-yl, 1,2,4-triazin-3-yl, 1,2,4-triazin-5-yl,1,2,4-triazin-6-yl, 1,2,3-triazin-4-yl, 1,2,3-triazin-5-yl, 1,2,4-,1,3,2-, 1,3,6- and 1,2,6-oxazinyl, isoxazol-3-yl, isoxazol-4-yl,isoxazol-5-yl, 1,3-oxazol-2-yl, 1,3-oxazol-4-yl, 1,3-oxazol-5-yl,isothiazol-3-yl, isothiazol-4-yl, isothiazol-5-yl, 1,3-thiazol-2-yl,1,3-thiazol-4-yl, 1,3-thiazol-5-yl, oxepinyl, thiepinyl,1,2,4-triazolonyl and 1,2,4-diazepinyl, 2H-1,2,3,4-tetrazol-5-yl,1H-1,2,3,4-tetrazol-5-yl, 1,2,3,4-oxatriazol-5-yl,1,2,3,4-thiatriazol-5-yl, 1,2,3,5-oxatriazol-4-yl,1,2,3,5-thiatriazol-4-yl. The heteroaryl groups according to theinvention may also be substituted by one or more identical or differentradicals. If two adjacent carbon atoms are part of a further aromaticring, the systems are fused heteroaromatic systems, such as benzofusedor polyannelated heteroaromatics.

Preferred examples are quinolines (e.g. quinolin-2-yl, quinolin-3-yl,quinolin-4-yl, quinolin-5-yl, quinolin-6-yl, quinolin-7-yl,quinolin-8-yl); isoquinolines (e.g. isoquinolin-1-yl, isoquinolin-3-yl,isoquinolin-4-yl, isoquinolin-5-yl, isoquinolin-6-yl, isoquinolin-7-yl,isoquinolin-8-yl); quinoxaline; quinazoline; cinnoline;1,5-naphthyridine; 1,6-naphthyridine; 1,7-naphthyridine;1,8-naphthyridine; 2,6-naphthyridine; 2,7-naphthyridine; phthalazine;pyridopyrazines; pyridopyrimidines; pyridopyridazines; pteridines;pyrimidopyrimidines. Examples of heteroaryl are also 5- or 6-memberedbenzofused rings from the group of 1H-indol-1-yl, 1H-indol-2-yl,1H-indol-3-yl, 1H-indol-4-yl, 1H-indol-5-yl, 1H-indol-6-yl,1H-indol-7-yl, 1-benzofuran-2-yl, 1-benzofuran-3-yl, 1-benzofuran-4-yl,1-benzofuran-5-yl, 1-benzofuran-6-yl, 1-benzofuran-7-yl,1-benzothiophen-2-yl, 1-benzothiophen-3-yl, 1-benzothiophen-4-yl,1-benzothiophen-5-yl, 1-benzothiophen-6-yl, 1-benzothiophen-7-yl,1H-indazol-1-yl, 1H-indazol-3-yl, 1H-indazol-4-yl, 1H-indazol-5-yl,1H-indazol-6-yl, 1H-indazol-7-yl, 2H-indazol-2-yl, 2H-indazol-3-yl,2H-indazol-4-yl, 2H-indazol-5-yl, 2H-indazol-6-yl, 2H-indazol-7-yl,2H-isoindol-2-yl, 2H-isoindol-1-yl, 2H-isoindol-3-yl, 2H-isoindol-4-yl,2H-isoindol-5-yl, 2H-isoindol-6-yl; 2H-isoindol-7-yl,1H-benzimidazol-1-yl, 1H-benzimidazol-2-yl, 1H-benzimidazol-4-yl,1H-benzimidazol-5-yl, 1H-benzimidazol-6-yl, 1H-benzimidazol-7-yl,1,3-benzoxazol-2-yl, 1,3-benzoxazol-4-yl, 1,3-benzoxazol-5-yl,1,3-benzoxazol-6-yl, 1,3-benzoxazol-7-yl, 1,3-benzothiazol-2-yl,1,3-benzothiazol-4-yl, 1,3-benzothiazol-5-yl, 1,3-benzothiazol-6-yl,1,3-benzothiazol-7-yl, 1,2-benzisoxazol-3-yl, 1,2-benzisoxazol-4-yl,1,2-benzisoxazol-5-yl, 1,2-benzisoxazol-6-yl, 1,2-benzisoxazol-7-yl,1,2-benzisothiazol-3-yl, 1,2-benzisothiazol-4-yl,1,2-benzisothiazol-5-yl, 1,2-benzisothiazol-6-yl,1,2-benzisothiazol-7-yl.

Independently of one another, the heteroaryls listed above arepreferably mono- to tetrasubstituted, for example, by hydrogen, halogen,alkyl, haloalkyl, hydroxyl, alkoxy, cycloalkoxy, aryloxy, alkoxyalkyl,alkoxyalkoxy, cycloalkyl, halocycloalkyl, aryl, arylalkyl, heteroaryl,heterocyclyl, alkenyl, alkylcarbonyl, cycloalkylcarbonyl, arylcarbonyl,heteroarylcarbonyl, alkoxycarbonyl, hydroxycarbonyl,cycloalkoxycarbonyl, cycloalkylalkoxycarbonyl, alkoxycarbonylalkyl,arylalkoxycarbonyl, arylalkoxycarbonylalkyl, alkynyl, alkynylalkyl,alkylalkynyl, trisalkylsilylalkynyl, nitro, amino, cyano, haloalkoxy,haloalkylthio, alkylthio, hydrothio, hydroxyalkyl, oxo,heteroarylalkoxy, arylalkoxy, heterocyclylalkoxy, heterocyclylalkylthio,heterocyclyloxy, heterocyclylthio, heteroaryloxy, bisalkylamino,alkylamino, cycloalkylamino, hydroxycarbonylalkylamino,alkoxycarbonylalkylamino, arylalkoxycarbonylalkylamino,alkoxycarbonylalkyl(alkyl)amino, aminocarbonyl, alkylaminocarbonyl,bisalkylaminocarbonyl, cycloalkylaminocarbonyl,hydroxycarbonylalkylaminocarbonyl, alkoxycarbonylalkylaminocarbonyl,arylalkoxycarbonylalkylaminocarbonyl.

The term “halogen” means fluorine, chlorine, bromine or iodine. If theterm is used for a radical, “halogen” means a fluorine, chlorine,bromine or iodine atom.

According to the nature of the substituents and the way in which theyare joined, the compounds of the formula (I) may be present asstereoisomers. If, for example, one or more asymmetrically substitutedcarbon atoms and/or sulfoxides are present, enantiomers anddiastereomers may occur. Stereoisomers can be obtained from the mixturesobtained in the preparation by customary separation methods, for exampleby chromatographic separation processes. It is likewise possible toselectively prepare stereoisomers by using stereoselective reactionswith use of optically active starting materials and/or auxiliaries.

The invention also relates to all stereoisomers and mixtures thereofwhich are encompassed by the formula (I) but not defined specifically.However, the following text will, for the sake of simplicity, alwaysmention compounds of the formula (I), even though this is understood asmeaning not only the pure compounds, but also, if appropriate, mixtureswith various amounts of isomeric compounds.

According to the nature of the substituents defined above, the compoundsof the formula (I) have acidic properties and can form salts, and ifappropriate also internal salts or adducts with inorganic or organicbases or with metal ions. If the compounds of the formula (I) carryhydroxyl, carboxyl or other groups which induce acidic properties, thesecompounds can be reacted with bases to give salts. Suitable bases are,for example, hydroxides, carbonates, bicarbonates of the alkali metalsand alkaline earth metals, in particular those of sodium, potassium,magnesium and calcium, furthermore ammonia, primary, secondary andtertiary amines having (C₁-C₄)-alkyl groups, mono-, di- andtrialkanolamines of (C₁-C₄)-alkanols, choline and chlorocholine, andalso organic amines such as trialkylamines, morpholine, piperidine orpyridine. These salts are compounds in which the acidic hydrogen isreplaced by an agriculturally suitable cation, for example metal salts,especially alkali metal salts or alkaline earth metal salts, inparticular sodium and potassium salts, or else ammonium salts, saltswith organic amines or quaternary ammonium salts, for example withcations of the formula [NRR′R″R′″]⁺ in which R to R′″ each independentlyof one another represent an organic radical, in particular alkyl, aryl,aralkyl or alkylaryl. Also suitable are alkylsulfonium andalkylsulfoxonium salts, such as (C₁-C₄)-trialkylsulfonium and(C₁-C₄)-trialkylsulfoxonium salts.

The compounds of the formula (I) can form salts by addition of asuitable inorganic or organic acid, for example mineral acids, forexample HCl, HBr, H₂SO₄, H₃PO₄ or HNO₃, or organic acids, for examplecarboxylic acids such as formic acid, acetic acid, propionic acid,oxalic acid, lactic acid or salicylic acid or sulfonic acids, forexample p-toluenesulfonic acid, onto a basic group, for example amino,alkylamino, dialkylamino, piperidino, morpholino or pyridino. In such acase, these salts comprise the conjugated base of the acid as the anion.

Suitable substituents present in deprotonated form, such as, forexample, sulfonic acids or carboxylic acids, may form inner salts withgroups which for their part can be protonated, such as amino groups.

If a group is polysubstituted by radicals, this means that this group issubstituted by one or more identical or different radicals from thosementioned.

In all the formulae specified hereinafter, the substituents and symbolshave the same meaning as described in formula (I), unless defineddifferently. Arrows in a chemical formula denote the points at which itis joined to the rest of the molecule.

There follows a description of preferred, particularly preferred andvery particularly preferred definitions of each of the individualsubstituents. The other substituents of the general formula (I) whichare not specified hereinafter have the definition given above.

According to a first embodiment of the present invention,

R¹ and R² preferably independently of one another each representhydrogen, fluorine, chlorine or cyano, or represent (C₁-C₃)-alkyl or(C₁-C₃)-alkoxy which are in each case substituted by m radicals from thegroup consisting of fluorine, chlorine, bromine and cyano.

Particularly preferably, R¹ and R² independently of one another eachrepresent hydrogen, fluorine, chlorine or cyano, or represent methyl ormethoxy which are in each case substituted by m radicals from the groupconsisting of fluorine and chlorine.

Most preferably, R¹ and R² each represent hydrogen.

According to a second embodiment of the present invention,

R³ preferably represents cyano, or (C₁-C₄)-alkyl, (C₃-05)-cycloalkyl,(C₂-C₄)-alkenyl, (C₂-C₄)-alkynyl or (C₁-C₄)-alkoxy, each of which issubstituted by m radicals from the group consisting of fluorine,chlorine, bromine, cyano, (C₁-C₄)-alkoxy and hydroxy.

Particularly preferably, R³ represents (C₁-C₃)-alkyl,(C₃-C₄)-cycloalkyl, (C₂-C₃)-alkenyl or (C₁-C₃)-alkoxy, each of which issubstituted by m radicals from the group consisting of fluorine,chlorine and (C₁-C₂)-alkoxy.

According to a third embodiment of the present invention,

R⁴ preferably represents hydrogen, or represents (C₁-C₆)-alkyl,(C₃-C₆)-cycloalkyl, (C₃-C₆)-cycloalkyl-(C₁-C₆)-alkyl, (C₂-C₆)-alkenyl,(C₅-C₆)-cycloalkenyl or (C₂-C₆)-alkynyl, each of which is substituted bym radicals from the group consisting of fluorine, chlorine, bromine,cyano, (C₁-C₄)-alkoxy, hydroxy and aryl.

According to a fourth embodiment of the present invention,

Y represents oxygen.

According to a fifth embodiment of the present invention,

W represents oxygen.

According to a sixth embodiment of the present invention,

Z preferably represents a group Z-1 to Z-22, where Z-1 to Z-22 have thefollowing meaning:

where the arrow in each case denotes a bond to the group C═W of theformula (I).

Particularly preferably, Z represents a group Z-1 to Z-12, where Z-1 toZ-12 have the following meaning:

where the arrow in each case denotes a bond to the group C═W of theformula (I).

Most preferably, Z represents Z-1, Z-4 or Z-6:

where the arrow in each case denotes a bond to the group C═W of theformula (I).

According to a seventh embodiment of the present invention,

R¹⁰ preferably represents fluorine, chlorine, cyano, CO₂H, CO₂CH₃ orCO₂CH₂CH₃, or represents (C₁-C₂)-alkyl or (C₁-C₂)-alkoxy, each of whichis substituted by m radicals from the group consisting of fluorine andchlorine.

According to an eighth embodiment of the present invention,

R¹¹ preferably represents hydrogen, or represents (C₁-C₃)-alkyl or(C₃-C₆)-cycloalkyl, each of which is substituted by m radicals from thegroup consisting of fluorine and chlorine.

According to a ninth embodiment of the present invention,

R¹² preferably represents hydrogen, cyano, OR⁷, S(O). R⁵, SO₂NR⁶R⁷,COR⁶, NR⁶R⁸, NR⁶COR⁸ or NR⁶SO₂R⁸, or represents (C₁-C₆)-alkyl,(C₃-C₆)-cycloalkyl, (C₂-C₃)-alkenyl or (C₂-C₃)-alkynyl, each of which issubstituted by m radicals from the group consisting of fluorine,chlorine, bromine, cyano, OR′, S(O)_(n)R⁵, NR⁶R⁸ and NR⁶CO₂R⁸.

According to a tenth embodiment of the present invention,

R¹¹ and R¹² together with the nitrogen atom to which they are attachedpreferably form a saturated, partially or fully unsaturated five-, six-or seven-membered ring which is optionally mono- to hexasubstituted byradicals from the group consisting of halogen, cyano, nitro,(C₁-C₆)-alkyl, halo-(C₁-C₆)-alkyl, oxo, OR⁷, S(O). R⁵, CO₂R⁸, COR⁶,NR⁶R⁸ and NR⁶SO₂R⁸ and which, in addition to this nitrogen atom,contains r carbon atoms, o oxygen atoms, p sulfur atoms and q elementsfrom the group consisting of NR⁷ and NCOR⁷ as ring atoms.

Particularly preferably, R¹¹ and R¹² together with the nitrogen atom towhich they are attached form a saturated, partially or fully unsaturatedfive-, six- or seven-membered ring which is optionally mono- tohexasubstituted by radicals from the group consisting of halogen, cyano,nitro, (C₁-C₆)-alkyl, halo-(C₁-C₆)-alkyl, oxo, OR⁷, CO₂R⁸ and NR⁶SO₂R⁸and which, in addition to this nitrogen atom, contains r carbon atoms, ooxygen atoms, p sulfur atoms and q elements from the group consisting ofMC and NCOR⁷ as ring atoms.

Most preferably, R¹¹ and R¹² together with the nitrogen atom to whichthey are attached form a saturated, partially or fully unsaturatedfive-, six- or seven-membered ring which is optionally mono- tohexasubstituted by radicals from the group consisting of halogen,(C₁-C₆)-alkyl, halo-(C₁-C₆)-alkyl and oxo and which, in addition to thisnitrogen atom, contains r carbon atoms, o oxygen atoms, p sulfur atomsand q elements from the group consisting of NR⁷ and NCOR⁷ as ring atoms.

According to an eleventh embodiment of the present invention,

X², X⁴ and X⁶ preferably independently of one another each representhydrogen, fluorine, chlorine, bromine or cyano, or represent methyl ormethoxy, each of which is substituted by m radicals from the groupconsisting of fluorine and chlorine.

Particularly preferably, X², X⁴ and X⁶ independently of one anotherrepresent hydrogen or fluorine.

According to a twelfth embodiment of the present invention,

X³ and X⁵ preferably independently of one another each representhydrogen, fluorine, chlorine, bromine, hydroxy or cyano, or represent(C₁-C₃)-alkyl, (C₁-C₃)-alkoxy, (C₃-C₄)-cycloalkyl, (C₂-C₃)-alkenyl or(C₂-C₃)-alkynyl, each of which is substituted by m radicals from thegroup consisting of fluorine, chlorine and bromine.

Particularly preferably, X³ and X⁵ independently of one another eachrepresent hydrogen, fluorine, chlorine, CF₃, CHF₂ or methyl.

According to a thirteenth embodiment of the present invention,

R⁵ preferably represents (C₁-C₆)-alkyl or (C₃-C₆)-cycloalkyl, each ofwhich is substituted by m radicals from the group consisting of fluorineand chlorine.

According to a fourteenth embodiment of the present invention,

R⁷ preferably represents hydrogen, or represents (C₁-C₆)-alkyl or(C₃-C₆)-cycloalkyl, each of which is substituted by m radicals from thegroup consisting of fluorine, chlorine and (C₁-C₂)-alkoxy.

According to a fifteenth embodiment of the present invention,

R⁸ preferably represents hydrogen, or represents (C₁-C₆)-alkyl or(C₃-C₆)-cycloalkyl, each of which is substituted by m radicals from thegroup consisting of fluorine, chlorine and (C₁-C₂)-alkoxy.

According to a sixteenth embodiment of the present invention,

m represents the running number 0, 1, 2 or 3.

In the context of the present invention, the individual preferred,particularly preferred and most preferred meanings of the substituentsR¹ to R⁸, R¹⁰ to R¹², X² to X⁶, W, Y and Z, and the running numbers k,m, n, o, p, q and r can be combined with one another as desired.

This means that the present invention encompasses compounds of thegeneral formula (I) in which, for example, the substituent R¹ has apreferred definition and the substituents R⁵ to R⁷ have the generaldefinition or else the substituent R² has a preferred definition, thesubstituent R³ has a particularly preferred or very particularlypreferred definition and the remaining substituents have a generaldefinition.

Four of these combinations of the definitions given above for thesubstituents R¹ to R⁸, R¹⁰ to R¹², X² to X⁶, W, Y and Z, and for therunning numbers k, m, n, o, p, q and r are illustrated below by way ofexample, and each of them is disclosed as a further embodiment:

According to a seventeenth embodiment of the present invention,

G represents a group of the formula OR⁴;

-   R¹ and R² independently of one another each represent hydrogen,    fluorine, chlorine or cyano, or represent (C₁-C₃)-alkyl or    (C₁-C₃)-alkoxy which are in each case substituted by m radicals from    the group consisting of fluorine, chlorine, bromine and cyano;-   R³ represents cyano, or represents (C₁-C₃)-alkyl,    (C₃-C₄)-cycloalkyl, (C₂-C₃)-alkenyl, (C₂-C₃)-alkynyl or    (C₁-C₃)-alkoxy, each of which is substituted by m radicals from the    group consisting of fluorine, chlorine, bromine, cyano,    (C₁-C₂)-alkoxy and hydroxy;-   R⁴ represents hydrogen, or represents (C₁-C₆)-alkyl,    (C₃-C₆)-cycloalkyl, (C₃-C₆)-cycloalkyl-(C₁-C₆)-alkyl,    (C₂-C₆)-alkenyl, (C₅-C₆)-cycloalkenyl or (C₂-C₆)-alkynyl, each of    which is substituted by m radicals from the group consisting of    fluorine, chlorine, bromine, cyano, (C₁-C₄)-alkoxy, hydroxy and    aryl.-   Y represents oxygen;-   W represents oxygen;-   Z represents a group Z-1 to Z-12, where Z-1 to Z-12 have the    following meaning:

-   -   where the arrow in each case denotes a bond to the group C═W of        the formula (I);

-   X², X⁴ and X⁶ independently of one another each represent hydrogen,    fluorine, chlorine, bromine or cyano, or represent methyl or    methoxy, each of which is substituted by m radicals from the group    consisting of fluorine and chlorine;

-   X³ and X⁵ independently of one another each represent hydrogen,    fluorine, chlorine, bromine, hydroxy or cyano, or represent    (C₁-C₃)-alkyl, (C₁-C₃)-alkoxy, (C₃-C₄)-cycloalkyl, (C₂-C₃)-alkenyl    or (C₂-C₃)-alkynyl, each of which is substituted by m radicals from    the group consisting of fluorine, chlorine and bromine; and

-   m represents the running number 0, 1, 2 or 3.

According to an eighteenth embodiment of the present invention,

-   G represents a group of the formula OR⁴;-   R¹ and R² each represent hydrogen;-   R³ represents (C₁-C₃)-alkyl, (C₃-C₄)-cycloalkyl, (C₂-C₃)-alkenyl or    (C₁-C₃)-alkoxy, each of which is substituted by m radicals from the    group consisting of fluorine, chlorine and (C₁-C₂)-alkoxy;-   R⁴ represents hydrogen, or represents (C₁-C₆)-alkyl,    (C₃-C₆)-cycloalkyl, (C₃-C₆)-cycloalkyl-(C₁-C₆)-alkyl,    (C₂-C₆)-alkenyl, (C₅-C₆)-cycloalkenyl or (C₂-C₆)-alkynyl, each of    which is substituted by m radicals from the group consisting of    fluorine, chlorine, bromine, cyano, (C₁-C₄)-alkoxy, hydroxy and    aryl;-   Y represents oxygen;-   W represents oxygen;-   Z represents a group Z-1, Z-4 or Z-6:

-   -   where the arrow in each case denotes a bond to the group C═W of        the formula (I);

-   X², X⁴ and X⁶ independently of one another each represent hydrogen    or fluorine;

-   X³ and X⁵ independently of one another each represent hydrogen,    fluorine, chlorine, CF₃, CHF₂ or methyl; and

-   m represents the running number 0, 1, 2 or 3.

According to a nineteenth embodiment of the present invention,

-   G represents a group of the formula NR¹¹R¹²;-   R¹ and R² independently of one another each represent hydrogen,    fluorine, chlorine or cyano, or represent (C₁-C₃)-alkyl or    (C₁-C₃)-alkoxy which are in each case substituted by m radicals from    the group consisting of fluorine, chlorine, bromine and cyano;-   R³ represents cyano, or represents (C₁-C₃)-alkyl,    (C₃-C₄)-cycloalkyl, (C₂-C₃)-alkenyl or (C₁-C₃)-alkoxy, each of which    is substituted by m radicals from the group consisting of fluorine,    chlorine, bromine, cyano, (C₁-C₂)-alkoxy and hydroxy;-   Y represents oxygen;-   W represents oxygen;-   Z represents a group Z-1 to Z-12, where Z-1 to Z-12 have the    following meaning:

-   where the arrow in each case denotes a bond to the group C═W of the    formula (I);-   X², X⁴ and X⁶ independently of one another each represent hydrogen,    fluorine, chlorine, bromine or cyano, or represent methyl or    methoxy, each of which is substituted by m radicals from the group    consisting of fluorine and chlorine;-   X³ and X⁵ independently of one another each represent hydrogen,    fluorine, chlorine, bromine, hydroxy or cyano, or represent    (C₁-C₃)-alkyl, (C₁-C₃)-alkoxy, (C₃-C₄)-cycloalkyl, (C₂-C₃)-alkenyl    or (C₂-C₃)-alkynyl, each of which is substituted by m radicals from    the group consisting of fluorine, chlorine and bromine; and-   R⁵ represents (C₁-C₆)-alkyl or (C₃-C₆)-cycloalkyl, each of which is    substituted by m radicals from the group consisting of fluorine and    chlorine;-   R⁶ represents hydrogen or R⁵;-   R⁷ represents hydrogen, or represents (C₁-C₆)-alkyl or    (C₃-C₆)-cycloalkyl, each of which is substituted by m radicals from    the group consisting of fluorine, chlorine and (C₁-C₂)-alkoxy;-   R⁸ represents hydrogen, or represents (C₁-C₆)-alkyl or    (C₃-C₆)-cycloalkyl, each of which is substituted by m radicals from    the group consisting of fluorine, chlorine and (C₁-C₂)-alkoxy;-   R¹¹ represents hydrogen, or represents (C₁-C₃)-alkyl or    (C₃-C₆)-cycloalkyl, each of which is substituted by m radicals from    the group consisting of fluorine and chlorine;-   R¹² preferably represents hydrogen, cyano, OR⁷, S(O). R⁵, SO₂NR⁶R⁷,    COR^(E), NR⁶R⁸, NR⁶COR⁸ or NR⁶SO₂R⁸, or represents (C₁-C₆)-alkyl,    (C₃-C₆)-cycloalkyl, (C₂-C₃)-alkenyl or (C₂-C₃)-alkynyl, each of    which is substituted by m radicals from the group consisting of    fluorine, chlorine, bromine, cyano, S(O)_(n)R⁵, NR⁶R⁸ and NR⁶CO₂R⁸;    -   or-   R¹¹ and R¹² together with the nitrogen atom to which they are    attached form a saturated, partially or fully unsaturated five-,    six- or seven-membered ring which is optionally mono- to    hexasubstituted by radicals from the group consisting of halogen,    cyano, nitro, (C₁-C₆)-alkyl, halo-(C₁-C₆)-alkyl, oxo, CO₂R⁸ and    NR⁶SO₂R⁸ and which, in addition to this nitrogen atom, contains r    carbon atoms, o oxygen atoms, p sulfur atoms and q elements from the    group consisting of NR⁷ and NCOR⁷ as ring atoms;-   m represents the running number 0, 1, 2 or 3;-   n represents the running number 0, 1 or 2;-   o represents the running number 0, 1 or 2;-   p represents the running number 0 or 1;-   q represents the running number 0 or 1; and-   r represents the running number 3, 4 or 5.

According to a twentieth embodiment of the present invention,

-   G represents a group of the formula NR″R′²;-   R¹ and R² each represent hydrogen;-   R³ represents (C₁-C₃)-alkyl, (C₃-C₄)-cycloalkyl, (C₂-C₃)-alkenyl or    (C₁-C₃)-alkoxy, each of which is substituted by m radicals from the    group consisting of fluorine, chlorine and (C₁-C₂)-alkoxy;-   Y represents oxygen;-   W represents oxygen;-   Z represents a group Z-1, Z-4 or Z-6:

-   -   where the arrow in each case denotes a bond to the group C═W of        the formula (I);

-   X², X⁴ and X⁶ independently of one another each represent hydrogen    or fluorine;

-   X³ and X⁵ independently of one another each represent hydrogen,    fluorine, chlorine, CF₃, CHF₂ or methyl;

-   R⁵ represents (C₁-C₆)-alkyl or (C₃-C₆)-cycloalkyl, each of which is    substituted by m radicals from the group consisting of fluorine and    chlorine;

-   R⁶ represents hydrogen or R⁵;

-   R⁷ represents hydrogen, or represents (C₁-C₆)-alkyl or    (C₃-C₆)-cycloalkyl, each of which is substituted by m radicals from    the group consisting of fluorine, chlorine and (C₁-C₂)-alkoxy;

-   R⁸ represents hydrogen, or represents (C₁-C₆)-alkyl or    (C₃-C₆)-cycloalkyl, each of which is substituted by m radicals from    the group consisting of fluorine, chlorine and (C₁-C₂)-alkoxy;

-   R¹¹ represents hydrogen, or represents (C₁-C₃)-alkyl or    (C₃-C₆)-cycloalkyl, each of which is substituted by m radicals from    the group consisting of fluorine and chlorine;

-   R¹² represents hydrogen, cyano, OR⁷, S(O). R⁵, SO₂NR⁶R⁷, COR^(E),    NR⁶R⁸, NR⁶COR⁸ or NR⁶SO₂R⁸, or represents (C₁-C₆)-alkyl,    (C₃-C₆)-cycloalkyl, (C₂-C₃)-alkenyl or (C₂-C₃)-alkynyl, each of    which is substituted by m radicals from the group consisting of    fluorine, chlorine, bromine, cyano, S(O)_(n)R⁵, NR⁶R⁸ and NR⁶CO₂R⁸;    -   or

-   R¹¹ and R¹² together with the nitrogen atom to which they are    attached form a saturated, partially or fully unsaturated five-,    six- or seven-membered ring which is optionally mono- to    hexasubstituted by radicals from the group consisting of halogen,    (C₁-C₆)-alkyl, halo-(C₁-C₆)-alkyl and oxo and which, in addition to    this nitrogen atom, contains r carbon atoms, o oxygen atoms, p    sulfur atoms and q elements from the group consisting of NIC and    NCOR⁷ as ring atoms;

-   m represents the running number 0, 1, 2 or 3;

-   n represents the running number 0, 1 or 2;

-   o represents the running number 0, 1 or 2;

-   p represents the running number 0 or 1;

-   q represents the running number 0 or 1; and

-   r represents the running number 3, 4 or 5.

Examples of the compounds of the general formula (I) are shown below intabular form. Table 1 below specifies the substituents defined ingeneral terms in formula (I).

TABLE 1.1 Compounds of the general formula (I) in which X² = X⁴ = X⁶ =R¹ = R² = H, Y = W = O and G = OR⁴ Example No.: X³ X⁵ R³ Z R⁴ CommentI-001 H F CH₃ Z-1 H (1R,4S)-cyclopent-2-en-1- carboxyl I-002 H F CH₃ Z-1H (1S,4R)-cyclopent-2-en-1- carboxyl I-003 H F CH₃ Z-1 CH₃(1R,4S)-cyclopent-2-en-1- carboxyl I-004 H F CH₃ Z-1 CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-005 H F CH₃ Z-1 CH₂CH₃(1R,4S)-cyclopent-2-en-1- carboxyl I-006 H F CH₃ Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-007 F F CH₃ Z-1 C(CH₃)₃(1S,4R)-cyclopent-2-en-1- carboxyl I-008 F F CH₃ Z-1 benzyl(1S,4R)-cyclopent-2-en-1- carboxyl I-009 F F CH₃ Z-1 CH₂CH₂Cl(1S,4R)-cyclopent-2-en-1- carboxyl I-010 F F CH₃ Z-1 CH₂CF₃(1S,4R)-cyclopent-2-en-1- carboxyl I-011 F F (S)—CH═CH₂ Z-1 H(1S,4R)-cyclopent-2-en-1- carboxyl I-012 F F (S)—CH═CH₂ Z-1 CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-013 F F (S)—CH═CH₂ Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-014 F F (S)—CH═CH₂ Z-1 H(1R,4R)-cyclopent-2-en-1- carboxyl I-015 F F CH═CH₂ Z-1 CH₂CF₃(1S,4R)-cyclopent-2-en-1- carboxyl I-016 F F CH═CH₂ Z-1 CH₂CHF₂(1S,4R)-cyclopent-2-en-1- carboxyl I-017 F F CH═CH₂ Z-1 CH₂CH₂CF₃(1S,4R)-cyclopent-2-en-1- carboxyl I-018 F F CH═CH₂ Z-1 CH₂CH₂OCH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-019 F F CH₃O Z-1 CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-020 F F CH3O Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-020 F F CH3O Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-021 H H CF₃ Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-022 CH₃ F CF₃ Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-023 CH₃ Cl CF₃ Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-024 CH₃ F CF₃ Z-1 CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-025 H H CF₃ Z-1 CH₂CH₂Cl(1S,4R)-cyclopent-2-en-1- carboxyl I-026 H H CF₃ Z-1 CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-027 CH₃ Cl CF₃ Z-1 CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-028 CH₃ Cl CF₃ Z-1 CH₂CH₂Cl(1S,4R)-cyclopent-2-en-1- carboxyl I-029 CH₃ Cl CF₃ Z-1 CH₂CF₃(1S,4R)-cyclopent-2-en-1- carboxyl I-030 H H CF₃ Z-1 CH₂CF₃(1S,4R)-cyclopent-2-en-1- carboxyl I-031 CH₃ F CF₃ Z-1 CH₂CH₂Cl(1S,4R)-cyclopent-2-en-1- carboxyl I-032 CH₃ F CF₃ Z-1 CH₂CF₃(1S,4R)-cyclopent-2-en-1- carboxyl I-033 F F CH═CH₂ Z-1 benzyl(1S,4R)-cyclopent-2-en-1- carboxyl I-034 F F CH═CH₂ Z-1 CH(CH₃)₂(1S,4R)-cyclopent-2-en-1- carboxyl I-035 F F CH═CH₂ Z-1 CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-036 CF₃ CH₃ CF₃ Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-037 F F CH═CH₂ Z-1 H(1S,4R)-cyclopent-2-en-1- carboxyl I-038 Cl Cl CF₃ Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-039 Cl Cl CF₃ Z-1 CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-040 Cl Cl CF₃ Z-1 CH₂CH₂Cl(1S,4R)-cyclopent-2-en-1- carboxyl I-041 Cl Cl CF₃ Z-1 CH₂CF₃(1S,4R)-cyclopent-2-en-1- carboxyl I-042 H Cl CF₃ Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-043 CH₃O CH₃O CF₃ Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-044 CH₃O CH₃O CF₃ Z-1 CH₂CH₂Cl(1S,4R)-cyclopent-2-en-1- carboxyl I-045 H Cl CF₃ Z-1 CH₂CH₂Cl(1S,4R)-cyclopent-2-en-1- carboxyl I-046 H Cl CF₃ Z-1 CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-047 CH₃O CH₃O CF₃ Z-1 CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-048 CF₃ CH₃ CF₃ Z-1 CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-049 CF₃ CH₃ CF₃ Z-1 CH₂CH₂Cl(1S,4R)-cyclopent-2-en-1- carboxyl I-050 CF₃ CH₃ CF₃ Z-1 CH₂CF₃(1S,4R)-cyclopent-2-en-1- carboxyl I-051 H Cl CF₃ Z-1 CH₂CF₃(1S,4R)-cyclopent-2-en-1- carboxyl I-052 CH₃O CH₃O CF₃ Z-1 CH₂CF₃(1S,4R)-cyclopent-2-en-1- carboxyl I-053 CH₃ CH₃ CF₃ Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-054 F F (S)—CH═CH₂ Z-1 CH₃(1R,4R)-cyclopent-2-en-1- carboxyl I-055 CH₃ CH₃ CF₃ Z-1 CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-056 CH₃ CH₃ CF₃ Z-1 CH₂CH₂Cl(1S,4R)-cyclopent-2-en-1- carboxyl I-057 CH₃ CH₃ CF₃ Z-1 CH₂CF₃(1S,4R)-cyclopent-2-en-1- carboxyl I-058 F F CF₃ Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-059 F F CH₃ Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-060 F F CH═CH₂ Z-1 C(CH₃)₃(1R,4S)-cyclopent-2-en-1- carboxyl I-061 F F CH═CH₂ Z-1 CH₂CH₂Cl(1R,4S)-cyclopent-2-en-1- carboxyl I-062 F F (R)—CF₃ Z-1 CH₃(1R,4R)-cyclopent-2-en-1- carboxyl I-063 F F CF₃ Z-1 CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-064 F F CF₃ Z-1 CH(CH₃)₂(1S,4R)-cyclopent-2-en-1- carboxyl I-065 F F CF₃ Z-1 benzyl(1S,4R)-cyclopent-2-en-1- carboxyl I-066 F F CF₃ Z-1 C(CH₃)₃(1S,4R)-cyclopent-2-en-1- carboxyl I-067 F F CF₃ Z-1 CH₂CH₂Cl(1S,4R)-cyclopent-2-en-1- carboxyl I-068 F F CF₃ Z-1 CH₂CF₃(1S,4R)-cyclopent-2-en-1- carboxyl I-069 CN H CH₃ Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-070 CN H CH₃ Z-1 H(1S,4R)-cyclopent-2-en-1- carboxyl I-071 CN F CF₃ Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-072 CN H CF₃ Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-073 CN F CH₃ Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-074 CONH₂ F CH₃ Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-075 CN F CH₃ Z-1 H(1S,4R)-cyclopent-2-en-1- carboxyl I-076 F F (R)—CF₃ Z-1 CH₂CH₂OCH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-077 F F (R)—CF₃ Z-1 CH₂CH₂OCH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-078 Cl F CF₃ Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-079 CN H CH₃ Z-1 CH₂CH₂Cl(1S,4R)-cyclopent-2-en-1- carboxyl I-080 CN H CH₃ Z-1 CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-081 CN H CH₃ Z-1 CH₂CH₂OCH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-082 CN F CH₃ Z-1 CH₂CH₂OCH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-083 CN F CH₃ Z-1 CH₂CH₂Cl(1S,4R)-cyclopent-2-en-1- carboxyl I-084 CN F CH₃ Z-1 CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-085 CN H CF₃ Z-1 H(1S,4R)-cyclopent-2-en-1- carboxyl I-086 CN H CF₃ Z-1 CH₂CH₂OCH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-087 CN H CF₃ Z-1 CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-088 CN H CF₃ Z-1 CH₂CH₂Cl(1S,4R)-cyclopent-2-en-1- carboxyl I-089 CN F CF₃ Z-1 CH₂CH₂Cl(1S,4R)-cyclopent-2-en-1- carboxyl I-090 CN F CF₃ Z-1 H(1S,4R)-cyclopent-2-en-1- carboxyl I-091 F F cyclopropyl Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-092 F F (R)—CH₃ Z-1 CH₂CH₂OCH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-093 F F (R)—CH₃ Z-1 CH₂CH₂OCH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-094 F F cyclopropyl Z-1 H(1S,4R)-cyclopent-2-en-1- carboxyl I-095 CN H CH₃ Z-1 C(CH₃)₃(1S,4R)-cyclopent-2-en-1- carboxyl I-096 CN F CF₃ Z-1 CH₂CF₃(1S,4R)-cyclopent-2-en-1- carboxyl I-097 CN F (S)— or Z-1 CH₃(1S,4R)-cyclopent-2-en-1- (R)—CF₃ carboxyl I-098 CN F (S) or Z-1 CH₃(1S,4R)-cyclopent-2-en-1- (R)—CF₃ carboxyl I-099 CN F (S)—CF₃ Z-1CH₂CH₂OCH₃ (1S,4R)-cyclopent-2-en-1- carboxyl I-100 CN F (R)—CF₃ Z-1CH₂CH₂OCH₃ (1S,4R)-cyclopent-2-en-1- carboxyl I-101 F F (S)—CH═CH₂ Z-1CH₂CH₂OCH₃ (1S,4R)-cyclopent-2-en-1- carboxyl I-102 F F (S)—CH═CH₂ Z-1CH₂CH₂OCH₂CH₃ (1S,4R)-cyclopent-2-en-1- carboxyl I-103 F F cyclopropylZ-1 C(CH₃)₃ (1S,4R)-cyclopent-2-en-1- carboxyl I-104 F F CN Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-105 F F (R)—CH₃ Z-1 CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-105 H F (R)—CH₃ Z-1 CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-105 H F (R)—CH₃ Z-1 CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-106 H F (S)—CH₃ Z-1 CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-107 F F (S)— or (R)— Z-1 CH₂CF₃(1S,4R)-cyclopent-2-en-1- cyclopropyl carboxyl I-108 F F (S)— or (R)—Z-1 CH₂CF₃ (1S,4R)-cyclopent-2-en-1- cyclopropyl carboxyl I-109 F F (S)—or (R)— Z-1 CH₂CF₃ (1R,4R)-cyclopent-2-en-1- cyclopropyl carboxyl I-110F F (S)— or (R)— Z-1 CH₂CF₃ (1R,4R)-cyclopent-2-en-1- cyclopropylcarboxyl I-111 F F CH₂Cl Z-1 H (1S,4R)-cyclopent-2-en-1- carboxyl I-112F F (S)— or (R)— Z-1 CH₂CH₂Cl (1S,4R)-cyclopent-2-en-1- cyclopropylcarboxyl I-113 F F (S)— or (R)— Z-1 CH₂CH₂Cl (1S,4R)-cyclopent-2-en-1-cyclopropyl carboxyl I-114 F F (S)— or (R)— Z-1 CH₂CH₂Cl(1R,4R)-cyclopent-2-en-1- cyclopropyl carboxyl I-115 F F (S)— or (R)—Z-1 CH₂CH₂Cl (1R,4R)-cyclopent-2-en-1- cyclopropyl carboxyl I-116 CN HCH₃ Z-1 CH₂CF₃ (1S,4R)-cyclopent-2-en-1- carboxyl I-117 F F (R)—CF₃ Z-1CH₃ (1S,4R)-cyclopent-2-en-1- carboxyl I-118 F F CH₂Cl Z-1 CH₂CH₂Cl(1S,4R)-cyclopent-2-en-1- carboxyl I-119 CN H CF₃ Z-1 C(CH₃)₃(1S,4R)-cyclopent-2-en-1- carboxyl I-120 F F CH₂Cl Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-121 F F cyclopropyl Z-1 CH₂CH₂OCH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-122 CN H CF₃ Z-1 CH₂CF₃(1S,4R)-cyclopent-2-en-1- carboxyl I-123 F F CH₂Cl Z-1 CH₂CHF₂(1S,4R)-cyclopent-2-en-1- carboxyl I-124 F F CH₂Cl Z-1 CH₂CH₂OCH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-125 F F CH₂Cl Z-1 CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-126 H H CH═CH₂ Z-1 CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-127 CH₃ F CH═CH₂ Z-1 CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-128 H H CH═CH₂ Z-1 H(1S,4R)-cyclopent-2-en-1- carboxyl I-129 CH₃ F (S)— or Z-1 CH₃(1S,4R)-cyclopent-2-en-1- (R)—CF₃ carboxyl I-130 CH₃ F (S)— or Z-1 CH₃(1S,4R)-cyclopent-2-en-1- (R)—CF₃ carboxyl I-131 H H (S)— or Z-1 CH₃(1S,4R)-cyclopent-2-en-1- (R)—CF₃ carboxyl I-132 H H (S)— or Z-1 CH₃(1S,4R)-cyclopent-2-en-1- (R)—CF₃ carboxyl I-133 CH₃ F CH═CH₂ Z-1 H(1S,4R)-cyclopent-2-en-1- carboxyl I-134 F F (R)—CF₃ Z-1 H(1S,4R)-cyclopent-2-en-1- carboxyl I-135 F F (S)—CH═CH₂ Z-1 CH₂CHF₂(1S,4R)-cyclopent-2-en-1- carboxyl I-136 F F (S)—CH═CH₂ Z-1 CH₂CHF₂(1R,4R)-cyclopent-2-en-1- carboxyl I-137 F F (S)—CH═CH₂ Z-1 CH₂CH₂CF₃(1S,4R)-cyclopent-2-en-1- carboxyl I-138 F F (S)—CH═CH₂ Z-1 CH₂CH₂CF₃(1R,4R)-cyclopent-2-en-1- carboxyl I-139 CN H CH₃ Z-1 CH₂CHF₂(1S,4R)-cyclopent-2-en-1- carboxyl I-140 F F (S)— or Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- (R)—CH₃O carboxyl I-141 F F (S)— or Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- (R)—CH₃O carboxyl I-142 F F (S)— or Z-1CH₂CH₂Cl (1S,4R)-cyclopent-2-en-1- (R)—CH₂Cl carboxyl I-143 F F (S)— orZ-1 CH₂CH₂Cl (1S,4R)-cyclopent-2-en-1- (R)—CH₂Cl carboxyl I-144 F F (S)—or Z-1 CH₂CH₂Cl (1R,4R)-cyclopent-2-en-1- (R)—CH₂Cl carboxyl I-145 F F(S)— or Z-1 CH₂CH₂Cl (1R,4R)-cyclopent-2-en-1- (R)—CH₂Cl carboxyl I-146H H (S)— or Z-1 CH₃ (1S,4R)-cyclopent-2-en-1- (R)—CH═CH₂ carboxyl I-147H H (S)— or Z-1 CH₃ (1S,4R)-cyclopent-2-en-1- (R)—CH═CH₂ carboxyl I-148CN H CF₃ Z-1 CH₂CHF₂ (1S,4R)-cyclopent-2-en-1- carboxyl I-149 F F CH₂ClZ-1 C(CH₃)₃ (1S,4R)-cyclopent-2-en-1- carboxyl I-150 CH₃ F (S)— or Z-1CH₂CH₃ (1S,4R)-cyclopent-2-en-1- (R)—CF₃ carboxyl I-151 CH₃ F (S)— orZ-1 CH₂CH₃ (1S,4R)-cyclopent-2-en-1- (R)—CF₃ carboxyl I-152 CH₃ F (S)—or Z-1 CH₂CH₃ (1R,4R)-cyclopent-2-en-1- (R)—CF₃ carboxyl I-153 CH₃ F(S)— or Z-1 CH₂CH₃ (1R,4R)-cyclopent-2-en-1- (R)—CF₃ carboxyl I-154 H H(S)— or Z-1 CH₂CH₃ (1S,4R)-cyclopent-2-en-1- (R)—CF₃ carboxyl I-155 H H(S)— or Z-1 CH₂CH₃ (1S,4R)-cyclopent-2-en-1- (R)—CF₃ carboxyl I-156 H H(S)— or Z-1 CH₂CH₃ (1R,4R)-cyclopent-2-en-1- (R)—CF₃ carboxyl I-157 H H(S)— or Z-1 CH₂CH₃ (1R,4R)-cyclopent-2-en-1- (R)—CF₃ carboxyl I-158 CNCl CH₃ Z-1 CH₃ (1S,4R)-cyclopent-2-en-1- carboxyl I-159 CN CN CH₃ Z-1CH₃ (1S,4R)-cyclopent-2-en-1- carboxyl I-160 CN Cl CH₃ Z-1 H(1S,4R)-cyclopent-2-en-1- carboxyl I-161 CN CN CH₃ Z-1 C(CH₃)₃(1S,4R)-cyclopent-2-en-1- carboxyl I-162 CN Cl CH₃ Z-1 C(CH₃)₃(1S,4R)-cyclopent-2-en-1- carboxyl I-163 H F (R)—CH₃ Z-1 H(1S,4R)-cyclopent-2-en-1- carboxyl I-164 CN Cl CH₃ Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-165 CN CN CH₃ Z-1 H(1S,4R)-cyclopent-2-en-1- carboxyl I-166 CN Cl CH₃ Z-1 CH₂CHF₂(1S,4R)-cyclopent-2-en-1- carboxyl I-167 CN Cl CH₃ Z-1 CH₂CH₂OCH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-168 CN Cl CH₃ Z-1 CH₂CH₂Cl(1S,4R)-cyclopent-2-en-1- carboxyl I-169 CH₃ F (S)— or Z-1 CH₃(1S,4R)-cyclopent-2-en-1- (R)—CH═CH₂ carboxyl I-170 CH₃ F (S)— or Z-1CH₃ (1S,4R)-cyclopent-2-en-1- (R)—CH═CH₂ carboxyl I-171 CN CN CH₃ Z-1CH₂CH₂OCH₃ (1S,4R)-cyclopent-2-en-1- carboxyl I-172 CN CN CH₃ Z-1CH₂CH₂Cl (1S,4R)-cyclopent-2-en-1- carboxyl I-173 CN CN CH₃ Z-1 CH₂CHF₂(1S,4R)-cyclopent-2-en-1- carboxyl I-174 F F CH₃O Z-1 H(1S,4R)-cyclopent-2-en-1- carboxyl I-175 H H CH═CH₂ Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-176 H H CH═CH₂ Z-1 CH₂CH₂Cl(1S,4R)-cyclopent-2-en-1- carboxyl I-177 H H CH═CH₂ Z-1 CH₂CH₂OCH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-178 CN Cl CF₃ Z-1 CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-179 CH₃ CH₃ CH═CH₂ Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-180 H F (R)—CH₃ Z-1 H(1R,4R)-cyclopent-2-en-1- carboxyl I-181 H F (S)— or Z-1 CH₃(1S,4R)-cyclopent-2-en-1- (R)—CF₃ carboxyl I-182 H H CH═CH₂ Z-1 CH₂CHF₂(1S,4R)-cyclopent-2-en-1- carboxyl I-183 H F (S)— or Z-1 CH₃(1S,4R)-cyclopent-2-en-1- (R)—CF₃ carboxyl I-184 CH₃ F CH═CH₂ Z-1CH₂CH₂Cl (1S,4R)-cyclopent-2-en-1- carboxyl I-185 CH₃ F CH═CH₂ Z-1CH₂CH₂OCH₃ (1S,4R)-cyclopent-2-en-1- carboxyl I-186 CH₃ F CH═CH₂ Z-1CH₂CHF₂ (1S,4R)-cyclopent-2-en-1- carboxyl I-187 CH₃ F CH═CH₂ Z-1 CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-188 H F (R)—CH₃ Z-1 CH₂CH₂CH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-189 H F (R)—CH₃ Z-1 CH(CH₃)₂(1S,4R)-cyclopent-2-en-1- carboxyl I-190 H F (R)—CH₃ Z-1 C(CH₃)₃(1S,4R)-cyclopent-2-en-1- carboxyl I-191 H F (R)—CH₃ Z-1 CH₂CH₂Cl(1S,4R)-cyclopent-2-en-1- carboxyl I-192 H F (R)—CH₃ Z-1 CH₂CH₂OCH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-193 H F (R)—CH₃ Z-1 benzyl(1S,4R)-cyclopent-2-en-1- carboxyl I-194 H F (R)—CH₃ Z-1 4-F-benzyl(1S,4R)-cyclopent-2-en-1- carboxyl I-195 F F (R)—CH₂Cl Z-1 CH₂CH₂OCH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-196 F F (R)—CH₂Cl Z-1 CH₂CH₂OCH₃(1R,4R)-cyclopent-2-en-1- carboxyl I-197 F F (S)—CH₂Cl Z-1 CH₂CH₂OCH₃(1S,4R)-cyclopent-2-en-1- carboxyl I-198 F F (S)—CH₂Cl Z-1 CH₂CH₂OCH₃(1R,4R)-cyclopent-2-en-1- carboxyl I-199 CN Cl (S)— or Z-1 CH₂CH₂OCH₃(1S,4R)-cyclopent-2-en-1- (R)—CH₃ carboxyl I-200 CN Cl (S)— or Z-1CH₂CH₂OCH₃ (1S,4R)-cyclopent-2-en-1- (R)—CH₃ carboxyl I-201 CN Cl (S)—or Z-1 CH₂CH₂OCH₃ (1R,4R)-cyclopent-2-en-1- (R)—CH₃ carboxyl I-202 Cl FCH₃ Z-1 CH₂CH₃ (1S,4R)-cyclopent-2-en-1- carboxyl I-203 F F (S)— or (R)—Z-1 CH₂CH₂OCH₃ (1S,4R)-cyclopent-2-en-1- cyclopropyl carboxyl I-204 F F(S)— or (R)— Z-1 CH₂CH₂OCH₃ (1S,4R)-cyclopent-2-en-1- cyclopropylcarboxyl I-206 CH₃ CH₃ CH═CH₂ Z-1 CH₃ (1S,4R)-cyclopent-2-en-1- carboxylI-207 CH₃ CH₃ CH═CH₂ Z-1 H (1S,4R)-cyclopent-2-en-1- carboxyl III-01 H FCH₃ Z-4 H (4R)-cyclopent-1-en-1- carboxyl III-02 H F CH₃ Z-4 H(4S)-cyclopent-1-en-1- carboxyl III-03 H F CH₃ Z-4 CH₃(4R)-cyclopent-1-en-1- carboxyl III-04 H F CH₃ Z-4 CH₃(4S)-cyclopent-1-en-1- carboxyl III-05 H F CH₃ Z-4 CH₂CH₃(4R)-cyclopent-1-en-1- carboxyl III-06 H F CH₃ Z-4 CH₂CH₃(4S)-cyclopent-1-en-1- carboxyl III-07 F F CH₃ Z-4 CH₂CH₃(4S)-cyclopent-1-en-1- carboxyl III-08 F F CH═CH₂ Z-4 CH₃(4S)-cyclopent-1-en-1- carboxyl III-09 F F CH═CH₂ Z-4 H(4S)-cyclopent-1-en-1- carboxyl III-10 F F CH₃ Z-4 CH₃(4S)-cyclopent-1-en-1- carboxyl III-11 F F CH₃ Z-4 CH(CH₃)₂(4S)-cyclopent-1-en-1- carboxyl III-12 F F CH₃ Z-4 benzyl(4S)-cyclopent-1-en-1- carboxyl III-13 F F CH═CH₂ Z-4 CH(CH₃)₂(4S)-cyclopent-1-en-1- carboxyl III-14 F F CH═CH₂ Z-4 CH₂CH₂Cl(4S)-cyclopent-1-en-1- carboxyl III-15 F F CH═CH₂ Z-4 CH₂CH₂OCH₃(4S)-cyclopent-1-en-1- carboxyl III-16 F F CH═CH₂ Z-4 CH₂CH₂OCH₂CH₃(4S)-cyclopent-1-en-1- carboxyl III-17 F F CH═CH₂ Z-4 CH₂CH₃(4S)-cyclopent-1-en-1- carboxyl III-18 F F CH═CH₂ Z-4 benzyl(4S)-cyclopent-1-en-1- carboxyl III-19 F F CF₃ Z-4 CH₃(4S)-cyclopent-1-en-1- carboxyl III-20 F F CH₃ Z-4 C(CH₃)₃(4S)-cyclopent-1-en-1- carboxyl III-21 F F CH₃ Z-4 CH₂CH₂Cl(4S)-cyclopent-1-en-1- carboxyl III-22 F F CF₃ Z-4 CH₂CH₃(4S)-cyclopent-1-en-1- carboxyl III-23 F F CF₃ Z-4 CH(CH3)2(4S)-cyclopent-1-en-1- carboxyl III-24 F F CF₃ Z-4 CH₂CH₂Cl(4S)-cyclopent-1-en-1- carboxyl III-25 F F CF₃ Z-4 benzyl(4S)-cyclopent-1-en-1- carboxyl III-26 F F CF₃ Z-4 C(CH₃)₃(4S)-cyclopent-1-en-1- carboxyl III-27 F F CF₃ Z-4 CH₂CH₂OCH₃(4S)-cyclopent-1-en-1- carboxyl III-28 F F CH₃ Z-4 CH₂CH₂OCH₃(4S)-cyclopent-1-en-1- carboxyl III-29 F F CF₃ Z-4 H(4S)-cyclopent-1-en-1- carboxyl V-01 F F (R)—CH₃ Z-6 H(3S)-cyclopent-1-en-1- carboxyl V-05 F F (R)—CF3 Z-6 CH3(3S)-cyclopent-1-en-1- carboxyl V-02 F F (R)—CH₃ Z-6 CH3(3S)-cyclopent-1-en-1- carboxyl V-03 F F (R)—CH₃ Z-6 CH₂CH₂OCH₃(3S)-cyclopent-1-en-1- carboxyl V-04 F F (R)—CF3 Z-6 H(3S)-cyclopent-1-en-1- carboxyl

TABLE 1.2 Compounds of the general formula (I) in which X² = X⁴ = X⁶ =R¹ = R² = H, Y = W = O and G = NR¹¹R¹² Example No.: X³ X⁵ R³ Z NR¹¹R¹²Comment II-01 H F CH₃ Z-1 methoxyamino (1R,4S)-cyclopent-2-en-1-carboxyl II-02 F F CH₃ Z-1 methoxyamino (1S,4R)-cyclopent-2-en-1-carboxyl II-03 H F CH₃ Z-1 ethoxyamino (1R,4S)-cyclopent-2-en-1-carboxyl II-04 H F CH₃ Z-1 ethoxyamino (1S,4R)-cyclopent-2-en-1-carboxyl II-05 H F CH₃ Z-1 isopropyloxyamino (1R,4S)-cyclopent-2-en-1-carboxyl II-06 F F CH₃ Z-1 1,2-oxazolidin-2-yl (1S,4R)-cyclopent-2-en-1-carboxyl II-07 F F CH₃ Z-1 oxazinan-2-yl (1S,4R)-cyclopent-2-en-1-carboxyl II-08 F F CH₃ Z-1 (1,1,1-trifluoro-2- (1S,4R)-cyclopent-2-en-methylpropan-2-yl)amino 1-carboxyl II-09 F F CH₃ Z-1(1-methoxy-2-methyl-1- (1S,4R)-cyclopent-2-en- oxopropan-2-yl)amino1-carboxyl II-10 F F CH₃ Z-1 2-cyanopropan-2-ylamino(1S,4R)-cyclopent-2-en- 1-carboxyl II-11 F F CH₃ Z-1(1-methoxy-3-methyl-1- (1S,4R)-cyclopent-2-en- oxobutan-2-yl)amino1-carboxyl II-12 F F CH₃ Z-1 (1-cyano-2- (1S,4R)-cyclopent-2-en-methylpropyl)amino 1-carboxyl II-13 H F CH₃ Z-1 methanesulfonamido(1R,4S)-cyclopent-2-en- 1-carboxyl II-14 F F CH═CH₂ Z-1propylsulfonylamino (1S,4R)-cyclopent-2-en- 1-carboxyl II-15 H F CH₃ Z-1trifluoromethylsulfonylamino (1R,4S)-cyclopent-2-en- 1-carboxyl II-16 HF CH₃ Z-1 trifluoromethylsulfonylamino (1S,4R)-cyclopent-2-en-1-carboxyl II-17 F F CH═CH₂ Z-1 (1-cyano-2- (1S,4R)-cyclopent-2-en-methylpropyl)amino 1-carboxyl II-18 F F CH═CH₂ Z-1 (2-methoxy-2-(1S,4R)-cyclopent-2-en- oxoethyl) sulfonylamino 1-carboxyl II-19 F FCH═CH₂ Z-1 2-cyanopropan-2-ylamino (1R,4R)-cyclopent-2-en- 1-carboxylII-20 F F CH═CH₂ Z-1 2-cyanopropan-2-ylamino (1S,4R)-cyclopent-2-en-1-carboxyl II-21 F F (R)—CH═CH₂ Z-1 (1-methoxy-2-methyl-1-(1S,4R)-cyclopent-2-en- oxopropan-2-yl)amino 1-carboxyl II-22 F F(S)—CH═CH₂ Z-1 (1-methoxy-2-methyl-1- (1S,4R)-cyclopent-2-en-oxopropan-2-yl)amino 1-carboxyl II-23 F F (S)— or Z-1(1,1,1-trifluoro-2- (1S,4R)-cyclopent-2-en- (R)—CH═CH₂methylpropan-2-yl)amino 1-carboxyl II-24 F F (S)— or Z-1(1,1,1-trifluoro-2- (1S,4R)-cyclopent-2-en- (R)—CH═CH₂methylpropan-2-yl)amino 1-carboxyl II-25 F F CH═CH₂ Z-1(1-methoxy-3-methyl-1- (1S,4R)-cyclopent-2-en- oxobutan-2-yl)amino1-carboxyl II-26 F F CH═CH₂ Z-1 (1-methoxy-3-methyl-1-(1S,4R)-cyclopent-2-en- oxobutan-2-yl)amino 1-carboxyl II-27 F F(S)—CH═CH₂ Z-1 1,2-oxazolidin-2-yl (1S,4R)-cyclopent-2-en- 1-carboxylII-28 F F (S)—CH═CH₂ Z-1 1,2-oxazolidin-2-yl (1S,4R)-cyclopent-2-en-1-carboxyl II-29 F F CH═CH₂ Z-1 oxazinan-2-yl (1R,4R)-cyclopent-2-en-1-carboxyl II-30 F F CH═CH₂ Z-1 oxazinan-2-yl (1S,4R)-cyclopent-2-en-1-carboxyl II-31 F F CF₃ Z-1 oxazinan-2-yl (1S,4R)-cyclopent-2-en-1-carboxyl II-32 F F CF₃ Z-1 1,2-oxazolidin-2-yl (1S,4R)-cyclopent-2-en-1-carboxyl II-33 F F CF₃ Z-1 propylsulfonylamino (1S,4R)-cyclopent-2-en-1-carboxyl II-34 F F CF₃ Z-1 2-cyanopropan-2-ylamino(1S,4R)-cyclopent-2-en- 1-carboxyl II-35 F F CF₃ Z-1 (1-cyano-2-(1S,4R)-cyclopent-2-en- methylpropyl)amino 1-carboxyl II-36 F F CF₃ Z-1(1-methoxy-2-methyl-1- (1S,4R)-cyclopent-2-en- oxopropan-2-yl)amino1-carboxyl II-37 F F CF₃ Z-1 (1-methoxy-3-methyl-1-(1S,4R)-cyclopent-2-en- oxobutan-2-yl)amino 1-carboxyl II-38 F F CF₃ Z-1(1,1,1-trifluoro-2- (1S,4R)-cyclopent-2-en- methylpropan-2-yl)amino1-carboxyl II-39 F F CF₃ Z-1 (2-methoxy-2- (1S,4R)-cyclopent-2-en-oxoethyl)sulfonylamino 1-carboxyl II-40 CN F CF₃ Z-1 (1,1,1-trifluoro-2-(1R,4R)-cyclopent-2-en- methylpropan-2-yl)amino 1-carboxyl II-41 F F CF₃Z-1 (1,1,1-trifluoro-2- (1S,4R)-cyclopent-2-en- methylpropan-2-yl)amino1-carboxyl II-42 F F (R)—CF₃ Z-1 3-oxo-2- (1S,4R)-cyclopent-2-en-azabicyclo[2.2.1]hept-5-en-2-yl 1-carboxyl II-43 F F ClCH₂ Z-1(2-methoxy-2- (1S,4R)-cyclopent-2-en- oxoethyl)sulfonylamino 1-carboxylII-44 H CN CF₃ Z-1 (1,1,1-trifluoro-2- (1R,4R)-cyclopent-2-en-methylpropan-2-yl)amino 1-carboxyl II-45 H CN CF₃ Z-1(1,1,1-trifluoro-2- (1S,4R)-cyclopent-2-en- methylpropan-2-yl)amino1-carboxyl II-46 H CN CH₃ Z-1 (1,1,1-trifluoro-2-(1R,4R)-cyclopent-2-en- methylpropan-2-yl)amino 1-carboxyl II-47 H CNCH₃ Z-1 (1,1,1-trifluoro-2- (1S,4R)-cyclopent-2-en-methylpropan-2-yl)amino 1-carboxyl II-48 F F ClCH₂ Z-1(1,1,1-trifluoro-2- (1S,4R)-cyclopent-2-en- methylpropan-2-yl)amino1-carboxyl II-49 H CN CF₃ Z-1 (2-methoxy-2- (1S,4R)-cyclopent-2-en-oxoethyl)sulfonylamino 1-carboxyl II-50 H CN (S) or Z-1 (2-methoxy-2-(1S,4R)-cyclopent-2-en- (R)—CH₃ oxoethyl)sulfonylamino 1-carboxyl II-51H CN (S) or Z-1 (2-methoxy-2- (1S,4R)-cyclopent-2-en- (R)—CH₃oxoethyl)sulfonylamino 1-carboxyl II-52 H CN (S) or Z-1 (2-methoxy-2-(1R,4R)-cyclopent-2-en- (R)— CH₃ oxoethyl)sulfonylamino 1-carboxyl II-53H CN (S)— or Z-1 (2-methoxy-2- (1R,4R)-cyclopent-2-en- (R)—CH₃oxoethyl)sulfonylamino 1-carboxyl II-54 F F ClCH₂ Z-1(1,1,1-trifluoro-2- (1R,4R)-cyclopent-2-en- methylpropan-2-yl)amino1-carboxyl II-55 CN CN CH₃ Z-1 (1,1,1-trifluoro-2-(1R,4R)-cyclopent-2-en- methylpropan-2-yl)amino 1-carboxyl II-56 CN ClCH₃ Z-1 (1,1,1-trifluoro-2- (1S,4R)-cyclopent-2-en-methylpropan-2-yl)amino 1-carboxyl II-57 CN Cl CH₃ Z-1(2-methoxy-2-oxoethyl)amino (1R,4R)-cyclopent-2-en- 1-carboxyl II-58 CNCl (S)— or Z-1 (2-methoxy-2-oxoethyl)amino (1S,4R)-cyclopent-2-en-(R)—CH₃ 1-carboxyl II-59 CN Cl CH₃ Z-1 (2-methoxy-2-(1S,4R)-cyclopent-2-en- oxoethyl)sulfonylamino 1-carboxyl II-60 CN CNCH₃ Z-1 (2-methoxy-2-oxoethyl)amino (1S,4R)-cyclopent-2-en- 1-carboxylII-61 CN CN CH₃ Z-1 (1,1,1-trifluoro-2- (1R,4R)-cyclopent-2-en-methylpropan-2-yl)amino 1-carboxyl II-62 CN CN CH₃ Z-1(1,1,1-trifluoro-2- (1S,4R)-cyclopent-2-en- methylpropan-2-yl)amino1-carboxyl II-63 CN CN CH₃ Z-1 (2-methoxy-2- (1S,4R)-cyclopent-2-en-oxoethyl)sulfonylamino 1-carboxyl IV-01 H F CH3 Z-4 dimethylamino(4R)-cyclopent-1-en-1- carboxyl IV-02 H F CH3 Z-4 dimethylamino(4S)-cyclopent-1-en-1- carboxyl IV-03 H F CH3 Z-4 methoxyamino(4R)-cyclopent-1-en-1- carboxyl IV-04 H F CH3 Z-4 methoxyamino(4S)-cyclopent-1-en-1- carboxyl IV-05 H F CH3 Z-4 dimethylhydrazino(4R)-cyclopent-1-en-1- carboxyl IV-06 H F CH3 Z-4 dimethylhydrazino(4S)-cyclopent-1-en-1- carboxyl IV-07 H F CH3 Z-4 methanesulfonamido(4S)-cyclopent-1-en-1- carboxvl IV-08 F F CH3 Z-4 sulfamoylamino(4S)-cyclopent-1-en-1- carboxyl IV-09 F F CF3 Z-4 sulfamoylamino(4S)-cyclopent-1-en-1- carboxyl IV-10 F F CH═CH2 Z-4 sulfamoylamino(4S)-cyclopent-1-en-1- carboxyl IV-11 F F CH═CH2 Z-4 (1,1,1-trifluoro-2-(4S)-cyclopent-1-en-1- methylpropan-2-yl)amino carboxyl IV-12 F F CH3Z-4 (1,1,1-trifluoro-2- (4S)-cyclopent-1-en-1- methylpropan-2-yl)aminocarboxyl IV-13 F F CF3 Z-4 (1,1,1-trifluoro-2- (4S)-cyclopent-1-en-1-methylpropan-2-yl)amino carboxyl

The compounds according to the invention can be prepared by variousprocesses, examples of which are given below:

In Scheme 1 and the schemes which follow, (X)^(n) represents thesubstituents X², X³, X⁴, X⁵ and X⁶. Such 1,3-dipolar cycloadditions ofnitrile oxides with suitable dipolarophiles are described, for example,in Reviews: 1,3 dipolar Cycloaddition Chemistry, Padwa, ed. Wiley, NewYork, 1984; Kanemasa and Tsuge, Heterocycles 1990, 30, 719. For thepreparation of chloroximes, see Kim, Jae N., Ryu, Eung K. J. Org. Chem.1992, 57, 6649).

Compounds according to the invention substituted in the 4 and 5positions of the isoxazoline ring system can likewise be prepared by1,3-dipolar cycloaddition by using suitably 1,2-disubstituted olefins asdipolarophiles. Usually, this reaction gives diastereomer mixtures whichcan be separated by column chromatography. Optically active isoxazolinescan be obtained by chiral HPLC of suitable precursors or end productsand also by enantioselective reactions such as, for example, enzymaticester or amide cleavage or by using chiral auxiliaries at thedipolarophile, as described by Olssen (J. Org. Chem. 1988, 53, 2468).

For preparation of the compounds according to the invention, it is alsopossible to use suitably substituted 2-alkoxyacrylamides (scheme 3).These are obtainable from the acrylic esters described in scheme 2 afterhydrolysis and amide formation.

One option for activating the acrylic acid is carbodiimides, for exampleEDCl (Chen, F. M. F.; Benoiton, N. L. Synthesis 1979, 709). Forpreparation of acrylamides, see U.S. Pat. No. 2,521,902, JP60112746, J.of Polymer Science 1979, 17 (6), 1655. Suitably substituted acrylamidescan be reacted in a 1,3-cycloaddition reaction with nitrile oxides togive the compounds according to the invention (Scheme 3).

Transformations of the functional groups R³ are possible either at thealkene stage or at the isoxazoline stage.

Collections of compounds of the formula (I) and/or salts thereof whichcan be synthesized by the abovementioned reactions can also be preparedin a parallelized manner, in which case this may be accomplished in amanual, partly automated or fully automated manner. It is possible, forexample, to automate the conduct of the reaction, the workup or thepurification of the products and/or intermediates. Overall, this isunderstood to mean a procedure as described, for example, by D. Tiebesin Combinatorial Chemistry—Synthesis, Analysis, Screening (editor:Gunther Jung), Wiley, 1999, on pages 1 to 34.

The compounds of the formula (I) according to the invention (and/orsalts thereof), referred to collectively as “compounds according to theinvention” hereinafter, have excellent herbicidal efficacy against abroad spectrum of economically important monocotyledonous anddicotyledonous annual harmful plants.

The present invention therefore also provides a method for controllingunwanted plants or for regulating the growth of plants, preferably inplant crops, in which one or more compound(s) of the invention is/areapplied to the plants (for example harmful plants such asmonocotyledonous or dicotyledonous weeds or unwanted crop plants), theseed (for example grains, seeds or vegetative propagules such as tubersor shoot parts with buds) or the area on which the plants grow (forexample the area under cultivation). The compounds of the invention canbe deployed, for example, prior to sowing (if appropriate also byincorporation into the soil), prior to emergence or after emergence.Specific examples of some representatives of the monocotyledonous anddicotyledonous weed flora which can be controlled by the compounds ofthe invention are as follows, though the enumeration is not intended toimpose a restriction to particular species.

Monocotyledonous harmful plants of the genera: Aegilops, Agropyron,Agrostis, Alopecurus, Apera, Avena, Brachiaria, Bromus, Cenchrus,Commelina, Cynodon, Cyperus, Dactyloctenium, Digitaria, Echinochloa,Eleocharis, Eleusine, Eragrostis, Eriochloa, Festuca, Fimbristylis,Heteranthera, Imperata, Ischaemum, Leptochloa, Lolium, Monochoria,Panicum, Paspalum, Phalaris, Phleum, Poa, Rottboellia, Sagittaria,Scirpus, Setaria, Sorghum.

Dicotyledonous weeds of the genera: Abutilon, Amaranthus, Ambrosia,Anoda, Anthemis, Aphanes, Artemisia, Atriplex, Bellis, Bidens, Capsella,Carduus, Cassia, Centaurea, Chenopodium, Cirsium, Convolvulus, Datura,Desmodium, Emex, Erysimum, Euphorbia, Galeopsis, Galinsoga, Galium,Hibiscus, Ipomoea, Kochia, Lamium, Lepidium, Lindernia, Matricaria,Mentha, Mercurialis, Mullugo, Myosotis, Papaver, Pharbitis, Plantago,Polygonum, Portulaca, Ranunculus, Raphanus, Rorippa, Rotala, Rumex,Salsola, Senecio, Sesbania, Sida, Sinapis, Solanum, Sonchus, Sphenoclea,Stellaria, Taraxacum, Thlaspi, Trifolium, Urtica, Veronica, Viola,Xanthium.

When the compounds according to the invention are applied to the soilsurface before germination, either the weed seedlings are preventedcompletely from emerging or the weeds grow until they have reached thecotyledon stage, but then stop growing.

If the active compounds are applied post-emergence to the green parts ofthe plants, growth stops after the treatment, and the harmful plantsremain at the growth stage at the time of application, or they diecompletely after a certain time, so that in this manner competition bythe weeds, which is harmful to the crop plants, is eliminated very earlyand in a sustained manner

The compounds according to the invention can be selective in crops ofuseful plants and can also be employed as non-selective herbicides.

By virtue of their herbicidal and plant growth regulatory properties,the active compounds can also be used to control harmful plants in cropsof genetically modified plants which are known or are yet to bedeveloped. In general, the transgenic plants are characterized byparticular advantageous properties, for example by resistances tocertain active compounds used in agroindustry, in particular certainherbicides, resistances to plant diseases or pathogens of plantdiseases, such as certain insects or microorganisms such as fungi,bacteria or viruses. Other specific characteristics relate, for example,to the harvested material with regard to quantity, quality, storability,composition and specific constituents. For instance, there are knowntransgenic plants with an elevated starch content or altered starchquality, or those with a different fatty acid composition in theharvested material. Further particular properties lie in tolerance orresistance to abiotic stress factors, for example heat, cold, drought,salinity and ultraviolet radiation.

Preference is given to using the compounds of the formula (I) accordingto the invention or salts thereof in economically important transgeniccrops of useful and ornamental plants.

The compounds of the formula (I) can be used as herbicides in crops ofuseful plants which are resistant, or have been made resistant bygenetic engineering, to the phytotoxic effects of the herbicides.

Conventional ways of producing novel plants which have modifiedproperties in comparison to existing plants consist, for example, intraditional cultivation methods and the generation of mutants.Alternatively, novel plants with altered properties can be generatedwith the aid of recombinant methods (see, for example, EP 0221044, EP0131624). What has been described are, for example, several cases ofgenetic modifications of crop plants for the purpose of modifying thestarch synthesized in the plants (e.g. WO 92/011376 A, WO 92/014827 A,WO 91/019806 A), transgenic crop plants which are resistant to certainherbicides of the glufosinate type (cf., for example, EP 0242236 A, EP0242246 A) or of the glyphosate type (WO 92/000377A) or of thesulfonylurea type (EP 0257993 A, U.S. Pat. No. 5,013,659) or tocombinations or mixtures of these herbicides through “gene stacking”,such as transgenic crop plants, for example corn or soya with the tradename or the designation Optimum™ GAT™ (Glyphosate ALS Tolerant),

-   -   transgenic crop plants, for example cotton, capable of producing        Bacillus thuringiensis toxins (Bt toxins), which make the plants        resistant to particular pests (EP 0142924 A, EP 0193259 A),    -   transgenic crop plants having a modified fatty acid composition        (WO 91/013972 A),    -   genetically modified crop plants having novel constituents or        secondary metabolites, for example novel phytoalexins, which        cause an increase in disease resistance (EP 0309862 A, EP        0464461 A),    -   genetically modified plants having reduced photorespiration,        which have higher yields and higher stress tolerance (EP 0305398        A),    -   transgenic crop plants which produce pharmaceutically or        diagnostically important proteins (“molecular pharming”),    -   transgenic crop plants which feature higher yields or better        quality, transgenic crop plants which are distinguished by a        combination, for example of the abovementioned novel properties        (“gene stacking”).

Numerous molecular biology techniques which can be used to produce noveltransgenic plants with modified properties are known in principle; see,for example, I. Potrykus and G. Spangenberg (eds), Gene Transfer toPlants, Springer Lab Manual (1995), Springer Verlag Berlin, Heidelbergor Christou, “Trends in Plant Science” 1 (1996) 423-431).

For such genetic manipulations, nucleic acid molecules which allowmutagenesis or sequence alteration by recombination of DNA sequences canbe introduced into plasmids. With the aid of standard methods, it ispossible, for example, to undertake base exchanges, remove partsequences or add natural or synthetic sequences. To join the DNAfragments with one another, adapters or linkers can be placed onto thefragments, see, for example, Sambrook et al., 1989, Molecular Cloning, ALaboratory Manual, 2nd ed. Cold Spring Harbor Laboratory Press, ColdSpring Harbor, N.Y.; or Winnacker “Gene and Klone” [Genes and Clones],VCH Weinheim 2nd edition 1996.

For example, the generation of plant cells with a reduced activity of agene product can be achieved by expressing at least one correspondingantisense RNA, a sense RNA for achieving a cosuppression effect, or byexpressing at least one suitably constructed ribozyme which specificallycleaves transcripts of the abovementioned gene product. To this end, itis firstly possible to use DNA molecules which encompass the entirecoding sequence of a gene product inclusive of any flanking sequenceswhich may be present, and also DNA molecules which only encompassportions of the coding sequence, in which case it is necessary for theseportions to be long enough to have an antisense effect in the cells. Itis also possible to use DNA sequences which have a high degree ofhomology to the coding sequences of a gene product, but are notcompletely identical to them.

When expressing nucleic acid molecules in plants, the proteinsynthesized may be localized in any desired compartment of the plantcell. However, to achieve localization in a particular compartment, itis possible, for example, to join the coding region to DNA sequenceswhich ensure localization in a particular compartment. Such sequencesare known to those skilled in the art (see, for example, Braun et al.,EMBO J. 11 (1992), 3219-3227; Wolter et al., Proc. Natl. Acad. Sci. USA85 (1988), 846-850; Sonnewald et al., Plant J. 1 (1991), 95-106). Thenucleic acid molecules can also be expressed in the organelles of theplant cells.

The transgenic plant cells can be regenerated by known techniques togive rise to entire plants. In principle, the transgenic plants may beplants of any desired plant species, i.e. not only monocotyledonous butalso dicotyledonous plants. Thus, transgenic plants can be obtainedwhose properties are altered by overexpression, suppression orinhibition of homologous (=natural) genes or gene sequences orexpression of heterologous (=foreign) genes or gene sequences.

The compounds (I) according to the invention can be used with preferencein transgenic crops which are resistant to growth regulators, forexample 2,4-D, dicamba, or to herbicides which inhibit essential plantenzymes, for example acetolactate synthases (ALS), EPSP synthases,glutamine synthases (GS) or hydroxyphenylpyruvate dioxygenases (HPPD),or to herbicides from the group of the sulfonylureas, the glyphosates,glufosinates or benzoylisoxazoles and analogous active compounds, or toany desired combinations of these active compounds.

The compounds of the invention can be used with particular preference intransgenic crop plants which are resistant to a combination ofglyphosates and glufosinates, glyphosates and sulfonylureas orimidazolinones. Most preferably, the compounds according to theinvention can be used in transgenic crop plants such as corn or soyawith the trade name or the designation Optimum™ GAT™ (glyphosate ALStolerant), for example.

When the active compounds of the invention are employed in transgeniccrops, not only do the effects towards harmful plants observed in othercrops occur, but frequently also effects which are specific to theapplication in the particular transgenic crop, for example an altered orspecifically widened spectrum of weeds which can be controlled, alteredapplication rates which can be used for the application, preferably goodcombinability with the herbicides to which the transgenic crop isresistant, and influencing of growth and yield of the transgenic cropplants.

The invention therefore also relates to the use of the compoundsaccording to the invention of the formula (I) as herbicides forcontrolling harmful plants in transgenic crop plants.

The compounds of the invention can be applied in the form of wettablepowders, emulsifiable concentrates, sprayable solutions, dustingproducts or granules in the customary formulations. The inventiontherefore also provides herbicidal and plant-growth-regulatingcompositions which comprise the compounds of the invention.

The compounds of the invention can be formulated in various ways,according to the biological and/or physicochemical parameters required.Possible formulations include, for example: wettable powders (WP),water-soluble powders (SP), water-soluble concentrates, emulsifiableconcentrates (EC), emulsions (EW), such as oil-in-water and water-in-oilemulsions, sprayable solutions, suspension concentrates (SC),dispersions based on oil or water, oil-miscible solutions, capsulesuspensions (CS), dusting products (DP), dressings, granules forscattering and soil application, granules (GR) in the form ofmicrogranules, spray granules, absorption and adsorption granules,water-dispersible granules (WG), water-soluble granules (SG), ULVformulations, microcapsules and waxes. These individual formulationtypes are known in principle and are described, for example, in:Winnacker-Küchler, “Chemische Technologic [Chemical Technology]”, Volume7, C. Hanser Verlag Munich, 4th Ed. 1986, Wade van Valkenburg,“Pesticide Formulations”, Marcel Dekker, N.Y., 1973, K. Martens, “SprayDrying” Handbook, 3rd Ed. 1979, G. Goodwin Ltd. London.

The formulation auxiliaries required, such as inert materials,surfactants, solvents and further additives, are likewise known and aredescribed, for example, in: Watkins, “Handbook of Insecticide DustDiluents and Carriers”, 2nd Ed., Darland Books, Caldwell N.J.; H. v.Olphen, “Introduction to Clay Colloid Chemistry”, 2nd ed., J. Wiley &Sons, N.Y.; C. Marsden, “Solvents Guide”, 2nd ed., Interscience, N.Y.1963; McCutcheon's “Detergents and Emulsifiers Annual”, MC Publ. Corp.,Ridgewood N.J.; Sisley and Wood, “Encyclopedia of Surface ActiveAgents”, Chem. Publ. Co. Inc., N.Y. 1964; Schonfeldt,“Grenzflächenaktive Athylenoxid-addukte” [Interface-active EthyleneOxide Adducts], Wiss. Verlagsgesell., Stuttgart 1976; Winnacker-Küchler,“Chemische Technologic”, volume 7, C Hanser Verlag Munich, 4th Ed. 1986.

On the basis of these formulations, it is also possible to producecombinations with other active compounds, for example insecticides,acaricides, herbicides, fungicides, and also with safeners, fertilizersand/or growth regulators, for example in the form of a finishedformulation or as a tank mix.

Active compounds which can be employed in combination with the compoundsaccording to the invention in mixed formulations or in the tank mix are,for example, known active compounds which are based on the inhibitionof, for example, acetolactate synthase, acetyl-CoA carboxylase,cellulose synthase, enolpyruvylshikimate-3-phosphate synthase, glutaminesynthetase, p-hydroxyphenylpyruvate dioxygenase, phytoene desaturase,photosystem I, photosystem II or protoporphyrinogen oxidase, as aredescribed in, for example, Weed Research 26 (1986) 441-445 or “ThePesticide Manual”, 16th edition, The British Crop Protection Council andthe Royal Soc. of Chemistry, 2006 and the literature cited therein.Known herbicides or plant growth regulators which can be combined withthe compounds according to the invention are, for example, thefollowing, where said active compounds are designated either with their“common name” in accordance with the International Organization forStandardization (ISO) or with the chemical name or with the code number.They always encompass all of the application forms such as, for example,acids, salts, esters and also all isomeric forms such as stereoisomersand optical isomers, even if they are not explicitly mentioned.

Examples of such herbicidal mixing partners are:

acetochlor, acifluorfen, acifluorfen-sodium, aclonifen, alachlor,allidochlor, alloxydim, alloxydim-sodium, ametryn, amicarbazone,amidochlor, amidosulfuron, aminocyclopyrachlor,aminocyclopyrachlor-potassium, aminocyclopyrachlor-methyl, aminopyralid,amitrole, ammonium sulfamate, anilofos, asulam, atrazine, azafenidin,azimsulfuron, beflubutamid, benazolin, benazolin-ethyl, benfluralin,benfuresate, bensulfuron, bensulfuron-methyl, bensulide, bentazone,benzobicyclon, benzofenap, bicyclopyron, bifenox, bilanafos,bilanafos-sodium, bispyribac, bispyribac-sodium, bromacil, bromobutide,bromofenoxim, bromoxynil, bromoxynil-butyrate, -potassium, -heptanoateand -octanoate, busoxinone, butachlor, butafenacil, butamifos,butenachlor, butralin, butroxydim, butylate, cafenstrole, carbetamide,carfentrazone, carfentrazone-ethyl, chloramben, chlorbromuron,chlorfenac, chlorfenac-sodium, chlorfenprop, chlorflurenol,chlorflurenol-methyl, chloridazon, chlorimuron, chlorimuron-ethyl,chlorophthalim, chlorotoluron, chlorthal-dimethyl, chlorsulfuron,3-[5-chloro-4-(trifluoromethyl)pyridin-2-yl]-4-hydroxy-1-methylimidazolidin-2-one,cinidon, cinidon-ethyl, cinmethylin, cinosulfuron, clacyfos, clethodim,clodinafop, clodinafop-propargyl, clomazone, clomeprop, clopyralid,cloransulam, cloransulam-methyl, cumyluron, cyanamide, cyanazine,cycloate, cyclopyranil, cyclopyrimorate, cyclosulfamuron, cycloxydim,cyhalofop, cyhalofop-butyl, cyprazine, 2,4-D, 2,4-D-butotyl, -butyl,-dimethylammonium, -diolamin, -ethyl, 2-ethylhexyl, -isobutyl,-isooctyl, -isopropylammonium, -potassium, -triisopropanolammonium and-trolamine, 2,4-DB, 2,4-DB-butyl, -dimethylammonium, isooctyl,-potassium and -sodium, daimuron (dymron), dalapon, dazomet, n-decanol,desmedipham, detosyl-pyrazolate (DTP), dicamba, dichlobenil,2-(2,4-dichlorobenzyl)-4,4-dimethyl-1,2-oxazolidin-3-one,2-(2,5-dichlorobenzyl)-4,4-dimethyl-1,2-oxazolidin-3-one, dichlorprop,dichlorprop-P, diclofop, diclofop-methyl, diclofop-P-methyl, diclosulam,difenzoquat, diflufenican, diflufenzopyr, diflufenzopyr-sodium,dimefuron, dimepiperate, dimethachlor, dimethametryn, dimethenamid,dimethenamid-P, dimetrasulfuron, dinitramine, dinoterb, diphenamid,diquat, diquat-dibromid, dithiopyr, diuron, DNOC, endothal, EPTC,esprocarb, ethalfluralin, ethametsulfuron, ethametsulfuron-methyl,ethiozin, ethofumesate, ethoxyfen, ethoxyfen-ethyl, ethoxysulfuron,etobenzanid, F-9600, F-5231, i.e.N-[2-chloro-4-fluoro-5-[4-(3-fluoropropyl)-4,5-dihydro-5-oxo-1H-tetrazol-1-yl]-phenyl]ethanesulfonamide, F-7967, i.e.3-[7-chloro-5-fluoro-2-(trifluoromethyl)-1H-benzimidazol-4-yl]-1-methyl-6-(trifluoromethyl)pyrimidine-2,4(1H,3H)-dione,fenoxaprop, fenoxaprop-P, fenoxaprop-ethyl, fenoxaprop-P-ethyl,fenoxasulfone, fenquinotrione, fentrazamide, flamprop,flamprop-M-isopropyl, flamprop-M-methyl, flazasulfuron, florasulam,florpyrauxifen, florpyrauxifen-benzyl, fluazifop, fluazifop-P,fluazifop-butyl, fluazifop-P-butyl, flucarbazone, flucarbazone-sodium,flucetosulfuron, fluchloralin, flufenacet, flufenpyr, flufenpyr-ethyl,flumetsulam, flumiclorac, flumiclorac-pentyl, flumioxazin, fluometuron,flurenol, flurenol-butyl, -dimethylammonium and -methyl, fluoroglycofen,fluoroglycofen-ethyl, flupropanate, flupyrsulfuron,flupyrsulfuron-methyl-sodium, fluridone, flurochloridone, fluroxypyr,fluroxypyr-meptyl, flurtamone, fluthiacet, fluthiacet-methyl, fomesafen,fomesafen-sodium, foramsulfuron, fosamine, glufosinate,glufosinate-ammonium, glufosinate-P-sodium, glufosinate-P-ammonium,glufosinate-P-sodium, glyphosate, glyphosate-ammonium,-isopropylammonium, -diammonium, -dimethylammonium, -potassium, -sodiumand -trimesium, H-9201, i.e. 0-(2,4-dimethyl-6-nitrophenyl) O-ethylisopropylphosphoramidothioate, halauxifen, halauxifen-methyl, halosafen,halosulfuron, halosulfuron-methyl, haloxyfop, haloxyfop-P,haloxyfop-ethoxyethyl, haloxyfop-P-ethoxy ethyl, haloxyfop-methyl,haloxyfop-P-methyl, hexazinone, HW-02, i.e. 1-(dimethoxyphosphoryl)ethyl(2,4-dichlorophenoxy)acetate,4-hydroxy-1-methoxy-5-methyl-3-[4-(trifluoromethyl)pyridin-2-yl]imidazolidin-2-one,4-hydroxy-1-methyl-3-[4-(trifluoromethyl)pyridin-2-yl]imidazolidin-2-one,imazamethabenz, imazamethabenz-methyl, imazamox, imazamox-ammonium,imazapic, imazapic-ammonium, imazapyr, imazapyr-isopropylammonium,imazaquin, imazaquin-ammonium, imazethapyr, imazethapyr-ammonium,imazosulfuron, indanofan, indaziflam, iodosulfuron,iodosulfuron-methyl-sodium, ioxynil, ioxynil-octanoate, -potassium andsodium, ipfencarbazone, isoproturon, isouron, isoxaben, isoxaflutole,karbutilate, KUH-043, i.e.3-({[5-(difluoromethyl)-1-methyl-3-(trifluoromethyl)-1H-pyrazol-4-yl]methyl}sulfonyl)-5,5-dimethyl-4,5-dihydro-1,2-oxazole,ketospiradox, lactofen, lenacil, linuron, MCPA, MCPA-butotyl,-dimethylammonium, -2-ethylhexyl, -isopropylammonium, -potassium and-sodium, MCPB, MCPB-methyl, -ethyl and -sodium, mecoprop,mecoprop-sodium and -butotyl, mecoprop-P, mecoprop-P-butotyl,-dimethylammonium, -2-ethylhexyl and -potassium, mefenacet, mefluidide,mesosulfuron, mesosulfuron-methyl, mesotrione, methabenzthiazuron,metam, metamifop, metamitron, metazachlor, metazosulfuron,methabenzthiazuron, methiopyrsulfuron, methiozolin, methylisothiocyanate, metobromuron, metolachlor, S-metolachlor, metosulam,metoxuron, metribuzin, metsulfuron, metsulfuron-methyl, molinate,monolinuron, monosulfuron, monosulfuron esters, MT-5950, i.e.N-[3-chloro-4-(1-methylethyl)-phenyl]-2-methylpentanamide, NGGC-011,napropamide, NC-310, i.e.4-(2,4-dichlorobenzoyl)-1-methyl-5-benzyloxypyrazole, neburon,nicosulfuron, nonanoic acid (pelargonic acid), norflurazon, oleic acid(fatty acids), orbencarb, orthosulfamuron, oryzalin, oxadiargyl,oxadiazon, oxasulfuron, oxaziclomefon, oxotrione (lancotrione),oxyfluorfen, paraquat, paraquat dichloride, pebulate, pendimethalin,penoxsulam, pentachlorphenol, pentoxazone, pethoxamid, petroleum oils,phenmedipham, picloram, picolinafen, pinoxaden, piperophos,pretilachlor, primisulfuron, primisulfuron-methyl, prodiamine,profoxydim, prometon, prometryn, propachlor, propanil, propaquizafop,propazine, propham, propisochlor, propoxycarbazone,propoxycarbazone-sodium, propyrisulfuron, propyzamide, prosulfocarb,prosulfuron, pyraclonil, pyraflufen, pyraflufen-ethyl, pyrasulfotole,pyrazolynate (pyrazolate), pyrazosulfuron, pyrazosulfuron-ethyl,pyrazoxyfen, pyribambenz, pyribambenz-isopropyl, pyribambenz-propyl,pyribenzoxim, pyributicarb, pyridafol, pyridate, pyriftalid,pyriminobac, pyriminobac-methyl, pyrimisulfan, pyrithiobac,pyrithiobac-sodium, pyroxasulfone, pyroxsulam, quinclorac, quinmerac,quinoclamine, quizalofop, quizalofop-ethyl, quizalofop-P,quizalofop-P-ethyl, quizalofop-P-tefuryl, rimsulfuron, saflufenacil,sethoxydim, siduron, simazine, simetryn, sulcotrion, sulfentrazone,sulfometuron, sulfometuron-methyl, sulfosulfuron, SYN-523, SYP-249, i.e.1-ethoxy-3-methyl-1-oxobut-3-en-2-yl5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrobenzoate, SYP-300, i.e.1-[7-fluoro-3-oxo-4-(prop-2-yn-1-yl)-3,4-dihydro-2H-1,4-benzoxazin-6-yl]-3-propyl-2-thioxoimidazolidine-4,5-dione,2,3,6-TBA, TCA (trifluoroacetic acid), TCA-sodium, tebuthiuron,tefuryltrione, tembotrione, tepraloxydim, terbacil, terbucarb,terbumeton, terbuthylazin, terbutryn, thenylchlor, thiazopyr,thiencarbazone, thiencarbazone-methyl, thifensulfuron,thifensulfuron-methyl, thiobencarb, tiafenacil, tolpyralate,topramezone, tralkoxydim, triafamone, tri-allate, triasulfuron,triaziflam, tribenuron, tribenuron-methyl, triclopyr, trietazine,trifloxysulfuron, trifloxysulfuron-sodium, trifludimoxazin, trifluralin,triflusulfuron, triflusulfuron-methyl, tritosulfuron, urea sulfate,vernolate, ZJ-0862, i.e.3,4-dichloro-N-{2-[(4,6-dimethoxypyrimidin-2-yl)oxy]benzyl}aniline, andalso the following compounds:

Examples of plant growth regulators as possible mixing partners are:

acibenzolar, acibenzolar-S-methyl, 5-aminolevulinic acid, ancymidol,6-benzylaminopurine, brassinolide, catechol, chlormequat chloride,cloprop, cyclanilide, 3-(cycloprop-1-enyl)propionic acid, daminozide,dazomet, n-decanol, dikegulac, dikegulac-sodium, endothal,endothal-dipotassium, -disodium, and mono(N,N-dimethylalkylammonium),ethephon, flumetralin, flurenol, flurenol-butyl, flurprimidol,forchlorfenuron, gibberellic acid, inabenfide, indole-3-acetic acid(IAA), 4-indol-3-ylbutyric acid, isoprothiolane, probenazole, jasmonicacid, jasmonic acid methyl ester, maleic hydrazide, mepiquat chloride,1-methylcyclopropene, 2-(1-naphthyl)acetamide, 1-naphthylacetic acid,2-naphthyloxyacetic acid, nitrophenolate mixture,4-oxo-4[(2-phenylethyl)amino]butyric acid, paclobutrazole,N-phenylphthalamic acid, prohexadione, prohexadione-calcium,prohydrojasmone, salicylic acid, strigolactone, tecnazene, thidiazuron,triacontanol, trinexapac, trinexapac-ethyl, tsitodef, uniconazole,uniconazole-P.

Safeners which can be employed in combination with the compounds of theformula (I) according to the invention and optionally in combinationwith further active compounds such as insecticides, acaricides,herbicides, fungicides as listed above are preferably selected from thegroup consisting of:

S1) Compounds of the formula (S1)

where the symbols and indices have the meanings below:n_(A) represents a natural number from 0 to 5, preferably from 0 to 3;R_(A) ¹ represents halogen, (C₁-C₄)-alkyl, (C₁-C₄)-alkoxy, nitro or(C₁-C₄)-haloalkyl;W_(A) represents an unsubstituted or substituted divalent heterocyclicradical from the group of the partially unsaturated or aromaticfive-membered heterocycles having 1 to 3 ring heteroatoms from the N andO group, where at least one nitrogen atom and at most one oxygen atom ispresent in the ring, preferably a radical from the group of (W_(A) ¹) to(W_(A) ⁴),m_(A) represents 0 or 1;

R_(A) ² represents OR_(A) ³, SR_(A) ³ or NR_(A) ³R_(A) ⁴ or a saturatedor unsaturated 3- to 7-membered heterocycle having at least one nitrogenatom and up to 3 heteroatoms, preferably from the group consisting of 0and S, which is joined to the carbonyl group in (S1) via the nitrogenatom and is unsubstituted or substituted by radicals from the groupconsisting of (C₁-C₄)-alkyl, (C₁-C₄)-alkoxy or optionally substitutedphenyl, preferably a radical of the formula OR_(A) ³, NHRA⁴ or N(CH₃)₂,especially of the formula OR_(A) ³;R_(A) ³ represents hydrogen or an unsubstituted or substituted aliphatichydrocarbon radical, preferably having a total of 1 to 18 carbon atoms;R_(A) ⁴ represents hydrogen, (C₁-C₆)-alkyl, (C₁-C₆)-alkoxy orsubstituted or unsubstituted phenyl;R_(A) ⁵ represents H, (C₁-C₈)-alkyl, (C₁-C₈)-haloalkyl,(C₁-C₄)-alkoxy-(C₁-C₈)-alkyl, cyano or COORA⁹, where R_(A) ⁹ representshydrogen, (C₁-C₈)-alkyl, (C₁-C₈)-haloalkyl,(C₁-C₄)-alkoxy-(C₁-C₄)-alkyl, (C₁-C₆)-hydroxyalkyl, (C₃-C₁₂)-cycloalkylor tri-(C₁-C₄)-alkylsilyl;R_(A) ⁶, R_(A) ⁷, R_(A) ⁸ are identical or different and representhydrogen, (C₁-C₈)-alkyl, (C₁-C₈)-haloalkyl, (C₃-C₁₂)-cycloalkyl orsubstituted or unsubstituted phenyl;preferably:a) compounds of the dichlorophenylpyrazoline-3-carboxylic acid type(S1^(a)), preferably compounds such as1-(2,4-dichlorophenyl)-5-(ethoxycarbonyl)-5-methyl-2-pyrazoline-3-carboxylicacid, ethyl1-(2,4-dichlorophenyl)-5-(ethoxycarbonyl)-5-methyl-2-pyrazoline-3-carboxylate(S1-1) (“mefenpyr-diethyl”), and related compounds as described inWO-A-91/07874;b) derivatives of dichlorophenylpyrazolecarboxylic acid (S1^(b)),preferably compounds such as ethyl1-(2,4-dichlorophenyl)-5-methylpyrazole-3-carboxylate (S1-2), ethyl1-(2,4-dichlorophenyl)-5-isopropylpyrazole-3-carboxylate (S1-3), ethyl1-(2,4-dichlorophenyl)-5-(1,1-dimethylethyl)pyrazole-3-carboxylate(S1-4) and related compounds as described in EP-A-333 131 and EP-A-269806;c) derivatives of 1,5-diphenylpyrazole-3-carboxylic acid (Sic),preferably compounds such as ethyl1-(2,4-dichlorophenyl)-5-phenylpyrazole-3-carboxylate (S1-5), methyl1-(2-chlorophenyl)-5-phenylpyrazole-3-carboxylate (S1-6) and relatedcompounds as described in EP-A-268 554, for example;d) compounds of the triazolecarboxylic acid type (S1^(d)), preferablycompounds such as fenchlorazole(-ethyl ester), i.e. ethyl1-(2,4-dichlorophenyl)-5-trichloromethyl-(1H)-1,2,4-triazole-3-carboxylate(S1-7), and related compounds as described in EP-A-174 562 and EP-A-346620;e) compounds of the 5-benzyl- or 5-phenyl-2-isoxazoline-3-carboxylicacid or of the 5,5-diphenyl-2-isoxazoline-3-carboxylic acid type (S1e),preferably compounds such as ethyl5-(2,4-dichlorobenzyl)-2-isoxazoline-3-carboxylate (S1-8) or ethyl5-phenyl-2-isoxazoline-3-carboxylate (S1-9) and related compounds asdescribed in WO-A-91/08202, or 5,5-diphenyl-2-isoxazoline-3-carboxylicacid (S1-10) or ethyl 5,5-diphenyl-2-isoxazoline-3-carboxylate (S1-11)(“isoxadifen-ethyl”) or n-propyl5,5-diphenyl-2-isoxazoline-3-carboxylate (S1-12) or ethyl5-(4-fluorophenyl)-5-phenyl-2-isoxazoline-3-carboxylate (S1-13), asdescribed in patent application WO-A-95/07897.S2) Quinoline derivatives of the formula (S2)

where the symbols and indices have the meanings below:R_(B) ¹ represents halogen, (C₁-C₄)-alkyl, (C₁-C₄)-alkoxy, nitro or(C₁-C₄)-haloalkyl;n_(B) represents a natural number from 0 to 5, preferably from 0 to 3;R_(B) ² represents OR_(B) ³, SR_(B) ³ or NR_(B) ³R_(B) ⁴ or a saturatedor unsaturated 3- to 7-membered heterocycle having at least one nitrogenatom and up to 3 heteroatoms, preferably from the group of O and S,which is joined via the nitrogen atom to the carbonyl group in (S2) andis unsubstituted or substituted by radicals from the group of(C₁-C₄)-alkyl, (C₁-C₄)-alkoxy or optionally substituted phenyl,preferably a radical of the formula OR_(B) ³, NHR_(B) ⁴ or N(CH₃)₂,especially of the formula OR_(B) ³;R_(B) ³ represents hydrogen or an unsubstituted or substituted aliphatichydrocarbon radical, preferably having a total of 1 to 18 carbon atoms;R_(B) ⁴ represents hydrogen, (C₁-C₆)-alkyl, (C₁-C₆)-alkoxy orsubstituted or unsubstituted phenyl;T_(B) represents a (C₁ or C₂)-alkanediyl chain which is unsubstituted orsubstituted by one or two (C₁-C₄)-alkyl radicals or by[(C₁-C₃)-alkoxy]carbonyl;preferably:a) compounds of the 8-quinolinoxyacetic acid type (S2a), preferably

-   1-methylhexyl (5-chloro-8-quinolinoxy)acetate (“cloquintocet-mexyl”)    (S2-1),-   (1,3-dimethylbut-1-yl) (5-chloro-8-quinolinoxy)acetate (S2-2),-   4-allyloxybutyl (5-chloro-8-quinolinoxy)acetate (S2-3),-   1-allyloxyprop-2-yl (5-chloro-8-quinolinoxy)acetate (S2-4),-   ethyl (5-chloro-8-quinolinoxy)acetate (S2-5),-   methyl (5-chloro-8-quinolinoxy)acetate (S2-6),-   allyl (5-chloro-8-quinolinoxy)acetate (S2-7),    2-(2-propylideneiminoxy)-1-ethyl (5-chloro-8-quinolinoxy)acetate    (S2-8), 2-oxoprop-1-yl (5-chloro-8-quinolinoxy)acetate (S2-9) and    related compounds, as described in EP-A-86 750, EP-A-94 349 and    EP-A-191 736 or EP-A-0 492 366, and also    (5-chloro-8-quinolinoxy)acetic acid (S2-10), hydrates and salts    thereof, for example the lithium, sodium, potassium, calcium,    magnesium, aluminum, iron, ammonium, quaternary ammonium, sulfonium    or phosphonium salts thereof, as described in WO-A-2002/34048;    b) compounds of the (5-chloro-8-quinolinoxy)malonic acid type    (S2^(b)), preferably compounds such as diethyl    (5-chloro-8-quinolinoxy)malonate, diallyl    (5-chloro-8-quinolinoxy)malonate, methyl ethyl    (5-chloro-8-quinolinoxy)malonate and related compounds, as described    in EP-A-0 582 198.    S3) Compounds of the formula (S3)

where the symbols and indices are defined as follows:R_(C) ¹ represents (C₁-C₄)-alkyl, (C₁-C₄)-haloalkyl, (C₂-C₄)-alkenyl,(C₂-C₄)-haloalkenyl, (C₃-C₇)-cycloalkyl, preferably dichloromethyl;R_(C) ², R_(C) ³ are identical or different and represent hydrogen,(C₁-C₄)alkyl, (C₂-C₄)alkenyl, (C₂-C₄)alkynyl, (C₁-C₄)haloalkyl,(C₂-C₄)haloalkenyl, (C₁-C₄)alkylcarbamoyl-(C₁-C₄)alkyl,(C₂-C₄)alkenylcarbamoyl-(C₁-C₄)alkyl, (C₁-C₄)alkoxy-(C₁-C₄)alkyl,dioxolanyl-(C₁-C₄)alkyl, thiazolyl, furyl, furylalkyl, thienyl,piperidyl, substituted or unsubstituted phenyl, or R_(C) ² and R_(C) ³together form a substituted or unsubstituted heterocyclic ring,preferably an oxazolidine, thiazolidine, piperidine, morpholine,hexahydropyrimidine or benzoxazine ring;preferably:

active compounds of the dichloroacetamide type, which are frequentlyused as pre-emergence safeners (soil-acting safeners), for example

-   “dichlormid” (N,N-diallyl-2,2-dichloroacetamide) (S3-1),-   “R-29148” (3-dichloroacetyl-2,2,5-trimethyl-1,3-oxazolidine) from    Stauffer (S3-2),-   “R-28725” (3-dichloroacetyl-2,2-dimethyl-1,3-oxazolidine) from    Stauffer (S3-3),-   “benoxacor”    (4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine) (S3-4),-   “PPG-1292” (N-allyl-N-[(1,3-dioxolan-2-yl)methyl]dichloroacetamide)    from PPG Industries (S3-5),-   “DKA-24” (N-allyl-N-[(allylaminocarbonyl)methyl]dichloroacetamide)    from Sagro-Chem (S3-6),-   “AD-67” or “MON 4660” (3-dichloroacetyl-1-oxa-3-azaspiro[4.5]decane)    from Nitrokemia or Monsanto (S3-7),-   “TI-35” (1-dichloroacetylazepane) from TRI-Chemical RT (S3-8),-   “diclonon” (dicyclonon) or “BAS145138” or “LAB145138” (S3-9)-   ((RS)-1-dichloroacetyl-3,3,8a-trimethylperhydropyrrolo[1,2-a]pyrimidin-6-one)    from BASF,-   “furilazole” or “MON 13900”    ((RS)-3-dichloroacetyl-5-(2-furyl)-2,2-dimethyloxazolidine) (S3-10);    and the (R) isomer thereof (S3-11).    S4) N-acylsulfonamides of the formula (S4) and salts thereof,

in which the symbols and indices are defined as follows:A_(D) represents SO₂—NR_(D) ²—CO or CO—NR_(D) ³⁻SO₂X_(D) represents CH or N;R_(D) ¹ represents CO—NR_(D) ⁵R_(D) ⁶ or NHCO—R_(D) ⁷;R_(D) ² represents halogen, (C₁-C₄)-haloalkyl, (C₁-C₄)-haloalkoxy,nitro, (C₁-C₄)-alkyl, (C₁-C₄)-alkoxy, (C₁-C₄)-alkylsulfonyl,(C₁-C₄)-alkoxycarbonyl or (C₁-C₄)-alkylcarbonyl;R_(D) ³ represents hydrogen, (C₁-C₄)-alkyl, (C₂-C₄)-alkenyl or(C₂-C₄)-alkynyl;R_(D) ⁴ represents halogen, nitro, (C₁-C₄)-alkyl, (C₁-C₄)-haloalkyl,(C₁-C₄)-haloalkoxy, (C₃-C₆)-cycloalkyl, phenyl, (C₁-C₄)-alkoxy, cyano,(C₁-C₄)-alkylthio, (C₁-C₄)-alkylsulfinyl, (C₁-C₄)-alkylsulfonyl,(C₁-C₄)-alkoxycarbonyl or (C₁-C₄)-alkylcarbonyl;R_(D) ⁵ represents hydrogen, (C₁-C₆)-alkyl, (C₃-C₆)-cycloalkyl,(C₂-C₆)-alkenyl, (C₂-C₆)-alkynyl, (C₅-C₆)-cycloalkenyl, phenyl or 3- to6-membered heterocyclyl containing v_(D) heteroatoms from the groupconsisting of nitrogen, oxygen and sulfur, where the seven latterradicals are substituted by v_(D) substituents from the group consistingof halogen, (C₁-C₆)-alkoxy, (C₁-C₆)-haloalkoxy, (C₁-C₂)-alkylsulfinyl,(C₁-C₂)-alkylsulfonyl, (C₃-C₆)-cycloalkyl, (C₁-C₄)-alkoxycarbonyl,(C₁-C₄)-alkylcarbonyl and phenyl and, in the case of cyclic radicals,also (C₁-C₄)-alkyl and (C₁-C₄)-haloalkyl;R_(D) ⁶ represents hydrogen, (C₁-C₆)-alkyl, (C₂-C₆)-alkenyl or(C₂-C₆)-alkynyl, where the three latter radicals are substituted byv_(D) radicals from the group consisting of halogen, hydroxyl,(C₁-C₄)-alkyl, (C₁-C₄)-alkoxy and (C₁-C₄)-alkylthio, orR_(D) ⁵ and R_(D) ⁶ together with the nitrogen atom carrying them form apyrrolidinyl or piperidinyl radical;R_(D) ¹ represents hydrogen, (C₁-C₄)-alkylamino, di-(C₁-C₄)-alkylamino,(C₁-C₆)-alkyl, (C₃-C₆)-cycloalkyl, where the 2 latter radicals aresubstituted by v_(D) substituents from the group consisting of halogen,(C₁-C₄)-alkoxy, (C₁-C₆)-haloalkoxy and (C₁-C₄)-alkylthio and, in thecase of cyclic radicals, also (C₁-C₄)-alkyl and (C₁-C₄)-haloalkyl;n_(D) represents 0, 1 or 2;m_(D) represents 1 or 2;v_(D) represents 0, 1, 2 or 3;among these, preference is given to compounds of the N-acylsulfonamidetype, for example of the formula (S4a) below, which are known, forexample, from WO-A-97/45016

in whichR_(D) ⁷ represents (C₁-C₆)-alkyl, (C₃-C₆)-cycloalkyl, where the 2 latterradicals are substituted by v_(D) substituents from the group consistingof halogen, (C₁-C₄)-alkoxy, (C₁-C₆)-haloalkoxy and (C₁-C₄)-alkylthioand, in the case of cyclic radicals, also (C₁-C₄)-alkyl and(C₁-C₄)-haloalkyl;R_(D) ⁴ represents halogen, (C₁-C₄)-alkyl, (C₁-C₄)-alkoxy, CF₃;m_(D) represents 1 or 2;v_(D) represents 0, 1, 2 or 3;and alsoacylsulfamoylbenzamides, for example of the formula (S4^(b)) below,which are known, for example, from WO-A-99/16744,

e.g. those in whichR_(D) ⁵=cyclopropyl and (R_(D) ⁴)=2-OMe (“cyprosulfamide”, S4-1),R_(D) ⁵=cyclopropyl and (R_(D) ⁴)=5-Cl-2-OMe (S4-2),R_(D) ⁵=ethyl and (R_(D) ⁴)=2-OMe (S4-3),R_(D) ⁵=isopropyl and (R_(D) ⁴)=5-Cl-2-OMe (S4-4) andR_(D) ⁵=isopropyl and (R_(D) ⁴)=2-OMe (S4-5)and alsocompounds of the N-acylsulfamoylphenylurea type, of the formula (S4c),which are known, for example, from EP-A-365484,

in whichR_(D) ⁸ and R_(D) ⁹ independently of one another represent hydrogen,(C₁-C₈)-alkyl, (C₃-C₈)-cycloalkyl, (C₃-C₆)-alkenyl, (C₃-C₆)-alkynyl,R_(D) ⁴ represents halogen, (C₁-C₄)-alkyl, (C₁-C₄)-alkoxy, CF₃,m_(D) represents 1 or 2;for example

-   1-[4-(N-2-methoxybenzoylsulfamoyl)phenyl]-3-methylurea    (“metcamifen”, S4-6),-   1-[4-(N-2-methoxybenzoylsulfamoyl)phenyl]-3,3-dimethylurea,-   1-[4-(N-4,5-dimethylbenzoylsulfamoyl)phenyl]-3-methylurea,    and also    N-phenylsulfonylterephthalamides of the formula (S4^(d)), which are    known, for example, from CN 101838227,

e.g. those in whichR_(D) ⁴ represents halogen, (C₁-C₄)-alkyl, (C₁-C₄)-alkoxy, CF₃;m_(D) represents 1 or 2;R_(D) ⁵ represents hydrogen, (C₁-C₆)-alkyl, (C₃-C₆)-cycloalkyl,(C₂-C₆)-alkenyl, (C₂-C₆)-alkynyl, (C₅-C₆)-cycloalkenyl.S5) Active compounds from the class of the hydroxyaromatics and thearomatic-aliphatic carboxylic acid derivatives (S5), for exampleethyl 3,4,5-triacetoxybenzoate, 3,5-dimethoxy-4-hydroxybenzoic acid,3,5-dihydroxybenzoic acid, 4-hydroxysalicylic acid, 4-fluorosalicylicacid, 2-hydroxycinnamic acid, 2,4-dichlorocinnamic acid, as described inWO-A-2004/084631, WO-A-2005/015994, WO-A-2005/016001.S6) Active compounds from the class of the 1,2-dihydroquinoxalin-2-ones(S6), for example1-methyl-3-(2-thienyl)-1,2-dihydroquinoxalin-2-one,1-methyl-3-(2-thienyl)-1,2-dihydroquinoxaline-2-thione,1-(2-aminoethyl)-3-(2-thienyl)-1,2-dihydroquinoxalin-2-onehydrochloride,1-(2-methylsulfonylaminoethyl)-3-(2-thienyl)-1,2-dihydroquinoxalin-2-one,as described in WO-A-2005/112630.S7) Compounds of the formula (S7), as described in WO-A-1998/38856,

in which the symbols and indices are defined as follows:R_(E) ¹, R_(E) ² independently of one another are halogen,(C₁-C₄)-alkyl, (C₁-C₄)-alkoxy, (C₁-C₄)-haloalkyl, (C₁-C₄)-alkylamino,di-(C₁-C₄)-alkylamino, nitro;A_(E) represents COOR_(E) ³ or COSR_(E) ⁴R_(E) ³, R_(E) ⁴ independently of one another are hydrogen,(C₁-C₄)-alkyl, (C₂-C₆)-alkenyl, (C₂-C₄)-alkynyl, cyanoalkyl,(C₁-C₄)-haloalkyl, phenyl, nitrophenyl, benzyl, halobenzyl,pyridinylalkyl and alkylammonium,n_(E) ¹ represents 0 or 1n_(E) ², n_(E) ³ independently of one another are 0, 1 or 2,preferably:diphenylmethoxyacetic acid,ethyl diphenylmethoxyacetate,methyl diphenylmethoxyacetate (CAS reg. no. 41858-19-9) (S7-1).S8) Compounds of the formula (S8), as described in WO-A-98/27,049,in which

X_(F) represents CH or N,n_(F) in the case that X_(F)═N represents an integer from 0 to 4 and

-   -   in the case that X_(F)═CH represents an integer from 0 to 5,        R_(F) ¹ represents halogen, (C₁-C₄)-alkyl, (C₁-C₄)-haloalkyl,        (C₁-C₄)-alkoxy, (C₁-C₄)-haloalkoxy, nitro, (C₁-C₄)-alkylthio,        (C₁-C₄)-alkylsulfonyl, (C₁-C₄)-alkoxycarbonyl, optionally        substituted phenyl, optionally substituted phenoxy,        R_(F) ² represents hydrogen or (C₁-C₄)-alkyl,        R_(F) ³ represents hydrogen, (C₁-C₈)-alkyl, (C₂-C₄)-alkenyl,        (C₂-C₄)-alkynyl or aryl, where each of the abovementioned        carbon-containing radicals is unsubstituted or substituted by        one or more, preferably up to three identical or different        radicals from the group consisting of halogen and alkoxy; or        salts thereof, preferably compounds in which        X_(F) represents CH,        n_(F) represents an integer from 0 to 2,        R_(F) ¹ represents halogen, (C₁-C₄)-alkyl, (C₁-C₄)-haloalkyl,        (C₁-C₄)-alkoxy, (C₁-C₄)-haloalkoxy,        R_(F) ² represents hydrogen or (C₁-C₄)-alkyl,        R_(F) ³ represents hydrogen, (C₁-C₈)-alkyl, (C₂-C₄)-alkenyl,        (C₂-C₄)-alkynyl or aryl, where each of the abovementioned        carbon-containing radicals is unsubstituted or substituted by        one or more, preferably up to three identical or different        radicals from the group consisting of halogen and alkoxy,        or salts thereof.        S9) Active compounds from the class of the        3-(5-tetrazolylcarbonyl)-2-quinolones (S9), for example        1,2-dihydro-4-hydroxy-1-ethyl-3-(5-tetrazolylcarbonyl)-2-quinolone        (CAS reg. no. 219479-18-2),        1,2-dihydro-4-hydroxy-1-methyl-3-(5-tetrazolylcarbonyl)-2-quinolone        (CAS Reg. No. 95855-00-8), as described in WO-A-1999/000020.        S10) Compounds of the formulae (S10″) or (S10′)    -   as described in WO-A-2007/023719 and WO-A-2007/023764

in whichR_(G) ¹ represents halogen, (C₁-C₄)-alkyl, methoxy, nitro, cyano, CF₃,OCF₃,Y_(G), Z_(G) independently of one another represent O or S,n_(G) represents an integer from 0 to 4,R_(G) ² represents (C₁-C₁₆)-alkyl, (C₂-C₆)-alkenyl, (C₃-C₆)-cycloalkyl,aryl; benzyl, halobenzyl,R_(G) ³ represents hydrogen or (C₁-C₆)-alkyl.S11) Active compounds of the oxyimino compounds type (S11), which areknown as seed-dressing agents, for example“oxabetrinil” ((Z)-1,3-dioxolan-2-ylmethoxyimino(phenyl)acetonitrile)(S11-1), which is known as a seed-dressing safener for millet/sorghumagainst metolachlor damage,“fluxofenim” (1-(4-chlorophenyl)-2,2,2-trifluoro-1-ethanoneO-(1,3-dioxolan-2-ylmethyl)oxime) (S11-2), which is known as aseed-dressing safener for millet/sorghum against metolachlor damage, and“cyometrinil” or “CGA-43089” ((Z)-cyanomethoxyimino(phenyl)acetonitrile)(S11-3), which is known as a seed-dressing safener for millet/sorghumagainst metolachlor damage.S12) Active compounds from the class of the isothiochromanones (S12),for example methyl[(3-oxo-1H-2-benzothiopyran-4(3H)-ylidene)methoxy]acetate (CAS Reg. No.205121-04-6) (S12-1) and related compounds from WO-A-1998/13361.S13) One or more compounds from group (S13):“naphthalic anhydride” (1,8-naphthalenedicarboxylic anhydride) (513-1),which is known as a seed-dressing safener for corn against thiocarbamateherbicide damage,“fenclorim” (4,6-dichloro-2-phenylpyrimidine) (S13-2), which is known asa safener for pretilachlor in sown rice,“flurazole” (benzyl2-chloro-4-trifluoromethyl-1,3-thiazole-5-carboxylate) (S13-3), which isknown as a seed-dressing safener for millet/sorghum against alachlor andmetolachlor damage,“CL 304415” (CAS Reg. No. 31541-57-8)(4-carboxy-3,4-dihydro-2H-1-benzopyran-4-acetic acid) (S13-4) fromAmerican Cyanamid, which is known as a safener for corn against damageby imidazolinones,“MG 191” (CAS Reg. No. 96420-72-3)(2-dichloromethyl-2-methyl-1,3-dioxolane) (S13-5) from Nitrokemia, whichis known as a safener for corn,“MG 838” (CAS Reg. No. 133993-74-5)(2-propenyl 1-oxa-4-azaspiro[4.5]decane-4-carbodithioate) (S13-6) fromNitrokemia,“disulfoton” (0,0-diethyl S-2-ethylthioethylphosphorodithioate) (S13-7),“dietholate” (0,0-diethyl 0-phenyl phosphorothioate) (513-8),“mephenate” (4-chlorophenyl methylcarbamate) (S13-9).S14) Active compounds which, in addition to herbicidal action againstharmful plants, also have safener action on crop plants such as rice,for example“dimepiperate” or “MY 93” (S-1-methyl1-phenylethylpiperidine-1-carbothioate), which is known as a safener forrice against damage by the herbicide molinate,“daimuron” or “SK 23” (1-(1-methyl-1-phenylethyl)-3-p-tolylurea), whichis known as a safener for rice against damage by the herbicideimazosulfuron,“cumyluron”=“JC 940”(3-(2-chlorophenylmethyl)-1-(1-methyl-1-phenylethyl)urea, seeJP-A-60087254), which is known as safener for rice against damage bysome herbicides,“methoxyphenone” or “NK 049” (3,3′-dimethyl-4-methoxybenzophenone),which is known as a safener for rice against damage by some herbicides,“CSB” (1-bromo-4-(chloromethylsulfonyl)benzene) from Kumiai, (CAS Reg.No. 54091-06-4), which is known as a safener against damage by someherbicides in rice.S15) Compounds of the formula (S15) or tautomers thereof.

as described in WO-A-2007/131861 and WO-A-2008/131860

-   -   in which        R_(H) ¹ represents a (C₁-C₆)-haloalkyl radical and        R_(H) ² represents hydrogen or halogen and        R_(H) ³, R_(H) ⁴ independently of one another represent        hydrogen, (C₁-C₁₆)-alkyl, (C₂-C₁₆)-alkenyl or (C₂-C₁₆)-alkynyl,        where each of the 3 latter radicals is unsubstituted or        substituted by one or more radicals from the group of halogen,        hydroxyl, cyano, (C₁-C₄)-alkoxy, (C₁-C₄)-haloalkoxy,        (C₁-C₄)-alkylthio, (C₁-C₄)-alkylamino, di[(C₁-C₄)-alkyl]amino,        [(C₁-C₄)-alkoxy]carbonyl, [(C₁-C₄)-haloalkoxy]carbonyl,        (C₃-C₆)-cycloalkyl which is unsubstituted or substituted, phenyl        which is unsubstituted or substituted, and heterocyclyl which is        unsubstituted or substituted,        or (C₃-C₆)-cycloalkyl, (C₄-C₆)-cycloalkenyl, (C₃-C₆)-cycloalkyl        fused on one side of the ring to a 4 to 6-membered saturated or        unsaturated carbocyclic ring, or (C₄-C₆)-cycloalkenyl fused on        one side of the ring to a 4 to 6-membered saturated or        unsaturated carbocyclic ring,        where each of the 4 latter radicals is unsubstituted or        substituted by one or more radicals from the group consisting of        halogen, hydroxyl, cyano, (C₁-C₄)-alkyl, (C₁-C₄)-haloalkyl,        (C₁-C₄)-alkoxy, (C₁-C₄)-haloalkoxy, (C₁-C₄)-alkylthio,        (C₁-C₄)-alkylamino, di[(C₁-C₄)-alkyl]amino,        [(C₁-C₄)-alkoxy]carbonyl, [(C₁-C₄)-haloalkoxy]carbonyl,        (C₃-C₆)-cycloalkyl which is unsubstituted or substituted, phenyl        which is unsubstituted or substituted, and heterocyclyl which is        unsubstituted or substituted,        or        R_(H) ³ represents (C₁-C₄)-alkoxy, (C₂-C₄)-alkenyloxy,        (C₂-C₆)-alkynyloxy or (C₂-C₄)-haloalkoxy and        R_(H) ⁴ represents hydrogen or (C₁-C₄)-alkyl or        R_(H) ³ and R_(H) ⁴ together with the directly attached nitrogen        atom represent a four- to eight-membered heterocyclic ring        which, as well as the nitrogen atom, may also contain further        ring heteroatoms, preferably up to two further ring heteroatoms        from the group of N, O and S, and which is unsubstituted or        substituted by one or more radicals from the group of halogen,        cyano, nitro, (C₁-C₄)-alkyl, (C₁-C₄)-haloalkyl, (C₁-C₄)-alkoxy,        (C₁-C₄)-haloalkoxy and (C₁-C₄)-alkylthio.        S16) Active compounds which are used primarily as herbicides but        also have safener action on crop plants, for example

-   (2,4-dichlorophenoxy)acetic acid (2,4-D),

-   (4-chlorophenoxy)acetic acid,

-   (R,S)-2-(4-chloro-o-tolyloxy)propionic acid (mecoprop),

-   4-(2,4-dichlorophenoxy)butyric acid (2,4-DB),

-   (4-chloro-o-tolyloxy)acetic acid (MCPA),

-   4-(4-chloro-o-tolyloxy)butyric acid,

-   4-(4-chlorophenoxy)butyric acid,

-   3,6-dichloro-2-methoxybenzoic acid (dicamba),

-   1-(ethoxycarbonyl)ethyl3,6-dichloro-2-methoxybenzoate    (lactidichlor-ethyl).

Particularly preferred safeners are mefenpyr-diethyl, cyprosulfamide,isoxadifen-ethyl, cloquintocet-mexyl, benoxacor, dichlormid andmetcamifen.

Wettable powders are preparations uniformly dispersible in water which,in addition to the active compound and apart from a diluent or inertsubstance, also comprise surfactants of ionic and/or nonionic type(wetting agent, dispersant), e.g. polyethoxylated alkylphenols,polyethoxylated fatty alcohols, polyethoxylated fatty amines, fattyalcohol polyglycolethersulfates, alkanesulfonates,alkylbenzenesulfonates, sodium lignosulfonate, sodium2,2′-dinaphthylmethane-6,6′-disulfonate, sodiumdibutylnaphthalenesulfonate or else sodium oleoylmethyltaurate. Toproduce the wettable powders, the herbicidally active compounds arefinely ground, for example in customary apparatuses such as hammermills, blower mills and air jet mills, and simultaneously orsubsequently mixed with the formulation auxiliaries.

Emulsifiable concentrates are produced by dissolving the active compoundin an organic solvent, for example butanol, cyclohexanone,dimethylformamide, xylene, or else relatively high-boiling aromatics orhydrocarbons or mixtures of the organic solvents, with addition of oneor more ionic and/or nonionic surfactants (emulsifiers). Examples ofemulsifiers which may be used are: calcium alkylarylsulfonates such ascalcium dodecylbenzenesulfonate, or nonionic emulsifiers such as fattyacid polyglycol esters, alkylaryl polyglycol ethers, fatty alcoholpolyglycol ethers, propylene oxide/ethylene oxide condensation products,alkyl polyethers, sorbitan esters, for example sorbitan fatty acidesters, or polyoxyethylene sorbitan esters, for example polyoxyethylenesorbitan fatty esters.

Dusting products are obtained by grinding the active compound withfinely distributed solids, for example talc, natural clays, such askaolin, bentonite and pyrophyllite, or diatomaceous earth.

Suspension concentrates may be water- or oil-based. They may beprepared, for example, by wet-grinding by means of commercial bead millsand optional addition of surfactants as have, for example, already beenlisted above for the other formulation types.

Emulsions, for example oil-in-water emulsions (EW), can be produced, forexample, by means of stirrers, colloid mills and/or static mixers usingaqueous organic solvents and optionally surfactants as already listedabove, for example, for the other formulation types.

Granules can be prepared either by spraying the active compound ontogranular inert material capable of adsorption or by applying activecompound concentrates to the surface of carrier substances, such assand, kaolinites or granular inert material, by means of adhesives, forexample polyvinyl alcohol, sodium polyacrylate or mineral oils. Suitableactive compounds can also be granulated in the manner customary for theproduction of fertilizer granules—if desired as a mixture withfertilizers.

Water-dispersible granules are produced generally by the customaryprocesses such as spray-drying, fluidized-bed granulation, pangranulation, mixing with high-speed mixers and extrusion without solidinert material.

For the production of pan, fluidized-bed, extruder and spray granules,see e.g. processes in “Spray-Drying Handbook” 3rd Ed. 1979, G. GoodwinLtd., London, J. E. Browning, “Agglomeration”, Chemical and Engineering1967, pages 147 ff.; “Perry's Chemical Engineer's Handbook”, 5th Ed.,McGraw-Hill, New York 1973, pp. 8-57.

For further details regarding the formulation of crop protectioncompositions, see, for example, G. C. Klingman, “Weed Control as aScience”, John Wiley and Sons, Inc., New York, 1961, pages 81-96 and J.D. Freyer, S. A. Evans, “Weed Control Handbook”, 5th Ed., BlackwellScientific Publications, Oxford, 1968, pages 101-103.

The agrochemical preparations contain generally 0.1 to 99% by weight,especially 0.1 to 95% by weight, of compounds of the invention. Inwettable powders, the active compound concentration is, for example,about 10 to 90% by weight, the remainder to 100% by weight consisting ofcustomary formulation constituents. In emulsifiable concentrates, theactive compound concentration may be about 1% to 90% and preferably 5%to 80% by weight. Formulations in the form of dusts comprise 1% to 30%by weight of active compound, preferably usually 5% to 20% by weight ofactive compound; sprayable solutions contain about 0.05% to 80% byweight, preferably 2% to 50% by weight of active compound. In the caseof water-dispersible granules, the active compound content dependspartially on whether the active compound is in liquid or solid form andon which granulation auxiliaries, fillers, etc., are used. In thewater-dispersible granules, the content of active compound is, forexample, between 1 and 95% by weight, preferably between 10 and 80% byweight.

In addition, the active compound formulations mentioned optionallycomprise the respective customary stickers, wetters, dispersants,emulsifiers, penetrants, preservatives, antifreeze agents and solvents,fillers, carriers and dyes, defoamers, evaporation inhibitors and agentswhich influence the pH and the viscosity.

On the basis of these formulations, it is also possible to producecombinations with other pesticidally active substances, for exampleinsecticides, acaricides, herbicides, fungicides, and also withsafeners, fertilizers and/or growth regulators, for example in the formof a finished formulation or as a tank mix.

For application, the formulations in commercial form are, ifappropriate, diluted in a customary manner, for example in the case ofwettable powders, emulsifiable concentrates, dispersions andwater-dispersible granules with water. Dust-type preparations, granulesfor soil application or granules for scattering and sprayable solutionsare not normally diluted further with other inert substances prior toapplication.

The required application rate of the compounds of the formula (I) andtheir salts varies according to the external conditions such as, interalia, temperature, humidity and the type of herbicide used. It can varywithin wide limits, for example between 0.001 and 10.0 kg/ha or more ofactive substance, but it is preferably between 0.005 and 5 kg/ha, morepreferably in the range of from 0.01 to 1.5 kg/ha, particularlypreferably in the range from 0.05 to 1 kg/ha g/ha. This applies both tothe pre-emergence and the post-emergence application.

A carrier is a natural or synthetic, organic or inorganic substance withwhich the active compounds are mixed or combined for betterapplicability, in particular for application to plants or plant parts orseed. The carrier, which may be solid or liquid, is generally inert andshould be suitable for use in agriculture. Useful solid or liquidcarriers include: for example ammonium salts and natural rock dusts,such as kaolins, clays, talc, chalk, quartz, attapulgite,montmorillonite or diatomaceous earth, and synthetic rock dusts, such asfinely divided silica, alumina and natural or synthetic silicates,resins, waxes, solid fertilizers, water, alcohols, especially butanol,organic solvents, mineral and vegetable oils, and derivatives thereof.It is likewise possible to use mixtures of such carriers. Useful solidcarriers for granules include: for example crushed and fractionatednatural rocks such as calcite, marble, pumice, sepiolite, dolomite, andsynthetic granules of inorganic and organic meals, and also granules oforganic material such as sawdust, coconut shells, corn cobs and tobaccostalks.

Suitable liquefied gaseous extenders or carriers are liquids which aregaseous at standard temperature and under atmospheric pressure, forexample aerosol propellants such as halogenated hydrocarbons, or elsebutane, propane, nitrogen and carbon dioxide.

In the formulations, it is possible to use tackifiers such ascarboxymethylcellulose, natural and synthetic polymers in the form ofpowders, granules or latices, such as gum arabic, polyvinyl alcohol andpolyvinyl acetate, or else natural phospholipids such as cephalins andlecithins, and synthetic phospholipids. Further additives may be mineraland vegetable oils.

When the extender used is water, it is also possible to use, forexample, organic solvents as auxiliary solvents. Useful liquid solventsare essentially: aromatics such as xylene, toluene or alkylnaphthalenes,chlorinated aromatics or chlorinated aliphatic hydrocarbons such aschlorobenzenes, chloroethylenes or dichloromethane, aliphatichydrocarbons such as cyclohexane or paraffins, for example mineral oilfractions, mineral and vegetable oils, alcohols such as butanol orglycol and their ethers and esters, ketones such as acetone, methylethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polarsolvents such as dimethylformamide and dimethyl sulfoxide, and alsowater.

The compositions according to the invention may additionally comprisefurther components, for example surfactants. Useful surfactants areemulsifiers and/or foam formers, dispersants or wetting agents havingionic or nonionic properties, or mixtures of these surfactants. Examplesthereof are salts of polyacrylic acid, salts of lignosulfonic acid,salts of phenolsulfonic acid or naphthalenesulfonic acid, polycondensates of ethylene oxide with fatty alcohols or with fatty acids orwith fatty amines, substituted phenols (preferably alkylphenols orarylphenols), salts of sulfosuccinic esters, taurine derivatives(preferably alkyl taurates), phosphoric esters of polyethoxylatedalcohols or phenols, fatty acid esters of polyols, and derivatives ofthe compounds containing sulfates, sulfonates and phosphates, forexample alkylaryl polyglycol ethers, alkylsulfonates, alkyl sulfates,arylsulfonates, protein hydrolysates, lignosulfite waste liquors andmethylcellulose. The presence of a surfactant is necessary if one of theactive compounds and/or one of the inert carriers is insoluble in waterand when application is effected in water. The proportion of surfactantsis between 5 and 40 percent by weight of the inventive composition. Itis possible to use dyes such as inorganic pigments, for example ironoxide, titanium oxide and Prussian Blue, and organic dyes such asalizarin dyes, azo dyes and metal phthalocyanine dyes, and tracenutrients such as salts of iron, manganese, boron, copper, cobalt,molybdenum and zinc.

If appropriate, it is also possible for other additional components tobe present, for example protective colloids, binders, adhesives,thickeners, thixotropic substances, penetrants, stabilizers,sequestrants, complexing agents. In general, the active compounds can becombined with any solid or liquid additive commonly used for formulationpurposes. In general, the compositions and formulations according to theinvention contain between 0.05 and 99% by weight, 0.01 and 98% byweight, preferably between 0.1 and 95% by weight, more preferablybetween 0.5 and 90% active compound, most preferably between 10 and 70percent by weight. The active compounds or compositions according to theinvention can be used as such or, depending on their respective physicaland/or chemical properties, in the form of their formulations or the useforms prepared therefrom, such as aerosols, capsule suspensions,cold-fogging concentrates, warm-fogging concentrates, encapsulatedgranules, fine granules, flowable concentrates for the treatment ofseed, ready-to-use solutions, dustable powders, emulsifiableconcentrates, oil-in-water emulsions, water-in-oil emulsions,macrogranules, microgranules, oil-dispersible powders, oil-miscibleflowable concentrates, oil-miscible liquids, foams, pastes, pesticidecoated seed, suspension concentrates, suspoemulsion concentrates,soluble concentrates, suspensions, wettable powders, soluble powders,dusts and granules, water-soluble granules or tablets, water-solublepowders for the treatment of seed, wettable powders, natural productsand synthetic substances impregnated with active compound, and alsomicroencapsulations in polymeric substances and in coating materials forseed, and also ULV cold-fogging and warm-fogging formulations.

The formulations mentioned can be produced in a manner known per se, forexample by mixing the active compounds with at least one customaryextender, solvent or diluent, emulsifier, dispersant and/or binder orfixative, wetting agent, water repellent, optionally siccatives and UVstabilizers and optionally dyes and pigments, antifoams, preservatives,secondary thickeners, tackifiers, gibberellins and other processingauxiliaries.

The compositions according to the invention include not onlyformulations which are already ready for use and can be deployed with asuitable apparatus onto the plant or the seed, but also commercialconcentrates which have to be diluted with water prior to use.

The active compounds according to the invention may be present as suchor in their (commercial standard) formulations, or else in the use formsprepared from these formulations as a mixture with other (known) activecompounds, such as insecticides, attractants, sterilants, bactericides,acaricides, nematicides, fungicides, growth regulators, herbicides,fertilizers, safeners or semiochemicals.

The treatment according to the invention of the plants and plant partswith the active compounds or compositions is carried out directly or byaction on their surroundings, habitat or storage space using customarytreatment methods, for example by dipping, spraying, atomizing,irrigating, evaporating, dusting, fogging, broadcasting, foaming,painting, spreading-on, watering (drenching), drip irrigating and, inthe case of propagation material, in particular in the case of seeds,furthermore as a powder for dry seed treatment, a solution for seedtreatment, a water-soluble powder for slurry treatment, by incrusting,by coating with one or more coats, etc. It is furthermore possible toapply the active compounds by the ultra-low volume method or to injectthe active compound preparation or the active compound itself into thesoil.

One of the advantages of the present invention is that the particularsystemic properties of the inventive active ingredients and compositionsmean that treatment of the seed with these active ingredients andcompositions protects not only the seed itself but also the resultingplants after emergence from phytopathogenic fungi. In this way, theimmediate treatment of the crop at the time of sowing or shortlythereafter can be dispensed with.

It is likewise considered to be advantageous that the inventive activeingredients or compositions can especially also be used for transgenicseed, in which case the plant which grows from this seed is capable ofexpressing a protein which acts against pests. The treatment of suchseed with the inventive active ingredients or compositions, merelythrough the expression of the protein, for example an insecticidalprotein, can result in control of certain pests. Surprisingly, a furthersynergistic effect can be observed in this case, which additionallyincreases the effectiveness for protection against attack by pests.

The compositions according to the invention are suitable for protectionof seed of any plant variety which is used in agriculture, in thegreenhouse, in forests or in horticulture and viticulture. Inparticular, this is the seed of cereals (such as wheat, barley, rye,triticale, sorghum/millet and oats), corn, cotton, soya beans, rice,potatoes, sunflower, bean, coffee, beet (for example sugar beet andfodder beet), peanut, oilseed rape, poppy, olive, coconut, cocoa, sugarcane, tobacco, vegetables (such as tomato, cucumbers, onions andlettuce), turf and ornamentals (see also below). The treatment of theseed of cereals (such as wheat, barley, rye, triticale and oats), cornand rice is of particular importance.

As also described below, the treatment of transgenic seed with theactive compounds according to the invention or compositions is ofparticular significance. This relates to the seed of plants containingat least one heterologous gene which enables the expression of apolypeptide or protein having insecticidal properties. The heterologousgene in transgenic seed can originate, for example, from microorganismsof the species Bacillus, Rhizobium, Pseudomonas, Serratia, Trichoderma,Clavibacter, Glomus or Gliocladium. This heterologous gene preferablyoriginates from Bacillus sp., in which case the gene product iseffective against the European corn borer and/or the Western cornrootworm. The heterologous gene more preferably originates from Bacillusthuringiensis.

In the context of the present invention, the inventive composition isapplied to the seed alone or in a suitable formulation. Preferably, theseed is treated in a state in which it is sufficiently stable for nodamage to occur in the course of treatment. In general, the seed can betreated at any time between harvest and sowing. It is customary to useseed which has been separated from the plant and freed from cobs,shells, stalks, coats, hairs or the flesh of the fruits. For example, itis possible to use seed which has been harvested, cleaned and dried downto a moisture content of less than 15% by weight. Alternatively, it isalso possible to use seed which, after drying, for example, has beentreated with water and then dried again.

In general, when treating the seed, it has to be ensured that the amountof the composition according to the invention and/or further additivesapplied to the seed is chosen such that the germination of the seed isnot impaired and the plant which arises therefrom is not damaged. Thishas to be ensured particularly in the case of active compounds which canexhibit phytotoxic effects at certain application rates.

The compositions according to the invention can be applied directly,i.e. without containing any other components and without having beendiluted. In general, it is preferable to apply the compositions to theseed in the form of a suitable formulation. Suitable formulations andmethods for seed treatment are known to those skilled in the art and aredescribed, for example, in the following documents: U.S. Pat. Nos.4,272,417 A, 4,245,432 A, 4,808,430, 5,876,739, US 2003/0176428 A1, WO2002/080675 A1, WO 2002/028186 A2.

The active compounds which can be used in accordance with the inventioncan be converted to the customary seed-dressing formulations, such assolutions, emulsions, suspensions, powders, foams, slurries or othercoating compositions for seed, and also ULV formulations.

These formulations are produced in a known manner, by mixing the activecompounds with customary additives, for example customary extenders andsolvents or diluents, dyes, wetting agents, dispersants, emulsifiers,antifoams, preservatives, secondary thickeners, adhesives, gibberellins,and also water.

Dyes which may be present in the seed-dressing formulations usable inaccordance with the invention are all dyes which are customary for suchpurposes. It is possible to use either pigments, which are sparinglysoluble in water, or dyes, which are soluble in water. Examples includethe dyes known by the names Rhodamine B, C.I. Pigment Red 112 and C.I.Solvent Red 1.

Useful wetting agents which may be present in the seed-dressingformulations usable in accordance with the invention are all substanceswhich promote wetting and which are customary for the formulation ofagrochemically active compounds. Alkyl naphthalenesulfonates, such asdiisopropyl or diisobutyl naphthalenesulfonates, can be used withpreference.

Suitable dispersants and/or emulsifiers which may be present in theseed-dressing formulations usable in accordance with the invention areall nonionic, anionic and cationic dispersants customary for theformulation of agrochemically active compounds. Preference is given tousing nonionic or anionic dispersants or mixtures of nonionic or anionicdispersants. Suitable nonionic dispersants include especially ethyleneoxide/propylene oxide block polymers, alkylphenol polyglycol ethers andtristryrylphenol polyglycol ether, and the phosphated or sulfatedderivatives thereof. Suitable anionic dispersants are especiallylignosulfonates, polyacrylic acid salts and arylsulfonate-formaldehydecondensates.

Antifoams which may be present in the seed-dressing formulations usablein accordance with the invention are all foam-inhibiting substancescustomary for the formulation of agrochemically active compounds.Silicone antifoams and magnesium stearate can be used with preference.

Preservatives which may be present in the seed-dressing formulationsusable in accordance with the invention are all substances usable forsuch purposes in agrochemical compositions. Examples includedichlorophene and benzyl alcohol hemiformal.

Secondary thickeners which may be present in the seed-dressingformulations usable in accordance with the invention are all substancesusable for such purposes in agrochemical compositions. Preferredexamples include cellulose derivatives, acrylic acid derivatives,xanthan, modified clays and finely divided silica.

Useful stickers which may be present in the seed-dressing formulationsusable in accordance with the invention are all customary binders usablein seed-dressing products. Preferred examples includepolyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol and tylose.

The seed-dressing formulations usable in accordance with the inventioncan be used, either directly or after previously having been dilutedwith water, for the treatment of a wide range of different seed,including the seed of transgenic plants. In this case, additionalsynergistic effects may also occur in interaction with the substancesformed by expression.

For the treatment of seed with the seed-dressing formulations usable inaccordance with the invention or with the preparations preparedtherefrom by addition of water, useful equipment is all mixing unitsusable customarily for seed dressing. Specifically, the seed dressingprocedure is to place the seed into a mixer, to add the particulardesired amount of seed-dressing formulations, either as such or afterprior dilution with water, and to mix them until the formulation isdistributed homogeneously on the seed. If appropriate, this is followedby a drying operation.

The active compounds according to the invention, given good plantcompatibility, favourable homeotherm toxicity and good environmentalcompatibility, are suitable for protection of plants and plant organs,for increasing harvest yields, and for improving the quality of theharvested crop. They can preferably be used as crop protection agents.They are active against normally sensitive and resistant species andalso against all or specific stages of development.

Plants which can be treated in accordance with the invention include thefollowing main crop plants: corn, soya bean, cotton, Brassica oil seedssuch as Brassica napus (e.g. Canola), Brassica rapa, B. juncea (e.g.(field) mustard) and Brassica carinata, rice, wheat, sugar beet, sugarcane, oats, rye, barley, millet and sorghum, triticale, flax, grapes andvarious fruit and vegetables from various botanic taxa, for exampleRosaceae sp. (for example pome fruits such as apples and pears, but alsostone fruits such as apricots, cherries, almonds and peaches, and berryfruits such as strawberries), Ribesioidae sp., Juglandaceae sp.,Betulaceae sp., Anacardiaceae sp., Fagaceae sp., Moraceae sp., Oleaceaesp., Actinidaceae sp., Lauraceae sp., Musaceae sp. (for example bananatrees and plantations), Rubiaceae sp. (for example coffee), Theaceaesp., Sterculiceae sp., Rutaceae sp. (for example lemons, oranges andgrapefruit); Solanaceae sp. (for example tomatoes, potatoes, peppers,aubergines), Liliaceae sp., Compositae sp. (for example lettuce,artichokes and chicory—including root chicory, endive or commonchicory), Umbelliferae sp. (for example carrots, parsley, celery andceleriac), Cucurbitaceae sp. (for example cucumbers—including gherkins,pumpkins, watermelons, calabashes and melons), Alliaceae sp. (forexample leeks and onions), Cruciferae sp. (for example white cabbage,red cabbage, broccoli, cauliflower, Brussels sprouts, pak choi,kohlrabi, radishes, horseradish, cress and chinese cabbage), Leguminosaesp. (for example peanuts, peas, and beans—for example runner beans andbroad beans), Chenopodiaceae sp. (for example Swiss chard, fodder beet,spinach, beetroot), Malvaceae (for example okra), Asparagaceae (forexample asparagus); useful plants and ornamental plants in the gardenand woods; and in each case genetically modified types of these plants.

As mentioned above, it is possible to treat all plants and their partsin accordance with the invention. In a preferred embodiment, wild plantspecies and plant cultivars, or those obtained by conventionalbiological breeding techniques, such as crossing or protoplast fusion,and parts thereof, are treated. In a further preferred embodiment,transgenic plants and plant cultivars obtained by genetic engineeringmethods, if appropriate in combination with conventional methods(genetically modified organisms), and parts thereof are treated. Theterm “parts” or “parts of plants” or “plant parts” has been explainedabove. Particular preference is given in accordance with the inventionto treating plants of the respective commercially customary plantcultivars or those that are in use. Plant cultivars are understood tomean plants having new properties (“traits”) which have been grown byconventional breeding, by mutagenesis or by recombinant DNA techniques.They may be cultivars, varieties, biotypes and genotypes.

The treatment method according to the invention can be used for thetreatment of genetically modified organisms (GMOs), e.g. plants orseeds. Genetically modified plants (or transgenic plants) are plants inwhich a heterologous gene has been stably integrated into the genome.The term “heterologous gene” means essentially a gene which is providedor assembled outside the plant and which, upon introduction into thenuclear genome, the chloroplast genome or the mitochondrial genome,imparts to the transformed plant novel or improved agronomical or othertraits because it expresses a protein or polypeptide of interest oranother gene which is present in the plant, or other genes which arepresent in the plant are down-regulated or switched off (for example bymeans of antisense technology, co-suppression technologies or RNAitechnologies [RNA interference]). A heterologous gene that is located inthe genome is also called a transgene. A transgene that is defined byits specific presence in the plant genome is called a transformation ortransgenic event.

Depending on the plant species or plant cultivars, their location andgrowth conditions (soils, climate, vegetation period, diet), theinventive treatment may also result in superadditive (“synergistic”)effects. For example, the following effects which exceed the effectsactually to be expected are possible: reduced application rates and/orwidened spectrum of activity and/or increased efficacy of the activeingredients and compositions which can be used in accordance with theinvention, better plant growth, increased tolerance to high or lowtemperatures, increased tolerance to drought or to water or soilsalinity, increased flowering performance, easier harvesting,accelerated maturation, higher harvest yields, bigger fruits, greaterplant height, greener leaf colour, earlier flowering, higher qualityand/or a higher nutritional value of the harvested products, highersugar concentration within the fruits, better storage stability and/orprocessability of the harvested products.

At certain application rates, the inventive active ingredientcombinations may also have a fortifying effect on plants. Accordingly,they are suitable for mobilizing the defence system of the plant againstattack by unwanted phytopathogenic fungi and/or microorganisms and/orviruses. This may possibly be one of the reasons for the enhancedactivity of the inventive combinations for example against fungi.Plant-fortifying (resistance-inducing) substances shall be understood tomean, in the present context, also those substances or combinations ofsubstances which are capable of stimulating the defence system of plantsin such a way that, when subsequently inoculated with unwantedphytopathogenic fungi, the plants treated display a substantial degreeof resistance to these unwanted phytopathogenic fungi. The inventivesubstances can therefore be used for protection of plants from attack bythe pathogens mentioned within a certain period of time after treatment.The period within which protection is achieved generally extends forfrom 1 to 10 days, preferably 1 to 7 days, after the treatment of theplants with the active ingredients.

Plants and plant cultivars which are preferably treated in accordancewith the invention include all plants which have genetic material whichimparts particularly advantageous, useful traits to these plants(whether obtained by breeding and/or biotechnological means).

Plants and plant cultivars which are likewise preferably treated inaccordance with the invention are resistant to one or more biotic stressfactors, meaning that these plants have a better defence against animaland microbial pests, such as nematodes, insects, mites, phytopathogenicfungi, bacteria, viruses and/or viroids.

Examples of nematode-resistant plants are described, for example, in thefollowing U.S. patent application Ser. Nos. 11/765,491, 11/765,494,10/926,819, 10/782,020, 12/032,479, 10/783,417, 10/782,096, 11/657,964,12/192,904, 11/396,808, 12/166,253, 12/166,239, 12/166,124, 12/166,209,11/762,886, 12/364,335, 11/763,947, 12/252,453, 12/209,354, 12/491,396and 12/497,221.

Plants and plant cultivars which may also be treated according to theinvention are those plants which are resistant to one or more abioticstress factors. Abiotic stress conditions may include, for example,drought, cold temperature exposure, heat exposure, osmotic stress,waterlogging, increased soil salinity, increased exposure to minerals,exposure to ozone, exposure to strong light, limited availability ofnitrogen nutrients, limited availability of phosphorus nutrients or lackof shade.

Plants and plant varieties which may also be treated according to theinvention are those plants characterized by enhanced yieldcharacteristics. Enhanced yield in said plants can be the result of, forexample, improved plant physiology, growth and development, such aswater use efficiency, water retention efficiency, improved nitrogen use,enhanced carbon assimilation, improved photosynthesis, increasedgermination efficiency and accelerated maturation. Yield can also beaffected by improved plant architecture (under stress and non-stressconditions), including but not limited to early flowering, floweringcontrol for hybrid seed production, seedling vigour, plant size,internode number and distance, root growth, seed size, fruit size, podsize, pod or ear number, seed number per pod or ear, seed mass, enhancedseed filling, reduced seed dispersal, reduced pod dehiscence and lodgingresistance. Further yield traits include seed composition, such ascarbohydrate content, protein content, oil content and oil composition,nutritional value, reduction in antinutritional compounds, improvedprocessability and better storage stability.

Plants that may be treated according to the invention are hybrid plantsthat already express the characteristics of heterosis, or hybrid effect,which results in generally higher yield, vigour, better health andresistance towards biotic and abiotic stress factors. Such plants aretypically produced by crossing an inbred male-sterile parent line (thefemale crossbreeding parent) with another inbred male-fertile parentline (the male crossbreeding parent). Hybrid seed is typically harvestedfrom the male-sterile plants and sold to growers. Male-sterile plantscan sometimes (e.g. in corn) be produced by detasselling (i.e. themechanical removal of the male reproductive organs or male flowers) but,more typically, male sterility is the result of genetic determinants inthe plant genome. In that case, and especially when seed is the desiredproduct to be harvested from the hybrid plants, it is typicallybeneficial to ensure that male fertility in hybrid plants, which containthe genetic determinants responsible for male sterility, is fullyrestored. This can be accomplished by ensuring that the malecrossbreeding parents have appropriate fertility restorer genes whichare capable of restoring the male fertility in hybrid plants thatcontain the genetic determinants responsible for male sterility. Geneticdeterminants for male sterility may be located in the cytoplasm.Examples of cytoplasmic male sterility (CMS) were for instance describedfor Brassica species. However, genetic determinants for male sterilitycan also be located in the nuclear genome. Male-sterile plants can alsobe obtained by plant biotechnology methods such as genetic engineering.A particularly useful means of obtaining male-sterile plants isdescribed in WO 89/10396 in which, for example, a ribonuclease such as abarnase is selectively expressed in the tapetum cells in the stamens.Fertility can then be restored by expression in the tapetum cells of aribonuclease inhibitor such as barstar.

Plants or plant cultivars (obtained by plant biotechnology methods suchas genetic engineering) which may be treated according to the inventionare herbicide-tolerant plants, i.e. plants made tolerant to one or moregiven herbicides. Such plants can be obtained either by genetictransformation, or by selection of plants containing a mutationimparting such herbicide tolerance.

Herbicide-tolerant plants are for example glyphosate-tolerant plants,i.e. plants made tolerant to the herbicide glyphosate or salts thereof.Plants can be made tolerant to glyphosate by various methods. Thus, forexample, glyphosate-tolerant plants can be obtained by transforming theplant with a gene encoding the enzyme 5-enolpyruvylshikimate-3-phosphatesynthase (EPSPS). Examples of such EPSPS genes are the AroA gene (mutantCT7) of the bacterium Salmonella typhimurium (Comai et al., 1983,Science, 221, 370-371), the CP4 gene of the bacterium Agrobacterium sp.(Barry et al., 1992, Curr. Topics Plant Physiol. 7, 139-145), the genesencoding a petunia EPSPS (Shah et al., 1986, Science 233, 478-481), atomato EPSPS (Gasser et al., 1988, J. Biol. Chem. 263, 4280-4289) or anEleusine EPSPS (WO 01/66704). It can also be a mutated EPSPS.Glyphosate-tolerant plants can also be obtained by expressing a genethat encodes a glyphosate oxidoreductase enzyme. Glyphosate-tolerantplants can also be obtained by expressing a gene that encodes aglyphosate acetyltransferase enzyme. Glyphosate-tolerant plants can alsobe obtained by selecting plants containing naturally-occurring mutationsof the abovementioned genes. Plants which express EPSPS genes whichimpart glyphosate tolerance have been described. Plants which expressother genes which impart glyphosate tolerance, for example decarboxylasegenes, have been described.

Other herbicide-resistant plants are for example plants made tolerant toherbicides inhibiting the enzyme glutamine synthase, such as bialaphos,phosphinothricin or glufosinate. Such plants can be obtained byexpressing an enzyme detoxifying the herbicide or a mutant of theglutamine synthase enzyme that is resistant to inhibition. One exampleof such an effective detoxifying enzyme is an enzyme encoding aphosphinothricin acetyltransferase (such as the bar or pat protein fromStreptomyces species). Plants expressing an exogenous phosphinothricinacetyltransferase have been described.

Further herbicide-tolerant plants are also plants that have been madetolerant to the herbicides inhibiting the enzyme hydroxyphenylpyruvatedioxygenase (HPPD). Hydroxyphenylpyruvate dioxygenases are enzymes thatcatalyse the reaction in which para-hydroxyphenylpyruvate (HPP) isconverted to homogentisate. Plants tolerant to HPPD inhibitors can betransformed with a gene encoding a naturally-occurring resistant HPPDenzyme, or a gene encoding a mutated or chimeric HPPD enzyme, asdescribed in WO 96/38567, WO 99/24585, WO 99/24586, WO 2009/144079, WO2002/046387 or U.S. Pat. No. 6,768,044. Tolerance to HPPD inhibitors canalso be obtained by transforming plants with genes encoding certainenzymes enabling the formation of homogentisate despite inhibition ofthe native HPPD enzyme by the HPPD inhibitor. Such plants are describedin WO 99/34008 and WO 02/36787. Tolerance of plants to HPPD inhibitorscan also be improved by transforming plants with a gene encoding aprephenate dehydrogenase enzyme in addition to a gene encoding anHPPD-tolerant enzyme, as described in WO 2004/024928. In addition,plants can be made more tolerant to HPPD inhibitors by inserting intothe genome thereof a gene which encodes an enzyme which metabolizes ordegrades HPPD inhibitors, for example CYP450 enzymes (see WO 2007/103567and WO 2008/150473).

Other herbicide-resistant plants are plants which have been renderedtolerant to acetolactate synthase (ALS) inhibitors. Known ALS inhibitorsinclude, for example, sulfonylurea, imidazolinone, triazolopyrimidines,pyrimidinyloxy (thio)benzoates, and/or sulfonylaminocarbonyltriazolinoneherbicides. It is known that different mutations in the ALS enzyme (alsoknown as acetohydroxy acid synthase, AHAS) confer tolerance to differentherbicides and groups of herbicides, as described, for example, inTranel and Wright (Weed Science 2002, 50, 700-712). The production ofsulfonylurea-tolerant plants and imidazolinone-tolerant plants has beendescribed. Further sulfonylurea- and imidazolinone-tolerant plants havealso been described.

Further plants tolerant to imidazolinone and/or sulfonylurea can beobtained by induced mutagenesis, by selection in cell cultures in thepresence of the herbicide or by mutation breeding (cf., for example, forsoya beans U.S. Pat. No. 5,084,082, for rice WO 97/41218, for sugar beetU.S. Pat. No. 5,773,702 and WO 99/057965, for lettuce U.S. Pat. No.5,198,599 or for sunflower WO 01/065922).

Plants or plant varieties (obtained by plant biotechnology methods suchas genetic engineering) which may also be treated according to theinvention are insect-resistant transgenic plants, i.e. plants maderesistant to attack by certain target insects. Such plants can beobtained by genetic transformation, or by selection of plants containinga mutation imparting such insect resistance.

In the present context, the term “insect-resistant transgenic plant”includes any plant containing at least one transgene comprising a codingsequence encoding the following:

1) an insecticidal crystal protein from Bacillus thuringiensis or aninsecticidal portion thereof, such as the insecticidal crystal proteinscompiled by Crickmore et al. (Microbiology and Molecular Biology Reviews1998, 62, 807-813), updated by Crickmore et al. (2005) in the Bacillusthuringiensis toxin nomenclature, online at:http://www.lifesci.sussex.ac.uk/Home/Neil_Crickmore/Bt/),or insecticidal portions thereof, for example proteins of the Cryprotein classes Cry1Ab, Cry1Ac, Cry1B, Cry1C, Cry1D, Cry1F, Cry2Ab,Cry3Aa, or Cry3Bb or insecticidal portions thereof (e.g. EP-A 1999141and WO 2007/107302), or those proteins encoded by synthetic genes asdescribed in U.S. patent application Ser. No. 12/249,016; or2) a crystal protein from Bacillus thuringiensis or a portion thereofwhich is insecticidal in the presence of a second crystal protein otherthan Bacillus thuringiensis or a portion thereof, such as the binarytoxin made up of the Cy34 and Cy35 crystal protein (Nat. Biotechnol.2001, 19, 668-72; Applied Environm. Microbiol. 2006, 71, 1765-1774) orthe binary toxin which consists of Cry1A or Cry1F proteins, and theCry2Aa or Cry2Ab or Cry2Ae proteins (U.S. patent application Ser. No.12/214,022 and EP08010791.5); or3) a hybrid insecticidal protein comprising parts of two differentinsecticidal crystal proteins from Bacillus thuringiensis, such as ahybrid of the proteins of 1) above or a hybrid of the proteins of 2)above, for example the CrylA.105 protein produced by corn event MON98034(WO 2007/027777); or 4) a protein of any one of 1) to 3) above whereinsome, particularly 1 to 10, amino acids have been replaced by anotheramino acid to obtain a higher insecticidal activity to a target insectspecies, and/or to expand the range of target insect species affected,and/or because of changes introduced into the encoding DNA duringcloning or transformation, such as the Cry3Bb1 protein in corn eventsMON863 or MON88017, or the Cry3A protein in corn event MIR604; or5) an insecticidal secreted protein from Bacillus thuringiensis orBacillus cereus, or an insecticidal portion thereof, such as thevegetative insecticidal proteins (VIP) listed at:http://www.lifesci.sussex.ac.uk/home/Neil_Crickmore/Bt/vip.html, forexample proteins from the VIP3Aa protein class; or6) a secreted protein from Bacillus thuringiensis or Bacillus cereuswhich is insecticidal in the presence of a second secreted protein fromBacillus thuringiensis or B. cereus, such as the binary toxin made up ofthe VIP1A and VIP2A proteins (WO 94/21795); or7) a hybrid insecticidal protein comprising parts from differentsecreted proteins from Bacillus thuringiensis or Bacillus cereus, suchas a hybrid of the proteins in 1) above or a hybrid of the proteins in2) above; or8) a protein of any one of points 5) to 7) above wherein some,particularly 1 to 10, amino acids have been replaced by another aminoacid to obtain a higher insecticidal activity to a target insectspecies, and/or to expand the range of target insect species affected,and/or because of changes induced in the encoding DNA during cloning ortransformation (while still encoding an insecticidal protein), such asthe VIP3Aa protein in cotton event COT 102; or9) a secreted protein from Bacillus thuringiensis or Bacillus cereuswhich is insecticidal in the presence of a crystal protein from Bacillusthuringiensis, such as the binary toxin made up of the proteins VIP3 andCry1A or Cry1F (U.S. patent applications 61/126,083 and 61/195,019), orthe binary toxin made up of the VIP3 protein and the Cry2Aa or Cry2Ab orCry2Ae proteins (U.S. patent application Ser. No. 12/214,022 and EP08010791.5); or10) a protein according to point 9) above wherein some, particularly 1to 10, amino acids have been replaced by another amino acid to obtain ahigher insecticidal activity to a target insect species, and/or toexpand the range of target insect species affected, and/or because ofchanges induced in the encoding DNA during cloning or transformation(while still encoding an insecticidal protein).

Of course, insect-resistant transgenic plants, as used herein, alsoinclude any plant comprising a combination of genes encoding theproteins of any one of the abovementioned classes 1 to 10. In oneembodiment, an insect-resistant plant contains more than one transgeneencoding a protein of any one of the above classes 1 to 10, to expandthe range of the target insect species affected or to delay insectresistance development to the plants, by using different proteinsinsecticidal to the same target insect species but having a differentmode of action, such as binding to different receptor binding sites inthe insect.

In the present context, an “insect-resistant transgenic plant”additionally includes any plant containing at least one transgenecomprising a sequence for production of double-stranded RNA which, afterconsumption of food by an insect pest, prevents the growth of this pest.

Plants or plant cultivars (obtained by plant biotechnology methods suchas genetic engineering) which may also be treated according to theinvention are tolerant to abiotic stress factors. Such plants can beobtained by genetic transformation, or by selection of plants containinga mutation imparting such stress resistance. Particularly usefulstress-tolerant plants include the following:

a. plants which contain a transgene capable of reducing the expressionand/or the activity of the poly(ADP-ribose) polymerase (PARP) gene inthe plant cells or plants;b. plants which contain a stress tolerance-enhancing transgene capableof reducing the expression and/or the activity of the PARG-encodinggenes of the plants or plant cells;c. plants which contain a stress tolerance-enhancing transgene codingfor a plant-functional enzyme of the nicotinamide adenine dinucleotidesalvage biosynthesis pathway, including nicotinamidase, nicotinatephosphoribosyltransferase, nicotinic acid mononucleotideadenyltransferase, nicotinamide adenine dinucleotide synthetase ornicotinamide phosphoribosyltransferase.

Plants or plant cultivars (obtained by plant biotechnology methods suchas genetic engineering) which may also be treated according to theinvention show altered quantity, quality and/or storage stability of theharvested product and/or altered properties of specific components ofthe harvested product such as, for example:

1) Transgenic plants which synthesize a modified starch which, in itsphysicochemical characteristics, in particular the amylose content orthe amylose/amylopectin ratio, the degree of branching, the averagechain length, the side chain distribution, the viscosity behaviour, thegelling strength, the starch granule size and/or the starch granulemorphology, is changed in comparison with the synthesized starch inwild-type plant cells or plants, so that this modified starch is bettersuited to specific applications.2) Transgenic plants which synthesize non-starch carbohydrate polymersor which synthesize non-starch carbohydrate polymers with alteredproperties in comparison to wild-type plants without geneticmodification. Examples are plants which produce polyfructose, especiallyof the inulin and levan type, plants which produce alpha-1,4-glucans,plants which produce alpha-1,6-branched alpha-1,4-glucans, and plantsproducing alternan.3) Transgenic plants which produce hyaluronan.4) Transgenic plants or hybrid plants such as onions with particularproperties, such as “high soluble solids content”, “low pungency” (LP)and/or “long storage” (LS).

Plants or plant cultivars (obtained by plant biotechnology methods suchas genetic engineering) which may also be treated according to theinvention are plants, such as cotton plants, with altered fibrecharacteristics. Such plants can be obtained by genetic transformation,or by selection of plants containing a mutation imparting such alteredfibre characteristics and include:

a) plants, such as cotton plants, containing an altered form ofcellulose synthase genes;b) plants, such as cotton plants, which contain an altered form of rsw2or rsw3 homologous nucleic acids, such as cotton plants with anincreased expression of sucrose phosphate synthase;c) plants, such as cotton plants, with increased expression of sucrosesynthase;d) plants, such as cotton plants, wherein the timing of theplasmodesmatal gating at the base of the fibre cell is altered, forexample through downregulation of fibre-selective β-1,3-glucanase;e) plants, such as cotton plants, which have fibres with alteredreactivity, for example through expression of theN-acetylglucosaminetransferase gene, including nodC, and chitin synthasegenes.

Plants or plant cultivars (obtained by plant biotechnology methods suchas genetic engineering) which may also be treated according to theinvention are plants, such as oilseed rape or related Brassica plants,with altered oil profile characteristics. Such plants can be obtained bygenetic transformation, or by selection of plants containing a mutationimparting such altered oil characteristics and include:

a) plants, such as oilseed rape plants, which produce oil having a higholeic acid content;b) plants, such as oilseed rape plants, which produce oil having a lowlinolenic acid content;c) plants, such as oilseed rape plants, which produce oil having a lowlevel of saturated fatty acids.

Plants or plant cultivars (which can be obtained by plant biotechnologymethods such as genetic engineering) which may also be treated accordingto the invention are plants such as potatoes which are virus-resistant,for example to the potato virus Y (SY230 and SY233 events fromTecnoplant, Argentina), or which are resistant to diseases such aspotato late blight (e.g. RB gene), or which exhibit reduced cold-inducedsweetness (which bear the genes Nt-Inh, II-INV) or which exhibit thedwarf phenotype (A-20 oxidase gene).

Plants or plant cultivars (obtained by plant biotechnology methods suchas genetic engineering) which may also be treated according to theinvention are plants, such as oilseed rape or related Brassica plants,with altered seed shattering characteristics. Such plants can beobtained by genetic transformation, or by selection of plants containinga mutation imparting such altered characteristics, and include plantssuch as oilseed rape with retarded or reduced seed shattering.

Particularly useful transgenic plants which can be treated according tothe invention are plants with transformation events or combinations oftransformation events which are the subject of granted or pendingpetitions for nonregulated status in the USA at the Animal and PlantHealth Inspection Service (APHIS) of the United States Department ofAgriculture (USDA). Information relating to this is available at anytime from APHIS (4700 River Road Riverdale, Md. 20737, USA), for examplevia the website http://www.aphis.usda.gov/brs/notreg.html. At the filingdate of this application, the petitions with the following informationwere either granted or pending at APHIS:

-   -   Petition: Identification number of the petition. The technical        description of the transformation event can be found in the        specific petition document available from APHIS on the website        via the petition number. These descriptions are hereby disclosed        by reference.    -   Extension of a petition: Reference to an earlier petition for        which an extension of scope or term is being requested.    -   Institution: Name of the person submitting the petition.    -   Regulated article: The plant species in question.    -   Transgenic phenotype: The trait imparted to the plant by the        transformation event.    -   Transformation event or line: The name of the event(s)        (sometimes also referred to as line(s)) for which nonregulated        status is being requested.    -   APHIS documents: Various documents which have been published by        APHIS with regard to the petition or can be obtained from APHIS        on request.

Particularly useful transgenic plants which can be treated in accordancewith the invention are plants which comprise one or more genes whichcode for one or more toxins, for example the transgenic plants which aresold under the following trade names: YIELD GARD® (for example corn,cotton, soya beans), KnockOut® (for example corn), BiteGard® (forexample corn), BT-Xtra® (for example corn), StarLink® (for examplecorn), Bollgard® (cotton), Nucotn® (cotton), Nucotn 33B® (cotton),NatureGard® (for example corn), Protecta® and NewLeaf® (potato).Examples of herbicide-tolerant plants include corn varieties, cottonvarieties and soya bean varieties which are available under thefollowing trade names: Roundup Ready® (tolerance to glyphosates, forexample corn, cotton, soya beans), Liberty Link® (tolerance tophosphinothricin, for example oilseed rape), IMI® (tolerance toimidazolinone) and SCS® (tolerance to sulfonylurea), for example corn.Herbicide-resistant plants (plants bred in a conventional manner forherbicide tolerance) which may be mentioned include the varieties soldunder the name Clearfield® (for example corn).

Particularly useful transgenic plants which may be treated according tothe invention are plants containing transformation events, or acombination of transformation events, and that are listed for example inthe databases for various national or regional regulatory agencies (seefor example http://gmoinfojrc.it/gmp_browse.aspx and http://cera-gmcorg/index.php?evidcode=&hstIDXCode=&gType=&AbbrCode=&atCode=&stCode=&coIDCode=&action=gm_crop_database&mode=Submit).

The active compounds or compositions according to the invention can alsobe used in the protection of materials, for protection of industrialmaterials against attack and destruction by unwanted microorganisms, forexample fungi and insects.

In addition, the compounds according to the invention can be used asantifouling compositions, alone or in combinations with other activecompounds.

Industrial materials in the present context are understood as meaningnon-living materials which have been prepared for use in industry. Forexample, industrial materials which are to be protected by activecompounds according to the invention from microbial alteration ordestruction may be adhesives, sizes, paper, wallpaper and cardboard,textiles, carpets, leather, wood, paints and plastic articles, coolinglubricants and other materials which can be infected with or destroyedby microorganisms. The range of materials to be protected also includesparts of production plants and buildings, for example cooling watercircuits, cooling and heating systems, and ventilation and airconditioning systems, which may be impaired by the proliferation ofmicroorganisms. Industrial materials within the scope of the presentinvention preferably include adhesives, sizes, paper and cardboard,leather, wood, paints, cooling lubricants and heat transfer fluids,particularly preferably wood. The active compounds or compositionsaccording to the invention may prevent adverse effects, such as rotting,decay, discoloration, decoloration or formation of mould. In addition,the compounds according to the invention can be used for protection ofobjects which come into contact with saltwater or brackish water,especially hulls, screens, nets, buildings, moorings and signallingsystems, from fouling.

The method according to the invention for controlling unwanted fungi canalso be employed for protecting storage goods. Here, storage goods areto be understood as meaning natural substances of vegetable or animalorigin or processing products thereof of natural origin, for whichlong-term protection is desired. Storage goods of vegetable origin, forexample plants or plant parts, such as stems, leaves, tubers, seeds,fruits, grains, can be protected freshly harvested or after processingby (pre)drying, moistening, comminuting, grinding, pressing or roasting.Storage goods also include timber, whether unprocessed, such asconstruction timber, electricity poles and barriers, or in the form offinished products, such as furniture. Storage goods of animal originare, for example, hides, leather, furs and hairs. The active compoundsaccording to the invention may prevent adverse effects, such as rotting,decay, discoloration, decoloration or formation of mould.

Non-limiting examples of pathogens of fungal diseases which can betreated in accordance with the invention include: Diseases caused bypowdery mildew pathogens, for example Blumeria species, for exampleBlumeria graminis; Podosphaera species, for example Podosphaeraleucotricha; Sphaerotheca species, for example Sphaerotheca fuliginea;Uncinula species, for example Uncinula necator; diseases caused by rustdisease pathogens, for example Gymnosporangium species, for exampleGymnosporangium sabinae; Hemileia species, for example Hemileiavastatrix; Phakopsora species, for example Phakopsora pachyrhizi andPhakopsora meibomiae; Puccinia species, for example Puccinia reconditaor Puccinia triticina; Uromyces species, for example Uromycesappendiculatus; diseases caused by pathogens from the group of theOomycetes, for example Bremia species, for example Bremia lactucae;Peronospora species, for example Peronospora pisi or P. brassicae;Phytophthora species, for example Phytophthora infestans; Plasmoparaspecies, for example Plasmopara viticola; Pseudoperonospora species, forexample Pseudoperonospora humuli or Pseudoperonospora cubensis; Pythiumspecies, for example Pythium ultimum; leaf blotch diseases and leaf wiltdiseases caused, for example, by Alternaria species, for exampleAlternaria solani; Cercospora species, for example Cercospora beticola;Cladiosporium species, for example Cladiosporium cucumerinum;Cochliobolus species, for example Cochliobolus sativus (conidia form:Drechslera, syn: Helminthosporium); Colletotrichum species, for exampleColletotrichum lindemuthanium; Cycloconium species, for exampleCycloconium oleaginum; Diaporthe species, for example Diaporthe citri;Elsinoe species, for example Elsinoe fawcettii; Gloeosporium species,for example Gloeosporium laeticolor; Glomerella species, for exampleGlomerella cingulata; Guignardia species, for example Guignardiabidwelli; Leptosphaeria species, for example Leptosphaeria maculans;Magnaporthe species, for example Magnaporthe grisea; Microdochiumspecies, for example Microdochium nivale; Mycosphaerella species, forexample Mycosphaerelle graminicola and M. fijiensis; Phaeosphaeriaspecies, for example Phaeosphaeria nodorum; Pyrenophora species, forexample Pyrenophora teres; Ramularia species, for example Ramulariacollo-cygni; Rhynchosporium species, for example Rhynchosporium secalis;Septoria species, for example Septoria apii; Typhula species, forexample Typhula incarnata; Venturia species, for example Venturiainaequalis; root and stem diseases caused, for example, by Corticiumspecies, for example Corticium graminearum; Fusarium species, forexample Fusarium oxysporum; Gaeumannomyces species, for exampleGaeumannomyces graminis; Rhizoctonia species, for example Rhizoctoniasolani; Tapesia species, for example Tapesia acuformis; Thielaviopsisspecies, for example Thielaviopsis basicola; ear and panicle diseases(including corn crops) caused, for example, by Alternaria species, forexample Alternaria spp.; Aspergillus species, for example Aspergillusflavus; Cladosporium species, for example Cladosporium spp.; Clavicepsspecies, for example Claviceps purpurea; Fusarium species, for exampleFusarium culmorum; Gibberella species, for example Gibberella zeae;Monographella species, for example Monographella nivalis; Septoriaspecies, for example Septoria nodorum; diseases caused by smut fungi,for example Sphacelotheca species, for example Sphacelotheca reiliana;Tilletia species, for example Tilletia caries, T. controversa; Urocystisspecies, for example Urocystis occulta; Ustilago species, for exampleUstilago nuda, U. nuda tritici; fruit rot caused, for example, byAspergillus species, for example Aspergillus flavus; Botrytis species,for example Botrytis cinerea; Penicillium species, for examplePenicillium expansum and P. purpurogenum; Sclerotinia species, forexample Sclerotinia sclerotiorum; Verticilium species, for exampleVerticilium alboatrum; seed- and soil-borne rot and wilt diseases, andalso diseases of seedlings, caused, for example, by Fusarium species,for example Fusarium culmorum; Phytophthora species, for examplePhytophthora cactorum; Pythium species, for example Pythium ultimum;Rhizoctonia species, for example Rhizoctonia solani; Sclerotium species,for example Sclerotium rolfsii; cancerous diseases, galls and witches'broom caused, for example, by Nectria species, for example Nectriagalligena;

wilt diseases caused, for example, by Monilinia species, for exampleMonilinia laxa;deformations of leaves, flowers and fruits caused, for example, byTaphrina species, for example Taphrina deformans; degenerative diseasesof woody plants caused, for example, by Esca species, for examplePhaemoniella clamydospora and Phaeoacremonium aleophilum and Fomitiporiamediterranea; diseases of flowers and seeds caused, for example, byBotrytis species, for example Botrytis cinerea; diseases of plant tuberscaused, for example, by Rhizoctonia species, for example Rhizoctoniasolani; Helminthosporium species, for example Helminthosporium solani;diseases caused by bacterial pathogens, for example Xanthomonas species,for example Xanthomonas campestris pv. oryzae; Pseudomonas species, forexample Pseudomonas syringae pv. lachrymans; Erwinia species, forexample Erwinia amylovora.

The following diseases of soya beans can be controlled with preference:

Fungal diseases on leaves, stems, pods and seeds caused, for example, byalternaria leaf spot (Alternaria spec. atrans tenuissima), Anthracnose(Colletotrichum gloeosporoides dematium var. truncatum), brown spot(Septoria glycines), cercospora leaf spot and blight (Cercosporakikuchii), choanephora leaf blight (Choanephora infundibulifera trispora(Syn.)), dactuliophora leaf spot (Dactuliophora glycines), downy mildew(Peronospora manshurica), drechslera blight (Drechslera glycini),frogeye leaf spot (Cercospora sojina), leptosphaerulina leaf spot(Leptosphaerulina trifolii), phyllostica leaf spot (Phyllostictasojaecola), pod and stem blight (Phomopsis sojae), powdery mildew(Microsphaera diffusa), pyrenochaeta leaf spot (Pyrenochaeta glycines),rhizoctonia aerial, foliage, and web blight (Rhizoctonia solani), rust(Phakopsora pachyrhizi, Phakopsora meibomiae), scab (Sphacelomaglycines), stemphylium leaf blight (Stemphylium botryosum), target spot(Corynespora cassiicola).

Fungal diseases on roots and the stem base caused, for example, by blackroot rot (Calonectria crotalariae), charcoal rot (Macrophominaphaseolina), fusarium blight or wilt, root rot, and pod and collar rot(Fusarium oxysporum, Fusarium orthoceras, Fusarium semitectum, Fusariumequiseti), mycoleptodiscus root rot (Mycoleptodiscus terrestris),neocosmospora (Neocosmospora vasinfecta), pod and stem blight (Diaporthephaseolorum), stem canker (Diaporthe phaseolorum var. caulivora),phytophthora rot (Phytophthora megasperma), brown stem rot (Phialophoragregata), pythium rot (Pythium aphanidermatum, Pythium irregulare,Pythium debaryanum, Pythium myriotylum, Pythium ultimum), rhizoctoniaroot rot, stem decay, and damping-off (Rhizoctonia solani), sclerotiniastem decay (Sclerotinia sclerotiorum), sclerotinia southern blight(Sclerotinia rolfsii), thielaviopsis root rot (Thielaviopsis basicola).

Microorganisms capable of degrading or altering the industrial materialsinclude, for example, bacteria, fungi, yeasts, algae and slimeorganisms. The active compounds according to the invention preferablyact against fungi, especially moulds, wood-discolouring andwood-destroying fungi (Basidiomycetes), and against slime organisms andalgae. Examples include microorganisms of the following genera:Alternaria, such as Alternaria tenuis; Aspergillus, such as Aspergillusniger; Chaetomium, such as Chaetomium globosum; Coniophora, such asConiophora puetana; Lentinus, such as Lentinus tigrinus; Penicillium,such as Penicillium glaucum; Polyporus, such as Polyporus versicolor;Aureobasidium, such as Aureobasidium pullulans; Sclerophoma, such asSclerophoma pityophila; Trichoderma, such as Trichoderma viride;Escherichia, such as Escherichia coli; Pseudomonas, such as Pseudomonasaeruginosa; Staphylococcus, such as Staphylococcus aureus.

In addition, the active compounds according to the invention also havevery good antimycotic activity. They have a very broad antimycoticactivity spectrum, in particular against dermatophytes and yeasts,moulds and diphasic fungi, (for example against Candida species, such asCandida albicans, Candida glabrata), and Epidermophyton floccosum,Aspergillus species, such as Aspergillus niger and Aspergillusfumigatus, Trichophyton species, such as Trichophyton mentagrophytes,Microsporon species such as Microsporon canis and audouinii. Theenumeration of these fungi in no way constitutes a restriction of themycotic spectrum that can be controlled, and is merely of illustrativecharacter.

The active compounds according to the invention can therefore be usedboth in medical and in non-medical applications.

If appropriate, the compounds according to the invention can, at certainconcentrations or application rates, also be used as herbicides,safeners, growth regulators or agents to improve plant properties, or asmicrobicides, for example as fungicides, antimycotics, bactericides,viricides (including agents against viroids) or as agents against MLO(mycoplasma-like organisms) and RLO (rickettsia-like organisms). Theycan, as the case may be, also be used as intermediates or precursors forthe synthesis of other active compounds.

A. Chemical Examples

The NMR data of disclosed examples are listed either in conventionalform (δ values, multiplet splitting, number of hydrogen atoms) or asso-called NMR peak lists. In the NMR peak list method, the NMR data ofselected examples are recorded in the form of NMR peak lists, where foreach signal peak first the δ value in ppm and then, separated by aspace, the signal intensity are listed. The δ value/signal intensitynumber pairs for different signal peaks are listed with separation fromone another by semicolons.

The peak list for one example therefore takes the form of:

δ₁ (intensity₁); δ₂ (intensity₂); . . . ; δ_(i) (intensity_(i)); . . . ;δ_(n) (intensity_(n))

The intensity of sharp signals correlates with the height of the signalsin a printed example of an NMR spectrum in cm and shows the true ratiosof the signal intensities. In the case of broad signals, several peaksor the middle of the signal and the relative intensity thereof may beshown in comparison to the most intense signal in the spectrum.

For calibration of the chemical shift of ¹H NMR spectra, we usetetramethylsilane and/or the chemical shift of the solvent, particularlyin the case of spectra which are measured in DMSO. Therefore, thetetramethylsilane peak may but need not occur in NMR peak lists.

The lists of the ¹H NMR peaks are similar to the conventional ¹H NMRprintouts and thus usually contain all peaks listed in a conventionalNMR interpretation.

In addition, like conventional ¹H NMR printouts, they may show solventsignals, signals of stereoisomers of the target compounds which arelikewise provided by the invention, and/or peaks of impurities.

In the reporting of compound signals within the delta range of solventsand/or water, our lists of ¹H NMR peaks show the standard solvent peaks,for example peaks of DMSO in DMSO-D₆ and the peak of water, whichusually have a high intensity on average.

The peaks of stereoisomers of the target compounds and/or peaks ofimpurities usually have a lower intensity on average than the peaks ofthe target compounds (for example with a purity of >90%).

Such stereoisomers and/or impurities may be typical of the particularpreparation process. Their peaks can thus help in identifyingreproduction of our preparation process with reference to “by-productfingerprints”.

An expert calculating the peaks of the target compounds by known methods(MestreC, ACD simulation, but also with empirically evaluated expectedvalues) can, if required, isolate the peaks of the target compounds,optionally using additional intensity filters. This isolation would besimilar to the relevant peak picking in conventional 1H NMRinterpretation.

Further details of ¹H NMR peak lists can be found in the Researchdisclosure Database Number 564025.

The examples which follow illustrate the invention in detail.

Intermediate 1 Preparation of 3,5-difluoro-N-hydroxybenzenecarboximidoylchloride

Analogously to the procedure in WO2012/130798 for3,5-dichloro-N-hydroxybenzenecarboximidoyl chloride,3,5-difluoro-N-hydroxybenzenecarboximidoyl chloride was prepared from3,5-difluorobenzaldehyde in two steps.

Intermediate 2 Preparation of methyl3-(3,5-difluorophenyl)-5-methyl-4H-isoxazole-5-carboxylate

Analogously to the procedure in WO2012/130798 for methyl3-(3,5-dichlorophenyl)-5-methyl-4H-isoxazole-5-carboxylate, methyl3-(3,5-difluorophenyl)-5-methyl-4H-isoxazole-5-carboxylate was preparedfrom 3,5-difluorobenzaldehyde in three steps.

Intermediate 3 Preparation of3-(3,5-difluorophenyl)-5-methyl-4H-isoxazole-5-carboxylic acid

Analogously to the procedure in WO2012/130798 for3-(3,5-dichlorophenyl)-5-methyl-4H-isoxazole-5-carboxylic acid,3-(3,5-difluorophenyl)-5-methyl-4H-isoxazole-5-carboxylic acid wasprepared by hydrolysis of methyl3-(3,5-difluorophenyl)-5-methyl-4H-isoxazole-5-carboxylate.

Intermediate 4 Preparation of3-(3,5-difluorophenyl)-5-methyl-4H-isoxazole-5-carbonyl chloride

Analogously to the procedure in WO2012/130798 forN-tert-butyl-3-(3,5-dichlorophenyl)-5-methyl-4,5-dihydro-1,2-oxazole-5-carboxamide,3-(3,5-difluorophenyl)-5-methyl-4H-isoxazole-5-carbonyl chloride wasprepared from 3-(3,5-difluorophenyl)-5-methyl-4H-isoxazole-5-carboxylicacid by reaction with oxalyl chloride and used as crude product withoutfurther purification.

Intermediate 5 Preparation of methyl3-(3,5-difluorophenyl)-5-(1-hydroxyethyl)-4H-isoxazole-5-carboxylate

19.9 g (104 mmol) of 3,5-difluoro-N-hydroxybenzimidoyl chloride (seeIntermediate 1) were dissolved in 330 ml of 2-propanol, and 15.0 g (104mmol) of methyl 3-hydroxy-2-methylenebutanoate were added.

After addition of 43.8 g (522 mmol) of sodium bicarbonate, thesuspension was heated to 50° C. and the temperature was maintained for 2h until complete conversion of the starting material. The suspension wasfiltered and the filtrate was concentrated under reduced pressure. Theresulting residue was taken up in dichloromethane and then washed withsaturated sodium chloride solution and the organic phase was dried withsodium sulfate and, after filtration, concentrated under reducedpressure. The crude product thus obtained was taken up in toluene and,by addition of n-heptane, crystallized. This gave 25.5 g (86%) of methyl3-(3,5-difluorophenyl)-5-(1-hydroxyethyl)-4H-isoxazole-5-carboxylate inthe form of colourless crystals.

Diastereomer 1: NMR (CDCl3): δ=1.20 (d, 3H), 2.36 (d, 1H), 3.52 (d, 1H),3.72 (d, 1H), 3.83 (s, 3H), 4.34 (m, 1H), 6.88 (m, 1H), 7.20 (m, 2H).

Diastereomer 2: NMR (CDCl3): δ=1.29 (d, 3H), 2.12 (d, 1H), 3.58 (d, 1H),3.68 (d, 1H), 3.83 (s, 3H), 4.23 (m, 1H), 6.88 (m, 1H), 7.20 (m, 2H).

Intermediate 6 Preparation of methyl3-(3,5-difluorophenyl)-5-[1-(trifluoromethylsulfonyloxy)ethyl]-4H-isoxazole-5-carboxylate

29.9 (105 mmol) of methyl 3-(3,5-difluorophenyl)-5-(1-hydroxyethyl)-4H-isoxazole-5-carboxylate in 660 ml of dichloromethane werecooled to 0° C., and 16.3 g (210 mmol) of pyridine were added. Asolution of 38.6 g (137 mmol) of trifluoromethanesulfonic anhydride in80 ml of dichloromethane was then added slowly. After 30 minutes at 0°C., 300 ml of dichloromethane were added and the organic phase waswashed three times with in each case 200 ml of a solution of saturatedsodium chloride solution and 1 N hydrochloric acid (3:1). The organicphase was then washed twice with saturated sodium chloride solution anddried over sodium sulfate, and the solvent was removed under reducedpressure. The resulting crude product was used in the next step withoutfurther purification.

Diastereomer 1: NMR (CDCl3): δ=1.54 (d, 3H), 3.44 (d, 1H), 3.89 (s, 3H),3.94 (d, 1H), 5.49 (q, 1H), 6.91 (m, 1H), 7.20 (m, 2H).

Diastereomer 2: NMR (CDCl3): δ=1.59 (d, 3H), 3.53 (d, 1H), 3.89 (s, 3H),3.90 (d, 1H), 5.57 (q, 1H), 6.91 (m, 1H), 7.20 (m, 2H).

Intermediate 7 Preparation of methyl3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazole-5-carboxylate

43.0 g (103 mmol) of the crude product from the previous step (methyl3-(3,5-difluorophenyl)-5-[1-(trifluoromethylsulfonyloxy)ethyl]-4H-isoxazole-5-carboxylate)were dissolved in 500 ml of dimethylacetamide, and a solution of 18.8 g(124 mmol) of DBU in 50 ml of dimethylacetamide was added dropwise over20 minutes. The reaction mixture was stirred at room temperature for 2 hand then poured onto 11 of ice-cooled 2 N hydrochloric acid andextracted twice with 500 ml of diethyl ether each time. The combinedorganic phases were dried over sodium sulfate, filtered and concentratedunder reduced pressure. After chromatographic purification on silica gelusing the mobile phase dichloromethane, the crude product wascrystallized from cyclohexane. This gave 23.4 g (85%) of colourlesscrystals.

¹H NMR (CDCl3): δ=3.34 (d, 1H), 3.84 (s, 3H), 3.93 (d, 1H), 5.38 (d,1H), 5.55 (d, 1H), 6.14 (dd, 1H), 6.88 (m, 1H), 7.19 (m, 2H).

Intermediate 8 Preparation of3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazole-5-carboxylic acid

21 ml of 2 N aqueous sodium hydroxide solution were added to 7.5 g (28.0mmol) of methyl3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazole-5-carboxylate and themixture was heated at reflux for 8 h. After cooling, the reactionmixture was washed with ethyl acetate, the aqueous phase was acidifiedto pH 1 with 2 N hydrochloric acid and the colourless precipitate wasfiltered off and air-dried. The yield was 6.8 g (96%).

1H NMR (CDCl3): δ=3.40 (d, 1H), 3.92 (d, 1H), 5.00 (dd, 1H), 5.45 (d,1H), 5.63 (d, 1H), 6.16 (dd, 1H), 6.87-6.93 (m, 1H), 7.16-7.21 (m, 2H).

Intermediate 9 Preparation of3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazole-5-carbonyl chloride

2.70 g (10.6 mmol) of3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazole-5-carboxylic acid were addedto 45 ml of dichloromethane, and three drops of dimethylformamide (DMF)followed by 2.03 g (15.9 mmol) of oxalyl chloride were then added. Avigorous evolution of gas was observed. The mixture was stirred at roomtemperature for 6 h and solvent and excess oxalyl chloride were thenevaporated under reduced pressure. The resulting crude product was usedin the next step without further purification.

Intermediate 10 Preparation of 3-fluoro-N-hydroxybenzenecarboximidoylchloride

Analogously to the procedure in WO2012/130798 for3,5-dichloro-N-hydroxybenzenecarboximidoyl chloride,3-fluoro-N-hydroxybenzenecarboximidoyl chloride was prepared in twosteps from 3-fluorobenzaldehy de.

Intermediate 11 Preparation of methyl3-(3-fluorophenyl)-5-methyl-4H-isoxazole-5-carboxylate

Analogously to the procedure in WO2012/130798 for methyl3-(3,5-dichlorophenyl)-5-methyl-4H-isoxazole-5-carboxylate, methyl3-(3-fluorophenyl)-5-methyl-4H-isoxazole-5-carboxylate was prepared from3-fluorobenzaldehyde in three steps.

Intermediate 12 Preparation of3-(3-fluorophenyl)-5-methyl-4H-isoxazole-5-carboxylic acid

Analogously to the procedure in WO2012/130798 for3-(3,5-dichlorophenyl)-5-methyl-4H-isoxazole-5-carboxylic acid,3-(3-fluorophenyl)-5-methyl-4H-isoxazole-5-carboxylic acid was preparedby hydrolysis of methyl3-(3-fluorophenyl)-5-methyl-4H-isoxazole-5-carboxylate.

Intermediate 13 Preparation of methyl(1R,4S)-4-aminocyclopent-2-ene-1-carboxylate hydrochloride

Methyl (1R,4S)-4-aminocyclopent-2-ene-1-carboxylate hydrochloride can beprepared from commercially available “Vince lactam”(1S,4R)-2-azabicyclo[2.2.1]hept-5-en-3-one analogously to the methoddescribed by Marco D. Migliore et al.: J. Med. Chem. 2007, 50,6485-6492.

Intermediate 14 Preparation of methyl(1S,4R)-4-aminocyclopent-2-ene-1-carboxylate hydrochloride

Methyl (1S,4R)-4-aminocyclopent-2-ene-1-carboxylate hydrochloride can beprepared from commercially available “Vince lactam”(1R,4S)-2-azabicyclo[2.2.1]hept-5-en-3-one by the method described byMarco D. Migliore et al.: J. Med. Chem. 2007, 50, 6485-6492.

Intermediate 15 Preparation of methyl(4R)-4-aminocyclopent-1-ene-1-carboxylate hydrochloride

Methyl (4R)-4-aminocyclopent-1-ene-1-carboxylate hydrochloride can beprepared from Intermediate 13 analogously to the method described by M.E. B. Smith et al.: Tetrahedron Letters 42 (2001) 1347-1350.

Intermediate 16 Preparation of methyl(4S)-4-aminocyclopent-1-ene-1-carboxylate hydrochloride

Methyl (4S)-4-aminocyclopent-1-ene-1-carboxylate hydrochloride can beprepared from Intermediate 14 by the method described by M. E. B. Smithet al.: Tetrahedron Letters 42 (2001) 1347-1350.

EXAMPLE I-003 Preparation of methyl(1R,4S)-4-[[[3-(3-fluorophenyl)-5-methyl-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopent-2-ene-1-carboxylate

200 mg (0.90 mmol) of3-(3-fluorophenyl)-5-methyl-4H-isoxazole-5-carboxylic acid and 154 mg(0.99 mmol) of 86% pure 1-hydroxybenzotriazole (HOBt) were stirredtogether in 10 ml of dichloromethane at room temperature for 30 min. 175mg (0.99 mmol) of methyl (1R,4S)-4-aminocyclopent-2-ene-1-carboxylatehydrochloride, 343 mg (1.79 mmol) of1-(3-dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride (EDAC) and347 mg (2.69 mmol) of N,N-diisopropylethylamine (DIPEA, “Hünig's base”)were then added in succession and the mixture was stirred at roomtemperature for 16 h.

The reaction mixture was then washed with 0.5M hydrochloric acid and theorganic phase was separated off, dried with sodium sulfate andconcentrated under reduced pressure. The evaporation residue waschromatographed on silica gel (mobile phase: ethyl acetate/n-heptane).This gave 290 mg (91%) of the title compound.

EXAMPLE I-001 Preparation of(1R,4S)-4-[[[3-(3-fluorophenyl)-5-methyl-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopent-2-ene-1-carboxylicacid

270 mg (0.78 mmol) of methyl(1R,4S)-4-[[[3-(3-fluorophenyl)-5-methyl-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopent-2-ene-1-carboxylatewere dissolved in 4 ml of tetrahydrofuran and cooled to 0° C. A solutionof 156 mg (3.90 mmol) of sodium hydroxide in 4 ml of water was thenadded dropwise to this solution, which was then allowed to warm to roomtemperature. After 3 h, the mixture was diluted with water and acidifiedwith 2M hydrochloric acid.

The mixture was extracted with ethyl acetate and the organic phase wasseparated off, dried with sodium sulfate and concentrated under reducedpressure. The evaporation residue was chromatographed on silica gel(mobile phase: ethyl acetate/n-heptane). This gave 190 mg (72%) of thetitle compound.

EXAMPLE II-01 Preparation of3-(3-fluorophenyl)-N-[(1S,4R)-4-[(methoxyamino)carbonyl]cyclopent-2-en-1-yl]-5-methyl-4H-1,2-oxazole-5-carboxamide

31 mg (0.09 mmol) of(1R,4S)-4-[[[3-(3-fluorophenyl)-5-methyl-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopent-2-ene-1-carboxylicacid and 16 mg (0.10 mmol) of 86% pure 1-hydroxybenzotriazole (HOBt)were taken up together in 2 ml of dichloromethane and the mixture wasstirred at room temperature for 20 min. 9 mg (0.11 mmol) ofmethoxylamine hydrochloride, 36 mg (0.19 mmol) of1-(3-dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride (EDAC) and37 mg (0.28 mmol) of N,N-diisopropylethylamine (DIPEA, “Hünig's base”)were then added in succession and the mixture was stirred at roomtemperature for 16 h.

The reaction mixture was then washed with 0.5M hydrochloric acid and theorganic phase was separated off, dried with sodium sulfate andconcentrated under reduced pressure. The evaporation residue waschromatographed on silica gel (mobile phase: ethyl acetate/n-heptane).This gave 26 mg (72%) of the title compound.

EXAMPLE III-03 Preparation of methyl(4R)-4-[[[(5SR)-3-(3-fluorophenyl)-5-methyl-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopentene-1-carboxylate

501 mg (2.25 mmol) of3-(3-fluorophenyl)-5-methyl-4H-isoxazole-5-carboxylic acid and 439 mg(2.47 mmol) of methyl (4R)-4-aminocyclopent-1-ene-1-carboxylate weredissolved in 20 ml of dichloromethane, 4.29 g (6.74 mmol) of 50%strength propylphosphonic anhydride solution (T3P) were added and themixture was left to stir at room temperature for 4 h.

The reaction mixture was then washed with saturated sodium bicarbonatesolution and the organic phase was separated off, dried with sodiumsulfate and concentrated under reduced pressure. The evaporation residuewas chromatographed on silica gel (mobile phase: ethylacetate/n-heptane). This gave 720 mg (90%) of the title compound.

EXAMPLE III-01 Preparation of(4R)-4-[[[(5SR)-3-(3-fluorophenyl)-5-methyl-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopentene-1-carboxylicacid

620 mg (1.79 mmol) of methyl(4R)-4-[[[(5SR)-3-(3-fluorophenyl)-5-methyl-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopentene-1-carboxylatewere dissolved in 6 ml of tetrahydrofuran and cooled to 0° C. A solutionof 129 mg (5.37 mmol) of lithium hydroxide in 6 ml of water was thenadded dropwise to this solution, which was then allowed to warm to roomtemperature. After 30 min, owing to the poor solubility of the startingmaterials, a further 1 ml of tetrahydrofuran and 1 ml of water wereadded. After altogether 4 h, the mixture was diluted with water andacidified with 2M hydrochloric acid. After extraction with ethylacetate, the organic phase was separated off, dried with sodium sulfateand concentrated under reduced pressure. The evaporation residue wasused crude. This gave 610 mg (100%) of the title compound.

EXAMPLE IV-03(5SR)-3-(3-Fluorophenyl)-N-[(1R)-3-[(methoxyamino)carbonyl]cyclopent-3-en-1-yl]-5-methyl-4H-1,2-oxazole-5-carboxamide

121 mg (0.36 mmol) of(4R)-4-[[[(5SR)-3-(3-fluorophenyl)-5-methyl-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopentene-1-carboxylicacid and 36 mg (0.44 mmol) of methoxylamine hydrochloride, 36 mg (0.19mmol) were dissolved in 5 ml of dichloromethane, 347 mg (0.55 mmol) of50% strength propylphosphonic anhydride solution (T3P) and 92 mg (0.91mmol) of triethylamine were added and the mixture was allowed to stir atroom temperature for 2 h.

The reaction mixture was then washed with saturated sodium bicarbonatesolution and the organic phase was separated off, dried with sodiumsulfate and concentrated under reduced pressure. The evaporation residuewas chromatographed on silica gel (mobile phase: ethylacetate/n-heptane). This gave 86 mg (65%) of the title compound.

Analytical data of Examples I-001-I-201 (see Table 1.1).

I-001: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.5180 (3.0); 7.4067 (1.1); 7.3989(1.3); 7.3884 (2.5); 7.3814 (1.4); 7.3766 (3.4); 7.3745 (4.5); 7.3712(5.4); 7.3647 (3.0); 7.3622 (3.9); 7.2894 (0.6); 7.2591 (545.2); 7.2347(0.6); 7.2301 (0.7); 7.2245 (1.0); 7.2213 (0.9); 7.1975 (0.7); 7.1489(0.7); 7.1426 (1.1); 7.1386 (0.7); 7.1322 (0.8); 7.1254 (1.1); 7.1207(1.1); 7.1164 (1.2); 7.1086 (0.7); 7.1045 (0.6); 7.0983 (0.5); 6.9951(3.1); 6.0127 (0.7); 6.0086 (0.8); 5.9989 (1.0); 5.9927 (1.5); 5.9886(1.5); 5.9822 (0.7); 5.9788 (0.7); 5.9724 (0.8); 5.9681 (0.7); 5.9171(0.9); 5.9115 (1.7); 5.9057 (1.0); 5.8976 (1.4); 5.8920 (0.7); 5.8426(0.8); 5.8368 (1.4); 5.8310 (0.8); 5.8229 (1.1); 5.8173 (0.6); 4.9851(0.8); 4.1309 (0.9); 4.1131 (1.0); 3.8227 (2.4); 3.8161 (2.9); 3.7795(2.8); 3.7729 (3.2); 3.5983 (0.7); 3.5919 (0.8); 3.5877 (0.8); 3.5769(0.9); 3.2322 (3.0); 3.2267 (2.5); 3.1890 (2.6); 3.1834 (2.2); 2.6391(0.6); 2.6176 (0.9); 2.6039 (0.7); 2.5963 (0.6); 2.5820 (1.6); 2.5603(1.6); 2.5464 (0.8); 2.5387 (0.7); 2.5249 (1.3); 2.5035 (0.7); 2.0438(4.6); 2.0280 (0.6); 2.0171 (1.0); 2.0060 (0.6); 1.9929 (0.5); 1.9820(0.9); 1.9484 (0.6); 1.9377 (1.1); 1.9269 (0.6); 1.9133 (0.6); 1.9022(1.0); 1.8917 (0.6); 1.7209 (14.2); 1.7131 (16.0); 1.2766 (1.4); 1.2587(3.3); 1.2408 (1.5); 0.1460 (0.6); 0.0080 (6.5); −0.0002 (211.6);−0.0085 (5.9); −0.1496 (0.7) I-002: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.5180(4.8); 7.4076 (1.1); 7.3987 (1.5); 7.3891 (2.5); 7.3779 (3.4); 7.3754(4.9); 7.3724 (5.5); 7.3631 (4.0); 7.3096 (1.4); 7.3015 (0.6); 7.2968(0.9); 7.2919 (1.3); 7.2887 (1.7); 7.2848 (1.4); 7.2840 (1.6); 7.2833(1.6); 7.2816 (1.8); 7.2808 (1.9); 7.2801 (1.9); 7.2792 (1.9); 7.2784(2.0); 7.2777 (2.3); 7.2768 (2.4); 7.2760 (2.7); 7.2752 (3.0); 7.2745(3.2); 7.2737 (3.3); 7.2729 (3.7); 7.2721 (3.9); 7.2713 (4.1); 7.2705(4.8); 7.2697 (5.3); 7.2689 (5.7); 7.2681 (6.6); 7.2673 (7.6); 7.2665(9.0); 7.2657 (10.5); 7.2648 (12.9); 7.2591 (844.5); 7.2536 (10.4);7.2528 (8.3); 7.2520 (6.2); 7.2511 (4.7); 7.2503 (4.0); 7.2495 (3.7);7.2487 (3.2); 7.2479 (2.9); 7.2471 (2.8); 7.2463 (2.4); 7.2455 (2.1);7.2447 (2.1); 7.2439 (1.9); 7.2431 (1.7); 7.2423 (1.6); 7.2415 (1.5);7.2407 (1.5); 7.2399 (1.4); 7.2383 (1.3); 7.2375 (1.1); 7.2359 (1.1);7.2320 (1.0); 7.2274 (1.3); 7.2256 (1.2); 7.2185 (1.0); 7.1971 (1.1);7.1503 (0.9); 7.1440 (1.2); 7.1386 (0.8); 7.1332 (0.9); 7.1267 (1.3);7.1204 (1.2); 7.1173 (1.2); 7.1099 (0.7); 7.0997 (0.6); 6.9951 (4.8);6.0126 (0.8); 6.0061 (0.8); 5.9983 (1.0); 5.9926 (1.6); 5.9884 (1.6);5.9823 (0.8); 5.9790 (0.9); 5.9750 (0.9); 5.9688 (0.8); 5.9164 (0.9);5.9107 (1.7); 5.9051 (1.0); 5.8969 (1.4); 5.8913 (0.8); 5.8427 (0.9);5.8371 (1.5); 5.8314 (0.9); 5.8232 (1.2); 5.8175 (0.7); 4.9869 (0.9);4.1309 (0.8); 4.1130 (0.9); 3.8225 (2.6); 3.8159 (2.8); 3.7793 (3.1);3.7727 (3.2); 3.5886 (0.9); 3.2321 (3.0); 3.2268 (2.7); 3.1889 (2.6);3.1835 (2.4); 2.6406 (0.6); 2.6190 (1.0); 2.6052 (0.8); 2.5977 (0.6);2.5839 (1.6); 2.5625 (1.7); 2.5487 (0.8); 2.5414 (0.7); 2.5274 (1.3);2.5062 (0.5); 2.0438 (4.3); 2.0173 (1.1); 2.0068 (0.6); 1.9927 (0.5);1.9821 (0.9); 1.9507 (0.7); 1.9398 (1.1); 1.9295 (0.6); 1.9153 (0.7);1.9049 (1.0); 1.8941 (0.7); 1.7212 (15.6); 1.7132 (16.0); 1.2766 (1.5);1.2588 (3.2); 1.2409 (1.3); 0.1460 (1.0); 0.0240 (0.6); 0.0208 (0.7);0.0160 (1.0); 0.0136 (1.3); 0.0128 (1.4); 0.0112 (1.8); 0.0080 (10.4);0.0065 (4.3); 0.0056 (4.7); 0.0048 (5.7); −0.0002 (325.4); −0.0058(4.9); −0.0066 (4.2); −0.0085 (9.4); −0.1494 (0.9) I-003: ¹H-NMR(400.0MHz, CDCl3): δ = 7.3828 (0.6); 7.3781 (1.0); 7.3739 (0.7); 7.3703 (0.6);7.2620 (75.2); 3.8274 (0.5); 3.8222 (0.5); 3.7842 (0.6); 3.7790 (0.6);3.7554 (4.0); 3.7254 (4.0); 3.2336 (0.6); 3.2264 (0.6); 1.7269 (2.8);1.7154 (2.8); 1.5533 (16.0); 0.0080 (0.8); −0.0002 (27.2); −0.0085 (0.8)I-004: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.5210 (0.7); 7.3897 (0.8); 7.3867(0.7); 7.3828 (1.4); 7.3781 (2.2); 7.3739 (1.5); 7.3704 (1.2); 7.3651(0.8); 7.2621 (120.2); 7.1298 (0.5); 6.9980 (0.7); 5.9476 (0.6); 5.8954(0.7); 5.8061 (0.6); 5.7923 (0.5); 3.8275 (1.1); 3.8223 (1.1); 3.7843(1.2); 3.7791 (1.2); 3.7555 (8.4); 3.7254 (8.3); 3.2337 (1.1); 3.2265(1.1); 3.1905 (1.0); 3.1833 (1.0); 1.7270 (5.9); 1.7154 (5.9); 1.5550(16.0); 0.0080 (1.4); −0.0002 (43.8); −0.0085 (1.2) I-007: ¹H-NMR(400.0MHz, CDCl3): δ = 7.5190 (1.4); 7.2762 (0.5); 7.2754 (0.5); 7.2746 (0.6);7.2738 (0.7); 7.2730 (0.7); 7.2722 (0.8); 7.2714 (0.9); 7.2706 (1.0);7.2698 (1.1); 7.2690 (1.2); 7.2682 (1.4); 7.2674 (1.6); 7.2666 (1.9);7.2658 (2.4); 7.2650 (3.0); 7.2600 (235.0); 7.2505 (0.9); 7.2489 (0.5);7.1761 (1.8); 7.1702 (2.6); 7.1665 (3.4); 7.1635 (2.4); 7.1607 (3.4);7.1562 (3.2); 7.1503 (3.4); 7.1466 (3.3); 7.1408 (2.0); 7.1340 (0.5);7.0784 (0.6); 6.9960 (1.4); 6.8947 (0.8); 6.8889 (1.6); 6.8835 (1.3);6.8729 (1.6); 6.8671 (2.7); 6.8614 (1.5); 6.8512 (0.8); 6.8453 (1.3);6.8395 (0.6); 5.9532 (0.9); 5.9497 (1.1); 5.9470 (1.0); 5.9433 (1.0);5.9394 (1.1); 5.9336 (1.6); 5.9298 (1.5); 5.9239 (0.7); 5.9203 (0.7);5.9163 (0.8); 5.9140 (0.8); 5.9101 (0.7); 5.8572 (0.8); 5.8517 (1.6);5.8461 (0.9); 5.8434 (0.7); 5.8379 (1.3); 5.8324 (0.8); 5.7706 (0.7);5.7650 (1.5); 5.7591 (1.2); 5.7512 (1.3); 5.7453 (0.9); 4.9764 (0.8);3.8038 (0.7); 3.7963 (2.5); 3.7910 (3.1); 3.7606 (0.8); 3.7532 (2.8);3.7479 (3.4); 3.4111 (0.8); 3.4052 (0.6); 3.2003 (0.7); 3.1962 (1.4);3.1919 (2.9); 3.1815 (2.3); 3.1571 (0.6); 3.1529 (1.2); 3.1488 (2.5);3.1383 (2.0); 2.5279 (0.5); 2.5068 (0.9); 2.4931 (0.7); 2.4857 (0.6);2.4775 (0.7); 2.4720 (1.1); 2.4564 (1.2); 2.4510 (0.7); 2.4427 (0.8);2.4352 (0.7); 2.4216 (1.2); 2.4005 (0.7); 1.9201 (0.9); 1.9099 (1.1);1.8997 (0.6); 1.8749 (0.9); 1.8646 (0.6); 1.8285 (0.8); 1.8179 (1.2);1.8073 (0.8); 1.7937 (0.6); 1.7833 (1.0); 1.7725 (1.2); 1.7222 (13.4);1.7164 (9.2); 1.7075 (16.0); 1.6794 (0.5); 1.5434 (18.6); 1.4979 (10.3);1.4791 (57.7); 1.4415 (67.5); 1.4258 (16.5); 1.3684 (0.5); 1.2550 (0.5);0.0080 (2.4); −0.0002 (90.6); −0.0085 (2.9) I-008: ¹H-NMR(400.0 MHz,CDCl3): δ = 7.5181 (9.4); 7.4220 (2.7); 7.4089 (3.0); 7.4038 (3.3);7.3792 (4.4); 7.3709 (14.2); 7.3659 (7.5); 7.3595 (10.2); 7.3555 (11.8);7.3504 (13.7); 7.3462 (11.5); 7.3399 (11.6); 7.3271 (5.6); 7.3096 (2.2);7.3072 (2.0); 7.3017 (1.6); 7.2961 (1.6); 7.2929 (1.6); 7.2912 (2.0);7.2889 (2.1); 7.2881 (2.2); 7.2858 (2.5); 7.2850 (2.4); 7.2841 (2.5);7.2834 (3.0); 7.2826 (2.6); 7.2818 (2.7); 7.2810 (3.1); 7.2802 (3.2);7.2794 (3.0); 7.2786 (3.2); 7.2778 (3.5); 7.2770 (3.5); 7.2762 (4.0);7.2754 (4.6); 7.2746 (4.8); 7.2738 (5.3); 7.2730 (5.4); 7.2722 (5.8);7.2714 (6.5); 7.2706 (7.2); 7.2698 (8.4); 7.2690 (9.6); 7.2682 (10.3);7.2675 (11.1); 7.2666 (12.7); 7.2658 (15.0); 7.2650 (18.2); 7.2642(22.7); 7.2634 (29.4); 7.2626 (39.5); 7.2592 (1761.4); 7.2545 (19.6);7.2536 (14.7); 7.2528 (11.4); 7.2520 (8.5); 7.2512 (6.5); 7.2504 (4.1);7.2496 (2.8); 7.2488 (1.6); 7.2480 (1.9); 7.2472 (1.9); 7.2464 (1.7);7.2456 (1.5); 7.2448 (1.4); 7.2095 (3.9); 7.1697 (3.0); 7.1641 (4.2);7.1594 (5.0); 7.1468 (3.0); 7.1442 (3.4); 7.1380 (2.2); 6.9952 (10.2);6.8705 (2.0); 6.0318 (1.3); 6.0221 (1.5); 6.0162 (1.6); 5.9762 (1.6);5.8918 (1.5); 5.8578 (1.6); 5.8517 (2.2); 5.8379 (1.9); 5.8056 (1.3);5.3058 (6.0); 5.2971 (11.0); 5.1835 (7.1); 5.1518 (4.5); 5.1302 (11.9);5.1154 (3.9); 3.8959 (1.2); 3.7963 (4.1); 3.7749 (1.8); 3.7530 (3.8);3.7486 (3.1); 3.7222 (2.4); 3.6983 (1.2); 3.1943 (3.1); 3.1820 (2.1);3.1508 (3.1); 3.1387 (1.7); 2.7370 (1.3); 2.7284 (1.2); 2.7161 (1.3);2.6931 (1.2); 2.0048 (11.1); 1.9740 (1.3); 1.9362 (1.3); 1.7564 (4.0);1.7124 (14.5); 1.7073 (16.0); 1.5325 (189.8); 1.2551 (1.3); 0.1458(1.5); 0.0080 (17.1); −0.0002 (649.1); −0.0085 (18.4); −0.0499 (1.5);−0.1496 (1.5) I-009: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.5184 (4.9); 7.3083(8.8); 7.2595 (719.7); 7.2087 (2.2); 7.1645 (5.2); 7.1503 (4.6); 6.9956(4.1); 6.8887 (1.9); 5.9882 (2.1); 5.9146 (1.6); 5.8146 (1.7); 4.5239(2.8); 4.5089 (1.6); 4.4260 (1.8); 4.4124 (2.7); 4.3877 (3.2); 4.3737(3.9); 4.3582 (3.8); 4.3514 (3.4); 4.3368 (3.5); 4.3213 (1.8); 3.8054(3.3); 3.7981 (4.3); 3.7878 (3.1); 3.7714 (4.4); 3.7544 (6.5); 3.7368(3.6); 3.7194 (4.5); 3.7049 (4.5); 3.6825 (4.3); 3.6683 (3.6); 3.6546(2.0); 3.2021 (2.8); 3.1951 (2.6); 3.1882 (2.3); 3.1595 (2.4); 3.1454(2.2); 2.0051 (5.6); 1.7278 (13.4); 1.7199 (16.0); 1.7127 (12.2); 1.5323(123.4); 0.0480 (3.2); −0.0002 (252.3); −0.0085 (10.0) I-010:¹H-NMR(400.0 MHz, CDCl3): δ = 7.5189 (2.2); 7.3103 (1.2); 7.2785 (0.6);7.2777 (0.6); 7.2769 (0.6); 7.2762 (0.7); 7.2754 (0.7); 7.2745 (0.8);7.2737 (0.9); 7.2730 (1.0); 7.2722 (1.1); 7.2714 (1.2); 7.2706 (1.4);7.2698 (1.4); 7.2690 (1.7); 7.2682 (1.9); 7.2674 (2.1); 7.2666 (2.6);7.2658 (3.2); 7.2650 (4.0); 7.2641 (5.2); 7.2633 (7.4); 7.2599 (391.8);7.2512 (1.4); 7.2487 (0.8); 7.2471 (0.6); 7.2100 (1.3); 7.1794 (1.4);7.1736 (1.9); 7.1709 (3.2); 7.1682 (2.5); 7.1651 (3.5); 7.1626 (3.0);7.1598 (2.6); 7.1538 (2.9); 7.1512 (3.2); 7.1490 (2.6); 7.1454 (2.8);7.1330 (0.5); 7.0631 (0.6); 6.9960 (2.4); 6.9098 (0.7); 6.9019 (0.8);6.8983 (0.9); 6.8880 (1.2); 6.8855 (1.2); 6.8824 (1.4); 6.8800 (1.3);6.8767 (1.5); 6.8744 (1.5); 6.8607 (0.7); 6.8528 (0.7); 6.7889 (0.6);6.0675 (1.2); 6.0632 (1.3); 6.0614 (1.3); 6.0570 (1.2); 6.0536 (1.4);6.0493 (1.5); 6.0474 (1.5); 6.0431 (1.5); 6.0389 (0.6); 6.0323 (0.6);6.0249 (0.7); 6.0185 (0.8); 5.9937 (0.6); 5.9854 (1.3); 5.9799 (2.4);5.9755 (1.8); 5.9715 (1.6); 5.9662 (2.2); 5.9619 (2.0); 5.9525 (0.7);5.9452 (1.3); 5.9398 (1.7); 5.9327 (1.6); 5.9267 (2.8); 5.9209 (1.7);5.9188 (1.8); 5.9131 (2.9); 5.9073 (1.5); 5.8994 (0.8); 5.8612 (0.6);5.8557 (1.3); 5.8474 (1.4); 5.8417 (1.4); 5.8362 (0.6); 5.8334 (0.7);5.2987 (0.5); 5.1930 (0.5); 5.1877 (0.7); 5.1822 (0.7); 5.1775 (0.8);5.1721 (0.6); 5.1666 (0.6); 5.1234 (0.7); 5.1026 (0.7); 5.0272 (0.6);4.6740 (2.3); 4.6718 (1.5); 4.6537 (6.9); 4.6515 (4.3); 4.6335 (7.2);4.6312 (4.2); 4.6132 (2.5); 4.6108 (1.5); 4.5666 (1.2); 4.5591 (0.8);4.5553 (0.9); 4.5457 (3.7); 4.5383 (2.1); 4.5345 (2.4); 4.5293 (2.4);4.5247 (4.1); 4.5174 (2.4); 4.5136 (2.5); 4.5084 (5.9); 4.5061 (3.9);4.5039 (2.1); 4.5004 (1.2); 4.4946 (2.6); 4.4875 (6.2); 4.4852 (3.9);4.4795 (2.8); 4.4737 (2.5); 4.4665 (2.2); 4.4585 (2.7); 4.4527 (0.9);4.4375 (0.9); 3.9071 (0.8); 3.9041 (1.4); 3.9011 (1.1); 3.8951 (1.1);3.8891 (0.9); 3.8852 (0.8); 3.8792 (1.1); 3.8732 (1.1); 3.8673 (0.9);3.8393 (0.5); 3.8335 (0.5); 3.8112 (0.5); 3.8045 (1.7); 3.7983 (2.9);3.7866 (2.1); 3.7612 (1.8); 3.7551 (3.6); 3.7465 (2.8); 3.7435 (2.4);3.7262 (0.6); 3.7109 (1.1); 3.6630 (0.6); 3.6316 (0.6); 3.2055 (1.8);3.2004 (2.2); 3.1922 (2.1); 3.1623 (1.6); 3.1572 (1.9); 3.1490 (1.8);2.7915 (1.1); 2.7795 (1.0); 2.7709 (1.1); 2.7588 (1.1); 2.7560 (1.3);2.7440 (1.3); 2.7353 (1.2); 2.7233 (1.3); 2.6884 (0.6); 2.6524 (0.6);2.6301 (0.9); 2.6239 (0.6); 2.6160 (0.7); 2.6088 (0.6); 2.6028 (1.0);2.5948 (0.9); 2.5879 (0.9); 2.5820 (0.6); 2.5736 (0.6); 2.5667 (1.5);2.5519 (0.6); 2.5452 (0.7); 2.5309 (0.8); 2.5099 (0.6); 2.0746 (0.5);2.0668 (0.8); 2.0530 (1.0); 2.0417 (1.1); 2.0311 (1.7); 2.0198 (1.2);2.0175 (1.0); 2.0051 (2.9); 1.9958 (1.2); 1.9849 (1.5); 1.9745 (0.7);1.9620 (0.5); 1.9507 (1.1); 1.9401 (0.6); 1.9173 (0.8); 1.9066 (0.8);1.8823 (0.5); 1.8716 (0.8); 1.8653 (0.5); 1.7560 (0.8); 1.7236 (13.3);1.7208 (16.0); 1.7129 (12.0); 1.5405 (29.0); 1.2558 (0.9); 0.0502 (0.6);0.0080 (4.2); −0.0002 (146.2); −0.0085 (3.8) I-011: ¹H-NMR(400.6 MHz,CDCl3): δ = 8.7204 (0.6); 7.3504 (5.3); 7.3284 (5.4); 7.2803 (5.6);7.1949 (1.0); 7.1894 (1.9); 7.1770 (9.8); 7.1716 (12.3); 7.1574 (12.2);7.1521 (9.6); 7.1398 (1.7); 6.8809 (2.4); 6.8753 (4.2); 6.8697 (2.4);6.8593 (4.8); 6.8536 (8.0); 6.8480 (4.3); 6.8376 (2.5); 6.8319 (4.0);6.8264 (2.0); 6.2028 (8.5); 6.1761 (9.4); 6.1598 (10.0); 6.1331 (10.2);6.0241 (5.3); 6.0202 (4.8); 6.0157 (5.6); 6.0120 (6.5); 5.9206 (4.8);5.9152 (8.6); 5.9096 (5.9); 5.9015 (7.0); 5.8962 (3.9); 5.5434 (16.0);5.5004 (14.1); 5.3397 (15.4); 5.3129 (14.5); 5.0674 (2.1); 5.0479 (3.9);5.0282 (2.1); 3.9584 (12.8); 3.9152 (14.4); 3.7392 (0.5); 3.5761 (3.5);3.5624 (3.6); 3.3609 (14.8); 3.3178 (12.9); 2.5451 (2.3); 2.5241 (4.6);2.5100 (3.3); 2.5033 (3.1); 2.4892 (5.0); 2.4684 (2.4); 2.0524 (1.1);1.9537 (2.7); 1.9442 (4.9); 1.9346 (2.8); 1.9187 (2.6); 1.9093 (4.4);1.8998 (2.5); 1.2609 (1.7); 1.2580 (2.3); −0.0002 (3.6) I-012:¹H-NMR(400.0 MHz, CDCl3): δ = 7.2616 (17.7); 7.1908 (1.4); 7.1877 (1.0);7.1850 (1.5); 7.1819 (0.9); 7.1741 (1.0); 7.1709 (1.6); 7.1652 (1.3);6.8999 (0.5); 6.8840 (0.6); 6.8781 (1.0); 6.8723 (0.5); 6.8564 (0.5);6.2027 (1.0); 6.1759 (1.2); 6.1596 (1.2); 6.1328 (1.3); 5.9550 (0.6);5.9512 (0.7); 5.9488 (0.7); 5.9450 (0.6); 5.8834 (0.6); 5.8779 (1.2);5.8722 (0.7); 5.8697 (0.5); 5.8640 (0.9); 5.5540 (1.7); 5.5523 (1.8);5.5109 (1.5); 5.5092 (1.5); 5.3417 (1.5); 5.3402 (1.5); 5.3150 (1.4);5.3135 (1.4); 3.9357 (1.9); 3.8928 (2.2); 3.7349 (16.0); 3.3290 (1.8);3.2860 (1.6); 2.5007 (0.8); 2.4868 (0.6); 2.4797 (0.5); 2.4658 (0.9);1.9029 (0.8); 1.8680 (0.7); 1.5730 (2.1); −0.0002 (6.6) I-013:¹H-NMR(400.0 MHz, CDCl3): δ = 7.2611 (45.2); 7.2013 (0.6); 7.1954 (0.6);7.1890 (2.7); 7.1859 (2.2); 7.1833 (3.2); 7.1802 (1.9); 7.1722 (1.8);7.1691 (3.0); 7.1634 (2.8); 7.1571 (0.7); 7.1511 (0.6); 6.9034 (0.6);6.8975 (1.0); 6.8917 (0.5); 6.8816 (1.2); 6.8758 (2.0); 6.8700 (1.0);6.8598 (0.6); 6.8541 (1.0); 6.2005 (2.0); 6.1737 (2.2); 6.1574 (2.4);6.1306 (2.4); 5.9689 (0.9); 5.9652 (1.0); 5.9627 (1.0); 5.9589 (1.0);5.9552 (1.2); 5.9514 (1.3); 5.9489 (1.3); 5.9451 (1.2); 5.8777 (1.2);5.8722 (2.3); 5.8666 (1.3); 5.8640 (1.0); 5.8583 (1.7); 5.8528 (0.9);5.5505 (3.2); 5.5488 (3.3); 5.5073 (2.9); 5.5057 (2.9); 5.3384 (2.9);5.3369 (2.9); 5.3117 (2.7); 5.3102 (2.7); 5.0256 (0.7); 5.0219 (0.7);4.2102 (1.5); 4.1930 (4.7); 4.1925 (4.7); 4.1751 (5.0); 4.1571 (1.7);3.9377 (3.7); 3.8948 (4.2); 3.5132 (0.5); 3.5095 (0.6); 3.5065 (0.6);3.5036 (0.6); 3.5005 (0.6); 3.4976 (0.7); 3.4948 (0.7); 3.4919 (0.6);3.4888 (0.7); 3.4859 (0.6); 3.4824 (0.6); 3.4792 (0.5); 3.3265 (3.6);3.2835 (3.2); 2.5160 (0.9); 2.4949 (1.6); 2.4810 (1.1); 2.4738 (0.9);2.4600 (1.8); 2.4389 (0.9); 1.9103 (0.8); 1.9006 (1.5); 1.8909 (0.8);1.8753 (0.7); 1.8656 (1.3); 1.8559 (0.7); 1.5651 (10.1); 1.2996 (7.7);1.2817 (16.0); 1.2639 (7.6); 0.0080 (0.5); −0.0002 (16.3) I-014:¹H-NMR(400.0 MHz, CDCl3): δ = 7.2623 (40.5); 7.1967 (0.9); 7.1910 (1.9);7.1785 (9.6); 7.1728 (11.6); 7.1698 (7.4); 7.1620 (7.4); 7.1588 (11.7);7.1532 (9.5); 7.1465 (1.8); 7.1407 (1.8); 6.9176 (2.4); 6.9119 (4.1);6.9061 (2.3); 6.8960 (5.0); 6.8902 (8.2); 6.8844 (4.3); 6.8743 (2.6);6.8686 (4.1); 6.8628 (2.0); 6.7857 (4.9); 6.7653 (5.0); 6.1919 (8.4);6.1651 (9.2); 6.1487 (9.8); 6.1220 (10.1); 6.0063 (4.4); 6.0018 (5.5);6.0004 (5.7); 5.9959 (5.0); 5.9924 (5.8); 5.9879 (6.7); 5.9865 (6.8);5.9820 (5.5); 5.8774 (5.2); 5.8718 (9.3); 5.8660 (5.9); 5.8637 (5.3);5.8579 (7.7); 5.8522 (4.2); 5.5474 (13.9); 5.5461 (14.2); 5.5043 (12.3);5.5029 (12.5); 5.3522 (12.9); 5.3511 (13.1); 5.3255 (12.2); 5.3244(12.3); 5.3001 (16.0); 5.1360 (1.8); 5.1305 (1.9); 5.1253 (2.4); 5.1204(3.2); 5.1154 (3.3); 5.1091 (3.4); 5.1045 (3.1); 5.0994 (2.5); 5.0948(2.0); 5.0890 (1.7); 3.9526 (13.2); 3.9094 (15.0); 3.7771 (2.5); 3.7713(3.5); 3.7655 (3.8); 3.7596 (3.6); 3.7552 (3.6); 3.7494 (4.0); 3.7435(3.7); 3.7377 (2.7); 3.6848 (0.5); 3.3362 (13.5); 3.2930 (11.9); 2.6937(3.2); 2.6820 (3.4); 2.6732 (3.5); 2.6613 (4.1); 2.6586 (4.5); 2.6469(3.8); 2.6380 (3.5); 2.6263 (3.4); 1.8828 (3.2); 1.8712 (3.4); 1.8607(3.6); 1.8484 (5.3); 1.8360 (3.4); 1.8255 (3.0); 1.8139 (3.1); 1.2558(3.5); 0.8806 (0.8); 0.0079 (2.0); −0.0002 (53.2); −0.0085 (2.4) I-015:¹H-NMR(400.0 MHz, CDCl3): δ = 7.5190 (0.6); 7.2602 (103.5); 7.1881(0.8); 7.1780 (1.6); 7.1724 (1.8); 7.1686 (1.5); 7.1624 (1.6); 7.1588(1.6); 6.9961 (0.6); 6.8849 (1.0); 6.8794 (0.9); 6.1980 (0.6); 6.1954(0.6); 6.1686 (0.7); 6.1551 (0.8); 6.1522 (0.8); 6.1282 (0.7); 6.1255(0.8); 5.9632 (0.7); 5.8718 (0.6); 5.5705 (0.9); 5.5512 (1.6); 5.5260(0.8); 5.5081 (1.4); 5.3590 (1.0); 5.3453 (0.7); 5.3321 (1.0); 5.3171(0.6); 4.5456 (0.8); 4.5377 (1.3); 4.5244 (0.8); 4.5200 (1.3); 4.5168(1.4); 4.5135 (0.8); 4.4991 (1.2); 4.4920 (0.6); 4.1796 (0.6); 4.1666(0.5); 3.9381 (1.2); 3.9319 (0.8); 3.9015 (0.6); 3.8951 (1.3); 3.8890(0.9); 3.5844 (0.6); 3.5697 (0.8); 3.3324 (1.5); 3.3273 (1.1); 3.2893(1.2); 3.2844 (1.0); 1.8561 (0.8); 1.8484 (1.1); 1.8409 (0.7); 1.8325(0.7); 1.5453 (16.0); 1.2559 (0.8); 0.9055 (0.5); 0.8898 (0.6); 0.0080(1.3); −0.0002 (37.3); −0.0085 (1.2) I-016: ¹H-NMR(400.0 MHz, CDCl3): δ= 7.5204 (1.5); 7.3604 (0.7); 7.3426 (0.5); 7.3138 (0.9); 7.3104 (0.6);7.3018 (0.9); 7.2992 (1.0); 7.2931 (1.2); 7.2898 (1.0); 7.2871 (1.2);7.2846 (1.3); 7.2829 (1.4); 7.2796 (1.7); 7.2738 (2.4); 7.2723 (2.6);7.2702 (3.9); 7.2615 (264.6); 7.2538 (3.3); 7.2515 (1.0); 7.2478 (1.0);7.2456 (1.0); 7.2442 (1.0); 7.2407 (1.1); 7.2389 (0.9); 7.2363 (1.1);7.2304 (0.8); 7.2262 (1.0); 7.2219 (0.9); 7.2200 (0.8); 7.2114 (2.0);7.2066 (1.4); 7.1886 (8.0); 7.1828 (11.0); 7.1807 (13.7); 7.1779 (14.1);7.1749 (16.4); 7.1721 (16.1); 7.1689 (14.0); 7.1632 (14.2); 7.1610(15.2); 7.1553 (12.4); 7.0943 (2.0); 7.0755 (3.0); 7.0565 (1.9); 6.9974(1.5); 6.9133 (3.5); 6.9071 (4.1); 6.9031 (4.6); 6.9010 (4.6); 6.8974(4.9); 6.8950 (5.1); 6.8916 (5.4); 6.8853 (6.3); 6.8813 (7.6); 6.8793(7.1); 6.8756 (5.2); 6.8735 (4.7); 6.8701 (3.0); 6.8635 (3.2); 6.8596(3.6); 6.8577 (3.3); 6.8539 (2.0); 6.8382 (1.5); 6.8338 (1.4); 6.8228(1.5); 6.8182 (1.0); 6.7565 (1.2); 6.7384 (1.2); 6.1991 (7.1); 6.1938(3.6); 6.1894 (2.3); 6.1829 (2.0); 6.1723 (7.8); 6.1669 (4.3); 6.1626(2.7); 6.1561 (10.1); 6.1505 (4.4); 6.1462 (2.8); 6.1398 (2.6); 6.1292(9.3); 6.1235 (5.3); 6.1130 (3.3); 6.1044 (3.9); 6.0942 (2.2); 6.0835(0.6); 6.0730 (1.4); 6.0624 (1.3); 6.0523 (0.6); 6.0098 (0.9); 5.9945(3.4); 5.9882 (3.4); 5.9843 (8.6); 5.9772 (8.4); 5.9742 (8.2); 5.9700(6.8); 5.9669 (11.9); 5.9639 (8.1); 5.9569 (8.9); 5.9538 (5.9); 5.9508(3.8); 5.9464 (4.5); 5.9406 (3.2); 5.9355 (2.9); 5.9248 (2.7); 5.9167(3.8); 5.9112 (6.1); 5.9056 (3.4); 5.9030 (2.5); 5.8974 (4.1); 5.8917(2.5); 5.8832 (2.2); 5.8774 (1.4); 5.8668 (3.6); 5.8611 (6.1); 5.8556(4.2); 5.8529 (4.2); 5.8471 (9.4); 5.8414 (4.9); 5.8330 (2.5); 5.8293(4.3); 5.8191 (2.0); 5.8082 (0.6); 5.7979 (1.3); 5.7872 (1.1); 5.6195(0.6); 5.6148 (0.6); 5.5916 (0.8); 5.5710 (8.7); 5.5696 (8.6); 5.5503(15.2); 5.5441 (3.6); 5.5280 (7.4); 5.5265 (7.4); 5.5071 (12.8); 5.5010(2.9); 5.4035 (0.9); 5.3905 (1.0); 5.3766 (1.1); 5.3597 (10.0); 5.3554(4.8); 5.3452 (8.4); 5.3438 (7.6); 5.3329 (9.4); 5.3287 (4.5); 5.3185(7.5); 5.1264 (0.8); 5.1210 (1.0); 5.1165 (1.2); 5.1109 (1.3); 5.1059(1.3); 5.1005 (1.3); 5.0958 (1.0); 5.0389 (3.2); 5.0346 (3.2); 4.6555(0.5); 4.6465 (0.8); 4.6359 (1.4); 4.6257 (1.5); 4.6156 (1.6); 4.6057(1.3); 4.5957 (0.8); 4.5857 (0.6); 4.4901 (0.6); 4.4807 (0.6); 4.4566(1.2); 4.4468 (1.2); 4.4227 (0.8); 4.4132 (0.8); 4.3881 (2.2); 4.3774(8.0); 4.3672 (7.5); 4.3588 (5.0); 4.3541 (4.6); 4.3488 (5.3); 4.3433(16.0); 4.3331 (14.2); 4.3250 (9.0); 4.3202 (5.8); 4.3151 (8.5); 4.3093(9.8); 4.2989 (7.6); 4.2909 (5.0); 4.2864 (6.0); 4.2810 (4.4); 4.2756(3.8); 4.2627 (1.9); 4.2523 (2.8); 4.2414 (1.7); 3.9689 (0.7); 3.9487(3.7); 3.9445 (4.2); 3.9388 (11.6); 3.9368 (12.5); 3.9296 (3.7); 3.9055(4.1); 3.9013 (4.9); 3.8959 (13.6); 3.8938 (14.5); 3.8864 (4.3); 3.8801(1.1); 3.8361 (0.7); 3.8303 (1.0); 3.8240 (1.1); 3.8161 (1.2); 3.8102(1.4); 3.8020 (1.3); 3.7943 (1.1); 3.7881 (0.9); 3.7822 (0.6); 3.6098(2.6); 3.6042 (3.1); 3.5989 (3.2); 3.5935 (3.2); 3.5911 (3.1); 3.5880(3.2); 3.5852 (2.9); 3.3846 (0.8); 3.3628 (2.3); 3.3482 (2.6); 3.3348(8.9); 3.3320 (13.6); 3.3283 (10.2); 3.3070 (1.2); 3.2890 (11.4); 3.2852(8.7); 3.0935 (0.6); 3.0729 (0.7); 3.0460 (1.1); 3.0246 (1.1); 3.0190(1.0); 2.9973 (1.0); 2.7229 (0.9); 2.7106 (0.9); 2.7023 (1.2); 2.6996(1.0); 2.6877 (2.0); 2.6787 (1.2); 2.6755 (1.1); 2.6671 (1.9); 2.6549(1.1); 2.6438 (1.1); 2.6316 (1.0); 2.6184 (2.2); 2.5973 (3.8); 2.5833(2.9); 2.5760 (2.9); 2.5722 (2.6); 2.5621 (4.3); 2.5511 (4.0); 2.5408(2.7); 2.5370 (3.3); 2.5301 (3.0); 2.5160 (4.6); 2.4948 (2.7); 2.4646(1.0); 2.4597 (1.0); 2.4332 (0.9); 2.4268 (0.9); 2.3858 (0.7); 1.9669(2.2); 1.9566 (4.3); 1.9462 (2.5); 1.9344 (3.3); 1.9239 (5.1); 1.9144(2.7); 1.9110 (2.8); 1.8992 (2.6); 1.8892 (3.9); 1.8793 (2.1); 1.8756(1.3); 1.8624 (0.9); 1.8517 (0.8); 1.8402 (0.8); 1.5840 (5.0); 0.9038(1.4); 0.9001 (1.5); 0.8883 (1.3); 0.8845 (1.4); 0.0081 (4.4); −0.0002(146.2); −0.0084 (5.6); −0.0138 (0.8); −0.0160 (0.6); −0.0504 (0.8)I-017: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.5201 (2.0); 7.3116 (2.0); 7.2613(353.0); 7.2285 (1.9); 7.2115 (1.8); 7.1871 (6.0); 7.1795 (11.5); 7.1738(13.4); 7.1676 (10.6); 7.1599 (12.5); 7.1542 (9.5); 7.1417 (2.6); 7.1139(1.7); 7.0955 (2.1); 6.9972 (2.0); 6.9070 (4.1); 6.9005 (4.2); 6.8944(3.8); 6.8911 (4.2); 6.8850 (5.9); 6.8794 (6.7); 6.8732 (4.1); 6.8637(2.7); 6.8571 (3.3); 6.7431 (1.2); 6.2023 (4.1); 6.1987 (5.0); 6.1948(2.5); 6.1756 (4.7); 6.1719 (5.5); 6.1681 (2.9); 6.1592 (5.2); 6.1555(6.9); 6.1390 (1.4); 6.1324 (4.9); 6.1288 (6.1); 6.1121 (1.0); 5.9631(3.3); 5.9490 (5.8); 5.9446 (5.5); 5.9398 (5.2); 5.9368 (5.2); 5.9255(2.8); 5.9193 (2.2); 5.8940 (2.5); 5.8885 (4.5); 5.8805 (3.4); 5.8748(3.7); 5.8690 (2.1); 5.8601 (1.9); 5.8458 (3.1); 5.8401 (4.4); 5.8344(2.7); 5.8264 (3.8); 5.8203 (2.6); 5.8138 (2.2); 5.8088 (1.6); 5.5703(7.0); 5.5688 (7.4); 5.5491 (12.5); 5.5271 (6.2); 5.5256 (6.3); 5.5060(11.0); 5.3577 (8.4); 5.3423 (5.9); 5.3309 (8.1); 5.3156 (5.5); 5.0955(1.1); 5.0328 (3.1); 4.6260 (0.7); 4.6157 (0.8); 4.6056 (1.1); 4.5960(0.8); 4.4041 (1.2); 4.3901 (3.8); 4.3784 (7.4); 4.3747 (6.0); 4.3717(5.6); 4.3657 (6.5); 4.3623 (7.2); 4.3586 (5.2); 4.3555 (7.1); 4.3523(7.5); 4.3476 (4.5); 4.3400 (4.4); 4.3364 (5.5); 4.3207 (3.2); 4.3181(3.3); 4.3101 (2.6); 4.3066 (3.0); 4.2947 (1.2); 4.2908 (1.3); 4.1926(1.8); 4.1798 (4.2); 4.1667 (3.8); 4.1290 (1.5); 4.1179 (1.7); 3.9494(2.9); 3.9447 (3.6); 3.9381 (14.1); 3.9284 (1.9); 3.9063 (3.4); 3.9016(4.0); 3.8951 (16.0); 3.8854 (2.1); 3.7431 (1.1); 3.5846 (5.4); 3.5697(5.8); 3.5638 (3.7); 3.5559 (4.2); 3.5408 (3.5); 3.3299 (10.0); 3.3273(9.8); 3.3094 (1.5); 3.2982 (1.6); 3.2869 (8.8); 3.2842 (8.6); 3.0154(0.8); 2.6826 (0.9); 2.6700 (1.4); 2.6494 (1.3); 2.6356 (0.9); 2.6142(0.6); 2.5831 (1.6); 2.5617 (4.4); 2.5500 (5.5); 2.5392 (5.4); 2.5355(7.4); 2.5237 (7.6); 2.5193 (6.4); 2.5128 (5.4); 2.5090 (8.4); 2.4975(8.4); 2.4832 (6.6); 2.4708 (5.0); 2.4548 (3.7); 2.4445 (2.0); 2.4288(1.6); 2.3503 (1.2); 2.3319 (0.9); 1.9505 (1.7); 1.9404 (2.7); 1.9347(1.9); 1.9116 (3.0); 1.9024 (4.4); 1.8961 (3.3); 1.8766 (3.7); 1.8644(6.4); 1.8572 (6.8); 1.8486 (8.1); 1.8413 (5.6); 1.8328 (5.2); 1.5628(12.0); 1.3002 (1.5); 1.2818 (1.5); 1.2555 (5.7); 1.0634 (0.9); 0.9033(4.3); 0.8966 (3.6); 0.8875 (4.6); 0.8808 (3.8); 0.0501 (0.7); 0.0080(3.7); −0.0002 (121.4); −0.0084 (5.1); −0.0498 (0.7) I-018: ¹H-NMR(400.0MHz, CDCl3): δ = 7.5189 (0.6); 7.2601 (108.4); 7.1902 (1.3); 7.1844(1.7); 7.1805 (2.0); 7.1746 (2.5); 7.1704 (2.4); 7.1645 (2.0); 7.1605(1.8); 7.1549 (1.8); 6.9961 (0.6); 6.8964 (0.8); 6.8807 (0.8); 6.8749(1.4); 6.8691 (0.7); 6.8531 (0.7); 6.2032 (1.0); 6.1999 (1.0); 6.1764(1.0); 6.1731 (1.1); 6.1601 (1.2); 6.1567 (1.2); 6.1333 (1.2); 6.1299(1.2); 5.9775 (0.6); 5.9751 (0.6); 5.9709 (0.9); 5.9672 (1.0); 5.9640(1.2); 5.9610 (1.0); 5.9572 (1.0); 5.9526 (0.6); 5.9504 (0.6); 5.8813(0.6); 5.8756 (1.1); 5.8701 (0.7); 5.8675 (0.5); 5.8619 (0.8); 5.8290(0.6); 5.8233 (1.0); 5.8177 (0.6); 5.8095 (0.8); 5.5719 (1.5); 5.5704(1.4); 5.5499 (1.6); 5.5483 (1.6); 5.5288 (1.3); 5.5272 (1.3); 5.5068(1.4); 5.5052 (1.4); 5.3540 (1.4); 5.3527 (1.3); 5.3376 (1.4); 5.3362(1.4); 5.3273 (1.3); 5.3259 (1.2); 5.3109 (1.3); 5.3094 (1.2); 5.0345(0.6); 4.3078 (1.0); 4.3015 (1.2); 4.2965 (2.2); 4.2889 (2.0); 4.2839(2.6); 4.2781 (1.2); 4.2717 (1.8); 4.2607 (1.1); 3.9398 (1.9); 3.9371(1.9); 3.8968 (2.1); 3.8942 (2.2); 3.6367 (2.0); 3.6259 (2.1); 3.6238(2.4); 3.6203 (1.7); 3.6186 (1.5); 3.6131 (2.0); 3.6073 (2.4); 3.5968(1.3); 3.5948 (1.4); 3.5892 (0.7); 3.5778 (0.8); 3.5675 (0.7); 3.5647(0.7); 3.5563 (0.7); 3.4053 (1.0); 3.3999 (14.2); 3.3939 (1.0); 3.3905(1.3); 3.3818 (16.0); 3.3726 (0.5); 3.3252 (1.9); 3.3209 (1.7); 3.2822(1.6); 3.2778 (1.5); 2.5489 (0.7); 2.5282 (0.7); 2.5139 (0.8); 2.5079(0.8); 2.4937 (0.7); 2.4729 (0.8); 1.9473 (0.6); 1.9217 (0.7); 1.9120(1.2); 1.9021 (0.7); 1.8768 (0.6); 1.5465 (4.3); 0.9019 (0.6); 0.8979(0.5); 0.8862 (0.6); 0.0080 (1.5); −0.0002 (42.1); −0.0085 (1.6) I-020:¹H-NMR(599.7 MHz, CDCl3): δ = 7.2614 (50.0); 7.2433 (1.6); 7.2321 (1.1);7.2203 (0.5); 7.2166 (0.8); 7.2129 (0.9); 7.2080 (3.0); 7.2045 (5.6);7.2015 (4.8); 7.1981 (3.4); 7.1946 (4.8); 7.1916 (5.6); 7.1882 (3.0);7.1834 (0.8); 7.1797 (0.6); 6.9120 (1.1); 6.9083 (1.9); 6.9046 (1.1);6.8976 (2.2); 6.8938 (3.6); 6.8901 (1.9); 6.8832 (1.2); 6.8793 (1.8);6.8757 (0.9); 5.9870 (1.2); 5.9832 (2.4); 5.9807 (2.5); 5.9741 (3.1);5.9716 (3.1); 5.9678 (1.5); 5.9284 (1.4); 5.9248 (2.6); 5.9210 (1.6);5.9156 (2.0); 5.9120 (1.2); 5.9075 (1.4); 5.9038 (2.6); 5.8999 (1.6);5.8946 (2.0); 5.8909 (1.1); 5.2999 (0.9); 5.1292 (0.6); 5.1161 (1.7);5.1022 (1.7); 5.0892 (0.6); 4.2093 (2.2); 4.1974 (7.0); 4.1929 (1.6);4.1855 (7.4); 4.1834 (4.7); 4.1810 (4.1); 4.1735 (2.9); 4.1714 (4.2);4.1691 (3.9); 4.1629 (0.5); 4.1594 (1.4); 4.1573 (1.3); 4.1511 (0.4);3.8563 (4.2); 3.8491 (4.2); 3.8262 (4.7); 3.8189 (4.6); 3.5480 (1.0);3.5437 (1.5); 3.5393 (1.8); 3.5345 (2.0); 3.5298 (1.9); 3.5254 (1.5);3.5211 (1.1); 3.3748 (30.5); 3.3668 (30.7); 3.3610 (0.9); 3.3566 (0.7);3.3522 (5.1); 3.3482 (5.0); 3.3220 (4.4); 3.3180 (4.5); 2.5618 (1.0);2.5478 (1.9); 2.5381 (1.8); 2.5337 (1.2); 2.5239 (3.4); 2.5140 (1.3);2.5098 (1.8); 2.5000 (2.1); 2.4859 (1.0); 1.9951 (1.0); 1.9891 (2.2);1.9816 (2.2); 1.9756 (1.1); 1.9718 (1.0); 1.9658 (2.0); 1.9582 (2.0);1.9522 (1.0); 1.5968 (2.7); 1.3098 (7.8); 1.2977 (19.9); 1.2853 (20.2);1.2733 (7.7); 1.2672 (0.6); 1.2628 (0.5); 1.2552 (0.7); 0.8821 (0.4);0.0695 (6.6); 0.0053 (1.4); −0.0001 (40.2); −0.0056 (1.3) I-021:¹H-NMR(400.0 MHz, CDCl3): δ = 7.8170 (1.1); 7.8139 (1.4); 7.8098 (0.7);7.8020 (0.5); 7.7968 (1.7); 7.7929 (1.2); 7.6775 (3.0); 7.6741 (3.7);7.6700 (4.4); 7.6667 (4.0); 7.6626 (2.9); 7.6575 (4.4); 7.6532 (4.3);7.6502 (4.6); 7.6459 (3.6); 7.5190 (0.6); 7.5016 (0.7); 7.4986 (1.1);7.4948 (0.9); 7.4892 (1.0); 7.4864 (1.3); 7.4800 (3.6); 7.4729 (1.9);7.4667 (3.4); 7.4627 (5.3); 7.4585 (3.5); 7.4519 (7.0); 7.4480 (4.4);7.4442 (1.7); 7.4375 (3.5); 7.4333 (7.4); 7.4208 (1.4); 7.4164 (2.5);7.4116 (2.1); 7.4080 (0.8); 7.3787 (1.2); 7.3737 (1.2); 7.2602 (83.3);6.0435 (0.6); 6.0352 (0.5); 6.0298 (0.8); 6.0243 (0.5); 6.0048 (1.0);6.0013 (1.1); 5.9983 (1.2); 5.9943 (1.8); 5.9907 (2.3); 5.9875 (2.4);5.9843 (2.3); 5.9807 (2.2); 5.9766 (1.4); 5.9737 (1.3); 5.9701 (1.2);5.9632 (0.6); 5.9560 (0.5); 5.9210 (1.2); 5.9154 (2.1); 5.9098 (1.3);5.9073 (1.0); 5.9017 (1.6); 5.8961 (0.9); 5.8492 (1.2); 5.8437 (2.0);5.8380 (1.3); 5.8356 (1.1); 5.8299 (1.7); 5.8243 (0.9); 5.3404 (0.5);5.1095 (0.5); 5.0902 (1.3); 5.0815 (0.9); 5.0777 (0.9); 5.0693 (1.2);4.2372 (2.1); 4.2193 (6.7); 4.2132 (2.4); 4.2014 (7.2); 4.1953 (6.8);4.1835 (2.8); 4.1812 (2.5); 4.1774 (6.8); 4.1596 (2.3); 4.0391 (3.1);3.9941 (4.6); 3.8189 (4.6); 3.8140 (4.7); 3.7740 (3.2); 3.7691 (3.3);3.5453 (0.8); 3.5391 (1.2); 3.5332 (1.3); 3.5265 (1.4); 3.5241 (1.4);3.5180 (1.5); 3.5144 (1.4); 3.5120 (1.5); 3.5055 (1.2); 3.5029 (1.0);3.4999 (0.8); 3.0156 (0.7); 2.5691 (0.8); 2.5480 (1.5); 2.5338 (1.1);2.5269 (0.9); 2.5193 (0.8); 2.5127 (1.8); 2.5050 (1.3); 2.4916 (1.0);2.4840 (2.3); 2.4698 (1.1); 2.4631 (1.2); 2.4488 (1.8); 2.4278 (0.8);2.0432 (1.2); 2.0060 (1.1); 1.9973 (1.6); 1.9891 (0.9); 1.9704 (0.8);1.9623 (2.1); 1.9538 (2.2); 1.9450 (0.8); 1.9274 (0.7); 1.9186 (1.3);1.9099 (0.7); 1.5605 (16.0); 1.3255 (7.2); 1.3076 (15.0); 1.2981 (7.5);1.2918 (7.4); 1.2898 (8.2); 1.2803 (14.5); 1.2741 (3.8); 1.2624 (7.7);1.2504 (0.7); 0.8818 (1.2); 0.0080 (1.2); −0.0002 (32.1); −0.0085 (1.2)I-023: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.4713 (2.0); 7.4665 (2.2); 7.4620(2.1); 7.3739 (0.8); 7.3454 (3.2); 7.3416 (3.0); 7.2717 (3.8); 7.2600(54.8); 6.0064 (0.7); 6.0030 (0.7); 5.9964 (1.3); 5.9928 (1.6); 5.9895(1.6); 5.9863 (1.6); 5.9828 (1.6); 5.9792 (1.0); 5.9762 (0.9); 5.9727(0.8); 5.9202 (0.8); 5.9147 (1.4); 5.9090 (0.9); 5.9009 (1.1); 5.8954(0.6); 5.8496 (0.8); 5.8441 (1.3); 5.8383 (0.9); 5.8303 (1.1); 5.8247(0.6); 5.0831 (0.9); 5.0624 (0.9); 4.2369 (1.3); 4.2191 (4.2); 4.2012(4.6); 4.1980 (4.3); 4.1831 (1.9); 4.1802 (4.1); 4.1623 (1.4); 4.0006(2.1); 3.9556 (3.1); 3.7722 (2.9); 3.7665 (2.9); 3.7272 (2.0); 3.7215(2.0); 3.5258 (1.0); 3.5200 (1.0); 3.5133 (1.0); 2.5583 (0.5); 2.5371(1.0); 2.5229 (0.7); 2.5160 (0.6); 2.5018 (1.2); 2.4920 (0.6); 2.4807(0.6); 2.4710 (1.1); 2.4569 (0.7); 2.4501 (0.6); 2.4359 (1.2); 2.4149(0.6); 2.3685 (16.0); 2.0036 (0.6); 1.9955 (1.1); 1.9876 (0.6); 1.9681(0.6); 1.9607 (1.2); 1.9537 (1.4); 1.9458 (0.6); 1.9271 (0.5); 1.9190(0.9); 1.9106 (0.5); 1.5490 (14.5); 1.3252 (4.3); 1.3073 (8.9); 1.3024(4.8); 1.2894 (4.9); 1.2846 (8.9); 1.2667 (4.9); 1.2525 (0.6); 0.8817(1.2); 0.0079 (0.8); −0.0002 (21.1); −0.0084 (0.9) I-024: ¹H-NMR(400.0MHz, CDCl3): δ = 7.3699 (0.6); 7.2607 (52.9); 7.2252 (2.3); 7.2237(2.3); 7.2188 (2.7); 7.2150 (3.3); 7.2135 (3.4); 7.2105 (3.1); 7.1912(1.2); 7.1871 (1.2); 7.0106 (1.3); 7.0086 (1.3); 6.9967 (1.1); 6.9892(1.2); 6.9856 (1.2); 6.0213 (0.6); 6.0174 (0.6); 6.0113 (0.6); 6.0073(1.1); 6.0033 (0.9); 6.0009 (0.9); 5.9970 (1.3); 5.9933 (1.2); 5.9900(1.3); 5.9868 (1.2); 5.9833 (1.3); 5.9797 (0.8); 5.9766 (0.7); 5.9731(0.6); 5.9265 (0.6); 5.9210 (1.2); 5.9154 (0.7); 5.9130 (0.5); 5.9073(0.8); 5.8695 (0.5); 5.8615 (0.8); 5.8559 (1.4); 5.8502 (0.9); 5.8423(0.9); 5.8367 (0.5); 5.2987 (0.6); 5.0745 (0.7); 4.0007 (1.8); 3.9556(2.7); 3.7857 (1.7); 3.7834 (1.9); 3.7777 (2.8); 3.7712 (2.8); 3.7623(4.5); 3.7590 (15.3); 3.7496 (3.1); 3.7397 (16.0); 3.7329 (2.2); 3.7262(1.8); 3.7043 (6.0); 3.6929 (5.5); 3.5527 (0.7); 3.5462 (0.7); 3.5409(0.8); 3.5364 (0.7); 3.5340 (0.7); 3.5250 (0.5); 2.5461 (0.9); 2.5318(0.6); 2.5251 (0.5); 2.5109 (1.1); 2.5041 (0.6); 2.4898 (0.6); 2.4831(1.0); 2.4688 (0.7); 2.4623 (0.6); 2.4480 (1.0); 2.4270 (0.6); 2.3877(14.8); 2.0027 (0.8); 1.9670 (0.9); 1.9571 (1.0); 1.9484 (0.7); 1.9216(0.8); 1.9132 (0.6); 1.5571 (5.3); 0.0078 (0.7); −0.0002 (19.9); −0.0085(0.7) I-025: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.6779 (1.8); 7.6745 (2.3);7.6703 (3.2); 7.6671 (3.3); 7.6632 (2.3); 7.6580 (2.8); 7.6536 (2.9);7.6504 (3.7); 7.6463 (3.0); 7.5186 (0.8); 7.5019 (0.9); 7.4931 (1.1);7.4830 (2.3); 7.4762 (1.5); 7.4700 (1.9); 7.4659 (3.3); 7.4615 (2.8);7.4552 (3.9); 7.4459 (1.6); 7.4408 (2.4); 7.4355 (3.7); 7.4244 (0.8);7.4189 (1.1); 7.4148 (0.7); 7.3311 (0.8); 7.3097 (0.8); 7.2597 (117.1);6.9957 (0.6); 6.0331 (0.6); 6.0272 (1.0); 6.0233 (1.0); 6.0207 (0.9);6.0127 (1.2); 6.0069 (1.3); 6.0030 (1.1); 5.9982 (0.8); 5.9945 (0.8);5.9916 (0.7); 5.9881 (0.7); 5.9455 (0.7); 5.9400 (1.3); 5.9344 (0.8);5.9262 (0.9); 5.9206 (0.5); 5.8753 (0.8); 5.8697 (1.2); 5.8640 (0.7);5.8616 (0.6); 5.8559 (1.0); 5.8503 (0.6); 5.0939 (0.7); 4.5542 (0.6);4.5394 (0.5); 4.4235 (1.9); 4.4095 (2.5); 4.4068 (1.9); 4.3950 (3.7);4.3913 (1.6); 4.3811 (2.5); 4.3767 (2.1); 4.3715 (0.9); 4.3662 (1.5);4.3631 (1.6); 4.3576 (1.4); 4.3426 (1.4); 4.3290 (0.7); 4.0380 (1.4);3.9931 (2.2); 3.8291 (1.6); 3.8236 (3.1); 3.8183 (3.1); 3.8121 (0.5);3.7889 (1.0); 3.7863 (1.1); 3.7841 (1.1); 3.7786 (2.0); 3.7735 (2.4);3.7598 (0.5); 3.7428 (2.6); 3.7285 (3.0); 3.7144 (5.2); 3.6999 (4.7);3.6861 (3.4); 3.6714 (1.4); 3.6591 (0.8); 3.6060 (0.6); 3.5989 (0.8);3.5919 (0.8); 3.5834 (0.8); 2.5891 (0.9); 2.5748 (0.6); 2.5679 (0.6);2.5537 (1.0); 2.5432 (0.5); 2.5325 (0.6); 2.5221 (1.0); 2.5079 (0.6);2.5011 (0.5); 2.4869 (1.0); 2.4658 (0.5); 2.0295 (0.9); 1.9948 (1.0);1.9873 (1.2); 1.9784 (0.6); 1.9522 (1.0); 1.5424 (16.0); 1.2558 (1.0);0.0079 (1.5); −0.0002 (43.1); −0.0085 (1.5) I-027: ¹H-NMR(400.0 MHz,CDCl3): δ = 7.5183 (1.0); 7.4721 (1.6); 7.4671 (2.1); 7.4624 (2.5);7.3490 (2.1); 7.3472 (2.2); 7.3426 (2.2); 7.3405 (2.2); 7.3386 (2.2);7.3349 (1.9); 7.2782 (2.5); 7.2735 (3.0); 7.2697 (2.5); 7.2594 (171.0);6.9954 (1.0); 6.0174 (0.5); 6.0113 (0.5); 6.0070 (0.8); 6.0028 (0.8);5.9963 (1.2); 5.9924 (1.2); 5.9891 (1.3); 5.9859 (1.3); 5.9824 (1.3);5.9787 (0.8); 5.9757 (0.7); 5.9724 (0.6); 5.9257 (0.6); 5.9202 (1.2);5.9146 (0.7); 5.9064 (0.8); 5.8601 (0.8); 5.8545 (1.4); 5.8488 (0.9);5.8407 (0.9); 5.0722 (0.7); 3.9987 (1.8); 3.9538 (2.6); 3.7791 (1.6);3.7738 (2.7); 3.7670 (3.0); 3.7593 (16.0); 3.7500 (2.2); 3.7405 (16.0);3.7289 (1.9); 3.7220 (1.8); 3.7040 (5.2); 3.6929 (5.0); 3.5539 (0.7);3.5454 (0.7); 3.5397 (0.7); 3.5338 (0.7); 2.5439 (0.9); 2.5295 (0.6);2.5228 (0.5); 2.5085 (1.0); 2.5010 (0.6); 2.4876 (0.5); 2.4801 (0.9);2.4658 (0.6); 2.4593 (0.5); 2.4449 (1.0); 2.4241 (0.6); 2.3717 (13.5);2.3706 (13.6); 2.0016 (0.8); 1.9660 (0.8); 1.9547 (0.9); 1.9463 (0.6);1.9194 (0.8); 1.9111 (0.6); 1.5378 (9.0); 0.0080 (2.0); −0.0002 (64.1);−0.0085 (2.4) I-028: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.5186 (0.6); 7.4652(2.6); 7.4614 (2.7); 7.3520 (1.0); 7.3480 (1.8); 7.3460 (2.2); 7.3385(2.3); 7.3344 (2.2); 7.3242 (0.6); 7.3146 (0.9); 7.3125 (0.9); 7.3083(1.1); 7.3035 (1.0); 7.3005 (0.9); 7.2969 (1.0); 7.2868 (2.2); 7.2830(2.4); 7.2789 (3.2); 7.2743 (3.6); 7.2683 (2.5); 7.2598 (106.4); 7.2571(9.4); 7.2519 (1.5); 7.2491 (1.3); 7.2417 (0.7); 7.2085 (0.8); 6.9958(0.6); 6.0419 (0.5); 6.0381 (0.6); 6.0284 (1.0); 6.0232 (0.9); 6.0152(1.2); 6.0118 (1.3); 6.0089 (1.3); 6.0053 (1.3); 6.0014 (0.8); 5.9979(0.7); 5.9948 (0.7); 5.9913 (0.7); 5.9443 (0.6); 5.9387 (1.2); 5.9331(0.7); 5.9249 (0.9); 5.8756 (0.7); 5.8699 (1.2); 5.8641 (0.7); 5.8561(0.9); 5.8505 (0.5); 5.0928 (0.7); 4.5685 (0.6); 4.5540 (0.8); 4.5393(0.7); 4.4234 (1.8); 4.4094 (2.4); 4.4068 (1.8); 4.3987 (1.5); 4.3953(3.5); 4.3852 (2.4); 4.3808 (1.8); 4.3703 (2.0); 4.3677 (1.5); 4.3589(1.4); 4.3430 (1.4); 4.3314 (0.8); 3.9991 (1.4); 3.9536 (2.1); 3.9299(0.5); 3.7887 (1.1); 3.7827 (1.8); 3.7767 (3.0); 3.7710 (2.7); 3.7596(0.8); 3.7418 (2.8); 3.7385 (1.4); 3.7314 (2.6); 3.7273 (3.9); 3.7185(2.9); 3.7136 (2.7); 3.7042 (3.6); 3.6996 (1.5); 3.6901 (3.1); 3.6852(1.5); 3.6749 (1.3); 3.6714 (1.3); 3.6611 (1.0); 3.6001 (0.8); 3.5926(0.9); 3.5853 (0.9); 2.5796 (0.8); 2.5651 (0.5); 2.5440 (0.9); 2.5330(0.5); 2.5232 (0.6); 2.5118 (0.8); 2.4975 (0.6); 2.4909 (0.5); 2.4766(1.0); 2.4555 (0.5); 2.3706 (13.5); 2.0278 (0.8); 1.9933 (1.0); 1.9861(1.0); 1.9594 (0.6); 1.9509 (0.8); 1.5413 (16.0); 0.0081 (1.3); −0.0002(38.6); −0.0029 (4.3); −0.0084 (1.6) I-029: ¹H-NMR(400.0 MHz, CDCl3): δ= 7.4632 (2.4); 7.3500 (1.5); 7.3481 (1.6); 7.3461 (1.8); 7.3440 (1.8);7.3421 (1.9); 7.3403 (1.8); 7.2779 (2.6); 7.2598 (74.5); 7.2127 (0.7);7.1926 (0.7); 6.0210 (0.6); 6.0183 (0.6); 6.0151 (0.8); 6.0035 (1.3);5.9980 (1.1); 5.9917 (0.8); 5.9891 (0.8); 5.9854 (0.7); 5.9688 (0.7);5.9633 (1.1); 5.9578 (0.7); 5.9495 (0.7); 5.9010 (0.7); 5.8953 (1.2);5.8896 (0.7); 5.8873 (0.6); 5.8815 (0.9); 5.8758 (0.6); 5.2984 (2.9);5.0966 (0.6); 5.0935 (0.6); 5.0812 (0.6); 5.0781 (0.6); 4.5675 (1.0);4.5466 (3.2); 4.5418 (1.0); 4.5379 (0.6); 4.5257 (3.4); 4.5209 (2.1);4.5170 (1.6); 4.5048 (1.3); 4.5000 (2.1); 4.4960 (1.6); 4.4888 (0.7);4.4791 (1.0); 4.4751 (0.6); 4.4679 (0.7); 3.9952 (1.3); 3.9505 (2.0);3.7859 (1.2); 3.7809 (2.2); 3.7737 (2.4); 3.7407 (0.9); 3.7359 (1.5);3.7287 (1.6); 3.6615 (0.6); 3.6585 (0.6); 3.6550 (0.7); 3.6524 (0.7);3.6490 (0.7); 3.6460 (0.7); 3.6430 (0.7); 3.6401 (0.8); 3.6372 (0.6);2.6358 (0.8); 2.6214 (0.6); 2.6146 (0.5); 2.6003 (0.9); 2.5792 (0.5);2.5622 (0.8); 2.5478 (0.6); 2.5413 (0.5); 2.5269 (0.9); 2.3703 (13.1);2.0236 (0.8); 2.0145 (0.5); 1.9956 (0.7); 1.9871 (1.1); 1.9787 (0.6);1.9594 (0.5); 1.9505 (0.7); 1.5416 (16.0); 0.0080 (0.9); −0.0002 (28.1);−0.0084 (1.1) I-033: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.5181 (2.7); 7.3763(3.6); 7.3684 (17.2); 7.3634 (7.0); 7.3563 (31.3); 7.3506 (18.4); 7.3426(5.8); 7.3382 (3.9); 7.3271 (1.9); 7.3086 (1.6); 7.2962 (1.5); 7.2592(478.9); 7.2268 (0.5); 7.2206 (0.5); 7.1967 (1.2); 7.1843 (5.6); 7.1789(6.3); 7.1751 (5.0); 7.1689 (5.2); 7.1644 (6.9); 7.1588 (5.7); 6.9952(2.6); 6.9037 (0.9); 6.8979 (1.6); 6.8906 (1.9); 6.8821 (1.8); 6.8760(3.2); 6.8688 (3.3); 6.8629 (1.8); 6.8542 (1.6); 6.8470 (1.7); 6.8411(0.7); 6.1970 (1.4); 6.1890 (1.5); 6.1703 (4.3); 6.1624 (1.7); 6.1539(1.7); 6.1459 (2.2); 6.1436 (3.3); 6.1272 (4.9); 6.1192 (1.8); 6.1004(3.4); 5.9658 (1.4); 5.9618 (1.8); 5.9589 (1.7); 5.9558 (1.8); 5.9520(1.7); 5.9478 (1.1); 5.9418 (0.8); 5.8796 (0.9); 5.8740 (1.6); 5.8682(1.0); 5.8602 (1.2); 5.8546 (0.7); 5.8292 (0.8); 5.8234 (1.6); 5.8176(1.0); 5.8096 (1.3); 5.8040 (0.8); 5.5626 (2.4); 5.5458 (7.8); 5.5193(2.1); 5.5027 (6.8); 5.3765 (5.5); 5.3496 (5.3); 5.3447 (2.6); 5.3360(2.3); 5.3179 (2.2); 5.3093 (2.2); 5.2938 (2.0); 5.2631 (8.4); 5.2458(8.3); 5.2150 (2.0); 5.1985 (0.7); 5.1783 (9.5); 5.1681 (4.7); 5.1615(4.6); 5.1310 (0.7); 5.0308 (1.0); 3.9367 (3.5); 3.9237 (5.4); 3.8936(4.0); 3.8814 (6.2); 3.5596 (1.1); 3.3470 (5.8); 3.3275 (2.8); 3.3213(2.8); 3.3046 (5.1); 3.2845 (2.4); 3.2782 (2.4); 2.5800 (0.7); 2.5591(1.2); 2.5452 (0.8); 2.5377 (1.0); 2.5239 (1.3); 2.5150 (1.2); 2.5012(1.0); 2.4942 (0.7); 2.4802 (1.3); 2.4588 (0.6); 1.9655 (0.7); 1.9552(1.1); 1.9452 (0.7); 1.9393 (0.7); 1.9295 (1.4); 1.9199 (1.3); 1.9104(0.6); 1.8942 (1.0); 1.8840 (0.5); 1.5549 (16.0); 0.1459 (0.6); 0.0079(7.0); −0.0002 (177.6); −0.0085 (6.8); −0.1491 (0.6) I-034: ¹H-NMR(400.0MHz, CDCl3): δ = 7.5189 (2.8); 7.3216 (0.6); 7.2941 (1.5); 7.2600(491.5); 7.2393 (11.7); 7.2368 (12.2); 7.2310 (8.9); 7.2257 (2.0);7.2098 (1.7); 7.2063 (1.4); 7.1936 (5.4); 7.1879 (6.7); 7.1847 (4.8);7.1739 (7.8); 7.1683 (7.3); 7.1601 (3.4); 7.1560 (3.4); 7.1503 (2.3);6.9960 (2.8); 6.9493 (1.0); 6.9437 (1.7); 6.9379 (1.0); 6.9258 (2.9);6.9220 (3.9); 6.9162 (2.4); 6.9098 (3.2); 6.9041 (5.2); 6.8984 (3.4);6.8882 (2.1); 6.8823 (3.1); 6.8765 (1.8); 6.8585 (0.8); 6.1921 (4.8);6.1653 (5.1); 6.1490 (5.8); 6.1222 (6.1); 6.0160 (1.3); 6.0115 (1.5);6.0079 (1.5); 6.0021 (2.1); 5.9977 (2.4); 5.9118 (0.8); 5.8977 (0.7);5.8922 (0.6); 5.8675 (1.2); 5.8576 (1.2); 5.8520 (2.0); 5.8461 (1.3);5.8379 (1.5); 5.8322 (0.9); 5.6506 (8.5); 5.6074 (7.3); 5.5647 (1.8);5.5508 (1.7); 5.5228 (1.6); 5.5077 (1.4); 5.4631 (7.8); 5.4363 (7.3);5.3592 (2.0); 5.3466 (1.2); 5.3324 (2.0); 5.3208 (1.2); 5.1652 (0.6);5.1495 (1.6); 5.1338 (2.2); 5.1180 (1.7); 5.1022 (0.8); 5.0354 (0.8);5.0198 (1.7); 5.0042 (2.2); 4.9885 (1.7); 4.9727 (0.6); 3.9528 (7.0);3.9354 (3.2); 3.9099 (8.2); 3.8923 (3.6); 3.7283 (0.9); 3.7220 (1.1);3.7161 (1.2); 3.7100 (1.2); 3.7064 (1.1); 3.7003 (1.2); 3.6944 (1.2);3.6881 (1.1); 3.5775 (1.5); 3.5216 (6.6); 3.4970 (7.0); 3.4248 (8.6);3.3820 (7.6); 3.3694 (2.6); 3.3368 (3.0); 3.3316 (3.4); 3.2936 (2.5);3.2884 (2.9); 3.1501 (1.9); 3.1372 (1.8); 2.7180 (0.7); 2.7056 (0.9);2.6972 (0.9); 2.6827 (1.0); 2.6704 (1.0); 2.6620 (0.9); 2.6497 (0.8);2.5886 (0.8); 2.5747 (0.6); 2.5678 (0.6); 2.5538 (1.1); 2.5398 (0.7);2.5043 (0.7); 2.3430 (0.7); 2.3274 (1.9); 2.3185 (0.8); 2.3118 (2.0);2.3029 (2.0); 2.2871 (2.0); 2.2716 (0.7); 1.9909 (0.9); 1.9650 (0.5);1.9551 (1.6); 1.9444 (1.2); 1.9330 (1.0); 1.9198 (1.2); 1.9086 (1.1);1.8978 (0.9); 1.8867 (0.8); 1.5282 (2.7); 1.5124 (3.8); 1.4146 (0.5);1.3984 (0.6); 1.3698 (15.4); 1.3612 (4.3); 1.3541 (16.0); 1.3458 (4.4);1.3249 (1.8); 1.3086 (0.7); 1.2832 (2.7); 1.2676 (2.7); 1.2453 (8.0);1.2401 (8.0); 1.2297 (8.2); 1.2245 (8.2); 1.0377 (0.8); 1.0204 (0.6);0.9529 (15.8); 0.9372 (16.0); 0.1458 (0.6); 0.0079 (6.0); −0.0002(196.6); −0.0085 (9.7); −0.0210 (3.8); −0.1496 (0.6) I-035: ¹H-NMR(400.0MHz, CDCl3): δ = 7.2607 (46.2); 7.1905 (1.7); 7.1847 (2.0); 7.1814(2.4); 7.1755 (2.6); 7.1708 (2.6); 7.1649 (2.6); 7.1615 (2.2); 7.1558(1.7); 7.1436 (0.5); 7.1378 (0.5); 6.8996 (0.7); 6.8976 (0.7); 6.8836(0.8); 6.8817 (0.9); 6.8778 (1.4); 6.8760 (1.4); 6.8721 (0.8); 6.8702(0.7); 6.8561 (0.7); 6.8543 (0.7); 6.2043 (1.3); 6.2028 (1.2); 6.1775(1.4); 6.1759 (1.4); 6.1612 (1.6); 6.1596 (1.5); 6.1344 (1.6); 6.1329(1.5); 5.9687 (0.6); 5.9650 (0.6); 5.9625 (0.6); 5.9578 (1.0); 5.9543(1.2); 5.9511 (1.4); 5.9482 (1.2); 5.9445 (1.2); 5.9397 (0.8); 5.9374(0.8); 5.9335 (0.7); 5.8832 (0.7); 5.8777 (1.3); 5.8721 (0.8); 5.8696(0.6); 5.8639 (1.0); 5.8583 (0.5); 5.8342 (0.7); 5.8286 (1.3); 5.8229(0.8); 5.8205 (0.6); 5.8148 (1.0); 5.8091 (0.6); 5.5740 (1.8); 5.5727(1.7); 5.5539 (1.8); 5.5524 (1.7); 5.5309 (1.6); 5.5296 (1.5); 5.5107(1.6); 5.5093 (1.5); 5.3568 (1.7); 5.3416 (1.7); 5.3300 (1.6); 5.3148(1.6); 5.0273 (0.8); 3.9375 (2.5); 3.9356 (2.4); 3.8945 (2.9); 3.8927(2.7); 3.7467 (16.0); 3.7349 (15.7); 3.5291 (0.8); 3.5260 (0.7); 3.5233(0.8); 3.5201 (0.8); 3.5172 (0.8); 3.5142 (0.8); 3.3284 (2.2); 3.3232(2.1); 3.2855 (1.9); 3.2801 (1.9); 2.5444 (0.9); 2.5306 (0.6); 2.5230(0.8); 2.5095 (1.0); 2.5008 (0.9); 2.4873 (0.8); 2.4797 (0.5); 2.4658(1.0); 2.4448 (0.5); 1.9408 (0.9); 1.9155 (0.6); 1.9125 (0.6); 1.9056(1.0); 1.9030 (1.0); 1.8959 (0.6); 1.8932 (0.6); 1.8679 (0.8); 1.5561(8.7); 0.0079 (0.6); −0.0002 (17.9); −0.0085 (0.6) I-037: ¹H-NMR(400.0MHz, CDCl3): δ = 7.2617 (68.3); 7.2085 (0.8); 7.1961 (0.9); 7.1839(3.3); 7.1781 (4.0); 7.1735 (3.8); 7.1674 (4.2); 7.1641 (4.5); 7.1582(4.0); 7.1535 (3.2); 7.1477 (2.2); 6.9007 (0.6); 6.8950 (1.3); 6.8910(1.2); 6.8790 (1.2); 6.8734 (2.1); 6.8694 (2.1); 6.8637 (1.0); 6.8574(0.6); 6.8516 (1.0); 6.8476 (1.0); 6.2006 (1.9); 6.1963 (1.8); 6.1738(2.1); 6.1695 (2.0); 6.1575 (2.2); 6.1532 (2.2); 6.1306 (2.2); 6.1264(2.2); 6.0200 (1.1); 6.0164 (1.2); 6.0138 (1.2); 6.0100 (1.2); 6.0002(2.3); 5.9908 (1.1); 5.9867 (1.1); 5.9805 (0.9); 5.9126 (1.0); 5.9070(1.8); 5.9012 (1.1); 5.8931 (1.4); 5.8874 (0.8); 5.8671 (1.2); 5.8616(1.9); 5.8558 (1.1); 5.8478 (1.7); 5.8421 (1.1); 5.5646 (2.7); 5.5632(2.6); 5.5501 (2.7); 5.5486 (2.6); 5.5214 (2.3); 5.5201 (2.2); 5.5109(1.0); 5.5070 (2.4); 5.5055 (2.3); 5.3591 (0.7); 5.3522 (2.6); 5.3420(2.5); 5.3327 (0.8); 5.3254 (2.4); 5.3152 (2.3); 5.2989 (8.3); 5.0248(1.1); 3.9593 (0.6); 3.9538 (0.7); 3.9384 (3.0); 3.9345 (3.1); 3.9162(0.7); 3.9107 (0.8); 3.8953 (3.4); 3.8915 (3.4); 3.7803 (0.8); 3.7762(1.6); 3.7726 (5.6); 3.7706 (3.7); 3.7663 (3.6); 3.7622 (4.7); 3.7560(13.4); 3.7499 (4.7); 3.7457 (3.3); 3.7414 (3.6); 3.7393 (5.5); 3.7357(1.3); 3.5871 (0.8); 3.5764 (1.1); 3.5734 (1.2); 3.3418 (1.0); 3.3344(2.9); 3.3273 (2.9); 3.2984 (0.9); 3.2913 (2.6); 3.2842 (2.5); 2.6055(0.6); 2.5844 (1.1); 2.5705 (0.8); 2.5631 (0.7); 2.5578 (0.7); 2.5492(1.2); 2.5366 (1.1); 2.5281 (0.7); 2.5226 (0.8); 2.5155 (0.7); 2.5015(1.2); 2.4805 (0.6); 1.9951 (0.6); 1.9846 (1.1); 1.9744 (0.6); 1.9599(0.6); 1.9489 (1.4); 1.9386 (1.6); 1.9281 (0.7); 1.9128 (0.6); 1.9030(1.2); 1.8929 (1.2); 1.8791 (1.4); 1.8750 (5.5); 1.8672 (5.2); 1.8630(3.7); 1.8584 (16.0); 1.8536 (3.8); 1.8497 (5.0); 1.8418 (5.2); 1.4320(1.4); 0.0079 (0.7); −0.0002 (24.0); −0.0085 (0.9) I-039: ¹H-NMR(400.0MHz, CDCl3): δ = 7.5587 (4.9); 7.5540 (5.5); 7.5478 (5.4); 7.5432 (7.0);7.5390 (2.0); 7.4776 (0.6); 7.4757 (0.9); 7.4730 (1.0); 7.4688 (1.9);7.4665 (1.9); 7.4642 (2.7); 7.4619 (2.7); 7.4596 (1.5); 7.4573 (1.3);7.3753 (0.6); 7.3558 (0.6); 7.2603 (59.9); 6.0122 (0.6); 6.0090 (0.7);6.0025 (1.0); 5.9988 (1.1); 5.9955 (1.2); 5.9922 (1.2); 5.9888 (1.2);5.9854 (0.7); 5.9821 (0.7); 5.9789 (0.6); 5.9305 (0.6); 5.9250 (1.1);5.9194 (0.6); 5.9112 (0.8); 5.8680 (0.8); 5.8623 (1.2); 5.8566 (0.7);5.8542 (0.8); 5.8485 (1.0); 5.2987 (4.2); 5.0758 (0.6); 5.0646 (0.6);3.9987 (1.6); 3.9536 (2.3); 3.7610 (16.0); 3.7573 (3.3); 3.7526 (1.6);3.7494 (2.7); 3.7424 (14.8); 3.7176 (0.7); 3.7121 (1.7); 3.7056 (4.1);3.6955 (3.4); 3.5556 (0.6); 3.5510 (0.7); 3.5444 (0.7); 3.5394 (0.7);2.5348 (0.8); 2.5204 (0.6); 2.4995 (0.9); 2.4677 (0.8); 2.4533 (0.5);2.4325 (0.9); 2.0053 (0.8); 1.9705 (0.9); 1.9640 (1.0); 1.9567 (0.5);1.9290 (0.7); 1.5473 (11.1); 1.2588 (0.7); 0.8817 (0.7); 0.0079 (0.7);−0.0002 (21.9); −0.0085 (0.8) I-040: ¹H-NMR(400.0 MHz, CDCl3): δ =7.5569 (10.4); 7.5522 (12.0); 7.5472 (14.3); 7.5425 (16.0); 7.5196(0.5); 7.4809 (1.1); 7.4786 (1.3); 7.4763 (1.9); 7.4740 (2.1); 7.4695(4.2); 7.4675 (4.2); 7.4649 (6.0); 7.4629 (6.0); 7.4604 (3.4); 7.4583(2.9); 7.3103 (1.4); 7.2971 (1.4); 7.2908 (1.5); 7.2750 (1.3); 7.2607(88.1); 6.9967 (0.5); 6.0483 (0.6); 6.0438 (1.0); 6.0363 (1.5); 6.0299(1.7); 6.0260 (1.6); 6.0226 (2.5); 6.0192 (2.7); 6.0161 (2.7); 6.0127(2.5); 6.0089 (1.6); 6.0054 (1.6); 6.0023 (1.5); 5.9989 (1.3); 5.9487(1.3); 5.9432 (2.3); 5.9376 (1.4); 5.9294 (1.7); 5.9239 (1.0); 5.8915(0.7); 5.8829 (1.6); 5.8773 (2.8); 5.8716 (1.8); 5.8692 (1.3); 5.8634(1.9); 5.8578 (1.1); 5.8386 (0.7); 5.8247 (0.6); 5.2988 (4.6); 5.1128(0.6); 5.0927 (1.4); 5.0741 (1.4); 5.0543 (0.5); 4.5688 (1.6); 4.5545(2.2); 4.5396 (1.8); 4.5293 (0.6); 4.4255 (4.4); 4.4135 (4.0); 4.4116(5.4); 4.4090 (3.8); 4.4021 (3.1); 4.3975 (6.1); 4.3887 (4.5); 4.3839(3.7); 4.3738 (3.6); 4.3713 (3.2); 4.3611 (1.8); 4.3565 (1.2); 4.3481(1.3); 4.3453 (1.8); 4.3341 (1.1); 3.9981 (3.1); 3.9625 (1.3); 3.9529(4.5); 3.9302 (0.7); 3.8221 (0.5); 3.8159 (0.6); 3.8098 (0.6); 3.7893(2.1); 3.7830 (0.5); 3.7745 (2.4); 3.7662 (2.5); 3.7603 (6.6); 3.7536(5.2); 3.7426 (5.4); 3.7310 (3.9); 3.7284 (6.0); 3.7264 (4.6); 3.7222(7.0); 3.7147 (8.2); 3.7082 (10.3); 3.7012 (2.1); 3.6942 (5.0); 3.6867(2.2); 3.6774 (1.8); 3.6729 (2.0); 3.6636 (1.3); 3.6179 (1.2); 3.6119(1.4); 3.6055 (1.6); 3.5980 (1.7); 3.5911 (1.6); 3.5847 (1.4); 3.5790(1.0); 2.5931 (0.9); 2.5721 (1.7); 2.5576 (1.2); 2.5509 (1.0); 2.5366(1.9); 2.5233 (1.0); 2.5155 (1.0); 2.5023 (1.7); 2.4879 (1.2); 2.4814(1.0); 2.4669 (1.9); 2.4459 (1.0); 2.0391 (1.0); 2.0312 (1.7); 2.0232(1.0); 2.0038 (1.8); 1.9957 (3.3); 1.9877 (1.8); 1.9684 (0.8); 1.9605(1.8); 1.9523 (0.8); 1.5523 (10.3); 1.2561 (1.4); 0.0080 (1.0); −0.0002(32.1); −0.0085 (1.2) I-041: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.5559 (2.2);7.5512 (2.6); 7.5469 (3.3); 7.5423 (3.6); 7.5184 (0.7); 7.4734 (0.8);7.4707 (1.1); 7.4688 (1.2); 7.4661 (1.5); 7.4616 (0.7); 7.2595 (122.0);6.9955 (0.7); 6.0110 (0.6); 6.0077 (0.6); 6.0041 (0.6); 5.9032 (0.6);5.2986 (2.1); 4.5699 (0.6); 4.5490 (1.8); 4.5280 (2.1); 4.5236 (0.8);4.5062 (0.9); 4.5027 (0.8); 3.9951 (0.6); 3.9499 (0.9); 3.7631 (1.1);3.7554 (1.3); 3.7425 (0.5); 3.7179 (0.7); 3.7103 (0.9); 1.9923 (0.7);1.5327 (16.0); 1.2561 (0.9); 0.0080 (1.5); −0.0002 (46.6); −0.0085 (1.8)I-042: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.6939 (2.0); 7.6893 (3.7); 7.6838(3.3); 7.6782 (4.0); 7.6738 (2.6); 7.5373 (1.4); 7.5340 (2.1); 7.5306(2.5); 7.5277 (2.3); 7.5238 (1.6); 7.5181 (1.9); 7.5147 (2.7); 7.5114(3.3); 7.5084 (2.8); 7.5047 (1.9); 7.4646 (1.7); 7.4613 (2.1); 7.4569(1.9); 7.4509 (0.7); 7.4446 (3.2); 7.4401 (3.6); 7.4369 (2.7); 7.4033(0.6); 7.3952 (4.8); 7.3843 (1.7); 7.3758 (6.4); 7.3654 (1.5); 7.3559(3.1); 7.2609 (51.7); 6.0098 (1.1); 6.0064 (1.2); 6.0033 (1.2); 5.9996(2.0); 5.9960 (2.5); 5.9928 (2.6); 5.9895 (2.5); 5.9860 (2.5); 5.9823(1.5); 5.9792 (1.4); 5.9757 (1.3); 5.9240 (1.3); 5.9184 (2.3); 5.9128(1.4); 5.9104 (1.1); 5.9047 (1.7); 5.8991 (1.0); 5.8551 (1.2); 5.8495(2.1); 5.8439 (1.4); 5.8415 (1.2); 5.8357 (1.7); 5.8302 (1.0); 5.2986(13.2); 5.1086 (0.5); 5.0863 (1.4); 5.0658 (1.4); 4.2383 (2.1); 4.2205(6.8); 4.2152 (2.6); 4.2026 (7.2); 4.1973 (7.2); 4.1848 (2.7); 4.1795(7.2); 4.1617 (2.6); 4.0181 (3.1); 3.9731 (4.5); 3.7928 (0.6); 3.7853(4.9); 3.7795 (4.8); 3.7403 (3.5); 3.7345 (3.5); 3.5422 (1.0); 3.5364(1.3); 3.5299 (1.5); 3.5222 (1.6); 3.5155 (1.6); 3.5091 (1.3); 3.5034(1.0); 3.0507 (0.7); 3.0070 (0.8); 2.9938 (0.8); 2.5585 (0.9); 2.5375(1.6); 2.5232 (1.1); 2.5164 (1.0); 2.5022 (1.8); 2.4909 (0.9); 2.4811(1.0); 2.4700 (1.8); 2.4557 (1.1); 2.4490 (1.0); 2.4348 (2.0); 2.4138(0.9); 2.0072 (0.9); 1.9994 (1.6); 1.9915 (0.9); 1.9693 (1.3); 1.9613(2.1); 1.9561 (1.2); 1.9530 (1.1); 1.9340 (0.8); 1.9258 (1.5); 1.9176(0.8); 1.5628 (6.4); 1.3259 (7.5); 1.3152 (0.7); 1.3080 (15.4); 1.3019(8.3); 1.2975 (1.5); 1.2901 (7.8); 1.2840 (16.0); 1.2662 (8.0); 1.2523(1.1); 1.2462 (0.6); 0.8818 (0.6); 0.0080 (1.0); −0.0002 (30.2); −0.0084(1.2) I-043: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.2607 (21.2); 6.7975 (2.3);6.7917 (2.7); 6.7890 (2.5); 6.7833 (2.5); 6.5578 (1.0); 6.5524 (1.6);6.5468 (0.8); 5.9893 (0.6); 5.9857 (0.6); 5.9824 (0.5); 5.9792 (0.5);5.9138 (0.5); 5.8467 (0.5); 5.2986 (2.7); 4.2346 (0.5); 4.2168 (2.2);4.1989 (3.4); 4.1811 (2.3); 4.1632 (0.6); 4.0039 (0.8); 3.9589 (1.2);3.8132 (16.0); 3.8103 (14.3); 3.7824 (1.2); 3.7784 (1.1); 3.7375 (0.8);3.7334 (0.8); 1.9563 (0.5); 1.5566 (3.4); 1.3239 (1.9); 1.3060 (4.0);1.3013 (2.0); 1.2881 (2.1); 1.2834 (3.9); 1.2656 (1.9); −0.0002 (8.2)I-044: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.2608 (15.6); 6.7967 (1.9); 6.7910(2.2); 6.7881 (2.1); 6.7823 (2.7); 6.7789 (1.0); 6.7764 (0.9); 6.5604(1.0); 6.5545 (1.4); 6.5487 (0.7); 4.4208 (0.8); 4.4068 (1.0); 4.4043(0.7); 4.3990 (0.5); 4.3924 (1.0); 4.3851 (0.9); 4.3801 (0.7); 4.3703(0.7); 4.3665 (0.5); 4.0018 (0.5); 3.9568 (0.8); 3.8140 (16.0); 3.8110(12.3); 3.7930 (0.6); 3.7869 (1.1); 3.7824 (1.0); 3.7740 (0.5); 3.7405(1.3); 3.7375 (0.8); 3.7259 (1.1); 3.7174 (1.0); 3.7120 (1.0); 3.7032(1.7); 3.6996 (0.5); 3.6891 (1.2); 1.9887 (0.5); 1.5575 (2.0); −0.0002(7.8) I-045: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.6925 (2.6); 7.6882 (4.9);7.6827 (5.1); 7.6772 (6.7); 7.6729 (4.2); 7.5388 (1.8); 7.5352 (2.6);7.5319 (3.7); 7.5290 (3.6); 7.5252 (2.9); 7.5198 (2.8); 7.5160 (3.4);7.5128 (4.8); 7.5098 (4.6); 7.5061 (3.6); 7.4773 (0.9); 7.4747 (1.0);7.4720 (1.1); 7.4656 (2.5); 7.4636 (3.0); 7.4602 (2.9); 7.4546 (1.9);7.4520 (1.8); 7.4481 (3.7); 7.4463 (4.2); 7.4434 (5.0); 7.4414 (4.1);7.4071 (1.3); 7.4051 (1.4); 7.3981 (4.6); 7.3855 (1.9); 7.3778 (5.8);7.3679 (1.0); 7.3587 (2.2); 7.3141 (1.6); 7.3005 (1.6); 7.2612 (92.0);6.8177 (0.6); 6.0509 (0.6); 6.0449 (0.9); 6.0409 (1.0); 6.0313 (1.9);6.0261 (2.0); 6.0224 (1.7); 6.0184 (3.1); 6.0149 (3.2); 6.0119 (3.3);6.0085 (3.0); 6.0043 (1.9); 6.0007 (1.9); 5.9978 (1.8); 5.9943 (1.7);5.9476 (1.6); 5.9421 (3.0); 5.9365 (1.8); 5.9283 (2.2); 5.9227 (1.2);5.8994 (0.5); 5.8937 (0.9); 5.8880 (0.6); 5.8800 (2.3); 5.8745 (3.2);5.8689 (1.8); 5.8666 (1.6); 5.8608 (2.4); 5.8552 (1.3); 5.8401 (0.8);5.8262 (0.8); 5.2988 (16.0); 5.0928 (1.7); 5.0762 (1.6); 4.5686 (7.3);4.5542 (9.2); 4.5525 (5.7); 4.5394 (7.9); 4.4247 (5.1); 4.4126 (5.0);4.4108 (6.4); 4.4082 (4.6); 4.3986 (4.4); 4.3963 (8.3); 4.3853 (5.6);4.3804 (4.7); 4.3705 (4.2); 4.3675 (3.6); 4.3596 (2.5); 4.3435 (2.4);4.3315 (1.4); 4.0156 (3.4); 3.9712 (4.9); 3.8990 (1.0); 3.8301 (0.5);3.8243 (0.5); 3.8204 (0.7); 3.8144 (0.9); 3.8082 (1.0); 3.8022 (1.1);3.7960 (3.0); 3.7896 (12.2); 3.7844 (7.1); 3.7763 (6.2); 3.7746 (9.5);3.7601 (7.6); 3.7510 (2.1); 3.7453 (6.4); 3.7431 (7.9); 3.7394 (5.4);3.7313 (4.5); 3.7287 (7.4); 3.7189 (7.0); 3.7148 (6.9); 3.7093 (1.9);3.7046 (9.1); 3.7005 (3.4); 3.6906 (7.0); 3.6863 (2.6); 3.6754 (2.3);3.6724 (2.3); 3.6616 (1.8); 3.6156 (1.2); 3.6091 (1.6); 3.6025 (2.0);3.5952 (2.1); 3.5879 (2.1); 3.5814 (1.7); 3.5752 (1.2); 2.6016 (1.1);2.5806 (2.1); 2.5662 (1.4); 2.5594 (1.2); 2.5451 (2.3); 2.5326 (1.2);2.5240 (1.3); 2.5117 (2.1); 2.4973 (1.4); 2.4906 (1.3); 2.4763 (2.4);2.4553 (1.2); 2.0392 (1.2); 2.0309 (2.1); 2.0226 (1.2); 2.0025 (1.8);1.9944 (3.3); 1.9865 (2.1); 1.9756 (0.5); 1.9663 (1.1); 1.9583 (1.9);1.9501 (1.2); 1.5628 (2.2); 0.0079 (1.3); −0.0002 (47.8); −0.0085 (1.9)I-046: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.6948 (1.1); 7.6902 (1.9); 7.6830(1.5); 7.6785 (2.5); 7.6743 (1.8); 7.5399 (0.7); 7.5367 (1.0); 7.5328(1.4); 7.5293 (1.3); 7.5256 (1.1); 7.5207 (1.2); 7.5175 (1.4); 7.5136(1.7); 7.5102 (1.6); 7.5065 (1.3); 7.4648 (1.0); 7.4625 (1.2); 7.4592(1.2); 7.4536 (0.8); 7.4508 (0.8); 7.4471 (1.5); 7.4451 (1.7); 7.4423(2.0); 7.4401 (1.6); 7.4037 (0.8); 7.3971 (2.1); 7.3839 (1.3); 7.3780(2.7); 7.3588 (1.2); 7.2612 (33.5); 6.0098 (0.8); 6.0058 (0.8); 6.0033(0.8); 5.9993 (1.2); 5.9956 (1.3); 5.9923 (1.3); 5.9890 (1.3); 5.9855(1.3); 5.9818 (0.8); 5.9787 (0.7); 5.9753 (0.6); 5.9295 (0.6); 5.9239(1.2); 5.9183 (0.7); 5.9101 (0.8); 5.8652 (0.8); 5.8597 (1.2); 5.8541(0.7); 5.8515 (0.7); 5.8459 (0.9); 5.8404 (0.5); 5.2987 (1.2); 5.0765(0.7); 4.0167 (1.8); 3.9717 (2.6); 3.7952 (1.0); 3.7929 (1.1); 3.7878(2.6); 3.7807 (2.6); 3.7604 (16.0); 3.7531 (1.4); 3.7499 (1.7); 3.7398(15.8); 3.7359 (2.6); 3.7048 (3.7); 3.6932 (3.7); 3.5533 (0.7); 3.5501(0.7); 3.5423 (0.8); 3.5356 (0.8); 2.5445 (0.8); 2.5301 (0.6); 2.5235(0.5); 2.5092 (1.0); 2.5001 (0.5); 2.4882 (0.5); 2.4792 (0.9); 2.4649(0.6); 2.4584 (0.5); 2.4441 (1.0); 2.0134 (0.5); 2.0054 (0.9); 1.9701(1.2); 1.9618 (1.4); 1.9266 (0.9); 1.5661 (0.6); 0.0079 (0.6); −0.0002(16.9); −0.0085 (0.6) I-047: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.2610(13.0); 6.7980 (1.8); 6.7923 (2.2); 6.7895 (2.0); 6.7837 (2.6); 6.7780(1.0); 6.7757 (0.9); 6.5596 (1.0); 6.5538 (1.4); 6.5482 (0.7); 5.9886(0.5); 5.9851 (0.5); 5.8570 (0.5); 4.1302 (0.5); 4.1123 (0.5); 4.0016(0.8); 3.9566 (1.2); 3.8140 (16.0); 3.8108 (12.2); 3.7930 (0.5); 3.7903(0.5); 3.7841 (1.0); 3.7789 (1.0); 3.7565 (5.5); 3.7488 (0.9); 3.7387(6.0); 3.7341 (1.0); 3.7036 (1.6); 3.6927 (1.6); 2.5163 (0.5); 2.0430(2.3); 1.5612 (2.1); 1.2762 (1.1); 1.2650 (1.3); 1.2584 (1.9); 1.2405(0.7); 0.8986 (0.6); 0.8818 (1.9); 0.8641 (0.8); −0.0002 (7.3) I-048:¹H-NMR(400.0 MHz, CDCl3): δ = 7.7131 (2.4); 7.6571 (1.8); 7.5349 (2.8);7.3893 (0.7); 7.3777 (0.6); 7.2609 (36.7); 6.0158 (0.5); 6.0115 (0.9);6.0079 (0.9); 6.0015 (0.9); 5.9977 (1.2); 5.9943 (1.3); 5.9914 (1.3);5.9881 (1.2); 5.9816 (0.8); 5.9785 (0.8); 5.9751 (0.7); 5.9321 (0.7);5.9266 (1.3); 5.9210 (0.8); 5.9129 (0.9); 5.9074 (0.5); 5.8633 (0.7);5.8578 (1.2); 5.8520 (0.8); 5.8439 (0.9); 5.8384 (0.5); 5.2985 (9.6);5.0744 (0.7); 4.0586 (2.0); 4.0135 (2.8); 3.8251 (1.2); 3.8194 (2.6);3.8124 (2.4); 3.7811 (1.0); 3.7744 (2.1); 3.7669 (2.7); 3.7623 (16.0);3.7522 (0.9); 3.7485 (1.3); 3.7390 (15.7); 3.7053 (4.0); 3.6926 (4.1);3.5639 (0.5); 3.5575 (0.7); 3.5510 (0.9); 3.5438 (0.9); 3.5367 (0.9);3.5305 (0.7); 3.5242 (0.5); 2.5443 (0.9); 2.5299 (0.6); 2.5232 (0.6);2.5090 (1.0); 2.4967 (0.6); 2.4879 (0.6); 2.4759 (1.3); 2.4602 (13.6);2.4407 (1.1); 2.4198 (0.5); 2.0091 (0.8); 1.9738 (1.0); 1.9634 (1.1);1.9545 (0.6); 1.9281 (0.9); 1.9194 (0.5); 1.5598 (4.2); −0.0002 (14.0);−0.0085 (0.5) I-049: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.7147 (2.9); 7.6602(2.4); 7.5361 (3.5); 7.3228 (0.9); 7.3078 (0.9); 7.2609 (45.6); 6.0428(0.6); 6.0321 (1.0); 6.0286 (1.1); 6.0248 (0.9); 6.0179 (1.6); 6.0147(1.7); 6.0115 (1.6); 6.0046 (0.9); 6.0010 (1.0); 5.9980 (0.9); 5.9946(0.8); 5.9507 (0.8); 5.9451 (1.5); 5.9395 (1.0); 5.9314 (1.2); 5.9258(0.6); 5.8785 (0.9); 5.8730 (1.4); 5.8672 (0.9); 5.8592 (1.2); 5.8536(0.7); 5.2986 (2.4); 5.0985 (0.9); 5.0821 (0.9); 4.5687 (0.8); 4.5544(1.0); 4.5395 (0.8); 4.4264 (2.6); 4.4125 (3.2); 4.4100 (2.2); 4.3981(4.4); 4.3941 (1.8); 4.3842 (2.9); 4.3795 (2.5); 4.3694 (1.8); 4.3660(1.7); 4.3596 (1.4); 4.3446 (1.4); 4.3313 (0.8); 4.0579 (2.1); 4.0128(3.0); 3.8284 (1.6); 3.8223 (3.3); 3.8162 (3.2); 3.7892 (1.1); 3.7832(1.1); 3.7770 (2.7); 3.7712 (2.3); 3.7601 (0.9); 3.7440 (3.1); 3.7321(2.2); 3.7297 (3.5); 3.7165 (5.0); 3.7028 (5.0); 3.6888 (4.2); 3.6729(1.5); 3.6609 (1.0); 3.6179 (0.7); 3.6108 (0.8); 3.6034 (1.1); 3.5970(1.2); 3.5897 (1.1); 3.5829 (0.9); 3.5761 (0.7); 2.6018 (0.6); 2.5806(1.0); 2.5662 (0.7); 2.5595 (0.6); 2.5452 (1.2); 2.5298 (0.6); 2.5241(0.7); 2.5089 (1.1); 2.4945 (0.8); 2.4878 (0.8); 2.4734 (1.7); 2.4599(16.0); 2.0436 (0.6); 2.0353 (1.0); 2.0272 (0.6); 2.0080 (0.6); 2.0004(1.3); 1.9938 (1.4); 1.9858 (0.7); 1.9672 (0.7); 1.9588 (1.0); 1.9503(0.6); 1.5559 (3.6); 0.0080 (0.6); −0.0002 (17.4); −0.0083 (0.8) I-050:¹H-NMR(400.0 MHz, CDCl3): δ = 7.7123 (2.4); 7.6612 (2.5); 7.5385 (3.3);7.2600 (54.8); 7.2220 (1.0); 7.2023 (1.0); 6.0273 (0.7); 6.0235 (0.9);6.0209 (0.9); 6.0174 (0.8); 6.0075 (1.7); 5.9982 (1.0); 5.9944 (1.0);5.9918 (1.0); 5.9882 (0.9); 5.9760 (0.9); 5.9705 (1.6); 5.9650 (0.9);5.9567 (1.0); 5.9512 (0.6); 5.9047 (0.8); 5.8992 (1.5); 5.8934 (0.9);5.8854 (1.2); 5.8797 (0.6); 5.2982 (4.1); 5.1033 (0.8); 5.0821 (0.8);4.5702 (1.3); 4.5493 (3.8); 4.5376 (0.8); 4.5335 (1.0); 4.5284 (4.0);4.5168 (2.1); 4.5126 (2.1); 4.5075 (1.5); 4.5016 (0.6); 4.4959 (2.1);4.4918 (2.1); 4.4750 (0.7); 4.4708 (0.7); 4.0517 (1.5); 4.0067 (2.1);3.8261 (3.0); 3.8183 (2.9); 3.7811 (2.1); 3.7733 (2.1); 3.7635 (0.6);3.7486 (0.5); 3.7390 (0.5); 3.7052 (0.8); 3.6925 (0.7); 3.6565 (0.9);3.6506 (1.0); 3.6445 (0.9); 3.6304 (0.5); 2.6576 (0.6); 2.6365 (1.0);2.6221 (0.7); 2.6154 (0.7); 2.6010 (1.1); 2.5796 (1.1); 2.5584 (1.1);2.5439 (0.7); 2.5374 (0.6); 2.5230 (1.2); 2.5021 (0.7); 2.4596 (16.0);2.0410 (0.6); 2.0320 (1.0); 2.0227 (0.6); 2.0028 (0.8); 1.9938 (1.3);1.9871 (0.8); 1.9672 (0.5); 1.9581 (0.9); 1.9489 (0.5); 1.5450 (3.0);0.0080 (0.8); −0.0002 (20.4); −0.0084 (0.8) I-051: ¹H-NMR(400.0 MHz,CDCl3): δ = 7.6905 (2.0); 7.6863 (3.3); 7.6813 (3.8); 7.6763 (4.6);7.6721 (3.1); 7.5396 (1.4); 7.5356 (1.9); 7.5325 (2.2); 7.5308 (2.4);7.5268 (2.1); 7.5204 (2.1); 7.5183 (2.9); 7.5134 (3.0); 7.5116 (3.2);7.5075 (2.6); 7.4715 (1.4); 7.4688 (1.9); 7.4665 (2.4); 7.4643 (2.1);7.4615 (2.0); 7.4513 (2.4); 7.4492 (3.1); 7.4463 (3.8); 7.4442 (3.2);7.4414 (2.3); 7.3986 (3.6); 7.3977 (3.3); 7.3874 (1.2); 7.3794 (4.5);7.3785 (4.4); 7.3593 (1.9); 7.2915 (0.5); 7.2701 (1.4); 7.2693 (1.5);7.2669 (2.2); 7.2660 (2.5); 7.2652 (2.9); 7.2596 (245.8); 7.2515 (4.3);7.2499 (3.4); 7.2300 (1.3); 7.2227 (1.7); 7.2187 (1.8); 7.1966 (1.5);6.9956 (1.4); 6.0242 (1.0); 6.0180 (1.2); 6.0064 (2.4); 5.9999 (2.0);5.9949 (1.7); 5.9924 (1.7); 5.9887 (1.6); 5.9721 (1.2); 5.9666 (2.1);5.9610 (1.2); 5.9528 (1.3); 5.9471 (0.8); 5.9057 (1.4); 5.9001 (2.3);5.8944 (1.4); 5.8920 (1.2); 5.8863 (1.9); 5.8806 (1.1); 5.1003 (1.2);5.0820 (1.1); 4.5689 (2.2); 4.5480 (6.8); 4.5418 (1.4); 4.5386 (1.3);4.5271 (7.0); 4.5208 (3.3); 4.5177 (3.2); 4.5062 (2.7); 4.5000 (3.5);4.4967 (3.2); 4.4891 (0.9); 4.4792 (1.5); 4.4759 (1.1); 4.4681 (0.8);4.0130 (2.4); 3.9680 (3.5); 3.7984 (1.1); 3.7930 (4.1); 3.7860 (5.2);3.7606 (2.8); 3.7480 (3.0); 3.7401 (6.4); 3.7049 (1.3); 3.6933 (0.9);3.6602 (1.1); 3.6574 (1.3); 3.6547 (1.2); 3.6480 (1.3); 3.6451 (1.3);3.6424 (1.3); 2.6579 (0.9); 2.6367 (1.5); 2.6223 (1.2); 2.6156 (1.1);2.6013 (1.7); 2.5835 (0.9); 2.5803 (1.1); 2.5625 (1.4); 2.5481 (1.0);2.5417 (0.8); 2.5272 (1.6); 2.5063 (0.8); 2.0359 (0.9); 2.0267 (1.5);2.0175 (1.0); 2.0005 (1.5); 1.9913 (2.6); 1.9822 (1.5); 1.9658 (0.7);1.9562 (1.2); 1.9469 (0.8); 1.5362 (16.0); 0.0080 (3.0); 0.0056 (1.3);0.0048 (1.5); −0.0002 (94.5); −0.0066 (2.2); −0.0084 (3.7) I-052:¹H-NMR(400.0 MHz, CDCl3): δ = 7.2599 (30.1); 6.7955 (2.0); 6.7897 (2.4);6.7878 (2.8); 6.7821 (2.9); 6.7779 (0.5); 6.5623 (0.8); 6.5606 (0.8);6.5566 (1.2); 6.5549 (1.4); 6.5510 (0.6); 6.5493 (0.7); 6.0029 (0.6);5.9999 (0.6); 5.9967 (0.6); 5.9931 (0.6); 5.9622 (0.5); 5.8978 (0.6);4.5449 (1.4); 4.5240 (1.5); 4.5204 (0.9); 4.5177 (0.8); 4.5030 (0.6);4.4995 (0.8); 4.4967 (0.7); 3.9969 (0.6); 3.9520 (0.9); 3.8136 (14.8);3.8109 (16.0); 3.7898 (1.0); 3.7842 (1.2); 3.7448 (0.6); 3.7391 (0.8);1.5432 (3.4); 1.2647 (0.8); 1.2585 (0.6); 0.8819 (1.4); 0.8642 (0.5);−0.0002 (14.8) I-053: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.3801 (0.6); 7.3717(0.7); 7.2752 (2.6); 7.2601 (23.2); 7.1038 (1.6); 5.9994 (0.5); 5.9957(0.6); 5.9930 (0.6); 5.9890 (0.8); 5.9855 (0.9); 5.9821 (0.9); 5.9790(0.8); 5.9753 (0.8); 5.9712 (0.5); 5.9093 (0.8); 5.8954 (0.6); 5.8317(0.7); 5.8179 (0.6); 4.2353 (0.8); 4.2174 (2.5); 4.1995 (2.8); 4.1973(2.6); 4.1868 (0.5); 4.1795 (2.4); 4.1616 (0.8); 4.0116 (1.0); 3.9666(1.5); 3.7988 (1.4); 3.7941 (1.4); 3.7539 (1.0); 3.7491 (1.0); 3.5265(0.5); 3.5201 (0.6); 3.5149 (0.6); 3.5107 (0.6); 3.5079 (0.6); 2.5467(0.5); 2.5113 (0.6); 2.4852 (0.7); 2.4498 (0.6); 2.4030 (1.8); 2.3719(1.8); 2.3510 (0.9); 2.3382 (16.0); 2.3058 (1.6); 1.9917 (0.5); 1.9564(0.5); 1.9483 (0.6); 1.9394 (0.6); 1.5716 (0.8); 1.3252 (2.5); 1.3207(0.8); 1.3073 (5.2); 1.3027 (1.9); 1.3004 (3.0); 1.2895 (3.0); 1.2869(1.9); 1.2826 (5.6); 1.2685 (1.6); 1.2647 (3.5); 1.2504 (0.6); 0.8818(1.5); 0.8641 (0.6); −0.0002 (12.6); −0.0085 (0.6) I-054: ¹H-NMR(400.0MHz, CDCl3): δ = 7.2601 (37.2); 7.1795 (1.7); 7.1741 (2.1); 7.1708(1.4); 7.1597 (2.0); 7.1543 (1.5); 6.9115 (0.7); 6.8955 (0.8); 6.8898(1.3); 6.8841 (0.7); 6.8681 (0.6); 6.7323 (0.6); 6.7124 (0.6); 6.1937(1.2); 6.1669 (1.3); 6.1505 (1.4); 6.1237 (1.5); 5.9849 (0.7); 5.9804(1.0); 5.9746 (0.8); 5.9711 (1.0); 5.9664 (1.3); 5.9608 (0.9); 5.8516(0.8); 5.8460 (1.5); 5.8400 (1.0); 5.8321 (1.2); 5.8265 (0.6); 5.5480(2.6); 5.5049 (2.3); 5.3506 (2.4); 5.3238 (2.2); 5.1148 (0.6); 5.1099(0.6); 5.1043 (0.6); 5.0990 (0.6); 3.9487 (2.3); 3.9056 (2.6); 3.7469(0.6); 3.7418 (1.4); 3.7349 (1.8); 3.7295 (0.7); 3.7250 (0.7); 3.7191(0.7); 3.7131 (0.7); 3.7071 (0.5); 3.6954 (0.7); 3.6844 (16.0); 3.3319(2.6); 3.2887 (2.2); 2.6854 (0.6); 2.6734 (0.6); 2.6648 (0.6); 2.6523(0.8); 2.6382 (0.7); 2.6297 (0.6); 2.6176 (0.6); 1.8654 (0.7); 1.8543(0.7); 1.8434 (0.7); 1.8316 (1.0); 1.8191 (0.7); 1.8083 (0.7); 1.7971(0.7); 0.0079 (0.9); −0.0002 (22.2); −0.0085 (0.8) I-055: ¹H-NMR(400.0MHz, CDCl3): δ = 7.3926 (0.6); 7.3835 (0.6); 7.3733 (0.6); 7.2781 (2.3);7.2764 (2.4); 7.2724 (2.6); 7.2636 (12.0); 7.1090 (1.5); 6.0013 (0.6);5.9974 (0.7); 5.9949 (0.7); 5.9904 (0.8); 5.9873 (0.8); 5.9838 (0.8);5.9809 (0.7); 5.9775 (0.6); 5.9173 (0.7); 5.8447 (0.6); 5.3018 (2.6);5.0733 (0.5); 4.0117 (1.0); 3.9667 (1.5); 3.8140 (0.6); 3.8115 (0.6);3.8063 (1.2); 3.8003 (1.2); 3.7595 (8.2); 3.7557 (3.0); 3.7476 (1.2);3.7408 (7.8); 3.7100 (0.6); 3.7040 (2.3); 3.6920 (2.1); 3.5453 (0.5);3.5430 (0.5); 3.5371 (0.5); 2.5167 (0.5); 2.4919 (0.6); 2.4043 (1.7);2.3738 (1.7); 2.3412 (16.0); 2.3093 (1.4); 1.9419 (0.5); 1.6041 (2.0);−0.0002 (6.5) I-056: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.3434 (0.6); 7.3210(0.6); 7.2717 (2.9); 7.2630 (18.1); 7.1096 (1.5); 6.0234 (0.6); 6.0173(0.7); 6.0134 (0.6); 6.0064 (0.8); 6.0037 (0.8); 5.9354 (0.7); 5.9216(0.5); 5.8596 (0.7); 5.8458 (0.5); 5.3019 (4.6); 4.4228 (1.0); 4.4089(1.5); 4.3981 (1.2); 4.3954 (2.1); 4.3848 (1.5); 4.3807 (1.4); 4.3699(1.1); 4.3676 (0.9); 4.3588 (0.7); 4.3434 (0.7); 4.0121 (0.8); 3.9671(1.3); 3.8141 (0.7); 3.8082 (1.5); 3.8036 (1.4); 3.7634 (1.0); 3.7585(0.9); 3.7468 (1.5); 3.7425 (0.5); 3.7324 (1.9); 3.7293 (1.2); 3.7205(1.9); 3.7186 (1.8); 3.7146 (0.9); 3.7062 (2.2); 3.7031 (1.0); 3.6922(2.0); 3.6776 (0.7); 3.6753 (0.6); 3.5979 (0.5); 3.5914 (0.6); 2.5508(0.5); 2.5220 (0.5); 2.4867 (0.5); 2.4045 (1.7); 2.3735 (1.6); 2.3412(16.0); 2.3093 (1.4); 1.9820 (0.6); 1.9731 (0.6); 1.5854 (2.7); −0.0002(10.3) I-057: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.2761 (2.6); 7.2729 (2.6);7.2624 (22.9); 7.2308 (0.5); 7.1120 (1.5); 6.0157 (0.5); 6.0094 (0.6);6.0055 (0.6); 6.0018 (0.9); 5.9981 (0.9); 5.9956 (0.9); 5.9918 (0.8);5.9592 (0.8); 5.8844 (0.7); 5.8705 (0.6); 5.3018 (2.6); 4.5675 (0.7);4.5466 (2.1); 4.5256 (2.2); 4.5172 (1.0); 4.5125 (1.0); 4.5046 (1.0);4.4962 (1.0); 4.4916 (1.0); 4.0079 (0.7); 3.9635 (1.1); 3.8119 (1.4);3.8054 (1.3); 3.7670 (1.0); 3.7606 (1.0); 3.6505 (0.5); 3.6451 (0.5);2.6063 (0.5); 2.5345 (0.5); 2.4044 (1.7); 2.3737 (1.6); 2.3410 (16.0);2.3082 (1.5); 1.9853 (0.6); 1.9750 (0.6); 1.5716 (3.6); −0.0002 (12.6)I-058: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.3735 (0.6); 7.3508 (0.6); 7.2598(77.6); 7.2113 (1.2); 7.2055 (1.6); 7.2016 (2.0); 7.1958 (2.4); 7.1920(2.3); 7.1862 (2.1); 7.1822 (1.7); 7.1765 (1.3); 6.9527 (0.8); 6.9378(0.9); 6.9320 (1.5); 6.9263 (0.8); 6.9104 (0.7); 6.0140 (0.5); 6.0105(0.6); 6.0041 (1.0); 6.0004 (1.2); 5.9972 (1.2); 5.9938 (1.2); 5.9904(1.3); 5.9840 (0.7); 5.9806 (0.6); 5.9262 (0.6); 5.9207 (1.1); 5.9152(0.7); 5.9070 (0.8); 5.8611 (0.6); 5.8556 (1.0); 5.8501 (0.7); 5.8419(0.9); 5.0868 (0.7); 5.0655 (0.7); 4.2383 (0.9); 4.2204 (3.0); 4.2170(1.4); 4.2025 (3.4); 4.1991 (3.7); 4.1846 (1.4); 4.1812 (3.7); 4.1634(1.4); 3.9961 (1.3); 3.9514 (1.9); 3.7513 (2.4); 3.7454 (2.5); 3.7062(1.7); 3.7003 (1.7); 3.5317 (0.7); 3.5199 (0.7); 2.5308 (0.8); 2.5165(0.6); 2.4954 (0.9); 2.4632 (0.8); 2.4488 (0.6); 2.4280 (1.0); 2.0004(0.8); 1.9734 (0.7); 1.9661 (1.3); 1.9584 (0.8); 1.9315 (0.7); 1.5384(16.0); 1.3248 (4.2); 1.3069 (9.0); 1.3039 (5.3); 1.2890 (5.6); 1.2860(9.2); 1.2681 (7.7); 1.2648 (5.3); 1.2540 (1.8); 1.2468 (0.9); 1.2360(0.6); 0.8989 (2.3); 0.8819 (7.8); 0.8642 (3.0); 0.0080 (1.5); −0.0002(46.2); −0.0085 (1.7) I-059: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.2615(42.4); 7.2120 (0.7); 7.2076 (0.8); 7.2022 (0.9); 7.1960 (0.7); 7.1895(2.1); 7.1837 (2.8); 7.1809 (2.9); 7.1750 (2.6); 7.1702 (3.6); 7.1644(3.9); 7.1612 (2.8); 7.1552 (2.2); 7.1508 (2.0); 7.1451 (1.6); 6.9133(0.7); 6.8974 (1.2); 6.8916 (2.2); 6.8858 (1.2); 6.8757 (1.3); 6.8699(2.3); 6.8642 (1.2); 6.8541 (0.5); 6.8484 (0.8); 5.9750 (0.8); 5.9717(0.9); 5.9689 (0.9); 5.9654 (0.7); 5.9615 (0.8); 5.9554 (1.4); 5.9515(1.4); 5.9452 (0.7); 5.9416 (0.7); 5.9377 (0.8); 5.9353 (0.8); 5.9315(0.7); 5.8945 (0.7); 5.8890 (1.3); 5.8833 (0.8); 5.8809 (0.6); 5.8751(1.0); 5.8696 (0.5); 5.8067 (0.6); 5.8011 (1.2); 5.7954 (0.8); 5.7931(0.7); 5.7873 (1.0); 5.7817 (0.6); 5.2991 (4.9); 5.0304 (0.6); 5.0136(0.8); 5.0094 (0.8); 5.0056 (0.8); 4.2306 (1.2); 4.2128 (3.9); 4.2016(1.4); 4.1991 (1.7); 4.1949 (4.1); 4.1840 (3.4); 4.1814 (1.9); 4.1771(1.5); 4.1662 (3.4); 4.1484 (1.1); 3.8676 (2.6); 3.8247 (3.0); 3.8019(2.2); 3.7977 (2.2); 3.7587 (2.5); 3.7545 (2.6); 3.5274 (0.5); 3.5212(0.6); 3.5068 (0.9); 3.5039 (0.8); 3.5006 (0.8); 3.2605 (2.7); 3.2177(2.4); 3.1978 (2.2); 3.1897 (2.2); 3.1545 (2.0); 3.1464 (1.9); 2.5625(0.5); 2.5414 (1.0); 2.5275 (0.7); 2.5203 (0.6); 2.5061 (1.5); 2.4848(1.4); 2.4707 (0.6); 2.4635 (0.6); 2.4497 (1.0); 2.4286 (0.5); 1.9706(0.7); 1.9613 (1.0); 1.9264 (0.8); 1.8867 (0.5); 1.8770 (0.9); 1.8421(0.8); 1.7874 (16.0); 1.7254 (11.8); 1.7197 (2.1); 1.7114 (12.0); 1.3224(4.0); 1.3106 (1.7); 1.3046 (8.3); 1.2913 (5.0); 1.2867 (4.5); 1.2734(8.6); 1.2621 (0.6); 1.2555 (4.2); 1.2444 (0.6); 0.0079 (0.8); −0.0002(24.4); −0.0085 (1.0) I-060: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.2599(26.2); 7.1845 (0.5); 7.1789 (0.8); 7.1763 (1.0); 7.1706 (0.9); 7.1680(0.8); 7.1649 (0.8); 7.1593 (1.0); 7.1567 (0.9); 7.1510 (0.6); 6.8722(0.8); 6.1992 (0.8); 6.1724 (0.8); 6.1561 (0.9); 6.1293 (0.9); 5.9349(0.5); 5.9296 (0.5); 5.5667 (0.7); 5.5465 (0.9); 5.5237 (0.6); 5.5034(0.8); 5.3483 (0.8); 5.3333 (0.7); 5.3215 (0.8); 5.3064 (0.6); 3.9383(1.2); 3.8954 (1.4); 3.3238 (0.8); 3.3179 (0.8); 3.2808 (0.8); 3.2749(0.7); 2.4630 (0.6); 1.4739 (16.0); 1.4510 (15.7); 1.4374 (3.1); 1.4265(2.9); 1.2586 (0.5); 0.8818 (0.6); 0.0079 (0.5); −0.0002 (15.2); −0.0082(0.8) I-061: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.5184 (0.6); 7.2596 (96.0);7.1889 (0.7); 7.1832 (0.8); 7.1802 (1.1); 7.1744 (1.2); 7.1694 (1.1);7.1634 (1.1); 7.1605 (1.0); 7.1549 (0.8); 6.9955 (0.5); 6.8780 (0.7);6.2037 (0.5); 6.2001 (0.5); 6.1769 (0.6); 6.1734 (0.6); 6.1606 (0.6);6.1570 (0.6); 6.1338 (0.6); 6.1302 (0.6); 5.9764 (0.6); 5.9724 (0.6);5.9661 (0.6); 5.8974 (0.6); 5.8472 (0.6); 5.5706 (0.8); 5.5510 (1.2);5.5288 (0.7); 5.5078 (1.0); 5.3567 (0.9); 5.3416 (0.8); 5.3299 (0.9);5.3140 (0.7); 4.5687 (2.2); 4.5543 (2.8); 4.5395 (2.4); 4.4164 (0.6);4.4092 (0.6); 4.4024 (1.0); 4.3957 (1.6); 4.3878 (0.7); 4.3815 (1.5);4.3678 (1.1); 3.9388 (1.9); 3.8958 (2.1); 3.7889 (2.4); 3.7741 (2.8);3.7597 (2.2); 3.7417 (1.0); 3.7275 (2.2); 3.7251 (1.6); 3.7129 (1.6);3.7108 (1.5); 3.6967 (1.2); 3.3287 (1.1); 3.3250 (1.0); 3.2856 (1.0);3.2820 (0.9); 1.9347 (0.6); 1.5335 (16.0); 0.0079 (1.9); −0.0002 (56.5);−0.0084 (2.1) I-062: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.2600 (36.4); 7.2027(1.4); 7.1970 (1.7); 7.1939 (1.2); 7.1866 (1.0); 7.1835 (1.7); 7.1778(1.5); 6.9680 (0.6); 6.9522 (0.7); 6.9464 (1.2); 6.9406 (0.6); 6.9249(0.6); 6.0291 (0.7); 6.0248 (0.8); 6.0229 (0.8); 6.0186 (0.7); 6.0152(0.8); 6.0108 (1.0); 6.0090 (1.0); 6.0047 (0.8); 5.8752 (0.7); 5.8695(1.4); 5.8637 (0.8); 5.8614 (0.7); 5.8556 (1.2); 5.8498 (0.7); 5.2983(2.6); 4.0055 (0.9); 3.9601 (1.3); 3.7791 (0.6); 3.7724 (0.6); 3.7664(0.7); 3.7615 (2.9); 3.7547 (0.7); 3.7505 (0.6); 3.7446 (0.7); 3.7408(0.7); 3.7387 (0.7); 3.7164 (1.8); 3.6951 (16.0); 3.0530 (0.5); 2.7231(0.6); 2.7113 (0.6); 2.7024 (0.6); 2.6905 (0.7); 2.6879 (0.8); 2.6760(0.7); 2.6671 (0.6); 2.6553 (0.6); 1.8975 (0.6); 1.8861 (0.6); 1.8755(0.6); 1.8639 (0.7); 1.8624 (0.7); 1.8508 (0.6); 1.8402 (0.5); 1.8288(0.5); 1.5437 (3.8); 0.0079 (0.6); −0.0002 (19.7); −0.0085 (0.8) I-063:¹H-NMR(400.0 MHz, CDCl3): δ = 7.3723 (0.6); 7.3531 (0.5); 7.2598 (81.9);7.2132 (1.3); 7.2075 (1.6); 7.2028 (2.2); 7.1969 (2.9); 7.1939 (3.0);7.1880 (2.2); 7.1834 (2.3); 7.1809 (1.9); 7.1777 (2.0); 6.9615 (0.5);6.9593 (0.6); 6.9556 (0.7); 6.9534 (0.8); 6.9497 (0.8); 6.9465 (0.8);6.9439 (0.7); 6.9399 (1.0); 6.9378 (1.0); 6.9340 (1.3); 6.9319 (1.3);6.9282 (0.9); 6.9261 (0.8); 6.9162 (0.5); 6.9124 (0.6); 6.9104 (0.6);6.0096 (0.7); 6.0038 (1.0); 5.9999 (1.0); 5.9966 (1.1); 5.9933 (1.0);5.9898 (1.1); 5.9835 (0.6); 5.9801 (0.6); 5.9313 (0.6); 5.9258 (1.0);5.9203 (0.6); 5.9120 (0.7); 5.8700 (0.8); 5.8650 (1.1); 5.8596 (0.7);5.8562 (0.7); 5.8512 (0.8); 5.0806 (0.6); 5.0658 (0.6); 3.9944 (1.6);3.9494 (2.2); 3.7640 (3.0); 3.7601 (16.0); 3.7529 (3.8); 3.7461 (2.8);3.7409 (15.0); 3.7141 (1.0); 3.7082 (2.3); 3.7059 (5.2); 3.7012 (1.9);3.6952 (5.0); 3.5537 (0.6); 3.5451 (0.6); 2.5382 (0.7); 2.5238 (0.5);2.5172 (0.5); 2.5028 (0.9); 2.4730 (0.9); 2.4586 (0.5); 2.4378 (1.0);2.0062 (0.7); 1.9754 (0.6); 1.9676 (0.9); 1.9592 (0.6); 1.9323 (0.7);1.9239 (0.5); 1.5384 (11.8); 0.0079 (1.4); −0.0002 (47.0); −0.0085 (1.7)I-064: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.5191 (0.5); 7.3604 (0.9); 7.3398(1.0); 7.2602 (91.3); 7.2118 (1.8); 7.2060 (2.5); 7.2023 (3.7); 7.1965(4.4); 7.1925 (3.9); 7.1866 (3.6); 7.1829 (3.3); 7.1773 (2.7); 6.9961(0.6); 6.9581 (0.9); 6.9519 (1.7); 6.9460 (1.4); 6.9364 (1.5); 6.9304(2.6); 6.9246 (1.5); 6.9149 (0.8); 6.9089 (1.2); 6.9032 (0.6); 6.0233(0.7); 6.0190 (0.8); 6.0172 (0.8); 6.0130 (0.7); 6.0052 (0.5); 6.0034(0.5); 5.9990 (1.0); 5.9955 (0.8); 5.9894 (1.3); 5.9822 (1.5); 5.9790(1.5); 5.9757 (1.6); 5.9696 (0.9); 5.9663 (0.8); 5.9183 (0.9); 5.9128(1.6); 5.9072 (1.0); 5.9048 (0.7); 5.8991 (1.1); 5.8935 (0.6); 5.8569(0.7); 5.8494 (1.1); 5.8437 (1.7); 5.8380 (1.1); 5.8302 (1.2); 5.8248(0.7); 5.8061 (0.6); 5.7922 (0.6); 5.1150 (0.6); 5.0996 (0.9); 5.0841(2.0); 5.0684 (2.8); 5.0530 (3.0); 5.0374 (2.8); 5.0217 (2.0); 5.0061(1.2); 4.9930 (0.8); 4.9903 (0.7); 4.0020 (1.8); 3.9967 (1.4); 3.9568(2.7); 3.9517 (2.0); 3.7602 (2.0); 3.7515 (3.5); 3.7467 (3.3); 3.7153(1.7); 3.7102 (1.0); 3.7064 (2.7); 3.7016 (2.5); 3.5038 (0.9); 3.4971(1.0); 3.4950 (0.9); 3.4888 (1.0); 3.4824 (1.0); 2.7020 (0.5); 2.5395(0.6); 2.5185 (1.1); 2.5042 (0.8); 2.4973 (0.7); 2.4831 (1.2); 2.4681(0.7); 2.4620 (0.7); 2.4472 (1.2); 2.4328 (0.8); 2.4262 (0.7); 2.4119(1.4); 2.3911 (0.6); 1.9896 (0.6); 1.9822 (1.1); 1.9745 (0.6); 1.9655(0.7); 1.9576 (1.3); 1.9468 (1.1); 1.9392 (0.6); 1.9303 (0.6); 1.9224(1.2); 1.9148 (0.6); 1.5444 (12.0); 1.2918 (7.8); 1.2806 (8.7); 1.2761(8.8); 1.2678 (10.3); 1.2648 (16.0); 1.2523 (9.0); 1.2488 (9.0); 1.2419(3.6); 1.2340 (3.7); 1.2304 (5.9); 1.2263 (3.4); 1.2184 (3.2); 1.2151(3.1); 0.0080 (1.7); −0.0002 (54.0); −0.0085 (1.8) I-065: ¹H-NMR(400.0MHz, CDCl3): δ = 7.5178 (1.0); 7.3767 (5.3); 7.3714 (12.5); 7.3651(5.3); 7.3633 (5.3); 7.3607 (4.1); 7.3532 (9.1); 7.3457 (4.8); 7.3362(2.7); 7.3318 (2.2); 7.3110 (0.8); 7.3067 (0.7); 7.3033 (0.6); 7.2963(0.7); 7.2590 (172.3); 7.2113 (1.4); 7.2088 (1.6); 7.2056 (1.7); 7.2022(2.1); 7.1963 (3.0); 7.1920 (3.0); 7.1864 (2.7); 7.1827 (2.0); 7.1771(2.3); 7.1714 (1.1); 6.9949 (1.0); 6.9604 (0.6); 6.9551 (1.0); 6.9484(0.8); 6.9394 (1.1); 6.9335 (1.7); 6.9273 (1.0); 6.9180 (0.6); 6.9117(0.8); 6.0173 (0.5); 6.0141 (0.6); 6.0110 (0.6); 6.0040 (1.1); 6.0005(1.2); 5.9974 (1.2); 5.9940 (1.2); 5.9870 (0.7); 5.9843 (0.7); 5.9808(0.6); 5.9256 (0.6); 5.9201 (1.2); 5.9145 (0.7); 5.9062 (0.9); 5.8623(0.7); 5.8568 (1.2); 5.8511 (0.7); 5.8430 (0.9); 5.8375 (0.5); 5.1886(4.1); 5.1858 (4.2); 5.1674 (3.8); 5.1639 (4.0); 5.1363 (1.9); 5.1249(1.8); 5.0862 (0.7); 5.0638 (0.7); 4.7125 (1.0); 4.7002 (1.0); 3.9918(1.5); 3.9464 (2.2); 3.7543 (3.5); 3.7471 (2.4); 3.7092 (2.6); 3.7020(1.7); 3.5793 (0.8); 3.5721 (0.8); 2.5549 (0.8); 2.5405 (0.6); 2.5197(0.9); 2.4987 (0.5); 2.4834 (0.9); 2.4691 (0.6); 2.4483 (1.0); 2.0171(0.8); 1.9994 (0.5); 1.9906 (1.1); 1.9821 (1.2); 1.9739 (0.6); 1.9558(0.8); 1.5332 (16.0); 1.2558 (0.6); 0.0080 (3.1); −0.0002 (100.0);−0.0085 (3.5) I-067: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.5186 (1.2); 7.3100(1.1); 7.3003 (1.2); 7.2597 (215.7); 7.2232 (0.8); 7.2114 (2.5); 7.2057(3.2); 7.2021 (4.4); 7.1963 (5.1); 7.1923 (4.8); 7.1864 (4.5); 7.1827(4.0); 7.1771 (3.1); 7.1648 (0.5); 6.9957 (1.2); 6.9610 (0.9); 6.9550(1.4); 6.9511 (1.2); 6.9478 (1.2); 6.9412 (1.8); 6.9393 (1.9); 6.9354(2.5); 6.9335 (2.5); 6.9296 (1.6); 6.9196 (1.1); 6.9137 (1.2); 6.9080(0.6); 6.0587 (0.5); 6.0495 (0.7); 6.0448 (1.0); 6.0368 (1.4); 6.0304(1.5); 6.0235 (2.0); 6.0199 (2.1); 6.0170 (2.1); 6.0135 (2.0); 6.0066(1.2); 6.0039 (1.1); 6.0004 (1.0); 5.9493 (1.1); 5.9438 (2.0); 5.9381(1.2); 5.9300 (1.6); 5.9245 (0.9); 5.8987 (0.6); 5.8928 (0.9); 5.8853(1.4); 5.8796 (2.4); 5.8739 (1.4); 5.8661 (1.6); 5.8605 (0.9); 5.8417(0.8); 5.8356 (0.5); 5.8277 (0.7); 5.0944 (1.1); 5.0773 (1.1); 4.5687(1.1); 4.5543 (1.4); 4.5394 (1.2); 4.4252 (3.6); 4.4133 (3.2); 4.4113(4.3); 4.4086 (3.1); 4.4031 (2.4); 4.3992 (2.9); 4.3971 (4.7); 4.3895(3.8); 4.3844 (3.0); 4.3746 (2.9); 4.3716 (2.7); 4.3613 (2.2); 4.3453(2.2); 4.3340 (1.3); 3.9944 (2.2); 3.9495 (3.2); 3.8224 (0.5); 3.8163(0.6); 3.8110 (0.6); 3.7890 (1.6); 3.7741 (1.6); 3.7625 (2.5); 3.7598(2.1); 3.7560 (4.4); 3.7500 (4.3); 3.7416 (4.7); 3.7300 (3.2); 3.7274(5.0); 3.7254 (3.6); 3.7211 (5.3); 3.7182 (2.7); 3.7134 (5.3); 3.7110(4.5); 3.7068 (7.5); 3.7010 (2.4); 3.6930 (4.6); 3.6866 (2.3); 3.6769(2.0); 3.6727 (2.0); 3.6631 (1.5); 3.6067 (1.2); 3.5989 (1.3); 3.5919(1.3); 2.5966 (0.8); 2.5756 (1.4); 2.5611 (0.9); 2.5545 (0.8); 2.5401(1.5); 2.5293 (0.8); 2.5189 (0.8); 2.5084 (1.5); 2.4941 (1.0); 2.4875(0.8); 2.4731 (1.6); 2.4521 (0.8); 2.0396 (0.8); 2.0315 (1.3); 2.0236(0.7); 2.0045 (1.0); 1.9982 (2.0); 1.9907 (1.2); 1.9721 (1.0); 1.9632(1.5); 1.9551 (0.9); 1.9266 (0.7); 1.5359 (16.0); 1.2555 (2.1); 0.0080(4.0); −0.0002 (125.2); −0.0085 (4.5) I-068: ¹H-NMR(400.0 MHz, CDCl3): δ= 7.5185 (2.3); 7.2964 (1.3); 7.2596 (414.7); 7.2262 (0.9); 7.2105(4.8); 7.2048 (6.5); 7.2022 (8.9); 7.1965 (9.8); 7.1916 (8.1); 7.1858(8.2); 7.1830 (8.2); 7.1774 (7.3); 6.9956 (2.3); 6.9636 (1.6); 6.9577(2.4); 6.9521 (1.5); 6.9440 (2.5); 6.9419 (3.1); 6.9383 (3.9); 6.9362(4.7); 6.9325 (2.4); 6.9304 (2.5); 6.9203 (1.8); 6.9146 (2.4); 6.9088(1.2); 6.0293 (1.5); 6.0256 (1.6); 6.0186 (3.0); 6.0150 (3.8); 6.0119(4.1); 6.0087 (3.9); 6.0051 (4.1); 6.0008 (2.8); 5.9981 (2.6); 5.9945(2.4); 5.9748 (2.0); 5.9693 (3.4); 5.9638 (2.0); 5.9555 (2.1); 5.9499(1.3); 5.9248 (0.6); 5.9116 (2.5); 5.9060 (4.5); 5.9005 (2.7); 5.8923(3.4); 5.8866 (1.9); 5.1034 (2.1); 5.0810 (1.9); 4.5694 (3.8); 4.5485(11.8); 4.5427 (2.2); 4.5276 (12.6); 4.5217 (5.2); 4.5066 (5.0); 4.5046(5.4); 4.5008 (5.1); 4.4907 (0.8); 4.4837 (1.7); 4.4799 (1.9); 4.4697(0.9); 3.9907 (4.6); 3.9456 (6.4); 3.7658 (1.3); 3.7597 (6.6); 3.7528(8.9); 3.7146 (4.8); 3.7077 (6.5); 3.6648 (2.2); 3.6486 (2.3); 2.6534(1.6); 2.6323 (3.0); 2.6178 (2.1); 2.6112 (1.9); 2.5967 (3.3); 2.5808(1.3); 2.5755 (1.8); 2.5598 (2.4); 2.5454 (1.6); 2.5389 (1.4); 2.5244(2.5); 2.5036 (1.3); 2.0370 (1.6); 2.0283 (3.0); 2.0193 (1.7); 2.0057(1.7); 2.0015 (2.0); 1.9964 (3.0); 1.9928 (3.4); 1.9839 (2.0); 1.9701(1.7); 1.9611 (2.8); 1.9526 (2.0); 1.9171 (1.1); 1.8074 (0.7); 1.7140(1.2); 1.6798 (1.3); 1.6152 (0.8); 1.5840 (0.7); 1.5368 (16.0); 1.3686(1.3); 1.3345 (1.4); 1.3057 (0.9); 1.2845 (0.9); 1.2553 (2.1); 1.1972(0.7); 1.1672 (0.7); 1.1441 (0.9); 1.1354 (1.0); 1.1056 (1.2); 1.0857(0.9); 0.1459 (0.9); 0.0366 (0.6); 0.0080 (7.3); −0.0002 (237.9);−0.0085 (8.5); −0.1498 (0.8) I-069: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.9525(1.4); 7.9494 (2.4); 7.9484 (2.5); 7.9454 (1.6); 7.9443 (1.5); 7.9383(1.6); 7.9353 (2.5); 7.9343 (2.5); 7.9313 (1.6); 7.8692 (1.1); 7.8660(1.3); 7.8618 (2.0); 7.8586 (1.4); 7.8543 (1.1); 7.8493 (1.3); 7.8462(1.5); 7.8451 (1.5); 7.8419 (2.2); 7.8388 (1.5); 7.8376 (1.5); 7.8345(1.2); 7.7082 (2.1); 7.7040 (1.3); 7.6930 (1.5); 7.6889 (2.6); 7.6848(1.4); 7.5521 (2.5); 7.5325 (4.0); 7.5128 (1.8); 7.2623 (46.2); 7.2059(0.6); 7.1845 (1.1); 7.1608 (0.6); 5.9776 (0.8); 5.9739 (0.8); 5.9714(0.9); 5.9676 (0.8); 5.9638 (1.1); 5.9600 (1.2); 5.9571 (1.4); 5.9538(1.4); 5.9494 (1.0); 5.9455 (0.9); 5.9419 (1.0); 5.9381 (1.0); 5.9356(1.0); 5.9318 (0.9); 5.8975 (1.0); 5.8920 (1.8); 5.8864 (1.0); 5.8838(0.8); 5.8782 (1.3); 5.8726 (0.7); 5.8045 (0.9); 5.7988 (1.7); 5.7931(1.0); 5.7908 (0.9); 5.7850 (1.4); 5.7794 (0.8); 5.0362 (0.5); 5.0298(0.6); 5.0264 (0.7); 5.0140 (1.0); 5.0088 (1.0); 4.9966 (0.7); 4.9933(0.6); 4.9903 (0.5); 4.2331 (1.7); 4.2152 (5.4); 4.2006 (2.0); 4.1974(5.6); 4.1829 (5.0); 4.1796 (2.2); 4.1651 (5.0); 4.1472 (1.7); 3.8541(2.9); 3.8479 (3.0); 3.8110 (3.3); 3.8047 (3.4); 3.5296 (0.5); 3.5265(0.5); 3.5235 (0.6); 3.5203 (0.6); 3.5172 (0.8); 3.5144 (0.8); 3.5112(0.9); 3.5082 (1.0); 3.5050 (1.0); 3.5018 (1.1); 3.4987 (0.9); 3.4955(0.8); 3.4927 (0.8); 3.4898 (0.6); 3.4866 (0.6); 3.4800 (0.5); 3.2313(3.0); 3.2223 (3.0); 3.1882 (2.7); 3.1791 (2.7); 2.5647 (0.6); 2.5436(1.2); 2.5298 (0.8); 2.5225 (0.7); 2.5086 (1.3); 2.5010 (0.7); 2.4876(0.7); 2.4799 (1.3); 2.4661 (0.8); 2.4589 (0.7); 2.4450 (1.4); 2.4239(0.7); 1.9728 (0.6); 1.9633 (1.2); 1.9537 (0.6); 1.9379 (0.6); 1.9283(1.0); 1.9188 (0.6); 1.8853 (0.7); 1.8756 (1.2); 1.8660 (0.6); 1.8504(0.6); 1.8406 (1.0); 1.8309 (0.6); 1.7388 (15.9); 1.7323 (2.5); 1.7250(16.0); 1.5759 (6.1); 1.3261 (5.8); 1.3082 (12.0); 1.2935 (6.4); 1.2904(6.2); 1.2757 (12.0); 1.2578 (5.8); 1.2436 (0.6); 0.0079 (0.8); −0.0002(25.6); −0.0085 (0.9) I-070: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.9617 (1.2);7.9576 (2.0); 7.9547 (1.3); 7.9414 (0.9); 7.9371 (1.8); 7.9330 (2.4);7.9289 (1.5); 7.8593 (0.5); 7.8562 (0.6); 7.8453 (2.1); 7.8407 (1.5);7.8362 (0.7); 7.8298 (1.3); 7.8255 (2.3); 7.7111 (1.1); 7.7066 (2.0);7.7047 (1.9); 7.7025 (1.5); 7.6916 (1.3); 7.6875 (2.1); 7.5526 (2.4);7.5514 (2.4); 7.5442 (0.8); 7.5329 (3.9); 7.5319 (3.8); 7.5191 (0.8);7.5134 (1.7); 7.5121 (1.7); 7.2602 (111.9); 7.2408 (0.6); 7.2120 (0.7);7.1883 (0.6); 6.9962 (0.6); 6.0275 (0.7); 6.0239 (0.9); 6.0212 (0.8);6.0171 (0.9); 6.0137 (1.0); 6.0101 (1.3); 6.0074 (1.1); 6.0036 (1.0);6.0009 (0.9); 5.9965 (1.0); 5.9906 (0.8); 5.9868 (0.8); 5.9828 (0.9);5.9806 (0.9); 5.9766 (0.8); 5.9305 (0.8); 5.9248 (1.5); 5.9191 (0.9);5.9168 (0.7); 5.9110 (1.2); 5.9054 (0.7); 5.8480 (0.8); 5.8423 (1.5);5.8366 (0.9); 5.8343 (0.8); 5.8285 (1.3); 5.8228 (0.7); 5.2985 (1.4);5.0059 (0.9); 3.8732 (0.5); 3.8647 (0.6); 3.8510 (2.6); 3.8468 (2.6);3.8298 (0.6); 3.8214 (0.7); 3.8078 (3.0); 3.8036 (3.0); 3.6061 (0.5);3.6012 (0.6); 3.5955 (0.8); 3.5918 (0.9); 3.5851 (0.9); 3.5816 (0.8);3.2472 (0.9); 3.2399 (2.6); 3.2317 (2.5); 3.2033 (0.8); 3.1967 (2.3);3.1884 (2.2); 2.6029 (1.0); 2.5890 (0.7); 2.5816 (0.6); 2.5677 (1.0);2.5540 (0.5); 2.5464 (0.5); 2.5328 (1.0); 2.5190 (0.7); 2.5117 (0.6);2.4978 (1.1); 2.4766 (0.5); 2.0443 (0.9); 2.0263 (0.5); 2.0160 (0.9);2.0056 (0.6); 1.9808 (0.8); 1.9282 (0.6); 1.9182 (1.0); 1.9081 (0.5);1.8932 (0.5); 1.8832 (0.8); 1.7359 (16.0); 1.7283 (14.1); 1.2588 (0.6);0.0079 (2.0); −0.0002 (65.3); −0.0085 (2.3) I-071: ¹H-NMR(400.0 MHz,CDCl3): δ = 7.7474 (2.1); 7.7441 (3.9); 7.7406 (2.7); 7.7365 (2.6);7.7331 (4.1); 7.7297 (2.4); 7.6671 (1.2); 7.6633 (1.2); 7.6609 (1.4);7.6566 (2.0); 7.6524 (1.5); 7.6500 (1.6); 7.6456 (2.0); 7.6414 (1.4);7.6390 (1.5); 7.6347 (2.0); 7.6305 (1.4); 7.6282 (1.5); 7.6244 (1.3);7.4840 (1.5); 7.4812 (2.1); 7.4783 (2.5); 7.4753 (2.1); 7.4726 (1.6);7.4650 (1.6); 7.4622 (2.2); 7.4593 (2.4); 7.4562 (1.9); 7.4536 (1.3);7.3881 (1.3); 7.3670 (1.3); 7.2609 (68.3); 6.0217 (1.0); 6.0185 (1.0);6.0150 (1.1); 6.0083 (2.1); 6.0052 (2.2); 6.0016 (2.2); 5.9985 (2.2);5.9920 (1.3); 5.9886 (1.2); 5.9855 (1.1); 5.9322 (1.2); 5.9267 (2.0);5.9211 (1.3); 5.9129 (1.5); 5.9074 (0.8); 5.8632 (1.2); 5.8578 (1.9);5.8522 (1.3); 5.8497 (1.1); 5.8440 (1.6); 5.8385 (0.9); 5.1114 (0.5);5.0879 (1.3); 5.0642 (1.2); 4.2423 (1.2); 4.2402 (1.3); 4.2244 (3.8);4.2224 (3.9); 4.2173 (2.5); 4.2065 (4.0); 4.2045 (4.1); 4.1994 (6.8);4.1885 (1.5); 4.1867 (1.6); 4.1816 (6.7); 4.1637 (2.2); 4.0391 (2.8);3.9941 (3.9); 3.7796 (0.5); 3.7717 (4.1); 3.7645 (4.2); 3.7266 (3.1);3.7194 (3.2); 3.5512 (1.0); 3.5448 (1.3); 3.5377 (1.4); 3.5307 (1.5);3.5256 (1.4); 3.5187 (1.3); 3.5124 (1.0); 2.5448 (0.8); 2.5238 (1.5);2.5094 (1.0); 2.5029 (0.9); 2.4884 (1.7); 2.4703 (1.0); 2.4676 (1.0);2.4496 (1.5); 2.4352 (1.0); 2.4288 (0.9); 2.4143 (1.7); 2.3936 (0.8);2.0136 (0.8); 2.0063 (1.5); 1.9993 (0.8); 1.9785 (1.5); 1.9712 (2.8);1.9640 (1.6); 1.9434 (0.7); 1.9360 (1.4); 1.9288 (0.7); 1.5588 (2.2);1.3274 (7.2); 1.3195 (0.6); 1.3095 (16.0); 1.2901 (16.0); 1.2722 (7.2);1.2659 (1.0); 1.2549 (0.8); 0.0080 (1.2); −0.0002 (39.8); −0.0084 (1.6)I-072: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.9856 (1.7); 7.9815 (3.0); 7.9785(2.2); 7.9772 (2.1); 7.9735 (2.2); 7.9704 (3.1); 7.9695 (3.1); 7.9664(2.0); 7.8935 (1.2); 7.8904 (1.6); 7.8892 (1.5); 7.8858 (2.2); 7.8825(1.7); 7.8782 (1.5); 7.8736 (1.6); 7.8706 (1.8); 7.8694 (1.8); 7.8659(2.5); 7.8626 (1.8); 7.8614 (1.8); 7.8583 (1.5); 7.7716 (1.4); 7.7673(2.4); 7.7631 (1.6); 7.7522 (1.8); 7.7481 (2.9); 7.7438 (1.6); 7.6006(2.0); 7.5988 (2.6); 7.5792 (4.3); 7.5613 (1.4); 7.5595 (1.9); 7.3909(1.3); 7.3687 (1.3); 7.3615 (1.1); 7.2608 (81.2); 6.0180 (0.9); 6.0145(1.0); 6.0113 (1.0); 6.0047 (1.8); 6.0014 (2.0); 5.9981 (2.0); 5.9949(1.9); 5.9884 (1.2); 5.9851 (1.2); 5.9819 (1.1); 5.9300 (1.1); 5.9245(1.9); 5.9189 (1.2); 5.9164 (0.9); 5.9107 (1.4); 5.9052 (0.8); 5.8599(1.1); 5.8543 (1.9); 5.8487 (1.2); 5.8462 (1.0); 5.8405 (1.5); 5.8350(0.9); 5.0895 (1.2); 5.0669 (1.2); 4.2422 (1.3); 4.2410 (1.3); 4.2243(4.1); 4.2232 (4.1); 4.2166 (2.3); 4.2064 (4.4); 4.2054 (4.3); 4.1987(6.6); 4.1884 (1.7); 4.1809 (6.6); 4.1631 (2.2); 4.0510 (2.6); 4.0060(3.6); 3.8037 (0.5); 3.7955 (4.1); 3.7891 (4.1); 3.7505 (3.0); 3.7440(3.1); 3.5485 (0.8); 3.5422 (1.1); 3.5349 (1.3); 3.5281 (1.4); 3.5217(1.4); 3.5153 (1.2); 3.5094 (0.8); 2.5532 (0.7); 2.5322 (1.4); 2.5179(1.0); 2.5112 (0.8); 2.4969 (1.6); 2.4801 (0.8); 2.4759 (0.9); 2.4593(1.5); 2.4449 (1.0); 2.4384 (0.8); 2.4240 (1.6); 2.4032 (0.8); 2.0132(0.8); 2.0058 (1.4); 1.9983 (0.8); 1.9768 (1.3); 1.9694 (2.2); 1.9618(1.2); 1.9412 (0.7); 1.9335 (1.2); 1.9257 (0.7); 1.5505 (16.0); 1.3282(7.0); 1.3103 (14.9); 1.3058 (7.7); 1.2925 (7.6); 1.2880 (14.8); 1.2701(7.0); 1.2654 (1.1); 1.2533 (0.9); 0.0080 (1.5); −0.0002 (46.3); −0.0085(1.7) I-073: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.7140 (1.8); 7.7106 (3.2);7.7071 (2.0); 7.7011 (2.0); 7.6978 (3.3); 7.6943 (1.9); 7.6332 (1.0);7.6295 (1.0); 7.6270 (1.1); 7.6232 (1.2); 7.6212 (1.2); 7.6174 (1.2);7.6149 (1.3); 7.6109 (1.8); 7.6070 (1.2); 7.6044 (1.2); 7.6007 (1.2);7.5987 (1.2); 7.5949 (1.1); 7.5924 (1.1); 7.5888 (1.0); 7.4201 (1.3);7.4176 (1.6); 7.4145 (1.9); 7.4117 (1.6); 7.4088 (1.2); 7.4010 (1.3);7.3986 (1.6); 7.3954 (1.8); 7.3925 (1.4); 7.3897 (1.0); 7.2613 (58.4);7.1898 (0.7); 7.1692 (1.2); 7.1477 (0.7); 5.9811 (0.8); 5.9776 (0.9);5.9749 (0.9); 5.9711 (0.9); 5.9674 (1.1); 5.9637 (1.3); 5.9605 (1.7);5.9570 (1.6); 5.9536 (1.0); 5.9498 (0.9); 5.9462 (1.0); 5.9424 (1.1);5.9397 (1.0); 5.9361 (0.9); 5.8993 (1.0); 5.8937 (1.8); 5.8881 (1.1);5.8856 (0.8); 5.8800 (1.3); 5.8744 (0.7); 5.8084 (1.0); 5.8027 (1.7);5.7970 (1.0); 5.7947 (0.9); 5.7889 (1.4); 5.7833 (0.8); 5.0335 (0.5);5.0305 (0.5); 5.0247 (0.7); 5.0188 (0.8); 5.0127 (1.0); 4.9878 (0.5);4.9850 (0.5); 4.2331 (1.7); 4.2153 (5.4); 4.2026 (1.7); 4.1974 (5.5);4.1848 (4.5); 4.1796 (2.0); 4.1669 (4.6); 4.1491 (1.6); 3.8346 (3.0);3.8287 (2.9); 3.7915 (3.4); 3.7856 (3.3); 3.5319 (0.6); 3.5288 (0.6);3.5257 (0.6); 3.5194 (0.8); 3.5169 (0.8); 3.5104 (1.2); 3.5075 (1.1);3.5045 (1.2); 3.4981 (0.8); 3.4956 (0.8); 3.4892 (0.6); 3.4861 (0.6);3.4833 (0.6); 3.2069 (3.0); 3.1967 (3.0); 3.1637 (2.6); 3.1535 (2.6);2.5545 (0.6); 2.5335 (1.2); 2.5195 (0.8); 2.5124 (0.7); 2.4985 (1.4);2.4889 (0.7); 2.4774 (0.7); 2.4678 (1.3); 2.4539 (0.8); 2.4468 (0.7);2.4329 (1.4); 2.4119 (0.7); 1.9739 (0.7); 1.9648 (1.2); 1.9557 (0.7);1.9389 (0.6); 1.9298 (1.1); 1.9207 (0.6); 1.8874 (0.8); 1.8782 (1.2);1.8690 (0.7); 1.8525 (0.6); 1.8432 (1.1); 1.8341 (0.6); 1.7414 (16.0);1.7335 (2.5); 1.7271 (15.9); 1.5612 (11.6); 1.3255 (5.7); 1.3077 (11.7);1.2971 (5.8); 1.2898 (5.8); 1.2793 (11.6); 1.2614 (5.8); 1.2455 (0.6);0.0079 (1.2); −0.0002 (32.4); −0.0085 (1.0) I-074: ¹H-NMR(400.0 MHz,CDCl3): δ = 7.8584 (1.9); 7.8548 (3.5); 7.8511 (2.0); 7.8389 (2.0);7.8353 (3.5); 7.8316 (2.1); 7.8266 (0.6); 7.6330 (0.9); 7.6292 (1.0);7.6268 (1.1); 7.6230 (1.1); 7.6195 (1.2); 7.6157 (1.3); 7.6131 (1.4);7.6113 (1.5); 7.6095 (1.5); 7.6076 (1.4); 7.6051 (1.2); 7.6013 (1.1);7.5978 (1.2); 7.5940 (1.2); 7.5916 (1.2); 7.5879 (1.0); 7.5213 (1.2);7.5200 (1.2); 7.5179 (1.3); 7.5147 (1.8); 7.5112 (1.8); 7.5082 (1.2);7.5046 (1.0); 7.4993 (1.2); 7.4957 (1.3); 7.4926 (1.7); 7.4890 (1.7);7.4861 (1.0); 7.4825 (0.9); 7.2610 (107.2); 7.2001 (0.8); 7.1836 (1.0);7.1635 (0.8); 7.1597 (0.6); 6.9970 (0.6); 5.9787 (0.9); 5.9749 (1.1);5.9723 (1.0); 5.9687 (1.0); 5.9648 (1.2); 5.9611 (1.4); 5.9586 (1.3);5.9547 (1.4); 5.9524 (1.2); 5.9485 (1.2); 5.9460 (1.1); 5.9421 (1.1);5.9384 (1.2); 5.9346 (1.3); 5.9321 (1.3); 5.9284 (1.3); 5.8961 (1.7);5.8904 (2.2); 5.8848 (1.3); 5.8822 (1.1); 5.8765 (1.5); 5.8710 (0.9);5.8086 (1.1); 5.8029 (2.0); 5.7972 (1.3); 5.7948 (1.1); 5.7891 (1.7);5.7836 (1.0); 5.0227 (0.9); 5.0138 (1.0); 4.2299 (1.8); 4.2120 (5.7);4.1942 (7.5); 4.1766 (7.5); 4.1588 (5.8); 4.1409 (2.0); 3.8802 (2.7);3.8661 (2.8); 3.8370 (3.1); 3.8230 (3.1); 3.5297 (0.6); 3.5204 (0.8);3.5176 (0.9); 3.5146 (1.0); 3.5034 (1.2); 3.4957 (1.0); 3.4930 (0.9);3.4834 (0.7); 3.2515 (2.9); 3.2397 (2.8); 3.2083 (2.6); 3.1964 (2.5);2.5642 (0.7); 2.5431 (1.2); 2.5292 (0.8); 2.5220 (0.8); 2.5082 (1.4);2.5036 (0.8); 2.4870 (0.8); 2.4824 (1.3); 2.4686 (0.9); 2.4612 (0.8);2.4474 (1.4); 2.4262 (0.8); 1.9711 (0.7); 1.9630 (3.1); 1.9521 (0.7);1.9360 (0.6); 1.9266 (1.1); 1.9171 (0.6); 1.8855 (0.8); 1.8759 (1.2);1.8664 (0.8); 1.8506 (0.6); 1.8409 (1.1); 1.8314 (0.6); 1.7366 (15.6);1.7249 (16.0); 1.5804 (1.1); 1.3233 (6.2); 1.3162 (0.6); 1.3054 (13.1);1.2985 (1.0); 1.2903 (8.0); 1.2876 (7.0); 1.2724 (13.4); 1.2592 (1.2);1.2546 (6.2); 1.2430 (0.8); 0.0079 (2.0); −0.0002 (61.5); −0.0085 (2.2)I-075: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.7247 (1.3); 7.7215 (2.4); 7.7180(1.7); 7.7129 (1.1); 7.7097 (1.1); 7.7070 (1.2); 7.7004 (1.7); 7.6971(2.6); 7.6938 (1.7); 7.6208 (1.2); 7.6176 (1.1); 7.6149 (1.2); 7.6110(1.0); 7.6088 (1.1); 7.6025 (1.5); 7.5986 (1.9); 7.5951 (1.3); 7.5925(1.2); 7.5885 (1.0); 7.5865 (1.0); 7.5826 (0.9); 7.5803 (0.9); 7.5766(0.8); 7.4326 (0.5); 7.4297 (0.6); 7.4268 (0.6); 7.4145 (1.8); 7.4119(2.0); 7.4091 (1.8); 7.3958 (1.5); 7.3929 (1.6); 7.3899 (1.4); 7.2658(10.1); 7.2373 (1.3); 7.2161 (0.8); 6.0359 (0.7); 6.0331 (0.9); 6.0297(0.8); 6.0228 (1.2); 6.0192 (1.4); 6.0059 (0.9); 6.0030 (1.0); 5.9998(1.0); 5.9963 (0.8); 5.9926 (0.8); 5.9887 (0.9); 5.9863 (0.9); 5.9826(0.8); 5.9404 (0.7); 5.9349 (1.3); 5.9291 (0.8); 5.9211 (1.0); 5.9155(0.6); 5.8562 (0.7); 5.8506 (1.3); 5.8447 (0.8); 5.8368 (1.1); 5.8309(0.8); 5.8242 (0.5); 5.0206 (0.8); 5.0121 (0.8); 4.1507 (1.1); 4.1328(3.4); 4.1150 (3.4); 4.0971 (1.2); 3.8717 (0.6); 3.8596 (0.6); 3.8397(3.6); 3.8281 (0.8); 3.8160 (1.0); 3.8101 (0.5); 3.7964 (4.2); 3.7884(0.5); 3.5887 (0.9); 3.5825 (0.9); 3.5671 (0.5); 3.2333 (1.4); 3.2294(2.3); 3.2190 (2.1); 3.1861 (2.1); 3.1756 (1.9); 2.5832 (0.8); 2.5691(0.6); 2.5621 (0.5); 2.5481 (0.9); 2.5273 (0.8); 2.5066 (0.8); 2.4924(0.6); 2.4714 (0.9); 2.0464 (14.9); 2.0267 (0.5); 2.0171 (0.9); 1.9820(0.7); 1.9168 (0.5); 1.9076 (0.9); 1.8985 (0.5); 1.8726 (0.8); 1.7398(16.0); 1.7328 (12.3); 1.2774 (4.0); 1.2596 (8.1); 1.2417 (4.0); −0.0002(8.4) I-076: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.3720 (0.7); 7.3514 (0.7);7.2610 (48.5); 7.2126 (1.4); 7.2069 (1.7); 7.2021 (2.3); 7.1964 (3.0);7.1935 (2.8); 7.1875 (2.3); 7.1828 (2.3); 7.1772 (1.7); 6.9590 (0.6);6.9520 (1.0); 6.9464 (1.0); 6.9432 (0.7); 6.9373 (1.0); 6.9315 (1.5);6.9250 (1.0); 6.9158 (0.5); 6.9099 (0.7); 6.0355 (0.5); 6.0280 (0.6);6.0246 (0.8); 6.0211 (0.6); 6.0141 (1.0); 6.0107 (1.1); 6.0076 (1.1);6.0043 (1.0); 6.0010 (0.7); 5.9974 (0.6); 5.9944 (0.6); 5.9910 (0.6);5.9302 (0.6); 5.9247 (1.0); 5.9190 (0.6); 5.9109 (0.8); 5.8650 (0.7);5.8594 (1.3); 5.8537 (0.8); 5.8455 (0.8); 5.0902 (0.6); 5.0694 (0.6);4.3249 (0.9); 4.3131 (1.6); 4.3099 (1.1); 4.3061 (0.5); 4.3002 (1.7);4.2981 (1.9); 4.2891 (2.2); 4.2760 (2.1); 4.2703 (0.6); 4.2659 (1.2);4.2590 (1.1); 4.2507 (1.1); 4.2469 (1.2); 4.2392 (0.8); 3.9972 (1.6);3.9522 (2.3); 3.7620 (1.1); 3.7594 (1.1); 3.7517 (2.3); 3.7456 (2.2);3.7168 (0.8); 3.7142 (0.8); 3.7067 (1.6); 3.7005 (1.6); 3.6396 (2.3);3.6279 (3.3); 3.6187 (2.0); 3.6161 (2.4); 3.6072 (4.0); 3.5955 (3.7);3.5837 (2.5); 3.5720 (1.2); 3.4020 (16.0); 3.3983 (3.0); 3.3879 (7.0);3.3844 (15.9); 3.3798 (1.8); 3.3768 (6.2); 2.9574 (0.6); 2.8845 (0.5);2.7276 (0.6); 2.5468 (0.7); 2.5324 (0.6); 2.5257 (0.5); 2.5114 (0.8);2.4768 (0.8); 2.4624 (0.5); 2.4416 (0.9); 2.0103 (0.7); 1.9832 (0.6);1.9785 (1.0); 1.9746 (0.9); 1.9515 (0.6); 1.9434 (0.7); 1.4320 (0.7);0.0080 (0.9); −0.0002 (28.2); −0.0085 (1.0) I-077: ¹H-NMR(400.0 MHz,CDCl3): δ = 7.5190 (1.0); 7.3767 (1.3); 7.3556 (1.4); 7.3101 (0.6);7.2601 (178.1); 7.2248 (0.7); 7.2116 (2.5); 7.2058 (3.4); 7.2010 (4.9);7.1952 (6.2); 7.1922 (5.6); 7.1863 (4.8); 7.1817 (4.7); 7.1760 (3.5);7.1632 (0.6); 6.9961 (1.2); 6.9680 (0.8); 6.9587 (1.1); 6.9522 (2.1);6.9464 (2.0); 6.9407 (1.2); 6.9370 (2.0); 6.9310 (3.0); 6.9251 (2.1);6.9154 (1.0); 6.9096 (1.4); 6.9038 (0.7); 6.7595 (0.6); 6.0580 (0.5);6.0537 (0.6); 6.0475 (0.9); 6.0436 (0.9); 6.0403 (0.9); 6.0377 (0.9);6.0336 (1.0); 6.0269 (1.5); 6.0231 (1.5); 6.0202 (1.1); 6.0166 (1.2);6.0129 (2.1); 6.0096 (2.2); 6.0065 (2.2); 6.0031 (2.1); 5.9996 (1.4);5.9961 (1.3); 5.9931 (1.2); 5.9897 (1.1); 5.9261 (1.1); 5.9207 (2.0);5.9150 (1.3); 5.9126 (1.1); 5.9069 (1.6); 5.9013 (0.9); 5.8707 (0.8);5.8618 (1.3); 5.8563 (2.4); 5.8507 (1.5); 5.8422 (1.6); 5.8366 (0.9);5.8190 (0.8); 5.8132 (0.5); 5.8051 (0.7); 5.1088 (0.6); 5.0877 (1.2);5.0656 (1.3); 4.4386 (0.6); 4.4266 (0.6); 4.4143 (0.6); 4.3372 (0.5);4.3191 (1.8); 4.3075 (4.1); 4.2965 (4.2); 4.2920 (2.8); 4.2901 (2.6);4.2849 (2.5); 4.2827 (3.0); 4.2793 (3.2); 4.2751 (2.7); 4.2666 (3.5);4.2614 (1.0); 4.2531 (1.5); 4.2496 (1.5); 4.2404 (1.7); 4.2379 (1.6);4.2272 (1.0); 3.9944 (3.0); 3.9495 (4.2); 3.8094 (0.6); 3.8035 (0.8);3.7975 (0.7); 3.7913 (0.6); 3.7819 (0.5); 3.7692 (0.8); 3.7614 (2.2);3.7588 (2.4); 3.7508 (4.5); 3.7443 (4.2); 3.7308 (0.8); 3.7160 (1.8);3.7138 (1.9); 3.7059 (3.6); 3.6992 (3.1); 3.6758 (4.3); 3.6638 (6.1);3.6556 (4.1); 3.6518 (4.5); 3.6431 (5.3); 3.6380 (1.7); 3.6315 (5.7);3.6191 (2.9); 3.6075 (2.2); 3.5958 (1.5); 3.5837 (1.5); 3.5762 (1.8);3.5725 (3.0); 3.5625 (1.1); 3.5581 (3.5); 3.5550 (8.0); 3.5470 (1.7);3.5377 (10.6); 3.5296 (3.3); 3.5208 (6.8); 3.5121 (3.0); 3.5037 (2.1);3.4946 (0.9); 2.9572 (0.8); 2.8846 (0.6); 2.7503 (0.5); 2.7425 (0.8);2.7300 (1.2); 2.7275 (1.2); 2.7150 (0.8); 2.7062 (0.6); 2.6943 (0.7);2.5652 (0.8); 2.5442 (1.4); 2.5299 (1.1); 2.5233 (1.0); 2.5090 (1.6);2.4941 (0.9); 2.4879 (1.0); 2.4731 (1.6); 2.4588 (1.0); 2.4522 (0.9);2.4379 (1.8); 2.4171 (0.8); 2.0162 (0.8); 2.0083 (1.5); 2.0004 (0.9);1.9848 (1.0); 1.9770 (1.9); 1.9731 (1.6); 1.9687 (1.4); 1.9569 (0.5);1.9498 (0.9); 1.9420 (1.5); 1.9334 (1.0); 1.8731 (0.5); 1.4319 (1.4);1.3790 (0.6); 1.2858 (0.5); 1.2552 (1.2); 1.2434 (1.1); 1.2371 (7.7);1.2321 (3.9); 1.2285 (2.4); 1.2240 (8.7); 1.2221 (6.0); 1.2196 (15.7);1.2146 (7.4); 1.2112 (3.4); 1.2065 (16.0); 1.2048 (8.9); 1.2021 (8.7);1.1971 (3.8); 1.1938 (1.8); 1.1890 (7.5); 1.1740 (0.7); 0.0691 (1.0);0.0080 (3.4); −0.0002 (107.4); −0.0085 (3.7) I-078: ¹H-NMR(400.0 MHz,CDCl3): δ = 7.3544 (0.6); 7.3367 (0.6); 7.2605 (63.5); 7.2124 (1.3);7.2066 (1.6); 7.2013 (2.2); 7.1959 (3.0); 7.1931 (2.9); 7.1872 (2.4);7.1819 (2.5); 7.1765 (1.8); 6.9618 (0.6); 6.9599 (0.6); 6.9559 (0.8);6.9537 (0.9); 6.9501 (0.8); 6.9471 (0.9); 6.9443 (0.7); 6.9403 (1.0);6.9383 (1.1); 6.9344 (1.3); 6.9324 (1.4); 6.9286 (0.9); 6.9265 (0.9);6.9187 (0.5); 6.9166 (0.5); 6.9128 (0.6); 6.9108 (0.6); 6.0409 (0.5);6.0357 (0.6); 6.0302 (0.5); 6.0263 (0.6); 6.0229 (0.8); 6.0116 (1.0);6.0083 (1.0); 6.0050 (1.0); 5.9970 (0.6); 5.9940 (0.6); 5.9906 (0.5);5.9376 (0.6); 5.9322 (1.0); 5.9266 (0.6); 5.9184 (0.7); 5.8737 (0.8);5.8682 (1.0); 5.8626 (0.6); 5.8600 (0.7); 5.8545 (0.8); 5.0905 (0.6);5.0720 (0.6); 4.3434 (2.1); 4.3389 (0.7); 4.3264 (4.6); 4.3220 (2.2);4.3093 (2.5); 4.3050 (4.0); 4.2912 (1.0); 4.2881 (2.0); 4.2803 (0.9);4.2743 (1.6); 4.2633 (1.6); 4.2573 (0.8); 4.2464 (0.8); 4.0020 (1.2);3.9948 (0.9); 3.9565 (1.7); 3.9494 (1.2); 3.9417 (0.6); 3.7616 (1.6);3.7537 (2.6); 3.7487 (2.2); 3.7454 (1.0); 3.7164 (1.0); 3.7087 (1.7);3.7036 (1.5); 3.5715 (0.6); 3.5654 (0.6); 3.5553 (0.6); 3.5500 (0.6);2.9624 (1.1); 2.8882 (0.9); 2.7851 (2.0); 2.7681 (4.5); 2.7618 (0.8);2.7492 (4.5); 2.7445 (1.3); 2.7323 (2.6); 2.7274 (1.8); 2.7204 (0.7);2.7168 (1.8); 2.7106 (1.0); 2.6998 (1.4); 2.5562 (0.7); 2.5419 (0.5);2.5208 (0.8); 2.4896 (0.8); 2.4752 (0.6); 2.4543 (0.8); 2.1848 (0.9);2.1830 (1.1); 2.1725 (2.4); 2.1677 (14.5); 2.1624 (2.4); 2.1508 (16.0);2.1406 (6.2); 2.1093 (2.0); 2.0256 (0.7); 1.9983 (0.8); 1.9904 (1.4);1.9823 (0.9); 1.9632 (0.5); 1.9552 (0.7); 1.9470 (0.6); 1.4319 (0.8);1.2568 (0.5); 0.0079 (1.1); −0.0002 (36.5); −0.0085 (1.4) I-079:¹H-NMR(400.0 MHz, CDCl3): δ = 7.9507 (1.3); 7.9465 (2.9); 7.9421 (3.4);7.9378 (3.6); 7.9367 (3.6); 7.9335 (3.4); 7.9295 (2.0); 7.8705 (1.0);7.8675 (1.2); 7.8662 (1.2); 7.8630 (1.8); 7.8597 (1.5); 7.8582 (1.7);7.8551 (2.2); 7.8506 (2.4); 7.8477 (2.1); 7.8431 (2.2); 7.8397 (1.7);7.8384 (2.0); 7.8353 (2.4); 7.8307 (1.6); 7.8279 (0.9); 7.7269 (0.7);7.7238 (1.4); 7.7202 (1.5); 7.7151 (1.3); 7.7105 (2.0); 7.7081 (2.1);7.7045 (2.1); 7.7008 (2.0); 7.6958 (1.6); 7.6915 (2.4); 7.6871 (1.4);7.5671 (1.0); 7.5657 (1.1); 7.5635 (1.1); 7.5622 (1.1); 7.5563 (1.6);7.5546 (2.0); 7.5528 (1.6); 7.5461 (1.9); 7.5438 (1.9); 7.5349 (3.2);7.5278 (1.0); 7.5265 (1.0); 7.5242 (0.9); 7.5171 (1.1); 7.5153 (1.4);7.2623 (48.6); 7.1621 (0.6); 7.1496 (0.8); 7.1284 (0.7); 6.7840 (0.7);6.7632 (0.7); 6.0105 (0.6); 6.0062 (0.7); 6.0045 (0.7); 5.9966 (1.6);5.9923 (2.1); 5.9907 (1.8); 5.9862 (1.8); 5.9811 (1.3); 5.9785 (1.8);5.9746 (1.4); 5.9725 (1.6); 5.9687 (1.0); 5.9662 (0.9); 5.9624 (0.8);5.9587 (0.9); 5.9549 (1.0); 5.9524 (1.0); 5.9486 (0.9); 5.9239 (0.9);5.9184 (1.6); 5.9128 (1.0); 5.9103 (0.7); 5.9046 (1.2); 5.8990 (0.7);5.8925 (0.7); 5.8868 (1.2); 5.8810 (0.7); 5.8787 (0.6); 5.8729 (1.0);5.8672 (0.5); 5.8321 (0.8); 5.8265 (1.6); 5.8207 (1.0); 5.8182 (1.0);5.8125 (1.7); 5.8069 (1.0); 5.8030 (0.7); 5.7971 (1.0); 5.7913 (0.5);5.1129 (0.5); 5.1064 (0.6); 5.1002 (0.6); 5.0941 (0.5); 5.0445 (0.5);5.0238 (1.0); 4.4286 (1.5); 4.4192 (1.5); 4.4152 (2.1); 4.4142 (2.0);4.4058 (1.8); 4.4043 (2.0); 4.4002 (1.8); 4.3915 (1.7); 4.3868 (2.0);4.3855 (2.0); 4.3740 (2.9); 4.3713 (2.4); 4.3696 (2.6); 4.3663 (1.9);4.3579 (2.6); 4.3541 (2.0); 4.3522 (2.3); 4.3498 (2.8); 4.3377 (3.2);4.3329 (1.7); 4.3212 (1.8); 3.8634 (1.8); 3.8573 (2.0); 3.8536 (3.0);3.8501 (2.9); 3.8201 (2.2); 3.8140 (2.4); 3.8104 (3.8); 3.8069 (3.6);3.8001 (0.8); 3.7943 (0.7); 3.7883 (0.8); 3.7827 (0.8); 3.7769 (0.6);3.7711 (0.6); 3.7669 (0.6); 3.7608 (0.7); 3.7567 (2.1); 3.7541 (2.2);3.7491 (0.7); 3.7423 (2.8); 3.7400 (3.5); 3.7288 (1.8); 3.7257 (1.8);3.7199 (3.6); 3.7056 (3.6); 3.6971 (2.3); 3.6917 (3.2); 3.6821 (4.0);3.6680 (3.4); 3.6537 (2.1); 3.5947 (0.5); 3.5918 (0.5); 3.5859 (0.7);3.5768 (1.0); 3.5739 (1.0); 3.5650 (0.7); 3.5593 (0.5); 3.5564 (0.5);3.5501 (0.5); 3.2396 (2.6); 3.2342 (3.0); 3.2263 (2.8); 3.1962 (2.3);3.1910 (2.7); 3.1831 (2.5); 2.7135 (0.5); 2.7113 (0.6); 2.6991 (0.5);2.6949 (0.5); 2.6908 (0.5); 2.6828 (0.6); 2.6785 (0.5); 2.6741 (0.5);2.6621 (0.6); 2.6597 (0.6); 2.6477 (0.5); 2.6391 (0.5); 2.6014 (0.6);2.5803 (1.1); 2.5663 (0.8); 2.5590 (0.7); 2.5451 (1.2); 2.5362 (0.6);2.5239 (0.7); 2.5150 (1.1); 2.5011 (0.8); 2.4938 (0.7); 2.4799 (1.2);2.4587 (0.6); 2.0109 (0.6); 2.0014 (1.0); 1.9919 (0.6); 1.9758 (0.5);1.9662 (0.9); 1.9565 (0.9); 1.9211 (0.6); 1.9186 (0.7); 1.9094 (1.3);1.8993 (1.0); 1.8881 (0.5); 1.8835 (0.6); 1.8739 (0.9); 1.8641 (1.0);1.8291 (0.6); 1.7417 (15.0); 1.7337 (16.0); 1.7271 (15.9); 1.5745 (9.2);1.2845 (0.8); 0.0079 (1.1); −0.0002 (34.2); −0.0085 (1.4) I-080:¹H-NMR(400.0 MHz, CDCl3): δ = 7.9522 (1.0); 7.9484 (1.8); 7.9437 (1.9);7.9353 (3.2); 7.8722 (0.7); 7.8689 (1.0); 7.8641 (1.1); 7.8604 (1.1);7.8558 (1.3); 7.8524 (1.9); 7.8487 (2.0); 7.8451 (1.5); 7.8404 (1.2);7.8359 (1.3); 7.8327 (1.3); 7.7258 (0.6); 7.7225 (1.3); 7.7191 (1.3);7.7146 (1.0); 7.7113 (1.6); 7.7075 (1.8); 7.7032 (1.8); 7.6996 (1.6);7.6952 (1.2); 7.6919 (1.9); 7.6885 (1.8); 7.5645 (1.0); 7.5618 (0.9);7.5525 (1.3); 7.5450 (1.6); 7.5421 (1.5); 7.5330 (2.0); 7.5252 (0.8);7.5212 (0.8); 7.5149 (0.9); 7.2614 (46.2); 7.1924 (0.6); 6.7714 (0.6);6.7513 (0.6); 5.9843 (0.6); 5.9799 (0.6); 5.9764 (1.5); 5.9720 (1.7);5.9705 (1.7); 5.9661 (1.5); 5.9626 (1.3); 5.9584 (1.4); 5.9565 (1.4);5.9523 (1.6); 5.9483 (0.7); 5.9458 (0.7); 5.9418 (0.6); 5.9383 (0.7);5.9343 (0.7); 5.9320 (0.7); 5.9281 (0.6); 5.9037 (0.7); 5.8982 (1.2);5.8926 (0.7); 5.8843 (0.9); 5.8702 (0.6); 5.8645 (1.0); 5.8587 (0.6);5.8506 (0.8); 5.8126 (0.7); 5.8070 (1.2); 5.8012 (0.7); 5.7988 (0.7);5.7934 (1.3); 5.7880 (1.3); 5.7824 (0.5); 5.7743 (0.7); 5.1013 (0.5);5.0958 (0.6); 5.0909 (0.6); 5.0857 (0.5); 5.0108 (0.8); 3.8611 (1.6);3.8557 (1.6); 3.8512 (2.2); 3.8460 (2.0); 3.8178 (1.8); 3.8124 (1.8);3.8080 (2.5); 3.8029 (2.3); 3.7658 (0.6); 3.7568 (15.3); 3.7439 (0.6);3.7380 (0.7); 3.7265 (14.8); 3.7108 (0.6); 3.6989 (9.8); 3.6820 (10.6);3.5219 (0.7); 3.2369 (2.5); 3.2323 (2.3); 3.2235 (2.1); 3.1936 (2.2);3.1891 (2.0); 3.1803 (1.8); 2.6383 (0.5); 2.5534 (0.8); 2.5395 (0.6);2.5185 (1.0); 2.4974 (0.5); 2.4855 (0.8); 2.4716 (0.6); 2.4506 (1.0);1.9678 (0.8); 1.9326 (0.8); 1.8955 (0.5); 1.8874 (0.6); 1.8777 (0.9);1.8680 (0.5); 1.8427 (0.8); 1.8349 (0.6); 1.8016 (0.5); 1.7397 (11.5);1.7313 (14.4); 1.7272 (12.5); 1.5626 (16.0); 0.0079 (1.2); −0.0002(33.7); −0.0085 (1.1) I-081: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.9567 (0.9);7.9527 (1.5); 7.9496 (1.0); 7.9395 (2.4); 7.9356 (3.2); 7.8675 (0.7);7.8644 (0.9); 7.8601 (1.5); 7.8562 (1.4); 7.8527 (1.2); 7.8474 (1.1);7.8445 (1.1); 7.8434 (1.1); 7.8402 (1.7); 7.8363 (1.6); 7.8329 (1.3);7.7226 (0.8); 7.7194 (0.8); 7.7150 (0.5); 7.7073 (1.9); 7.7032 (1.7);7.7002 (1.0); 7.6957 (0.6); 7.6878 (1.7); 7.5659 (0.7); 7.5615 (0.6);7.5513 (1.6); 7.5497 (1.3); 7.5475 (1.3); 7.5417 (1.0); 7.5317 (2.4);7.5214 (0.7); 7.5121 (1.0); 7.2625 (34.0); 7.1753 (0.7); 6.7707 (0.5);6.7495 (0.5); 5.9959 (0.7); 5.9905 (1.4); 5.9861 (1.1); 5.9810 (0.8);5.9768 (1.1); 5.9708 (1.0); 5.9669 (1.0); 5.9636 (0.7); 5.9611 (0.6);5.9571 (0.6); 5.9535 (0.6); 5.9497 (0.7); 5.9472 (0.6); 5.9434 (0.6);5.9022 (0.6); 5.8966 (1.1); 5.8910 (0.6); 5.8885 (0.5); 5.8828 (0.8);5.8772 (0.5); 5.8683 (0.8); 5.8544 (0.7); 5.8090 (0.6); 5.8034 (1.1);5.7974 (1.0); 5.7898 (1.1); 5.7838 (0.8); 5.7775 (0.6); 5.0183 (0.6);5.0149 (0.6); 5.0099 (0.6); 5.0063 (0.5); 4.3161 (1.0); 4.3092 (1.1);4.3049 (1.8); 4.2968 (1.9); 4.2924 (1.2); 4.2857 (1.3); 4.2741 (1.8);4.2716 (1.2); 4.2633 (1.6); 4.2603 (2.0); 4.2563 (0.9); 4.2529 (1.4);4.2507 (1.2); 4.2443 (1.6); 4.2395 (1.0); 4.2337 (1.5); 4.2262 (1.1);4.2213 (0.8); 4.2155 (0.7); 3.8592 (1.6); 3.8569 (2.4); 3.8477 (1.8);3.8158 (1.9); 3.8137 (2.8); 3.8046 (2.1); 3.7790 (0.5); 3.7728 (0.5);3.6447 (1.6); 3.6343 (2.2); 3.6314 (1.9); 3.6216 (1.4); 3.6203 (1.4);3.6170 (1.4); 3.6139 (1.2); 3.6033 (3.0); 3.5909 (2.9); 3.5862 (2.0);3.5799 (1.7); 3.5742 (2.6); 3.5626 (1.9); 3.4036 (16.0); 3.3851 (10.2);3.3793 (15.4); 3.3695 (11.3); 3.2359 (2.3); 3.2295 (1.9); 3.2193 (1.9);3.1925 (2.0); 3.1864 (1.7); 3.1761 (1.6); 2.6746 (0.5); 2.6623 (0.6);2.5559 (0.7); 2.5420 (0.5); 2.5209 (0.8); 2.4925 (0.8); 2.4575 (0.8);1.9760 (0.7); 1.9412 (0.7); 1.9320 (0.6); 1.8976 (0.7); 1.8876 (0.8);1.8525 (0.9); 1.7389 (10.2); 1.7303 (12.6); 1.7233 (10.1); 1.5811(11.6); 0.0079 (0.7); −0.0002 (24.0); −0.0085 (0.8) I-082: ¹H-NMR(400.0MHz, CDCl3): δ = 7.7172 (1.0); 7.7138 (2.0); 7.7103 (1.3); 7.7067 (1.0);7.7027 (2.5); 7.6989 (3.3); 7.6953 (1.8); 7.6337 (0.6); 7.6300 (0.6);7.6275 (0.7); 7.6238 (0.7); 7.6207 (0.8); 7.6143 (1.3); 7.6109 (1.6);7.6077 (1.2); 7.6048 (1.0); 7.6013 (0.8); 7.5981 (0.9); 7.5919 (1.2);7.5881 (1.1); 7.4303 (0.7); 7.4270 (0.7); 7.4197 (0.9); 7.4168 (1.4);7.4137 (1.6); 7.4112 (1.5); 7.4082 (1.3); 7.4006 (0.9); 7.3975 (1.0);7.3949 (1.1); 7.3922 (0.9); 7.2614 (60.1); 7.1584 (0.7); 6.0023 (0.8);5.9980 (0.9); 5.9962 (1.0); 5.9919 (1.1); 5.9884 (0.9); 5.9844 (0.9);5.9808 (0.8); 5.9777 (0.9); 5.9743 (0.8); 5.9712 (1.0); 5.9655 (0.6);5.9618 (0.5); 5.9581 (0.6); 5.9544 (0.6); 5.9517 (0.6); 5.9481 (0.5);5.9040 (0.6); 5.8984 (1.1); 5.8928 (0.6); 5.8903 (0.5); 5.8846 (0.8);5.8670 (0.7); 5.8531 (0.6); 5.8131 (0.6); 5.8075 (1.0); 5.8018 (0.6);5.7994 (0.6); 5.7937 (1.0); 5.7898 (0.8); 5.7760 (0.6); 5.0149 (0.6);5.0062 (0.6); 4.3172 (1.0); 4.3057 (1.6); 4.2964 (1.8); 4.2936 (1.4);4.2877 (1.1); 4.2855 (1.2); 4.2775 (1.3); 4.2750 (1.9); 4.2642 (2.1);4.2618 (1.3); 4.2575 (0.8); 4.2541 (1.4); 4.2520 (1.2); 4.2477 (0.9);4.2451 (1.3); 4.2414 (1.2); 4.2368 (1.2); 4.2343 (0.9); 4.2286 (1.0);4.2241 (0.7); 4.2180 (0.6); 3.8419 (1.3); 3.8378 (2.6); 3.8283 (1.7);3.7986 (1.6); 3.7946 (3.1); 3.7852 (2.2); 3.7809 (0.6); 3.6436 (1.7);3.6331 (2.1); 3.6306 (1.9); 3.6198 (2.5); 3.6170 (1.4); 3.6089 (1.5);3.6044 (2.6); 3.5962 (1.6); 3.5928 (2.6); 3.5878 (1.9); 3.5802 (1.7);3.5758 (2.6); 3.5643 (1.6); 3.4037 (15.0); 3.3853 (10.6); 3.3833 (16.0);3.3711 (9.8); 3.2116 (2.0); 3.2053 (1.9); 3.1940 (1.7); 3.1682 (1.8);3.1622 (1.6); 3.1508 (1.5); 2.5457 (0.7); 2.5107 (0.8); 2.4809 (0.8);2.4460 (0.8); 1.9771 (0.7); 1.9420 (0.7); 1.8896 (0.8); 1.8546 (0.7);1.7417 (9.5); 1.7326 (11.1); 1.7257 (10.1); 1.7164 (0.7); 1.5619 (12.4);1.2588 (0.6); 0.8818 (0.8); 0.0080 (1.1); −0.0002 (33.9); −0.0085 (1.2)I-083: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.7145 (1.5); 7.7111 (2.9); 7.7076(2.6); 7.7042 (2.8); 7.7007 (4.0); 7.6974 (3.8); 7.6942 (1.9); 7.6325(0.8); 7.6288 (0.9); 7.6263 (1.0); 7.6220 (1.4); 7.6179 (1.6); 7.6152(1.8); 7.6116 (2.1); 7.6062 (1.4); 7.6039 (1.2); 7.5995 (1.5); 7.5955(1.6); 7.5927 (1.8); 7.5892 (1.8); 7.5863 (1.0); 7.5830 (0.6); 7.4358(0.6); 7.4326 (1.1); 7.4295 (1.1); 7.4263 (1.1); 7.4231 (1.5); 7.4205(1.5); 7.4171 (2.2); 7.4136 (2.3); 7.4111 (1.6); 7.4073 (1.2); 7.4040(1.6); 7.4010 (1.5); 7.3983 (1.6); 7.3954 (1.3); 7.3925 (0.9); 7.2611(80.9); 7.1282 (0.8); 7.1150 (0.7); 6.7372 (0.6); 6.7178 (0.6); 6.0159(0.5); 6.0098 (0.6); 6.0024 (1.3); 5.9978 (1.7); 5.9919 (1.3); 5.9898(1.4); 5.9856 (1.6); 5.9791 (1.6); 5.9745 (0.9); 5.9717 (0.8); 5.9679(0.8); 5.9643 (0.9); 5.9606 (0.9); 5.9580 (0.9); 5.9542 (0.8); 5.9249(0.8); 5.9194 (1.6); 5.9138 (0.9); 5.9113 (0.7); 5.9055 (1.1); 5.9001(0.6); 5.8910 (0.5); 5.8853 (1.0); 5.8795 (0.6); 5.8714 (0.8); 5.8352(0.8); 5.8295 (1.5); 5.8238 (0.9); 5.8216 (0.8); 5.8156 (1.7); 5.8098(1.6); 5.8038 (0.6); 5.8016 (0.5); 5.7957 (0.8); 5.2988 (1.6); 5.0980(0.5); 5.0244 (0.9); 4.4288 (1.4); 4.4200 (1.5); 4.4151 (2.1); 4.4067(1.9); 4.4052 (1.9); 4.4004 (1.7); 4.3908 (2.3); 4.3771 (2.6); 4.3755(2.6); 4.3735 (2.3); 4.3675 (1.5); 4.3621 (2.7); 4.3532 (2.6); 4.3514(2.3); 4.3393 (3.0); 4.3357 (1.5); 4.3241 (1.6); 3.8460 (1.5); 3.8393(1.7); 3.8349 (2.8); 3.8311 (2.8); 3.8026 (1.9); 3.7958 (2.3); 3.7916(3.6); 3.7881 (3.5); 3.7795 (0.7); 3.7633 (0.5); 3.7548 (2.1); 3.7530(2.0); 3.7391 (3.7); 3.7270 (2.0); 3.7232 (3.8); 3.7089 (3.5); 3.6977(2.3); 3.6950 (3.2); 3.6838 (3.6); 3.6697 (3.7); 3.6560 (1.8); 3.6037(0.5); 3.6009 (0.5); 3.5977 (0.6); 3.5911 (0.6); 3.5886 (0.7); 3.5819(1.0); 3.5789 (0.9); 3.5758 (1.0); 3.5693 (0.7); 3.5668 (0.7); 3.5602(0.5); 3.5542 (0.5); 3.2152 (2.2); 3.2096 (2.8); 3.2009 (2.6); 3.1718(1.9); 3.1664 (2.4); 3.1577 (2.3); 2.6643 (0.5); 2.5940 (0.6); 2.5729(1.0); 2.5589 (0.7); 2.5517 (0.6); 2.5377 (1.2); 2.5286 (0.6); 2.5165(0.6); 2.5075 (1.1); 2.4935 (0.7); 2.4863 (0.6); 2.4723 (1.2); 2.4512(0.6); 2.0111 (0.6); 2.0021 (1.0); 1.9929 (0.6); 1.9760 (0.5); 1.9670(0.9); 1.9577 (0.5); 1.9200 (1.0); 1.9110 (1.1); 1.9068 (0.6); 1.9019(0.6); 1.8849 (0.8); 1.8759 (0.9); 1.8667 (0.5); 1.8271 (0.5); 1.7443(14.3); 1.7360 (13.4); 1.7291 (14.6); 1.5545 (16.0); 1.2641 (0.8);1.2585 (0.7); 0.8818 (1.3); 0.8640 (0.5); 0.0080 (1.5); −0.0002 (46.5);−0.0085 (1.6) I-084: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.7153 (1.1); 7.7120(2.1); 7.7082 (1.6); 7.7029 (2.8); 7.6992 (3.5); 7.6958 (1.8); 7.6365(0.6); 7.6329 (0.7); 7.6303 (0.8); 7.6266 (0.7); 7.6237 (0.8); 7.6199(0.8); 7.6171 (1.1); 7.6139 (1.8); 7.6103 (1.6); 7.6078 (1.4); 7.6042(1.2); 7.6012 (0.9); 7.5975 (0.8); 7.5946 (1.0); 7.5913 (1.2); 7.5879(0.9); 7.5852 (0.7); 7.4317 (0.8); 7.4286 (0.8); 7.4255 (0.9); 7.4226(1.1); 7.4196 (1.4); 7.4164 (1.8); 7.4131 (1.8); 7.4100 (1.4); 7.4064(1.0); 7.4035 (1.1); 7.4005 (1.4); 7.3974 (1.4); 7.3943 (1.2); 7.3913(0.7); 7.2620 (46.4); 7.1770 (0.7); 5.9835 (0.6); 5.9796 (1.0); 5.9772(1.4); 5.9735 (1.1); 5.9700 (1.1); 5.9658 (1.1); 5.9632 (1.2); 5.9596(1.2); 5.9566 (1.2); 5.9532 (0.7); 5.9505 (0.6); 5.9467 (0.6); 5.9431(0.7); 5.9393 (0.7); 5.9367 (0.7); 5.9329 (0.6); 5.9054 (0.6); 5.8998(1.2); 5.8942 (0.7); 5.8917 (0.5); 5.8860 (0.8); 5.8631 (0.8); 5.8491(0.6); 5.8162 (0.6); 5.8106 (1.1); 5.8049 (0.7); 5.8026 (0.6); 5.7968(1.0); 5.7917 (0.7); 5.7869 (0.7); 5.7730 (0.6); 5.2991 (1.5); 5.0075(0.8); 3.8444 (1.2); 3.8385 (1.2); 3.8328 (2.1); 3.8279 (2.0); 3.8011(1.4); 3.7951 (1.4); 3.7896 (2.4); 3.7847 (2.3); 3.7673 (0.5); 3.7572(16.0); 3.7453 (0.5); 3.7390 (0.6); 3.7294 (15.7); 3.7195 (0.5); 3.7001(8.2); 3.6847 (8.7); 3.5398 (0.5); 3.5372 (0.6); 3.5308 (0.8); 3.5278(0.7); 3.5248 (0.8); 3.5184 (0.6); 3.5158 (0.5); 3.2135 (1.9); 3.2091(2.2); 3.1993 (2.0); 3.1701 (1.6); 3.1659 (1.9); 3.1561 (1.8); 2.5441(0.8); 2.5302 (0.6); 2.5231 (0.5); 2.5092 (0.9); 2.4753 (0.8); 2.4613(0.6); 2.4403 (0.9); 1.9693 (0.8); 1.9343 (0.7); 1.9255 (0.6); 1.8902(0.7); 1.8801 (1.1); 1.8707 (0.5); 1.8453 (0.7); 1.7428 (11.0); 1.7333(10.6); 1.7295 (12.0); 1.5672 (7.5); 0.0080 (0.8); −0.0002 (27.0);−0.0085 (1.0) I-085: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.9992 (5.1); 7.9959(8.8); 7.9920 (5.6); 7.9745 (9.8); 7.9708 (11.6); 7.9670 (6.9); 7.8833(3.3); 7.8792 (3.1); 7.8729 (6.6); 7.8695 (9.1); 7.8659 (7.9); 7.8531(7.5); 7.8496 (9.8); 7.8459 (7.2); 7.7804 (3.4); 7.7683 (6.6); 7.7650(11.5); 7.7617 (9.9); 7.7489 (8.1); 7.7455 (11.6); 7.7423 (7.0); 7.6111(3.6); 7.5991 (10.0); 7.5915 (6.0); 7.5794 (16.0); 7.5720 (3.2); 7.5597(7.2); 7.5187 (2.5); 7.3483 (2.8); 7.3269 (3.5); 7.3139 (3.1); 7.2977(1.1); 7.2598 (412.8); 7.2101 (1.0); 6.9958 (2.2); 6.8311 (0.8); 6.8064(1.6); 6.7859 (1.0); 6.0808 (1.2); 6.0700 (4.2); 6.0669 (5.3); 6.0533(7.4); 6.0437 (3.4); 6.0399 (3.7); 6.0365 (3.8); 6.0335 (3.7); 6.0301(3.4); 5.9726 (3.3); 5.9670 (5.9); 5.9613 (3.7); 5.9532 (4.6); 5.9476(2.6); 5.9237 (1.4); 5.9180 (2.3); 5.9094 (4.2); 5.9038 (7.5); 5.8981(4.4); 5.8899 (4.8); 5.8842 (2.7); 5.8668 (1.1); 5.8610 (2.1); 5.8546(1.2); 5.8470 (1.8); 5.8413 (1.0); 5.2984 (3.0); 5.1902 (1.1); 5.1793(1.1); 5.1585 (1.1); 5.1025 (2.5); 5.0819 (4.8); 5.0615 (2.4); 4.1494(0.6); 4.1316 (1.6); 4.1136 (1.6); 4.0959 (0.6); 4.0726 (1.8); 4.0657(1.7); 4.0450 (8.0); 4.0275 (2.3); 4.0202 (2.4); 3.9999 (11.2); 3.8517(1.2); 3.8455 (1.2); 3.8357 (1.6); 3.8296 (1.9); 3.8235 (2.2); 3.8176(2.1); 3.8090 (8.1); 3.8014 (12.9); 3.7917 (12.1); 3.7640 (5.5); 3.7563(8.6); 3.7466 (8.6); 3.6075 (4.0); 3.6015 (4.0); 2.7933 (0.6); 2.7817(0.7); 2.7733 (1.0); 2.7607 (1.1); 2.7583 (1.4); 2.7538 (0.6); 2.7459(1.6); 2.7377 (1.4); 2.7329 (1.1); 2.7305 (0.8); 2.7249 (1.4); 2.7118(1.4); 2.7090 (1.3); 2.6971 (1.1); 2.6884 (1.1); 2.6766 (1.0); 2.6136(2.1); 2.5927 (4.0); 2.5782 (2.9); 2.5717 (2.6); 2.5571 (4.4); 2.5397(2.9); 2.5362 (2.9); 2.5191 (4.2); 2.5046 (3.1); 2.4982 (2.8); 2.4838(4.7); 2.4629 (2.3); 2.1144 (1.1); 2.0634 (2.2); 2.0552 (4.0); 2.0446(8.7); 2.0278 (2.1); 2.0197 (3.6); 2.0113 (2.5); 1.9978 (2.9); 1.9890(4.8); 1.9809 (2.6); 1.9629 (2.6); 1.9536 (4.0); 1.9451 (3.1); 1.9330(1.1); 1.9229 (1.1); 1.9107 (1.2); 1.8976 (1.0); 1.8873 (0.9); 1.8759(0.8); 1.4319 (1.7); 1.2767 (2.2); 1.2589 (4.5); 1.2411 (2.1); 0.1461(1.1); 0.0080 (9.0); −0.0002 (297.1); −0.0085 (11.0); −0.0498 (0.9);−0.1495 (1.0) I-086: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.9889 (0.9); 7.9850(1.6); 7.9807 (1.6); 7.9764 (2.4); 7.9723 (3.1); 7.9684 (1.6); 7.8930(0.7); 7.8900 (0.9); 7.8854 (1.4); 7.8807 (1.5); 7.8775 (1.4); 7.8731(1.3); 7.8702 (1.1); 7.8655 (1.6); 7.8608 (1.7); 7.8577 (1.5); 7.8530(0.6); 7.7820 (0.9); 7.7787 (1.0); 7.7750 (0.6); 7.7714 (0.8); 7.7662(1.7); 7.7626 (1.8); 7.7592 (1.3); 7.7556 (0.7); 7.7519 (1.0); 7.7480(1.5); 7.6125 (0.6); 7.6091 (0.7); 7.5991 (1.3); 7.5939 (1.1); 7.5893(1.2); 7.5794 (2.0); 7.5698 (0.6); 7.5598 (0.9); 7.3839 (0.6); 7.3622(0.6); 7.2621 (36.8); 6.7728 (0.5); 6.0583 (0.5); 6.0566 (0.5); 6.0528(0.7); 6.0488 (0.8); 6.0429 (0.9); 6.0388 (0.8); 6.0330 (0.8); 6.0291(0.9); 6.0256 (0.6); 6.0221 (0.5); 6.0154 (1.0); 6.0122 (1.1); 6.0089(1.0); 6.0023 (0.6); 5.9989 (0.6); 5.9957 (0.6); 5.9923 (0.5); 5.9341(0.6); 5.9285 (1.0); 5.9229 (0.6); 5.9205 (0.5); 5.9148 (0.8); 5.8781(0.7); 5.8641 (1.0); 5.8584 (1.2); 5.8527 (0.6); 5.8503 (0.5); 5.8445(0.8); 5.8200 (0.8); 5.8061 (0.7); 5.0930 (0.6); 5.0708 (0.6); 4.3287(0.9); 4.3169 (1.4); 4.3119 (0.9); 4.3051 (1.1); 4.2997 (2.2); 4.2884(2.8); 4.2753 (2.1); 4.2711 (1.0); 4.2649 (1.4); 4.2600 (1.6); 4.2511(1.6); 4.2470 (1.7); 4.2402 (1.0); 4.2378 (1.0); 4.2339 (0.8); 4.2269(0.6); 4.0576 (0.9); 4.0510 (1.6); 4.0123 (1.3); 4.0060 (2.3); 3.8055(1.8); 3.8031 (2.1); 3.7966 (2.5); 3.7897 (2.2); 3.7603 (1.1); 3.7578(1.3); 3.7515 (1.6); 3.7446 (1.4); 3.6425 (1.9); 3.6308 (3.0); 3.6191(2.4); 3.6092 (3.7); 3.5966 (3.4); 3.5948 (3.7); 3.5831 (3.2); 3.5709(1.4); 3.4040 (13.8); 3.3877 (13.0); 3.3857 (16.0); 3.3753 (8.9); 2.7113(0.6); 2.5480 (0.6); 2.5126 (0.7); 2.4733 (0.7); 2.4381 (0.8); 2.0155(0.6); 1.9882 (0.9); 1.9797 (1.4); 1.9721 (0.7); 1.9532 (0.6); 1.9440(0.8); 1.5683 (5.6); 0.8817 (0.5); 0.0079 (0.6); −0.0002 (21.0); −0.0084(0.8) I-087: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.9868 (1.0); 7.9827 (2.2);7.9782 (2.5); 7.9740 (2.7); 7.9708 (2.4); 7.9671 (1.2); 7.8979 (0.7);7.8948 (0.9); 7.8901 (0.9); 7.8860 (0.9); 7.8818 (1.2); 7.8778 (1.6);7.8750 (1.9); 7.8705 (1.2); 7.8662 (1.0); 7.8620 (1.2); 7.8596 (1.1);7.8572 (1.1); 7.8553 (1.0); 7.8526 (0.6); 7.7821 (1.0); 7.7787 (1.0);7.7740 (0.9); 7.7711 (1.5); 7.7674 (1.5); 7.7628 (1.4); 7.7592 (1.3);7.7546 (1.2); 7.7516 (1.7); 7.7482 (1.6); 7.7454 (0.8); 7.6098 (0.8);7.6016 (1.3); 7.5917 (1.3); 7.5900 (1.4); 7.5820 (2.0); 7.5721 (0.6);7.5704 (0.7); 7.5623 (0.9); 7.3913 (0.6); 7.3705 (0.6); 7.2617 (41.4);6.0405 (0.5); 6.0387 (0.5); 6.0342 (0.6); 6.0308 (0.6); 6.0267 (1.0);6.0204 (0.8); 6.0145 (1.0); 6.0084 (0.9); 6.0034 (1.0); 6.0007 (1.1);5.9975 (1.1); 5.9942 (1.0); 5.9882 (0.6); 5.9849 (0.6); 5.9816 (0.6);5.9352 (0.6); 5.9297 (1.2); 5.9241 (0.7); 5.9217 (0.6); 5.9159 (0.8);5.8738 (0.8); 5.8689 (0.8); 5.8641 (1.1); 5.8595 (0.9); 5.8553 (0.7);5.8502 (0.8); 5.8176 (0.8); 5.8116 (0.5); 5.8036 (0.8); 5.0841 (0.6);5.0682 (0.6); 4.0627 (0.6); 4.0576 (0.8); 4.0506 (1.7); 4.0173 (0.9);4.0123 (1.2); 4.0055 (2.4); 3.8048 (2.3); 3.7991 (2.6); 3.7914 (2.5);3.7848 (0.6); 3.7786 (0.5); 3.7749 (0.7); 3.7639 (14.9); 3.7540 (2.3);3.7462 (2.5); 3.7418 (16.0); 3.7070 (9.8); 3.6950 (8.2); 3.5629 (0.6);3.5553 (0.8); 3.5492 (0.8); 3.5423 (0.8); 3.5357 (0.6); 2.7256 (0.5);2.5404 (0.7); 2.5260 (0.5); 2.5050 (0.8); 2.4701 (0.9); 2.4557 (0.6);2.4349 (1.0); 2.0119 (0.7); 1.9765 (1.2); 1.9693 (1.2); 1.9646 (0.6);1.9616 (0.6); 1.9425 (0.8); 1.9342 (0.8); 1.5596 (6.8); 0.0080 (0.7);−0.0002 (23.3); −0.0085 (0.9) I-088: ¹H-NMR(400.0 MHz, CDCl3): δ =7.9802 (10.5); 7.9777 (11.3); 7.9743 (11.3); 7.9697 (9.6); 7.9657 (4.8);7.8956 (2.9); 7.8916 (4.0); 7.8885 (5.3); 7.8841 (4.4); 7.8809 (5.8);7.8760 (6.6); 7.8730 (6.0); 7.8686 (6.3); 7.8644 (5.0); 7.8611 (6.4);7.8585 (4.8); 7.7828 (3.9); 7.7794 (4.2); 7.7745 (3.9); 7.7716 (6.1);7.7681 (6.2); 7.7635 (5.7); 7.7599 (5.5); 7.7551 (4.9); 7.7521 (7.1);7.7489 (6.6); 7.6108 (3.7); 7.6010 (5.5); 7.5910 (6.0); 7.5821 (8.8);7.5715 (2.9); 7.5626 (3.8); 7.5203 (0.8); 7.3244 (1.9); 7.3113 (3.0);7.2898 (2.2); 7.2614 (154.1); 6.9974 (0.9); 6.8076 (1.3); 6.7857 (2.2);6.7625 (1.1); 6.0654 (1.8); 6.0596 (2.2); 6.0545 (2.7); 6.0514 (2.8);6.0475 (3.9); 6.0410 (5.0); 6.0344 (4.3); 6.0297 (3.5); 6.0245 (4.7);6.0213 (4.9); 6.0181 (4.6); 6.0115 (2.6); 6.0080 (2.7); 6.0049 (2.6);6.0015 (2.3); 5.9532 (2.7); 5.9477 (4.7); 5.9420 (2.9); 5.9339 (3.5);5.9284 (2.0); 5.9029 (1.5); 5.8972 (2.8); 5.8914 (1.8); 5.8891 (1.7);5.8836 (4.2); 5.8784 (4.8); 5.8730 (2.7); 5.8649 (3.4); 5.8593 (2.0);5.8455 (1.8); 5.8397 (3.3); 5.8338 (2.1); 5.8258 (3.0); 5.8200 (1.6);5.2019 (0.5); 5.1959 (0.6); 5.1913 (0.7); 5.1862 (1.0); 5.1810 (1.2);5.1672 (1.3); 5.1571 (1.4); 5.1526 (1.6); 5.1472 (1.5); 5.1422 (1.2);5.1366 (1.0); 5.1318 (0.8); 5.1260 (1.2); 5.1208 (1.3); 5.0992 (2.6);5.0806 (2.7); 4.4285 (7.9); 4.4146 (9.5); 4.4120 (6.5); 4.4030 (6.3);4.4002 (11.3); 4.3895 (8.8); 4.3843 (7.4); 4.3747 (9.1); 4.3713 (6.2);4.3614 (9.3); 4.3578 (5.4); 4.3458 (8.9); 4.3337 (4.6); 4.0592 (3.1);4.0491 (6.3); 4.0139 (4.4); 4.0041 (9.0); 3.8477 (1.1); 3.8417 (1.5);3.8355 (1.7); 3.8295 (1.7); 3.8255 (2.1); 3.8194 (2.7); 3.8131 (3.6);3.8072 (11.9); 3.8018 (11.4); 3.7952 (9.3); 3.7852 (1.3); 3.7620 (7.1);3.7568 (7.4); 3.7501 (6.8); 3.7449 (9.6); 3.7333 (6.5); 3.7306 (10.0);3.7288 (7.4); 3.7225 (10.8); 3.7168 (9.2); 3.7135 (3.3); 3.7083 (16.0);3.7019 (7.7); 3.6944 (9.8); 3.6910 (9.0); 3.6877 (8.6); 3.6767 (7.0);3.6739 (8.3); 3.6630 (4.9); 3.6216 (1.8); 3.6154 (2.5); 3.6089 (3.2);3.6019 (3.4); 3.5947 (3.3); 3.5881 (2.7); 3.5819 (2.0); 2.7856 (1.4);2.7732 (1.3); 2.7651 (1.5); 2.7526 (1.7); 2.7503 (1.8); 2.7416 (1.4);2.7378 (1.7); 2.7298 (2.5); 2.7209 (1.4); 2.7173 (1.6); 2.7092 (1.4);2.7065 (1.4); 2.6946 (1.2); 2.6857 (1.2); 2.6739 (1.1); 2.5988 (1.5);2.5777 (2.9); 2.5633 (2.0); 2.5566 (1.8); 2.5422 (3.3); 2.5270 (1.9);2.5212 (1.8); 2.5061 (3.4); 2.4916 (2.2); 2.4851 (2.0); 2.4707 (3.8);2.4497 (1.8); 2.0453 (1.7); 2.0375 (2.9); 2.0296 (1.7); 2.0083 (2.7);2.0003 (6.0); 1.9919 (2.8); 1.9784 (1.6); 1.9723 (1.9); 1.9646 (4.3);1.9548 (2.1); 1.9430 (1.3); 1.9323 (1.4); 1.9284 (1.3); 1.9168 (1.1);1.9064 (1.2); 1.8935 (1.5); 1.8815 (1.1); 1.8710 (1.0); 1.8595 (1.0);1.5561 (14.6); 1.2561 (0.9); 0.0080 (3.0); −0.0002 (91.0); −0.0085 (3.5)I-089: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.7480 (2.9); 7.7449 (6.1); 7.7417(6.7); 7.7382 (6.7); 7.7344 (6.2); 7.7307 (3.0); 7.6680 (1.4); 7.6641(1.6); 7.6617 (1.9); 7.6583 (2.7); 7.6546 (2.5); 7.6522 (2.9); 7.6484(3.3); 7.6460 (3.1); 7.6422 (2.7); 7.6399 (2.2); 7.6364 (2.8); 7.6328(2.5); 7.6303 (2.8); 7.6266 (3.0); 7.6241 (1.6); 7.6205 (1.1); 7.5200(0.6); 7.4964 (1.7); 7.4932 (1.9); 7.4901 (1.9); 7.4873 (2.8); 7.4844(2.9); 7.4811 (3.5); 7.4779 (3.9); 7.4748 (2.9); 7.4712 (2.0); 7.4683(2.8); 7.4654 (2.9); 7.4623 (2.9); 7.4592 (2.4); 7.4565 (1.4); 7.3183(1.0); 7.3110 (1.0); 7.2966 (1.7); 7.2744 (1.3); 7.2612 (102.3); 6.9971(0.6); 6.7656 (0.7); 6.7434 (1.0); 6.7211 (0.6); 6.0721 (0.9); 6.0679(1.1); 6.0662 (1.1); 6.0618 (1.1); 6.0585 (1.5); 6.0540 (1.9); 6.0481(1.9); 6.0454 (2.1); 6.0412 (1.9); 6.0392 (2.2); 6.0350 (2.0); 6.0291(2.4); 6.0257 (2.5); 6.0225 (2.4); 6.0161 (1.4); 6.0128 (1.4); 6.0095(1.4); 6.0062 (1.2); 5.9552 (1.4); 5.9496 (2.5); 5.9439 (1.6); 5.9358(1.9); 5.9304 (1.1); 5.9014 (0.7); 5.8956 (1.4); 5.8873 (1.9); 5.8817(3.2); 5.8760 (2.0); 5.8678 (1.8); 5.8622 (1.0); 5.8443 (0.9); 5.8385(1.7); 5.8326 (1.1); 5.8306 (1.0); 5.8246 (1.5); 5.8188 (0.8); 5.2990(0.5); 5.1822 (0.6); 5.1717 (0.7); 5.1674 (0.6); 5.1628 (0.7); 5.1571(0.7); 5.1527 (0.8); 5.1474 (0.7); 5.1424 (0.6); 5.1262 (0.6); 5.1212(0.7); 5.0983 (1.5); 5.0794 (1.5); 5.0592 (0.6); 4.4290 (4.5); 4.4218(0.8); 4.4172 (3.8); 4.4151 (5.2); 4.4123 (3.6); 4.4060 (3.1); 4.4012(6.5); 4.3926 (4.8); 4.3872 (3.9); 4.3777 (3.6); 4.3745 (4.6); 4.3635(4.3); 4.3588 (2.7); 4.3499 (2.7); 4.3475 (4.4); 4.3363 (2.2); 4.0552(1.1); 4.0492 (1.4); 4.0375 (3.5); 4.0098 (1.6); 4.0039 (2.0); 3.9924(4.9); 3.8489 (0.6); 3.8428 (0.8); 3.8366 (0.9); 3.8305 (0.8); 3.8270(1.2); 3.8211 (1.4); 3.8150 (1.4); 3.8090 (1.0); 3.8051 (0.7); 3.7992(0.7); 3.7933 (0.8); 3.7834 (5.1); 3.7779 (5.4); 3.7708 (4.6); 3.7443(5.4); 3.7381 (4.2); 3.7328 (7.5); 3.7303 (6.7); 3.7279 (5.4); 3.7253(9.3); 3.7163 (6.0); 3.7110 (8.6); 3.7062 (1.7); 3.7029 (3.9); 3.6971(5.3); 3.6932 (3.7); 3.6886 (4.2); 3.6791 (3.2); 3.6748 (3.6); 3.6653(2.4); 3.6250 (1.0); 3.6189 (1.4); 3.6114 (1.6); 3.6061 (1.7); 3.5996(1.6); 3.5920 (1.5); 3.5861 (1.1); 2.7894 (0.7); 2.7770 (0.7); 2.7688(0.8); 2.7564 (0.9); 2.7540 (0.9); 2.7460 (0.7); 2.7415 (0.9); 2.7338(1.1); 2.7253 (0.7); 2.7211 (0.8); 2.7135 (0.7); 2.7108 (0.7); 2.6990(0.6); 2.6901 (0.6); 2.6784 (0.6); 2.5921 (0.8); 2.5711 (1.6); 2.5566(1.1); 2.5500 (1.0); 2.5355 (1.8); 2.5207 (1.0); 2.5145 (1.0); 2.4999(1.8); 2.4853 (1.2); 2.4789 (1.1); 2.4644 (2.0); 2.4435 (1.0); 2.0458(0.9); 2.0382 (1.6); 2.0306 (0.9); 2.0097 (1.7); 2.0020 (3.1); 1.9979(1.5); 1.9945 (1.8); 1.9871 (0.8); 1.9753 (1.2); 1.9657 (2.2); 1.9586(1.0); 1.9517 (0.7); 1.9406 (0.6); 1.9298 (0.7); 1.9260 (0.6); 1.9143(0.6); 1.9040 (0.6); 1.8923 (0.7); 1.8790 (0.5); 1.8572 (0.5); 1.5528(16.0); 1.3072 (1.0); 1.2976 (0.7); 1.2893 (0.7); 1.2798 (0.6); 1.2649(1.4); 0.8985 (0.7); 0.8818 (2.3); 0.8641 (0.9); 0.0080 (1.8); −0.0002(56.4); −0.0085 (2.0) I-090: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.7620 (2.0);7.7587 (3.8); 7.7553 (2.3); 7.7491 (1.0); 7.7456 (2.1); 7.7414 (3.7);7.7374 (4.6); 7.7339 (2.4); 7.6600 (0.6); 7.6556 (1.8); 7.6496 (2.0);7.6459 (2.4); 7.6423 (1.5); 7.6398 (1.7); 7.6337 (2.0); 7.6296 (2.0);7.6240 (2.4); 7.6205 (1.5); 7.6181 (1.4); 7.6143 (1.2); 7.4968 (0.8);7.4935 (0.8); 7.4909 (0.8); 7.4879 (0.8); 7.4815 (2.2); 7.4782 (3.0);7.4755 (2.9); 7.4723 (2.6); 7.4626 (2.2); 7.4593 (2.3); 7.4565 (2.0);7.4533 (1.8); 7.3357 (1.0); 7.3251 (1.2); 7.3115 (1.2); 7.3039 (1.1);7.2613 (67.3); 6.7814 (0.6); 6.0809 (1.3); 6.0760 (1.4); 6.0718 (1.7);6.0666 (1.8); 6.0602 (2.2); 6.0570 (2.4); 6.0524 (1.4); 6.0497 (1.1);6.0457 (1.2); 6.0424 (1.2); 6.0392 (1.2); 6.0359 (1.1); 5.9810 (1.1);5.9754 (1.9); 5.9697 (1.2); 5.9674 (1.0); 5.9616 (1.5); 5.9560 (0.9);5.9200 (1.0); 5.9178 (1.2); 5.9122 (2.3); 5.9064 (1.8); 5.8984 (1.7);5.8928 (0.9); 5.8624 (0.7); 5.8485 (0.6); 5.2991 (1.8); 5.1044 (0.8);5.0826 (1.6); 5.0620 (0.8); 4.1505 (1.1); 4.1326 (3.4); 4.1147 (3.4);4.0969 (1.1); 4.0727 (0.5); 4.0634 (0.6); 4.0391 (2.4); 4.0276 (0.8);4.0181 (0.8); 3.9939 (3.4); 3.8371 (0.5); 3.8311 (0.7); 3.8252 (0.7);3.8192 (0.5); 3.7884 (2.5); 3.7824 (3.9); 3.7705 (3.7); 3.7431 (1.9);3.7373 (2.9); 3.7253 (2.8); 3.6264 (1.2); 3.6211 (1.3); 3.6143 (1.3);3.6093 (1.3); 3.6041 (1.3); 2.6070 (0.6); 2.5860 (1.3); 2.5714 (0.9);2.5650 (0.8); 2.5505 (1.4); 2.5295 (1.3); 2.5086 (1.3); 2.4941 (1.0);2.4878 (0.8); 2.4733 (1.4); 2.4525 (0.7); 2.0643 (0.8); 2.0564 (1.4);2.0461 (16.0); 2.0287 (0.6); 2.0209 (1.2); 2.0129 (0.7); 1.9923 (0.8);1.9843 (1.4); 1.9757 (1.0); 1.9568 (0.7); 1.9491 (1.3); 1.9407 (0.8);1.2774 (4.5); 1.2595 (9.2); 1.2416 (4.4); 0.0079 (1.2); −0.0002 (39.6);−0.0085 (1.4) I-091: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.5195 (0.6); 7.2725(0.9); 7.2607 (100.5); 7.1863 (0.6); 7.1740 (2.7); 7.1682 (3.5); 7.1656(4.1); 7.1598 (3.9); 7.1570 (3.5); 7.1542 (3.8); 7.1485 (4.1); 7.1458(3.5); 7.1401 (2.8); 7.1280 (0.6); 7.1030 (0.8); 7.0832 (1.5); 7.0629(0.9); 6.9966 (0.6); 6.8942 (0.9); 6.8887 (1.6); 6.8826 (1.0); 6.8723(1.8); 6.8668 (3.0); 6.8617 (1.7); 6.8514 (1.0); 6.8454 (1.6); 6.8399(0.9); 5.9704 (1.4); 5.9668 (1.3); 5.9645 (1.4); 5.9608 (1.5); 5.9566(2.2); 5.9529 (2.8); 5.9504 (2.6); 5.9468 (2.6); 5.9427 (1.4); 5.9390(1.5); 5.9348 (1.8); 5.9319 (2.1); 5.9287 (2.6); 5.9049 (1.4); 5.8994(2.6); 5.8939 (1.5); 5.8912 (1.1); 5.8856 (1.8); 5.8801 (1.0); 5.8179(1.2); 5.8122 (2.3); 5.8065 (1.4); 5.8043 (1.3); 5.7985 (2.0); 5.7929(1.1); 5.2096 (0.8); 5.2061 (1.4); 5.2024 (0.8); 5.0531 (1.3); 5.0348(1.2); 5.0315 (1.2); 4.2272 (2.3); 4.2093 (7.2); 4.2013 (2.3); 4.1915(7.5); 4.1834 (7.0); 4.1736 (2.8); 4.1703 (2.0); 4.1656 (7.2); 4.1526(1.7); 4.1478 (2.5); 4.1420 (0.5); 4.1348 (0.6); 3.8245 (4.5); 3.8229(4.5); 3.7811 (5.4); 3.7796 (5.4); 3.5261 (0.9); 3.5229 (1.0); 3.5079(1.7); 3.5020 (1.7); 3.4991 (1.6); 3.3436 (4.0); 3.3382 (4.0); 3.3003(3.3); 3.2948 (3.4); 2.5767 (0.9); 2.5556 (1.6); 2.5418 (1.1); 2.5345(1.0); 2.5207 (1.8); 2.5127 (1.2); 2.4996 (1.0); 2.4916 (2.2); 2.4778(1.4); 2.4706 (1.3); 2.4567 (2.4); 2.4356 (1.2); 1.9582 (1.3); 1.9486(1.6); 1.9392 (0.9); 1.9233 (1.1); 1.9137 (1.5); 1.9043 (0.8); 1.8939(1.0); 1.8839 (1.6); 1.8740 (0.9); 1.8589 (0.8); 1.8491 (1.4); 1.8393(0.8); 1.5707 (1.1); 1.5578 (3.6); 1.5535 (2.8); 1.5504 (2.3); 1.5442(1.4); 1.5398 (2.6); 1.5367 (2.6); 1.5265 (1.5); 1.5233 (1.6); 1.5190(1.5); 1.5160 (1.3); 1.5055 (0.8); 1.5024 (0.7); 1.3210 (7.7); 1.3032(15.9); 1.2988 (3.2); 1.2914 (8.1); 1.2853 (8.2); 1.2809 (5.2); 1.2735(16.0); 1.2631 (2.7); 1.2557 (7.9); 1.2463 (0.7); 0.8437 (0.9); 0.8240(0.8); 0.7171 (0.8); 0.7134 (0.8); 0.7038 (0.9); 0.6997 (0.9); 0.6927(0.7); 0.6887 (1.0); 0.6793 (1.1); 0.6760 (0.9); 0.6684 (1.0); 0.6652(0.9); 0.6592 (0.9); 0.6496 (0.8); 0.6457 (1.2); 0.6365 (1.2); 0.6323(0.8); 0.6234 (0.8); 0.5926 (0.6); 0.5803 (1.3); 0.5711 (2.0); 0.5685(2.4); 0.5647 (2.6); 0.5619 (2.6); 0.5526 (3.0); 0.5501 (2.8); 0.5473(2.9); 0.5442 (3.1); 0.5410 (3.2); 0.5373 (1.8); 0.5317 (3.3); 0.5236(1.6); 0.5198 (1.7); 0.5102 (2.0); 0.5049 (1.1); 0.4978 (1.2); 0.4912(1.2); 0.4847 (1.3); 0.4729 (1.7); 0.4693 (2.2); 0.4602 (1.9); 0.4558(1.6); 0.4496 (0.8); 0.4470 (0.8); 0.4411 (0.9); 0.4362 (0.6); 0.4324(0.5); 0.0080 (1.6); −0.0002 (55.2); −0.0084 (2.2) I-094: ¹H-NMR(400.0MHz, CDCl3): δ = 7.5185 (6.9); 7.3095 (5.2); 7.2923 (1.9); 7.2596(1208.8); 7.2462 (3.8); 7.2334 (1.7); 7.2100 (2.2); 7.1714 (8.9); 7.1655(12.8); 7.1620 (16.8); 7.1562 (16.4); 7.1516 (15.5); 7.1456 (16.7);7.1421 (14.2); 7.1367 (9.4); 7.1000 (3.0); 7.0790 (3.5); 7.0450 (2.8);6.9956 (7.0); 6.8970 (3.5); 6.8895 (5.8); 6.8838 (4.7); 6.8750 (6.6);6.8680 (10.0); 6.8621 (6.0); 6.8521 (3.3); 6.8466 (5.1); 6.6739 (1.5);6.0153 (4.5); 6.0013 (10.2); 5.9951 (10.9); 5.9912 (9.5); 5.9836 (8.4);5.9771 (5.9); 5.9654 (3.8); 5.9330 (4.7); 5.9274 (8.2); 5.9218 (4.9);5.9136 (5.9); 5.9080 (3.7); 5.9004 (2.2); 5.8864 (1.6); 5.8633 (4.2);5.8576 (7.7); 5.8518 (5.0); 5.8438 (6.6); 5.8274 (1.5); 5.2328 (4.3);5.1372 (1.6); 5.0264 (4.8); 3.8226 (12.7); 3.8133 (12.2); 3.7792 (16.0);3.7699 (14.7); 3.5901 (5.2); 3.3615 (5.5); 3.3499 (13.1); 3.3446 (12.6);3.3181 (4.6); 3.3065 (10.9); 3.3012 (10.9); 2.7662 (1.2); 2.7108 (1.2);2.6341 (2.7); 2.6129 (5.2); 2.5989 (3.6); 2.5917 (3.4); 2.5774 (5.7);2.5524 (6.1); 2.5386 (4.2); 2.5312 (3.5); 2.5172 (6.1); 2.4960 (3.2);2.0166 (3.6); 2.0069 (5.6); 1.9974 (3.1); 1.9818 (3.2); 1.9716 (5.0);1.9617 (3.0); 1.9451 (3.8); 1.9346 (6.2); 1.9241 (4.1); 1.9099 (3.6);1.8993 (5.4); 1.8889 (3.5); 1.8496 (1.4); 1.5743 (3.0); 1.5654 (4.4);1.5535 (6.5); 1.5442 (7.8); 1.5401 (8.6); 1.5313 (5.5); 1.5239 (4.4);1.5195 (4.7); 1.5058 (2.6); 1.4322 (2.6); 1.3050 (2.4); 1.2878 (2.4);1.2555 (2.8); 0.9562 (1.6); 0.9033 (1.3); 0.8794 (1.8); 0.8774 (2.9);0.8732 (1.7); 0.8369 (2.0); 0.8346 (1.8); 0.8301 (2.9); 0.8235 (4.0);0.8221 (3.2); 0.8176 (3.4); 0.8105 (2.5); 0.8087 (1.9); 0.8072 (2.0);0.8033 (2.8); 0.8016 (3.4); 0.7984 (2.6); 0.7945 (2.0); 0.7885 (1.7);0.7851 (1.7); 0.7685 (1.4); 0.6938 (2.2); 0.6691 (5.7); 0.6608 (6.2);0.6561 (5.4); 0.6467 (4.8); 0.6417 (4.8); 0.6321 (5.2); 0.6188 (3.8);0.5776 (6.6); 0.5720 (6.8); 0.5675 (10.1); 0.5638 (9.9); 0.5589 (11.4);0.5470 (11.4); 0.5374 (11.3); 0.5281 (7.7); 0.5246 (7.3); 0.5149 (5.7);0.5065 (2.7); 0.4983 (2.7); 0.4776 (4.6); 0.4728 (5.7); 0.4685 (6.4);0.4599 (6.6); 0.4545 (5.6); 0.4464 (4.8); 0.4356 (3.2); 0.4260 (1.8);0.1459 (2.5); 0.0498 (2.3); 0.0080 (22.1); −0.0002 (690.0); −0.0085(25.8); −0.0496 (1.7); −0.1496 (2.6) I-095: ¹H-NMR(400.0 MHz, CDCl3): δ= 7.9437 (0.6); 7.9406 (0.5); 7.9313 (0.6); 7.8366 (0.5); 7.7049 (0.6);7.6888 (0.5); 7.6854 (0.7); 7.5487 (0.6); 7.5291 (1.0); 7.2611 (16.5);3.8517 (0.6); 3.8456 (0.7); 3.8086 (0.7); 3.8025 (0.8); 3.2291 (0.7);3.2177 (0.6); 3.1859 (0.6); 3.1745 (0.5); 1.7360 (3.4); 1.7297 (1.0);1.7212 (4.0); 1.4816 (13.0); 1.4400 (16.0); 1.4243 (1.6); −0.0002 (9.5)I-096: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.7373 (16.0); 7.7335 (15.3);7.7298 (11.6); 7.6690 (2.0); 7.6628 (2.7); 7.6593 (5.1); 7.6532 (5.8);7.6495 (6.3); 7.6473 (6.5); 7.6438 (5.4); 7.6412 (5.1); 7.6375 (5.5);7.6313 (5.6); 7.6277 (5.9); 7.5192 (1.7); 7.4976 (4.6); 7.4946 (5.1);7.4903 (5.8); 7.4871 (5.4); 7.4839 (5.5); 7.4809 (7.4); 7.4783 (6.8);7.4716 (5.6); 7.4682 (5.1); 7.4650 (4.6); 7.4620 (3.8); 7.4590 (2.3);7.2603 (278.8); 7.1921 (2.6); 7.1695 (2.6); 6.9963 (1.6); 6.9470 (1.2);6.9099 (2.1); 6.9041 (1.3); 6.8828 (1.1); 6.8776 (1.6); 6.8729 (1.1);6.7742 (1.2); 6.7522 (1.8); 6.7304 (1.1); 6.0587 (1.6); 6.0530 (1.9);6.0452 (2.7); 6.0401 (4.0); 6.0346 (4.2); 6.0249 (4.4); 6.0213 (5.3);6.0180 (4.2); 6.0145 (4.0); 6.0077 (2.6); 6.0047 (2.5); 6.0012 (2.3);5.9811 (2.2); 5.9755 (3.8); 5.9699 (2.3); 5.9617 (2.4); 5.9562 (1.4);5.9334 (1.6); 5.9277 (3.0); 5.9220 (1.9); 5.9138 (4.5); 5.9082 (5.1);5.9026 (2.5); 5.8945 (3.1); 5.8888 (1.8); 5.8777 (1.7); 5.8719 (3.1);5.8660 (1.9); 5.8579 (2.7); 5.8522 (1.4); 5.1556 (1.5); 5.1501 (1.4);5.1449 (1.2); 5.1244 (1.3); 5.1032 (2.2); 5.0860 (2.1); 4.7178 (0.6);4.7084 (1.0); 4.6986 (1.3); 4.6886 (1.4); 4.6783 (1.4); 4.6690 (1.0);4.6589 (0.6); 4.5786 (1.3); 4.5734 (2.8); 4.5669 (2.0); 4.5578 (4.1);4.5522 (9.7); 4.5461 (6.6); 4.5368 (4.4); 4.5311 (12.9); 4.5253 (9.5);4.5101 (8.2); 4.5053 (9.9); 4.4928 (7.7); 4.4892 (2.9); 4.4839 (6.6);4.4719 (7.5); 4.4626 (2.0); 4.4509 (2.5); 4.0532 (2.4); 4.0475 (2.8);4.0332 (5.8); 4.0080 (3.4); 4.0018 (3.9); 3.9881 (8.3); 3.9064 (1.0);3.9003 (1.3); 3.8941 (1.5); 3.8847 (2.0); 3.8786 (2.5); 3.8727 (2.4);3.8667 (1.8); 3.8571 (1.4); 3.8513 (1.3); 3.8455 (0.9); 3.7906 (4.6);3.7851 (13.1); 3.7796 (8.0); 3.7721 (7.8); 3.7453 (3.3); 3.7398 (9.6);3.7344 (5.6); 3.7270 (5.7); 3.6504 (2.4); 3.1213 (1.0); 3.1106 (1.2);3.1014 (1.1); 3.0908 (1.0); 3.0687 (1.1); 3.0509 (1.3); 3.0112 (0.5);2.7935 (1.2); 2.7811 (1.3); 2.7730 (1.4); 2.7605 (1.5); 2.7578 (1.7);2.7460 (2.2); 2.7372 (1.8); 2.7254 (2.2); 2.7143 (1.4); 2.7112 (1.4);2.6997 (1.3); 2.6906 (1.2); 2.6787 (1.3); 2.6499 (1.4); 2.6289 (2.7);2.6144 (1.9); 2.6078 (2.1); 2.5932 (3.4); 2.5724 (2.1); 2.5597 (1.5);2.5537 (3.8); 2.5390 (2.5); 2.5326 (2.1); 2.5181 (3.4); 2.4972 (2.4);2.4490 (0.6); 2.0437 (1.5); 2.0350 (2.8); 2.0304 (1.9); 2.0268 (1.7);2.0195 (1.5); 2.0080 (3.6); 1.9983 (5.6); 1.9905 (2.8); 1.9840 (1.5);1.9723 (2.1); 1.9629 (4.0); 1.9540 (1.7); 1.9415 (1.2); 1.9294 (1.6);1.9164 (1.2); 1.9062 (1.0); 1.8944 (1.1); 1.5410 (15.3); 1.2569 (0.7);0.1462 (0.7); 0.0080 (5.0); −0.0002 (157.1); −0.0084 (5.9); −0.1498(0.6) I-101: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.2622 (7.1); 7.1906 (1.4);7.1849 (1.8); 7.1815 (1.4); 7.1742 (1.5); 7.1708 (2.0); 7.1650 (1.7);7.1586 (0.7); 7.1559 (0.8); 7.1530 (0.7); 6.8969 (0.6); 6.8811 (0.6);6.8753 (1.1); 6.8694 (0.6); 6.8536 (0.5); 6.2000 (1.1); 6.1732 (1.2);6.1569 (1.2); 6.1301 (1.3); 5.9816 (0.6); 5.9778 (0.6); 5.9755 (0.6);5.9716 (0.6); 5.9678 (0.7); 5.9640 (0.8); 5.9617 (0.7); 5.9578 (0.6);5.8813 (0.8); 5.8758 (1.3); 5.8702 (0.8); 5.8678 (0.6); 5.8620 (1.0);5.8564 (0.6); 5.5499 (1.7); 5.5483 (2.0); 5.5068 (1.5); 5.5051 (1.7);5.3374 (1.5); 5.3362 (1.6); 5.3106 (1.5); 5.3094 (1.5); 5.2991 (5.9);4.2956 (1.0); 4.2838 (2.0); 4.2714 (1.9); 4.2607 (1.0); 3.9374 (1.9);3.8945 (2.2); 3.6202 (1.4); 3.6187 (1.4); 3.6072 (2.6); 3.5967 (1.2);3.5949 (1.3); 3.5890 (0.5); 3.5770 (1.0); 3.5652 (0.7); 3.3817 (16.0);3.3724 (3.3); 3.3305 (0.6); 3.3257 (1.9); 3.2828 (1.7); 2.5078 (0.8);2.4939 (0.6); 2.4729 (0.9); 1.9218 (0.6); 1.9120 (0.9); 1.8770 (0.8);1.5856 (1.0); −0.0002 (9.2) I-102: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.2621(14.9); 7.2022 (0.6); 7.1963 (0.6); 7.1899 (2.8); 7.1842 (3.5); 7.1812(2.8); 7.1732 (2.6); 7.1701 (3.6); 7.1644 (3.2); 7.1578 (1.5); 7.1523(1.0); 6.9024 (0.6); 6.8964 (1.3); 6.8904 (0.9); 6.8806 (1.3); 6.8748(2.2); 6.8689 (1.2); 6.8589 (0.7); 6.8531 (1.0); 6.8473 (0.5); 6.2000(2.2); 6.1945 (0.5); 6.1732 (2.4); 6.1677 (0.6); 6.1569 (2.6); 6.1513(0.6); 6.1301 (2.6); 6.1246 (0.6); 5.9804 (1.1); 5.9767 (1.2); 5.9742(1.1); 5.9703 (1.1); 5.9666 (1.3); 5.9628 (1.4); 5.9604 (1.4); 5.9565(1.3); 5.8775 (1.4); 5.8720 (2.5); 5.8663 (1.4); 5.8638 (1.2); 5.8581(1.9); 5.8526 (1.2); 5.8470 (0.5); 5.5496 (3.5); 5.5480 (4.0); 5.5065(3.1); 5.5048 (3.5); 5.3493 (0.8); 5.3364 (3.0); 5.3350 (3.0); 5.3226(0.7); 5.3096 (2.9); 5.3081 (2.9); 5.2989 (12.7); 5.0457 (0.5); 5.0364(0.5); 5.0280 (0.8); 5.0240 (0.8); 4.2886 (2.0); 4.2832 (2.1); 4.2783(2.4); 4.2762 (2.6); 4.2716 (2.5); 4.2692 (2.3); 4.2641 (2.1); 4.2593(2.1); 4.2405 (0.8); 4.2304 (0.6); 3.9481 (0.8); 3.9365 (3.9); 3.9050(0.9); 3.8936 (4.4); 3.6560 (2.9); 3.6517 (1.0); 3.6435 (6.9); 3.6355(1.0); 3.6321 (2.5); 3.6306 (2.5); 3.6254 (1.0); 3.6132 (1.0); 3.6012(0.8); 3.5764 (0.6); 3.5724 (0.7); 3.5663 (0.8); 3.5608 (0.8); 3.5531(2.8); 3.5424 (1.2); 3.5356 (7.0); 3.5250 (1.7); 3.5181 (7.1); 3.5075(1.6); 3.5006 (2.4); 3.4900 (0.6); 3.3309 (0.9); 3.3252 (3.7); 3.2877(0.8); 3.2822 (3.3); 2.5265 (0.8); 2.5054 (1.6); 2.4915 (1.1); 2.4844(1.0); 2.4705 (1.8); 2.4495 (0.9); 2.0700 (0.6); 2.0433 (0.7); 1.9205(1.0); 1.9105 (1.6); 1.9006 (0.9); 1.8855 (0.8); 1.8757 (1.5); 1.8657(1.0); 1.5838 (2.3); 1.2585 (0.9); 1.2203 (8.0); 1.2028 (16.0); 1.1853(7.7); 0.0079 (0.6); −0.0002 (18.4); −0.0085 (0.6) I-103: ¹H-NMR(400.0MHz, CDCl3): δ = 7.2640 (5.3); 7.1638 (1.7); 7.1574 (1.6); 7.1464 (1.6);7.0361 (0.6); 7.0153 (0.6); 6.8866 (0.6); 6.8704 (0.8); 6.8650 (1.0);6.8596 (0.6); 5.9366 (1.0); 5.9314 (1.0); 5.9124 (0.6); 5.8707 (0.7);5.7794 (0.6); 5.7726 (0.6); 5.7657 (0.5); 3.8291 (1.2); 3.7858 (1.5);3.4165 (0.7); 3.3440 (1.1); 3.3365 (0.9); 3.3007 (1.0); 3.2931 (0.8);1.6172 (1.2); 1.5523 (0.6); 1.5457 (0.6); 1.5377 (0.8); 1.5328 (0.8);1.5247 (0.6); 1.5187 (0.6); 1.4986 (0.6); 1.4785 (14.8); 1.4529 (7.4);1.4457 (16.0); 1.4352 (1.0); 1.4280 (1.8); 0.5636 (1.2); 0.5438 (1.5);0.5295 (0.9); 0.5162 (0.6); 0.4855 (0.5); 0.4792 (0.6); 0.4667 (0.7);0.4551 (0.6); −0.0002 (2.8) I-104: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.4391(0.6); 7.4177 (0.7); 7.3837 (0.7); 7.3709 (0.6); 7.3650 (0.8); 7.3622(0.8); 7.2635 (21.8); 7.2072 (0.5); 7.2005 (2.6); 7.1947 (3.1); 7.1913(2.0); 7.1882 (3.1); 7.1843 (3.5); 7.1816 (4.6); 7.1795 (3.6); 7.1756(3.2); 7.1736 (2.1); 7.1724 (2.1); 7.1691 (3.3); 7.1663 (2.6); 7.1633(2.8); 7.1564 (0.7); 7.1504 (0.5); 6.9806 (0.7); 6.9784 (0.8); 6.9748(1.3); 6.9726 (1.3); 6.9691 (0.8); 6.9669 (0.7); 6.9590 (1.5); 6.9569(1.6); 6.9533 (2.6); 6.9511 (2.6); 6.9475 (1.5); 6.9454 (1.4); 6.9375(0.9); 6.9353 (1.0); 6.9317 (1.4); 6.9296 (1.4); 6.9260 (0.8); 6.9238(0.7); 6.0464 (0.8); 6.0435 (0.9); 6.0397 (1.0); 6.0369 (1.0); 6.0326(1.3); 6.0298 (1.4); 6.0259 (1.4); 6.0232 (1.4); 6.0099 (1.0); 6.0069(1.1); 6.0031 (1.1); 6.0004 (1.2); 5.9962 (1.3); 5.9932 (1.3); 5.9895(1.3); 5.9866 (1.3); 5.9791 (1.3); 5.9736 (2.1); 5.9681 (1.3); 5.9656(1.0); 5.9599 (1.5); 5.9545 (0.9); 5.8700 (1.1); 5.8645 (1.8); 5.8589(1.2); 5.8564 (1.1); 5.8507 (1.6); 5.8453 (1.0); 5.2995 (13.1); 5.0582(1.1); 5.0521 (1.0); 5.0474 (0.8); 5.0410 (0.8); 5.0361 (1.0); 5.0300(1.2); 5.0082 (0.5); 4.2443 (1.2); 4.2412 (1.2); 4.2264 (3.9); 4.2233(3.8); 4.2085 (4.0); 4.2055 (3.9); 4.2006 (2.6); 4.1963 (0.6); 4.1906(1.5); 4.1877 (1.5); 4.1827 (7.3); 4.1649 (7.4); 4.1470 (2.4); 4.1149(2.6); 4.0965 (2.5); 4.0711 (5.7); 4.0527 (5.7); 4.0075 (5.6); 3.9945(5.7); 3.9636 (2.6); 3.9506 (2.5); 3.5605 (1.0); 3.5540 (1.0); 3.5467(1.1); 3.5396 (1.9); 3.5341 (2.0); 3.5271 (1.2); 3.5199 (1.2); 3.5134(1.1); 2.5295 (0.8); 2.5087 (1.5); 2.4940 (1.0); 2.4879 (0.9); 2.4732(1.8); 2.4524 (0.9); 2.4482 (0.9); 2.4275 (1.6); 2.4128 (1.0); 2.4069(0.9); 2.3922 (1.8); 2.3715 (0.9); 2.0828 (0.8); 2.0762 (1.5); 2.0696(0.9); 2.0473 (0.7); 2.0407 (1.3); 2.0341 (0.8); 1.9800 (0.8); 1.9735(1.6); 1.9670 (0.9); 1.9446 (0.7); 1.9382 (1.4); 1.9317 (0.8); 1.6059(0.8); 1.3259 (7.6); 1.3175 (1.2); 1.3081 (15.8); 1.2995 (1.2); 1.2950(8.1); 1.2902 (8.0); 1.2772 (16.0); 1.2593 (7.7); −0.0002 (12.4);−0.0085 (0.5) I-105: ¹H-NMR(400.0 MHz, CDCl3): δ = 8.0165 (1.0); 7.4105(0.7); 7.4062 (0.8); 7.4039 (0.6); 7.3913 (1.0); 7.3886 (1.0); 7.3864(1.5); 7.3824 (2.5); 7.3799 (2.1); 7.3782 (2.1); 7.3756 (1.8); 7.3700(0.8); 7.3675 (1.2); 7.2613 (12.9); 7.1370 (0.5); 7.1297 (0.6); 7.1218(0.6); 5.9732 (0.5); 5.9694 (0.6); 5.9672 (0.6); 5.9633 (0.6); 5.9594(0.8); 5.9555 (0.8); 5.9533 (0.8); 5.9495 (0.7); 5.9011 (0.7); 5.8956(1.3); 5.8900 (0.8); 5.8874 (0.6); 5.8818 (0.9); 5.8762 (0.5); 5.2998(2.1); 3.8248 (2.0); 3.7816 (2.3); 3.7244 (16.0); 3.4961 (0.7); 3.2356(2.2); 3.1924 (1.9); 2.4995 (0.9); 2.4855 (0.6); 2.4784 (0.5); 2.4645(1.0); 2.4435 (0.5); 1.8767 (0.9); 1.8418 (0.8); 1.7150 (11.6); 0.0080(0.6); −0.0002 (14.9); −0.0084 (0.6) I-106: ¹H-NMR(400.0 MHz, CDCl3): δ= 7.4007 (0.6); 7.3973 (0.8); 7.3934 (0.9); 7.3908 (0.8); 7.3875 (0.9);7.3791 (1.1); 7.3753 (3.8); 7.3718 (2.2); 7.3692 (1.8); 7.3622 (1.4);7.2620 (6.3); 7.1237 (0.6); 7.1168 (0.5); 5.9460 (0.5); 5.9420 (0.6);5.9398 (0.6); 5.9358 (0.6); 5.9322 (0.7); 5.9282 (0.8); 5.9260 (0.7);5.9220 (0.6); 5.8108 (0.6); 5.8052 (1.2); 5.7995 (0.7); 5.7971 (0.6);5.7914 (1.0); 5.7857 (0.6); 3.8270 (2.0); 3.7838 (2.3); 3.7533 (16.0);3.2238 (2.1); 3.1806 (1.9); 2.5612 (0.8); 2.5474 (0.6); 2.5401 (0.5);2.5263 (0.9); 1.9630 (0.8); 1.9281 (0.7); 1.7246 (11.4); −0.0002 (6.2)I-107: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.5191 (0.9); 7.2602 (154.7);7.1916 (1.4); 7.1859 (2.2); 7.1798 (1.6); 7.1733 (7.3); 7.1677 (8.6);7.1566 (5.1); 7.1534 (8.3); 7.1478 (6.9); 7.1413 (1.4); 7.1356 (1.3);7.1297 (0.6); 6.9961 (2.8); 6.9719 (2.3); 6.9009 (1.8); 6.8951 (3.2);6.8893 (1.8); 6.8792 (3.5); 6.8734 (6.0); 6.8676 (3.2); 6.8575 (1.8);6.8516 (3.0); 6.8459 (1.6); 5.9818 (2.1); 5.9782 (2.2); 5.9680 (4.6);5.9643 (5.9); 5.9625 (6.2); 5.9595 (6.1); 5.9540 (6.0); 5.9494 (9.2);5.9443 (4.6); 5.9403 (1.6); 5.9355 (3.2); 5.9304 (2.1); 5.0737 (1.2);5.0683 (1.3); 5.0521 (2.2); 5.0465 (2.1); 5.0358 (1.2); 5.0309 (1.2);5.0258 (1.1); 4.5334 (5.2); 4.5125 (15.7); 4.4915 (16.0); 4.4705 (5.4);3.9927 (1.2); 3.8632 (1.3); 3.8202 (12.6); 3.8171 (10.7); 3.7738 (11.4);3.6374 (1.8); 3.6338 (2.0); 3.6283 (2.2); 3.6263 (2.1); 3.6226 (2.3);3.6174 (2.3); 3.6123 (2.2); 3.6069 (2.1); 3.6014 (1.9); 3.3514 (10.3);3.3081 (8.7); 3.1802 (1.4); 3.1377 (1.6); 2.5925 (2.5); 2.5715 (4.5);2.5574 (3.1); 2.5504 (2.8); 2.5364 (5.0); 2.5153 (2.6); 2.3285 (1.8);1.9278 (2.5); 1.9172 (4.4); 1.9066 (2.4); 1.8927 (2.3); 1.8821 (4.1);1.8715 (2.3); 1.7286 (8.0); 1.5723 (2.0); 1.5589 (4.0); 1.5515 (4.3);1.5453 (3.2); 1.5380 (6.2); 1.5309 (2.4); 1.5247 (3.4); 1.5171 (3.2);1.5037 (1.6); 1.2568 (1.5); 0.6763 (1.0); 0.6700 (1.3); 0.6664 (1.6);0.6632 (1.4); 0.6603 (1.9); 0.6560 (2.5); 0.6528 (1.8); 0.6463 (2.7);0.6424 (3.4); 0.6330 (3.4); 0.6290 (2.0); 0.6197 (2.1); 0.5994 (1.3);0.5904 (1.3); 0.5782 (3.3); 0.5687 (3.3); 0.5648 (2.6); 0.5579 (4.2);0.5538 (3.3); 0.5478 (4.2); 0.5437 (4.4); 0.5375 (3.1); 0.5335 (4.2);0.5261 (2.5); 0.5223 (3.4); 0.5127 (3.3); 0.5007 (1.2); 0.4915 (1.5);0.4834 (2.4); 0.4744 (2.1); 0.4702 (3.7); 0.4611 (3.2); 0.4566 (2.7);0.4506 (1.8); 0.4471 (2.3); 0.4433 (1.9); 0.4404 (1.5); 0.4371 (1.6);0.4331 (1.3); 0.4267 (1.0); 0.0079 (3.1); −0.0002 (88.0); −0.0084 (3.3)I-108: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.5192 (1.2); 7.2603 (209.4);7.2095 (0.5); 7.1918 (1.3); 7.1860 (1.9); 7.1783 (2.2); 7.1723 (3.7);7.1661 (10.3); 7.1603 (10.6); 7.1572 (7.2); 7.1492 (7.0); 7.1462 (10.6);7.1405 (8.4); 7.1282 (1.5); 7.1224 (0.6); 6.9962 (1.9); 6.9733 (3.2);6.9519 (2.9); 6.8990 (2.4); 6.8932 (3.9); 6.8875 (2.3); 6.8773 (4.6);6.8715 (7.6); 6.8658 (4.0); 6.8555 (2.3); 6.8497 (3.8); 6.8440 (1.9);5.9645 (4.6); 5.9590 (5.1); 5.9542 (5.0); 5.9505 (5.7); 5.9468 (5.8);5.9446 (6.1); 5.9406 (4.8); 5.8712 (4.5); 5.8656 (8.4); 5.8598 (5.0);5.8576 (4.2); 5.8517 (6.4); 5.8461 (3.5); 5.0903 (1.5); 5.0868 (1.7);5.0688 (2.9); 5.0476 (2.0); 5.0438 (1.9); 4.5761 (0.6); 4.5653 (3.9);4.5628 (4.1); 4.5552 (0.9); 4.5444 (11.9); 4.5418 (12.3); 4.5336 (1.9);4.5234 (12.3); 4.5208 (12.4); 4.5125 (4.1); 4.5024 (4.3); 4.4998 (4.2);4.4916 (3.9); 4.4706 (1.3); 3.9928 (1.3); 3.8632 (1.8); 3.8244 (12.9);3.8203 (16.0); 3.7811 (14.1); 3.7738 (3.2); 3.6573 (2.0); 3.6526 (2.4);3.6469 (2.6); 3.6432 (2.8); 3.6358 (3.0); 3.6324 (3.1); 3.6265 (3.0);3.6220 (2.6); 3.3513 (2.9); 3.3447 (12.6); 3.3080 (2.4); 3.3012 (10.7);3.1803 (1.8); 3.1378 (2.0); 2.6637 (3.0); 2.6426 (5.3); 2.6286 (3.8);2.6214 (3.4); 2.6074 (5.8); 2.5863 (3.1); 2.5715 (1.1); 2.5576 (0.8);2.5504 (0.7); 2.5364 (1.1); 2.5155 (0.6); 2.3284 (1.0); 1.9877 (3.0);1.9775 (5.4); 1.9673 (3.0); 1.9526 (2.8); 1.9424 (4.8); 1.9321 (2.8);1.9171 (1.1); 1.9065 (0.6); 1.8927 (0.5); 1.8821 (1.0); 1.8715 (0.5);1.7930 (0.6); 1.7286 (10.6); 1.5711 (2.3); 1.5577 (5.8); 1.5502 (7.8);1.5448 (6.0); 1.5369 (8.6); 1.5298 (3.2); 1.5236 (4.4); 1.5161 (4.1);1.5027 (2.1); 1.2571 (1.4); 0.7131 (1.5); 0.7103 (1.8); 0.7066 (2.1);0.7002 (1.7); 0.6955 (2.8); 0.6860 (2.4); 0.6824 (3.8); 0.6734 (3.5);0.6694 (2.8); 0.6606 (2.5); 0.6461 (0.7); 0.6424 (0.8); 0.6329 (0.9);0.6195 (0.6); 0.6078 (1.2); 0.5996 (1.3); 0.5863 (3.6); 0.5779 (4.6);0.5709 (5.2); 0.5685 (5.9); 0.5655 (6.7); 0.5623 (4.5); 0.5574 (4.4);0.5528 (6.7); 0.5480 (6.0); 0.5443 (4.5); 0.5412 (4.6); 0.5317 (4.5);0.5192 (1.5); 0.5104 (2.0); 0.5042 (2.6); 0.4960 (2.6); 0.4911 (3.9);0.4831 (4.1); 0.4781 (2.1); 0.4703 (3.5); 0.4610 (2.6); 0.4584 (2.5);0.4546 (2.1); 0.0080 (3.8); −0.0002 (120.1); −0.0085 (4.8) I-109:¹H-NMR(400.0 MHz, CDCl3): δ = 7.5187 (1.3); 7.2599 (220.2); 7.1652(8.4); 7.1597 (10.6); 7.1454 (10.1); 7.1401 (8.1); 6.9957 (1.3); 6.9122(2.1); 6.9064 (3.4); 6.9006 (2.4); 6.8905 (4.2); 6.8848 (6.3); 6.8790(3.7); 6.8689 (2.3); 6.8631 (3.3); 6.8579 (1.9); 6.6755 (3.4); 6.6559(3.4); 5.9910 (3.1); 5.9862 (4.4); 5.9773 (5.0); 5.9721 (6.4); 5.9672(4.7); 5.9217 (4.3); 5.9162 (7.4); 5.9104 (4.8); 5.9023 (5.1); 5.8968(2.9); 5.1464 (2.8); 5.1414 (3.2); 5.1358 (3.0); 5.1310 (2.8); 4.5339(0.9); 4.5021 (5.6); 4.4811 (15.8); 4.4601 (16.0); 4.4392 (5.5); 3.9925(0.6); 3.8478 (2.5); 3.8420 (3.3); 3.8360 (3.7); 3.8302 (4.1); 3.8223(11.7); 3.8141 (4.3); 3.8084 (2.8); 3.7788 (11.2); 3.3591 (10.6); 3.3156(8.8); 2.7020 (2.6); 2.6903 (2.6); 2.6814 (2.9); 2.6668 (3.9); 2.6547(3.1); 2.6459 (3.0); 2.6340 (2.8); 1.9156 (2.8); 1.9041 (2.8); 1.8934(3.0); 1.8809 (4.5); 1.8686 (2.8); 1.8580 (2.6); 1.8467 (2.6); 1.7951(0.7); 1.5834 (1.7); 1.5700 (3.5); 1.5626 (4.4); 1.5488 (9.6); 1.5363(10.2); 1.5287 (6.8); 1.5148 (3.0); 1.3555 (0.8); 1.2563 (4.5); 0.8559(1.3); 0.6571 (2.6); 0.6513 (3.0); 0.6430 (3.1); 0.6380 (3.8); 0.6296(4.0); 0.6163 (4.2); 0.5960 (3.8); 0.5864 (4.3); 0.5828 (3.9); 0.5754(5.5); 0.5658 (5.3); 0.5622 (5.6); 0.5533 (5.3); 0.5416 (4.2); 0.5327(3.6); 0.5200 (1.6); 0.5109 (1.6); 0.4802 (2.3); 0.4679 (4.0); 0.4583(3.8); 0.4445 (3.2); 0.1457 (0.5); −0.0002 (123.7); −0.1496 (0.7) I-110:¹H-NMR(400.0 MHz, CDCl3): δ = 7.5189 (1.6); 7.2600 (266.5); 7.1632(10.7); 7.1578 (12.5); 7.1436 (12.1); 6.9960 (1.5); 6.9042 (4.0); 6.8881(5.2); 6.8823 (7.4); 6.8768 (4.8); 6.8607 (4.0); 6.6874 (3.4); 6.6659(3.5); 5.9836 (3.8); 5.9781 (5.2); 5.9732 (4.9); 5.9698 (5.1); 5.9646(5.8); 5.9595 (4.2); 5.9164 (1.2); 5.9025 (0.9); 5.8636 (3.8); 5.8580(6.6); 5.8518 (4.8); 5.8441 (5.5); 5.8383 (3.0); 5.1300 (3.0); 5.1246(3.2); 5.1187 (3.1); 5.1139 (2.9); 4.6432 (0.8); 4.6222 (0.7); 4.5740(0.7); 4.5524 (1.8); 4.5315 (2.2); 4.5178 (5.5); 4.4969 (15.7); 4.4759(16.0); 4.4602 (3.6); 4.4550 (5.7); 4.4394 (1.1); 3.9929 (0.6); 3.8754(2.2); 3.8696 (3.1); 3.8634 (3.5); 3.8573 (3.4); 3.8533 (3.3); 3.8477(3.8); 3.8416 (3.7); 3.8355 (3.3); 3.8188 (10.2); 3.7752 (11.2); 3.3613(11.4); 3.3177 (9.5); 3.1367 (0.8); 2.7602 (2.4); 2.7479 (2.6); 2.7396(2.8); 2.7251 (3.8); 2.7124 (3.1); 2.7044 (3.2); 2.6922 (2.9); 2.6667(0.8); 2.6337 (0.6); 1.9844 (2.6); 1.9732 (2.8); 1.9623 (2.9); 1.9502(4.0); 1.9380 (2.6); 1.9270 (2.6); 1.9159 (2.9); 1.8932 (0.6); 1.8814(0.8); 1.8686 (0.7); 1.7944 (0.9); 1.5864 (2.5); 1.5729 (4.8); 1.5655(5.9); 1.5521 (9.8); 1.5388 (7.9); 1.5313 (6.7); 1.5181 (3.8); 1.3552(1.0); 1.2572 (4.1); 0.8800 (1.3); 0.6618 (2.8); 0.6576 (3.3); 0.6511(3.8); 0.6436 (3.7); 0.6378 (4.5); 0.6298 (4.8); 0.6247 (3.6); 0.6162(4.5); 0.5993 (4.8); 0.5898 (5.4); 0.5777 (7.0); 0.5666 (6.4); 0.5597(6.9); 0.5466 (4.9); 0.5382 (3.8); 0.5258 (2.0); 0.5167 (1.9); 0.4836(2.5); 0.4714 (4.3); 0.4621 (4.2); 0.4582 (3.9); 0.4484 (3.5); 0.4433(3.5); 0.1465 (0.6); −0.0002 (152.4); −0.1504 (0.8) I-111: ¹H-NMR(400.0MHz, CDCl3): δ = 7.3618 (1.1); 7.3505 (1.3); 7.3409 (1.3); 7.3296 (1.2);7.2610 (24.9); 7.1999 (0.6); 7.1941 (0.6); 7.1873 (3.2); 7.1817 (4.6);7.1784 (3.2); 7.1710 (5.0); 7.1675 (5.9); 7.1653 (6.0); 7.1621 (5.6);7.1556 (2.6); 7.1513 (3.4); 7.1456 (2.7); 7.1389 (0.6); 7.1332 (0.6);6.9280 (0.6); 6.9118 (2.0); 6.9099 (2.1); 6.9062 (2.6); 6.9004 (1.7);6.8940 (2.0); 6.8900 (2.8); 6.8883 (3.2); 6.8844 (3.4); 6.8787 (1.6);6.8723 (0.9); 6.8666 (1.4); 6.8627 (1.5); 6.8570 (0.7); 6.0459 (0.6);6.0423 (1.4); 6.0388 (1.7); 6.0361 (1.7); 6.0323 (2.0); 6.0257 (3.0);6.0223 (3.2); 6.0193 (2.9); 6.0125 (1.5); 6.0085 (1.5); 6.0060 (1.4);6.0022 (1.3); 5.9412 (1.3); 5.9356 (2.4); 5.9299 (1.4); 5.9276 (1.2);5.9218 (1.9); 5.9162 (1.1); 5.8992 (0.8); 5.8853 (0.6); 5.8770 (1.3);5.8713 (2.3); 5.8656 (1.4); 5.8634 (1.2); 5.8575 (1.9); 5.8519 (1.1);5.8396 (0.7); 5.8257 (0.7); 5.0351 (1.2); 5.0269 (1.2); 5.0222 (1.2);4.1500 (1.1); 4.1321 (3.4); 4.1143 (3.4); 4.0964 (1.2); 4.0609 (1.0);4.0420 (3.1); 4.0308 (1.9); 4.0281 (2.9); 4.0203 (0.6); 4.0119 (5.7);3.9980 (5.8); 3.9556 (6.6); 3.9537 (6.4); 3.9468 (1.8); 3.9389 (1.7);3.9255 (3.2); 3.9235 (3.2); 3.9167 (1.0); 3.9089 (1.1); 3.8006 (0.6);3.7945 (0.6); 3.7885 (0.6); 3.7437 (1.0); 3.7407 (1.0); 3.7097 (3.3);3.7073 (3.3); 3.6994 (1.6); 3.6965 (1.6); 3.6657 (5.6); 3.6632 (5.5);3.6086 (0.8); 3.6056 (0.8); 3.6021 (1.1); 3.5993 (1.2); 3.5964 (1.4);3.5935 (1.5); 3.5899 (1.5); 3.5870 (1.6); 3.5841 (1.5); 3.5807 (1.6);3.5778 (1.5); 3.5747 (1.2); 3.5718 (1.3); 3.5631 (5.4); 3.5511 (4.4);3.5372 (1.3); 3.5190 (2.8); 3.5070 (2.6); 3.4928 (0.9); 2.6095 (0.7);2.5884 (1.4); 2.5742 (1.1); 2.5673 (1.0); 2.5531 (1.6); 2.5370 (1.0);2.5322 (1.0); 2.5160 (1.6); 2.5018 (1.1); 2.4950 (1.0); 2.4809 (1.7);2.4599 (0.9); 2.0596 (0.9); 2.0454 (16.0); 2.0244 (0.7); 2.0150 (1.3);2.0055 (0.8); 1.9614 (0.9); 1.9568 (0.6); 1.9520 (1.6); 1.9426 (0.9);1.9262 (0.7); 1.9168 (1.4); 1.9075 (0.8); 1.2769 (4.5); 1.2590 (9.2);1.2411 (4.4); 0.0079 (1.0); −0.0002 (32.7); −0.0085 (1.1) I-112:¹H-NMR(400.0 MHz, CDCl3): δ = 7.5190 (1.3); 7.2601 (235.5); 7.1923(0.7); 7.1868 (1.5); 7.1745 (7.1); 7.1688 (8.6); 7.1658 (5.3); 7.1577(5.4); 7.1546 (8.6); 7.1489 (7.1); 7.1367 (1.4); 7.1310 (0.6); 7.0601(2.4); 7.0381 (2.4); 6.9961 (1.4); 6.8987 (1.8); 6.8929 (3.1); 6.8870(1.7); 6.8770 (3.5); 6.8712 (6.0); 6.8654 (3.1); 6.8553 (1.9); 6.8494(3.0); 6.8437 (1.4); 5.9916 (2.8); 5.9879 (3.1); 5.9855 (3.2); 5.9817(2.9); 5.9778 (4.2); 5.9741 (4.8); 5.9717 (4.7); 5.9680 (4.1); 5.9295(4.0); 5.9240 (7.4); 5.9185 (4.4); 5.9159 (3.2); 5.9102 (5.0); 5.9046(2.8); 5.0734 (1.4); 5.0700 (1.4); 5.0482 (2.4); 5.0303 (1.4); 5.0269(1.3); 4.3876 (7.5); 4.3856 (7.7); 4.3742 (12.7); 4.3713 (10.6); 4.3703(10.6); 4.3588 (8.9); 4.3577 (9.0); 3.8230 (10.2); 3.7797 (11.9); 3.7164(14.1); 3.7019 (16.0); 3.6881 (12.3); 3.5720 (2.3); 3.5692 (2.2); 3.5663(2.3); 3.5633 (2.3); 3.5606 (2.2); 3.5569 (2.3); 3.3467 (10.7); 3.3033(9.0); 2.5475 (2.5); 2.5263 (4.7); 2.5124 (3.2); 2.5052 (2.8); 2.4913(5.2); 2.4701 (2.6); 1.9268 (2.6); 1.9171 (4.6); 1.9075 (2.5); 1.8919(2.2); 1.8821 (4.2); 1.8723 (2.4); 1.7287 (0.5); 1.5730 (1.4); 1.5596(3.3); 1.5518 (4.9); 1.5439 (15.2); 1.5390 (10.2); 1.5317 (3.0); 1.5254(3.4); 1.5178 (3.1); 1.5045 (1.5); 1.2565 (1.4); 1.2007 (0.7); 0.8806(0.5); 0.6792 (1.1); 0.6735 (1.4); 0.6698 (1.8); 0.6646 (1.9); 0.6592(2.6); 0.6563 (1.9); 0.6499 (2.6); 0.6458 (3.5); 0.6364 (3.4); 0.6325(2.1); 0.6233 (2.1); 0.5969 (1.3); 0.5881 (1.2); 0.5756 (3.2); 0.5663(3.4); 0.5624 (2.8); 0.5565 (3.9); 0.5546 (4.2); 0.5459 (4.1); 0.5436(3.9); 0.5340 (4.2); 0.5258 (2.6); 0.5224 (3.6); 0.5127 (3.4); 0.5005(1.2); 0.4914 (1.5); 0.4825 (2.2); 0.4735 (2.2); 0.4693 (3.6); 0.4603(3.2); 0.4555 (2.4); 0.4467 (2.3); 0.4415 (2.2); 0.4362 (1.7); 0.4324(1.4); 0.4266 (1.0); 0.0080 (4.4); −0.0002 (135.2); −0.0084 (6.0) I-113:¹H-NMR(400.0 MHz, CDCl3): δ = 7.5191 (0.8); 7.2602 (140.6); 7.1782(1.1); 7.1658 (5.3); 7.1603 (6.6); 7.1490 (4.3); 7.1459 (6.5); 7.1403(5.3); 7.1283 (1.0); 7.0508 (2.0); 7.0296 (2.0); 6.9962 (0.9); 6.8968(1.3); 6.8911 (2.3); 6.8852 (1.2); 6.8751 (2.7); 6.8693 (4.4); 6.8636(2.3); 6.8534 (1.4); 6.8475 (2.2); 6.8418 (1.1); 5.9697 (2.3); 5.9635(2.8); 5.9596 (2.7); 5.9560 (3.1); 5.9520 (3.4); 5.9498 (3.4); 5.9459(2.8); 5.8448 (2.8); 5.8391 (5.1); 5.8333 (3.3); 5.8253 (4.1); 5.8197(2.3); 5.0819 (1.2); 5.0596 (2.0); 5.0422 (1.2); 4.4345 (0.6); 4.4185(4.9); 4.4147 (5.0); 4.4045 (8.3); 4.4008 (7.9); 4.3900 (5.5); 4.3868(5.4); 4.3703 (0.6); 3.8222 (7.4); 3.7789 (8.8); 3.7449 (8.9); 3.7308(16.0); 3.7168 (7.2); 3.5925 (1.9); 3.5835 (1.8); 3.5772 (2.0); 3.3404(7.9); 3.2970 (6.7); 2.6142 (1.8); 2.5931 (3.3); 2.5792 (2.3); 2.5719(2.0); 2.5580 (3.8); 2.5368 (1.9); 1.9924 (2.0); 1.9829 (3.6); 1.9733(2.0); 1.9574 (1.8); 1.9478 (3.2); 1.9383 (1.8); 1.5763 (1.0); 1.5630(2.4); 1.5553 (3.3); 1.5446 (11.2); 1.5289 (2.8); 1.5213 (2.4); 1.5079(1.2); 1.2561 (1.0); 0.7176 (1.5); 0.7137 (1.7); 0.7021 (2.1); 0.6897(2.4); 0.6806 (2.1); 0.6769 (1.7); 0.6683 (1.4); 0.6059 (0.7); 0.5986(0.6); 0.5845 (2.2); 0.5765 (2.7); 0.5717 (4.4); 0.5681 (4.3); 0.5638(4.2); 0.5551 (3.6); 0.5506 (4.3); 0.5477 (3.9); 0.5429 (3.0); 0.5336(2.6); 0.5205 (0.8); 0.5123 (1.1); 0.5047 (1.6); 0.4970 (1.7); 0.4917(2.3); 0.4844 (2.3); 0.4794 (1.4); 0.4725 (2.3); 0.4688 (2.0); 0.4598(1.7); 0.4551 (1.6); 0.0079 (3.2); −0.0002 (80.0); −0.0084 (3.8) I-114:¹H-NMR(400.0 MHz, CDCl3): δ = 7.5188 (2.0); 7.2714 (1.3); 7.2599(375.1); 7.1816 (0.7); 7.1759 (1.4); 7.1634 (6.8); 7.1604 (5.4); 7.1577(8.0); 7.1545 (4.8); 7.1467 (4.7); 7.1436 (8.1); 7.1379 (6.8); 7.1256(1.3); 6.9959 (2.1); 6.9080 (1.7); 6.9022 (3.0); 6.8963 (1.6); 6.8863(3.4); 6.8805 (5.9); 6.8747 (3.0); 6.8646 (1.8); 6.8588 (3.0); 6.8530(1.4); 6.6721 (2.3); 6.6528 (2.3); 5.9969 (3.4); 5.9927 (3.9); 5.9910(4.0); 5.9866 (3.6); 5.9831 (4.2); 5.9788 (4.6); 5.9771 (4.6); 5.9728(4.1); 5.8315 (3.6); 5.8257 (6.9); 5.8199 (4.1); 5.8177 (3.6); 5.8118(6.0); 5.8060 (3.3); 5.1468 (0.9); 5.1415 (1.1); 5.1361 (1.2); 5.1316(1.7); 5.1260 (2.2); 5.1212 (2.3); 5.1156 (2.3); 5.1108 (2.1); 5.1053(1.8); 5.1006 (1.2); 5.0951 (1.3); 5.0901 (0.9); 4.3679 (10.1); 4.3556(9.8); 4.3539 (12.7); 4.3514 (9.5); 4.3396 (12.8); 3.8202 (10.5); 3.8128(3.2); 3.8066 (3.1); 3.8006 (2.8); 3.7969 (2.8); 3.7909 (3.2); 3.7846(3.4); 3.7768 (12.2); 3.6988 (13.6); 3.6868 (8.4); 3.6845 (14.8); 3.6705(12.3); 3.3580 (10.0); 3.3144 (8.6); 2.7567 (2.8); 2.7443 (2.8); 2.7362(2.9); 2.7238 (3.4); 2.7216 (3.6); 2.7092 (3.3); 2.7011 (3.0); 2.6887(2.9); 1.9518 (2.8); 1.9408 (2.7); 1.9298 (2.8); 1.9187 (3.3); 1.9167(3.2); 1.9057 (2.7); 1.8946 (2.5); 1.8837 (2.6); 1.5862 (1.3); 1.5727(2.7); 1.5652 (2.8); 1.5587 (2.2); 1.5517 (6.0); 1.5384 (16.0); 1.5175(2.0); 1.3437 (0.8); 1.2565 (3.2); 0.8804 (1.1); 0.6713 (1.0); 0.6669(1.3); 0.6631 (1.6); 0.6587 (2.1); 0.6520 (2.0); 0.6445 (1.9); 0.6388(3.1); 0.6308 (2.8); 0.6255 (2.1); 0.6169 (3.5); 0.6083 (1.2); 0.5961(3.5); 0.5867 (3.3); 0.5831 (2.7); 0.5782 (3.6); 0.5752 (5.3); 0.5706(2.6); 0.5658 (4.5); 0.5623 (2.8); 0.5573 (5.0); 0.5544 (3.5); 0.5494(2.5); 0.5450 (3.2); 0.5364 (2.9); 0.5236 (1.1); 0.5150 (1.1); 0.4834(1.8); 0.4750 (2.0); 0.4709 (3.1); 0.4618 (3.1); 0.4579 (1.9); 0.4518(1.6); 0.4481 (2.1); 0.4425 (2.4); 0.4380 (1.6); 0.4339 (1.3); 0.4287(1.0); 0.1459 (0.7); 0.0080 (6.4); −0.0002 (217.6); −0.0085 (7.4);−0.1494 (0.6) I-115: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.5187 (2.1); 7.2599(364.5); 7.1787 (1.5); 7.1661 (7.2); 7.1604 (8.4); 7.1572 (5.0); 7.1494(5.0); 7.1463 (8.5); 7.1406 (6.8); 7.1341 (1.2); 7.1283 (1.3); 6.9958(2.0); 6.9110 (1.9); 6.9052 (3.2); 6.8994 (1.7); 6.8893 (3.6); 6.8835(6.0); 6.8777 (3.0); 6.8676 (1.8); 6.8618 (3.0); 6.8560 (1.5); 6.6637(2.5); 6.6423 (2.6); 6.0046 (3.3); 6.0002 (3.9); 5.9987 (3.9); 5.9943(3.6); 5.9907 (4.3); 5.9863 (5.0); 5.9847 (4.8); 5.9804 (4.2); 5.8913(3.9); 5.8856 (7.2); 5.8799 (4.2); 5.8775 (3.6); 5.8717 (5.8); 5.8660(3.1); 5.1643 (1.0); 5.1590 (1.2); 5.1531 (1.3); 5.1489 (1.8); 5.1433(2.2); 5.1381 (2.4); 5.1327 (2.4); 5.1277 (2.3); 5.1222 (1.7); 5.1180(1.3); 5.1121 (1.2); 5.1067 (0.8); 4.3518 (8.8); 4.3381 (11.7); 4.3354(9.2); 4.3236 (11.8); 3.8239 (9.8); 3.7971 (1.0); 3.7911 (2.5); 3.7850(4.0); 3.7803 (13.5); 3.7733 (3.4); 3.7691 (3.0); 3.7632 (3.4); 3.7572(3.2); 3.7512 (2.4); 3.7451 (0.9); 3.6843 (13.9); 3.6699 (15.5); 3.6560(12.4); 3.3568 (10.4); 3.3132 (8.7); 2.6997 (2.9); 2.6877 (2.8); 2.6790(3.0); 2.6669 (3.5); 2.6645 (3.7); 2.6525 (3.3); 2.6438 (3.1); 2.6318(3.0); 1.8799 (2.9); 1.8686 (2.9); 1.8578 (3.0); 1.8463 (3.8); 1.8334(2.8); 1.8226 (2.6); 1.8114 (2.6); 1.5840 (1.5); 1.5706 (3.0); 1.5631(3.3); 1.5568 (2.8); 1.5496 (7.4); 1.5382 (16.0); 1.5291 (5.8); 1.5154(2.1); 1.3438 (1.0); 1.2569 (4.1); 0.8803 (1.6); 0.6718 (1.0); 0.6662(1.4); 0.6625 (1.8); 0.6576 (2.1); 0.6517 (2.3); 0.6430 (2.6); 0.6382(3.3); 0.6297 (3.2); 0.6249 (2.2); 0.6158 (2.7); 0.6049 (1.3); 0.5927(3.6); 0.5832 (3.4); 0.5795 (2.7); 0.5719 (4.0); 0.5623 (3.6); 0.5595(4.0); 0.5522 (4.0); 0.5432 (2.5); 0.5391 (3.4); 0.5301 (3.1); 0.5176(1.3); 0.5086 (1.4); 0.4794 (2.1); 0.4708 (2.0); 0.4667 (3.4); 0.4574(3.3); 0.4531 (2.3); 0.4472 (1.8); 0.4437 (2.3); 0.4389 (2.0); 0.4337(1.6); 0.4295 (1.3); 0.4236 (1.0); 0.1459 (0.8); 0.0079 (6.8); −0.0002(216.9); −0.0085 (7.4); −0.1495 (0.7) I-116: ¹H-NMR(400.0 MHz, CDCl3): δ= 7.9415 (2.8); 7.9375 (3.6); 7.9334 (2.6); 7.9291 (2.1); 7.9251 (1.4);7.8749 (0.8); 7.8719 (1.0); 7.8673 (1.3); 7.8640 (1.1); 7.8597 (0.9);7.8517 (2.0); 7.8474 (2.0); 7.8442 (1.3); 7.8398 (1.0); 7.8364 (0.8);7.8337 (1.1); 7.8318 (1.3); 7.7280 (0.6); 7.7252 (1.2); 7.7214 (1.3);7.7180 (1.1); 7.7149 (1.6); 7.7112 (1.5); 7.7086 (1.6); 7.7058 (1.6);7.7021 (1.6); 7.6985 (1.4); 7.6955 (1.8); 7.6919 (1.7); 7.6892 (0.9);7.5647 (1.1); 7.5555 (1.8); 7.5451 (1.7); 7.5358 (2.8); 7.5254 (0.8);7.5194 (0.8); 7.5162 (1.2); 7.2606 (98.2); 7.0727 (0.7); 6.9966 (0.6);6.7955 (0.6); 6.7747 (0.6); 5.9909 (0.6); 5.9831 (1.3); 5.9786 (1.4);5.9728 (1.4); 5.9703 (1.5); 5.9654 (1.7); 5.9574 (0.7); 5.9537 (0.8);5.9480 (1.5); 5.9430 (2.0); 5.9375 (0.8); 5.9291 (0.8); 5.9234 (0.9);5.9176 (1.0); 5.9119 (0.6); 5.9037 (0.7); 5.8588 (0.7); 5.8531 (1.3);5.8474 (0.9); 5.8438 (1.2); 5.8392 (1.2); 5.8336 (0.7); 5.8297 (0.8);5.0290 (0.7); 5.0242 (0.7); 4.5696 (1.1); 4.5487 (3.5); 4.5278 (3.9);4.5162 (0.8); 4.5083 (3.8); 4.4995 (1.0); 4.4953 (2.4); 4.4874 (3.5);4.4785 (2.4); 4.4743 (2.5); 4.4665 (1.2); 4.4576 (2.3); 4.4534 (0.9);4.4366 (0.8); 3.8662 (0.6); 3.8622 (1.6); 3.8550 (2.9); 3.8507 (0.9);3.8424 (2.3); 3.8392 (0.9); 3.8333 (0.6); 3.8189 (1.8); 3.8117 (3.6);3.8055 (0.7); 3.7992 (2.5); 3.6327 (0.7); 3.6272 (0.7); 3.4900 (1.2);3.2436 (1.8); 3.2413 (1.9); 3.2375 (2.4); 3.2286 (2.1); 3.2002 (1.6);3.1979 (1.7); 3.1944 (2.1); 3.1853 (1.8); 2.6531 (0.5); 2.6319 (0.9);2.6180 (0.6); 2.6108 (0.5); 2.5968 (0.8); 2.5626 (0.8); 2.5485 (0.6);2.5415 (0.5); 2.5274 (0.9); 2.5062 (0.5); 2.0044 (0.5); 1.9904 (1.1);1.9794 (0.6); 1.9673 (0.6); 1.9556 (1.1); 1.9449 (0.6); 1.9171 (0.5);1.9065 (0.8); 1.8981 (0.6); 1.8715 (0.8); 1.8632 (0.6); 1.7374 (13.7);1.7347 (16.0); 1.7267 (12.0); 1.5523 (6.9); 0.0080 (1.8); −0.0002(55.8); −0.0085 (1.8) I-117: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.2601(29.3); 7.2136 (1.3); 7.2080 (1.6); 7.2046 (1.0); 7.1977 (1.0); 7.1942(1.6); 7.1886 (1.3); 6.9561 (0.6); 6.9402 (0.7); 6.9344 (1.1); 6.9287(0.6); 6.9129 (0.6); 6.0133 (0.5); 6.0101 (0.6); 6.0068 (0.6); 6.0035(0.6); 5.9996 (0.8); 5.9963 (0.8); 5.9931 (0.8); 5.9898 (0.7); 5.9315(0.7); 5.9260 (1.2); 5.9204 (0.8); 5.9123 (0.9); 5.9067 (0.5); 5.2986(3.3); 5.0676 (0.5); 3.9956 (1.0); 3.9505 (1.4); 3.7540 (2.6); 3.7411(16.0); 3.7090 (1.8); 3.5545 (0.6); 3.5483 (0.5); 3.5338 (0.5); 2.4731(0.9); 2.4587 (0.6); 2.4523 (0.5); 2.4379 (1.0); 2.4170 (0.5); 1.9755(0.5); 1.9675 (0.9); 1.9323 (0.8); 1.5444 (5.6); 0.0079 (0.5); −0.0002(16.1); −0.0084 (0.6) I-118: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.2607(75.3); 7.2476 (2.6); 7.2151 (0.7); 7.2092 (1.0); 7.2039 (1.2); 7.1968(3.8); 7.1911 (4.7); 7.1861 (6.7); 7.1803 (9.1); 7.1771 (9.1); 7.1713(7.1); 7.1663 (7.7); 7.1607 (7.1); 7.1564 (3.3); 7.1483 (1.5); 7.1435(0.9); 6.9356 (0.9); 6.9326 (1.4); 6.9299 (1.4); 6.9239 (1.8); 6.9177(2.5); 6.9139 (2.6); 6.9111 (3.0); 6.9082 (2.8); 6.9023 (3.3); 6.8980(3.8); 6.8963 (3.8); 6.8923 (2.8); 6.8903 (2.6); 6.8867 (1.8); 6.8807(1.9); 6.8763 (2.2); 6.8747 (2.2); 6.8704 (1.8); 6.8459 (1.1); 6.0310(1.1); 6.0267 (1.3); 6.0249 (1.4); 6.0211 (2.0); 6.0170 (2.4); 6.0111(3.3); 6.0072 (3.4); 6.0013 (3.8); 5.9975 (3.8); 5.9944 (3.3); 5.9912(3.0); 5.9876 (2.9); 5.9842 (1.9); 5.9805 (1.6); 5.9276 (1.6); 5.9220(2.9); 5.9164 (1.7); 5.9139 (1.4); 5.9082 (2.2); 5.9026 (1.3); 5.8884(1.2); 5.8827 (2.1); 5.8770 (1.3); 5.8746 (1.2); 5.8688 (1.8); 5.8631(1.1); 5.8561 (1.4); 5.8504 (2.6); 5.8447 (1.6); 5.8425 (1.4); 5.8366(2.2); 5.8306 (2.0); 5.8245 (2.0); 5.8186 (1.2); 5.8165 (1.2); 5.8105(1.7); 5.8048 (1.0); 5.1501 (0.6); 5.1447 (0.7); 5.1398 (0.9); 5.1347(1.0); 5.1290 (1.0); 5.1249 (1.0); 5.1192 (1.1); 5.1140 (1.0); 5.1088(1.0); 5.1044 (0.8); 5.0987 (0.6); 5.0938 (0.5); 5.0437 (1.6); 5.0340(1.6); 5.0130 (0.9); 4.4414 (0.7); 4.4253 (3.0); 4.4209 (3.0); 4.4114(4.5); 4.4071 (4.2); 4.3970 (3.3); 4.3931 (3.2); 4.3841 (3.2); 4.3806(3.2); 4.3705 (6.1); 4.3667 (5.8); 4.3557 (8.4); 4.3400 (5.8); 4.3272(3.4); 4.0476 (4.7); 4.0293 (2.8); 4.0206 (4.5); 4.0176 (8.9); 3.9993(4.9); 3.9907 (7.4); 3.9508 (9.3); 3.9435 (4.9); 3.9344 (4.4); 3.9215(4.7); 3.9135 (2.6); 3.9044 (2.8); 3.8270 (0.7); 3.8209 (0.9); 3.8147(1.0); 3.8085 (0.9); 3.8052 (1.1); 3.7991 (1.6); 3.7933 (1.6); 3.7875(1.4); 3.7819 (1.1); 3.7776 (1.1); 3.7717 (1.3); 3.7658 (1.4); 3.7549(5.8); 3.7461 (1.5); 3.7409 (9.6); 3.7360 (2.1); 3.7312 (4.1); 3.7268(5.8); 3.7229 (5.2); 3.7175 (5.1); 3.7148 (7.5); 3.7004 (9.2); 3.6981(6.4); 3.6866 (16.0); 3.6789 (7.7); 3.6731 (9.5); 3.6699 (6.6); 3.6585(4.1); 3.6058 (1.0); 3.6027 (1.0); 3.5975 (1.3); 3.5907 (1.7); 3.5856(2.0); 3.5762 (2.0); 3.5695 (1.7); 3.5644 (1.7); 3.5573 (6.6); 3.5526(7.3); 3.5295 (3.5); 3.5133 (3.7); 3.5085 (4.3); 3.4852 (2.2); 2.7529(0.8); 2.7405 (0.8); 2.7324 (0.9); 2.7182 (1.7); 2.7054 (1.3); 2.6975(1.7); 2.6846 (1.5); 2.6715 (1.0); 2.6625 (0.9); 2.6509 (0.9); 2.5956(1.0); 2.5745 (1.8); 2.5603 (1.3); 2.5533 (1.2); 2.5392 (2.0); 2.5314(1.2); 2.5180 (1.1); 2.5104 (2.0); 2.4962 (1.4); 2.4893 (1.2); 2.4751(2.2); 2.4540 (1.1); 2.0418 (1.0); 2.0330 (1.8); 2.0240 (1.0); 2.0065(1.0); 1.9977 (1.8); 1.9890 (1.7); 1.9780 (1.0); 1.9709 (1.3); 1.9671(1.3); 1.9619 (2.2); 1.9534 (1.7); 1.9426 (0.9); 1.9356 (1.1); 1.9320(1.0); 1.9266 (1.8); 1.9177 (1.0); 1.8946 (0.9); 1.8830 (0.8); 1.8725(0.8); 1.8598 (1.1); 1.8477 (0.8); 1.8372 (0.7); 1.8258 (0.8); 1.5565(4.1); 1.2542 (0.5); 0.0079 (2.6); −0.0002 (78.5); −0.0085 (3.4) I-119:¹H-NMR(400.0 MHz, CDCl3): δ = 7.9791 (0.7); 7.9761 (0.5); 7.9677 (0.7);7.7647 (0.7); 7.7484 (0.5); 7.7452 (0.8); 7.7421 (0.5); 7.5968 (0.7);7.5771 (1.1); 7.5574 (0.5); 7.2613 (4.4); 4.0080 (0.5); 3.9990 (0.5);3.7933 (0.9); 3.7875 (0.9); 3.7483 (0.7); 3.7424 (0.6); 1.5601 (0.9);1.4889 (0.6); 1.4822 (15.6); 1.4489 (16.0); 1.4332 (1.2); −0.0002 (5.2)I-120: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.3162 (1.1); 7.3008 (1.1); 7.2636(9.0); 7.2041 (0.5); 7.1973 (2.6); 7.1916 (3.1); 7.1865 (3.2); 7.1807(4.2); 7.1775 (4.4); 7.1716 (3.4); 7.1666 (2.8); 7.1609 (2.4); 7.1542(0.5); 6.9216 (0.8); 6.9158 (1.4); 6.9101 (0.8); 6.8999 (1.6); 6.8941(2.8); 6.8884 (1.5); 6.8782 (0.8); 6.8724 (1.4); 6.8667 (0.8); 5.9909(1.0); 5.9872 (1.2); 5.9841 (1.9); 5.9805 (2.0); 5.9772 (2.3); 5.9736(2.4); 5.9704 (2.5); 5.9668 (2.4); 5.9637 (1.4); 5.9600 (1.1); 5.9008(1.3); 5.8953 (2.4); 5.8897 (1.4); 5.8872 (1.1); 5.8815 (1.8); 5.8759(1.0); 5.8284 (1.0); 5.8228 (1.9); 5.8171 (1.2); 5.8147 (1.0); 5.8090(1.6); 5.8033 (0.9); 5.0506 (0.5); 5.0472 (0.6); 5.0443 (0.7); 5.0411(0.9); 5.0384 (1.0); 5.0354 (1.1); 5.0326 (1.1); 5.0297 (1.1); 5.0259(1.0); 5.0222 (1.1); 5.0196 (1.1); 5.0165 (1.2); 5.0137 (1.1); 5.0078(0.8); 5.0047 (0.6); 5.0016 (0.6); 4.9987 (0.5); 4.2329 (1.9); 4.2151(6.0); 4.1972 (8.1); 4.1790 (8.5); 4.1611 (7.0); 4.1433 (2.4); 4.0414(2.5); 4.0190 (2.6); 4.0114 (4.9); 3.9890 (6.1); 3.9538 (10.3); 3.9237(4.8); 3.7209 (3.2); 3.7179 (2.9); 3.6769 (5.3); 3.6740 (4.8); 3.5591(4.6); 3.5506 (4.0); 3.5332 (0.8); 3.5304 (0.8); 3.5255 (1.0); 3.5150(3.9); 3.5114 (1.9); 3.5066 (3.6); 3.4988 (1.1); 3.4926 (0.9); 3.4897(0.9); 2.5582 (0.8); 2.5372 (1.4); 2.5231 (1.0); 2.5161 (0.9); 2.5020(1.6); 2.4933 (0.9); 2.4810 (0.8); 2.4723 (1.7); 2.4583 (1.1); 2.4514(1.0); 2.4373 (1.9); 2.4163 (0.9); 2.0054 (0.8); 1.9966 (1.4); 1.9878(0.8); 1.9703 (0.7); 1.9615 (1.2); 1.9527 (0.7); 1.9348 (0.9); 1.9257(1.7); 1.9166 (0.9); 1.8997 (0.8); 1.8907 (1.5); 1.8816 (0.8); 1.3242(6.7); 1.3063 (13.8); 1.2892 (10.3); 1.2718 (16.0); 1.2611 (0.6); 1.2540(7.7); −0.0002 (11.9) I-121: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.2672 (6.3);7.1766 (1.3); 7.1734 (1.2); 7.1708 (1.6); 7.1670 (2.7); 7.1611 (3.3);7.1569 (3.2); 7.1508 (2.5); 7.1470 (2.9); 7.1414 (2.6); 7.1373 (1.1);7.0801 (0.7); 6.8943 (0.6); 6.8888 (1.1); 6.8833 (1.2); 6.8785 (1.0);6.8726 (1.1); 6.8668 (1.5); 6.8617 (1.1); 6.8569 (0.6); 6.8509 (0.6);6.8459 (0.7); 6.8448 (0.7); 6.0003 (0.5); 5.9986 (0.6); 5.9966 (0.6);5.9943 (0.6); 5.9907 (1.0); 5.9863 (1.1); 5.9844 (1.1); 5.9803 (1.2);5.9783 (1.0); 5.9727 (0.8); 5.9701 (0.7); 5.9658 (1.1); 5.9599 (1.1);5.9552 (0.6); 5.9517 (0.6); 5.9478 (0.7); 5.9453 (0.7); 5.9415 (0.6);5.9105 (0.6); 5.9050 (1.1); 5.8994 (0.6); 5.8912 (0.8); 5.8690 (0.9);5.8632 (0.5); 5.8551 (0.7); 5.8240 (0.6); 5.8183 (1.1); 5.8130 (1.0);5.8102 (0.7); 5.8076 (1.0); 5.8045 (1.1); 5.8019 (0.6); 5.7992 (0.8);5.7937 (0.7); 5.0571 (0.6); 5.0541 (0.5); 5.0394 (0.5); 5.0362 (0.5);4.3124 (1.0); 4.3036 (1.3); 4.3010 (1.9); 4.2914 (2.1); 4.2885 (1.4);4.2863 (1.2); 4.2803 (1.2); 4.2764 (1.7); 4.2737 (1.4); 4.2662 (1.6);4.2629 (1.7); 4.2594 (1.0); 4.2557 (1.6); 4.2538 (1.3); 4.2470 (1.5);4.2429 (1.4); 4.2379 (1.5); 4.2299 (1.2); 4.2252 (0.8); 4.2192 (0.7);3.8279 (2.0); 3.8249 (2.1); 3.8221 (2.0); 3.7845 (2.8); 3.7817 (2.7);3.7783 (2.8); 3.7712 (0.7); 3.6399 (2.2); 3.6291 (2.5); 3.6272 (2.4);3.6160 (2.4); 3.6130 (1.4); 3.6064 (1.7); 3.6013 (2.6); 3.5944 (2.5);3.5906 (2.9); 3.5829 (2.0); 3.5784 (2.8); 3.5669 (2.0); 3.5618 (0.8);3.5584 (0.6); 3.4031 (16.0); 3.3877 (10.5); 3.3790 (15.1); 3.3731(12.3); 3.3554 (2.4); 3.3440 (1.7); 3.3365 (1.9); 3.3118 (2.0); 3.3007(1.5); 3.2931 (1.6); 2.6825 (0.6); 2.6701 (0.6); 2.5675 (0.8); 2.5536(0.5); 2.5325 (0.8); 2.5057 (0.7); 2.4708 (0.8); 1.9623 (0.7); 1.9274(0.7); 1.8967 (0.7); 1.8617 (0.7); 1.5695 (0.7); 1.5618 (0.7); 1.5590(0.7); 1.5563 (0.8); 1.5486 (1.6); 1.5378 (1.3); 1.5354 (1.6); 1.5277(1.0); 1.5248 (0.7); 1.5225 (0.6); 1.5170 (0.7); 1.5146 (0.8); 0.6629(0.6); 0.6604 (0.6); 0.6555 (0.6); 0.6493 (1.0); 0.6402 (0.8); 0.6362(1.0); 0.6274 (0.9); 0.6230 (0.5); 0.6140 (0.6); 0.5927 (0.6); 0.5895(0.6); 0.5832 (0.7); 0.5797 (1.2); 0.5754 (0.8); 0.5716 (1.5); 0.5673(1.7); 0.5626 (1.8); 0.5591 (1.8); 0.5546 (1.3); 0.5511 (1.7); 0.5496(1.7); 0.5462 (1.8); 0.5426 (1.7); 0.5365 (1.1); 0.5298 (1.3); 0.5221(0.6); 0.5185 (0.7); 0.5087 (0.9); 0.5059 (0.6); 0.4862 (0.6); 0.4821(0.6); 0.4777 (0.5); 0.4736 (1.0); 0.4693 (1.3); 0.4649 (0.7); 0.4605(1.2); 0.4559 (1.2); 0.4500 (0.7); 0.4458 (0.8); 0.4410 (0.8); 0.4363(0.6); 0.4320 (0.6); −0.0002 (7.8) I-122: ¹H-NMR(400.0 MHz, CDCl3): δ =7.9778 (11.7); 7.9741 (16.0); 7.9701 (12.1); 7.9656 (9.5); 7.9645 (9.3);7.9615 (5.8); 7.8996 (3.7); 7.8966 (4.6); 7.8921 (6.8); 7.8890 (5.0);7.8846 (4.4); 7.8797 (7.5); 7.8771 (9.1); 7.8724 (9.2); 7.8691 (5.6);7.8679 (5.3); 7.8647 (4.6); 7.8576 (5.6); 7.7870 (2.7); 7.7810 (4.7);7.7775 (5.4); 7.7744 (7.6); 7.7708 (7.5); 7.7678 (6.8); 7.7650 (6.0);7.7580 (6.5); 7.7550 (8.9); 7.7514 (8.4); 7.7486 (4.2); 7.6124 (4.9);7.6049 (5.8); 7.6032 (7.0); 7.6011 (5.6); 7.5927 (8.2); 7.5835 (11.1);7.5731 (3.8); 7.5656 (4.0); 7.5639 (4.7); 7.5193 (0.6); 7.2603 (119.5);7.2090 (3.5); 7.1872 (3.4); 6.9963 (0.9); 6.8172 (1.3); 6.7957 (2.1);6.7723 (1.2); 6.0522 (2.0); 6.0479 (2.4); 6.0463 (2.4); 6.0415 (3.3);6.0382 (3.2); 6.0325 (5.2); 6.0275 (5.8); 6.0229 (5.1); 6.0197 (6.3);6.0164 (7.6); 6.0132 (6.2); 6.0097 (6.0); 6.0066 (3.6); 6.0027 (3.5);6.0000 (3.3); 5.9963 (3.0); 5.9787 (3.5); 5.9733 (6.3); 5.9677 (3.5);5.9650 (2.4); 5.9594 (3.9); 5.9539 (2.2); 5.9350 (1.9); 5.9293 (3.5);5.9236 (2.1); 5.9212 (1.8); 5.9154 (2.9); 5.9103 (4.1); 5.9049 (5.5);5.8992 (3.4); 5.8968 (2.8); 5.8911 (4.4); 5.8855 (2.4); 5.8788 (2.1);5.8730 (3.9); 5.8671 (2.2); 5.8650 (2.0); 5.8591 (3.3); 5.8532 (1.8);5.2036 (0.6); 5.1882 (1.1); 5.1826 (1.4); 5.1767 (1.6); 5.1712 (1.4);5.1657 (1.4); 5.1603 (1.4); 5.1557 (1.8); 5.1500 (1.7); 5.1451 (1.4);5.1397 (1.0); 5.1294 (1.6); 5.1240 (1.6); 5.1049 (2.9); 5.0985 (2.6);5.0890 (2.8); 5.0864 (2.9); 5.0678 (1.2); 4.5727 (4.4); 4.5647 (0.8);4.5518 (13.6); 4.5468 (3.9); 4.5432 (4.1); 4.5310 (14.2); 4.5259 (10.6);4.5222 (10.6); 4.5103 (6.4); 4.5048 (12.5); 4.5014 (11.6); 4.4908 (9.5);4.4831 (8.0); 4.4698 (9.4); 4.4619 (2.4); 4.4489 (3.2); 4.0630 (2.8);4.0584 (3.2); 4.0453 (5.9); 4.0176 (4.0); 4.0134 (4.5); 4.0003 (8.5);3.9055 (1.2); 3.8995 (1.6); 3.8933 (1.8); 3.8872 (1.7); 3.8834 (2.4);3.8773 (3.2); 3.8713 (3.2); 3.8653 (2.5); 3.8608 (1.7); 3.8550 (1.7);3.8493 (1.5); 3.8433 (1.2); 3.8375 (0.6); 3.8095 (13.4); 3.8040 (12.3);3.7970 (11.1); 3.7643 (9.6); 3.7589 (8.8); 3.7519 (8.1); 3.6761 (2.0);3.6733 (2.6); 3.6705 (2.8); 3.6676 (3.0); 3.6640 (3.5); 3.6614 (3.6);3.6555 (3.4); 3.6520 (3.5); 3.6494 (3.6); 3.6462 (3.1); 3.6404 (2.6);3.6377 (2.1); 2.7900 (1.5); 2.7777 (1.5); 2.7694 (1.7); 2.7571 (1.9);2.7544 (2.0); 2.7423 (3.0); 2.7339 (1.9); 2.7309 (1.6); 2.7217 (3.0);2.7101 (1.6); 2.7071 (1.7); 2.6954 (1.6); 2.6864 (1.5); 2.6747 (1.5);2.6563 (2.1); 2.6353 (3.8); 2.6208 (2.7); 2.6141 (2.4); 2.5997 (4.2);2.5795 (3.2); 2.5592 (4.4); 2.5447 (3.0); 2.5382 (2.6); 2.5238 (4.8);2.5028 (2.4); 2.0426 (2.1); 2.0336 (4.9); 2.0248 (2.3); 2.0110 (2.1);2.0067 (4.0); 1.9977 (8.3); 1.9887 (3.9); 1.9754 (1.6); 1.9709 (2.2);1.9621 (3.8); 1.9536 (2.6); 1.9440 (1.5); 1.9323 (1.8); 1.9189 (1.3);1.9085 (1.2); 1.8969 (1.2); 1.5441 (6.0); 1.2549 (0.5); 0.0080 (4.4);−0.0002 (151.0); −0.0085 (5.3) I-123: ¹H-NMR(400.0 MHz, CDCl3): δ =7.2625 (36.5); 7.2189 (2.9); 7.2078 (2.6); 7.1954 (7.8); 7.1923 (6.9);7.1896 (7.9); 7.1853 (9.9); 7.1797 (13.5); 7.1756 (13.0); 7.1699 (10.4);7.1653 (10.1); 7.1601 (9.9); 7.1550 (4.1); 7.1476 (1.5); 7.1421 (0.9);6.9391 (1.0); 6.9363 (1.2); 6.9334 (1.9); 6.9306 (2.0); 6.9279 (2.4);6.9256 (2.3); 6.9223 (3.0); 6.9200 (3.0); 6.9173 (3.1); 6.9146 (3.4);6.9118 (4.0); 6.9090 (4.0); 6.9062 (4.7); 6.9039 (4.4); 6.9006 (5.5);6.8983 (5.2); 6.8949 (3.8); 6.8927 (3.7); 6.8902 (2.9); 6.8873 (2.9);6.8846 (3.4); 6.8823 (3.4); 6.8789 (3.9); 6.8767 (3.7); 6.8732 (2.8);6.8616 (1.5); 6.8549 (1.4); 6.1420 (1.0); 6.1320 (2.1); 6.1220 (1.0);6.0993 (1.1); 6.0892 (2.5); 6.0783 (1.9); 6.0753 (0.9); 6.0679 (0.9);6.0652 (1.5); 6.0552 (0.7); 6.0145 (1.6); 6.0101 (2.0); 6.0084 (2.2);6.0044 (5.0); 5.9998 (4.6); 5.9945 (9.2); 5.9902 (6.3); 5.9848 (7.8);5.9817 (5.9); 5.9792 (6.2); 5.9751 (5.0); 5.9722 (3.0); 5.9683 (2.5);5.9619 (2.4); 5.9517 (5.1); 5.9412 (6.1); 5.9360 (5.4); 5.9304 (4.4);5.9277 (4.9); 5.9221 (3.3); 5.9172 (2.5); 5.9049 (1.7); 5.8992 (3.0);5.8935 (1.8); 5.8910 (1.5); 5.8853 (2.4); 5.8796 (1.4); 5.8705 (2.4);5.8648 (4.2); 5.8571 (4.2); 5.8510 (3.6); 5.8472 (3.2); 5.8416 (3.1);5.8357 (1.8); 5.8335 (1.7); 5.8276 (2.6); 5.8244 (1.6); 5.8218 (1.6);5.8143 (2.6); 5.8031 (1.9); 5.8003 (0.9); 5.7929 (0.8); 5.7902 (1.5);5.7802 (0.7); 5.1578 (0.5); 5.1521 (0.6); 5.1478 (0.7); 5.1426 (1.0);5.1380 (1.3); 5.1325 (1.4); 5.1270 (1.4); 5.1232 (1.3); 5.1175 (1.4);5.1125 (1.4); 5.1070 (1.3); 5.1026 (1.1); 5.0970 (0.8); 5.0925 (0.6);5.0866 (0.6); 5.0613 (1.1); 5.0585 (1.3); 5.0555 (1.3); 5.0526 (1.6);5.0494 (1.8); 5.0466 (1.9); 5.0435 (2.1); 5.0404 (2.3); 5.0378 (2.3);5.0315 (2.3); 5.0281 (2.1); 5.0249 (1.9); 5.0223 (1.8); 5.0192 (1.6);5.0161 (1.3); 5.0133 (1.2); 5.0104 (1.1); 5.0073 (0.9); 4.3870 (3.7);4.3770 (3.7); 4.3528 (7.7); 4.3428 (10.6); 4.3368 (3.4); 4.3327 (3.8);4.3266 (3.3); 4.3242 (3.4); 4.3186 (4.5); 4.3141 (3.5); 4.3086 (10.3);4.3026 (6.3); 4.2986 (6.9); 4.2925 (6.0); 4.2900 (6.0); 4.2799 (5.1);4.2744 (3.5); 4.2684 (3.2); 4.2645 (3.4); 4.2583 (3.0); 4.2558 (3.1);4.2457 (2.4); 4.0490 (4.2); 4.0437 (5.6); 4.0309 (3.9); 4.0223 (6.1);4.0191 (7.2); 4.0137 (9.8); 4.0008 (7.0); 3.9923 (10.9); 3.9472 (16.0);3.9401 (6.7); 3.9304 (5.9); 3.9171 (8.1); 3.9101 (3.6); 3.9004 (3.7);3.8535 (0.9); 3.8474 (1.2); 3.8412 (1.3); 3.8351 (1.2); 3.8317 (1.4);3.8258 (2.2); 3.8198 (2.1); 3.8143 (1.8); 3.8087 (1.4); 3.8043 (1.2);3.7983 (1.4); 3.7925 (1.3); 3.7866 (0.9); 3.7327 (4.1); 3.7298 (4.0);3.7193 (9.5); 3.6886 (6.1); 3.6856 (6.3); 3.6752 (15.4); 3.6388 (0.6);3.6295 (1.4); 3.6265 (1.3); 3.6208 (1.8); 3.6146 (2.4); 3.6114 (2.6);3.6084 (2.6); 3.6054 (2.6); 3.6025 (2.6); 3.5997 (2.4); 3.5939 (1.8);3.5882 (1.4); 3.5847 (1.5); 3.5785 (0.9); 3.5755 (0.7); 3.5563 (8.9);3.5520 (6.9); 3.5493 (8.8); 3.5265 (4.8); 3.5123 (5.4); 3.5077 (4.2);3.5052 (5.4); 3.4822 (3.1); 2.7452 (1.2); 2.7327 (1.2); 2.7247 (1.4);2.7104 (2.3); 2.6976 (1.7); 2.6898 (2.2); 2.6769 (2.1); 2.6639 (1.3);2.6548 (1.2); 2.6431 (1.2); 2.6232 (1.5); 2.6021 (2.6); 2.5879 (2.0);2.5810 (1.8); 2.5668 (2.9); 2.5541 (1.7); 2.5457 (1.7); 2.5330 (3.1);2.5188 (2.2); 2.5120 (1.9); 2.4978 (3.3); 2.4768 (1.8); 2.1707 (0.7);2.1476 (0.6); 2.1455 (0.8); 2.0300 (1.6); 2.0204 (3.1); 2.0112 (1.7);2.0082 (1.5); 1.9964 (1.7); 1.9857 (3.6); 1.9759 (1.6); 1.9728 (1.4);1.9616 (2.7); 1.9516 (3.6); 1.9424 (1.7); 1.9264 (1.5); 1.9168 (2.8);1.9132 (1.7); 1.9072 (1.6); 1.9015 (1.3); 1.8910 (1.2); 1.8790 (1.6);1.8661 (1.1); 1.8556 (1.0); 1.8440 (1.0); 1.5841 (0.9); 1.2565 (0.7);0.0080 (1.7); −0.0002 (47.5); −0.0085 (1.6) I-124: ¹H-NMR(400.0 MHz,CDCl3): δ = 7.3009 (0.5); 7.2883 (0.5); 7.2803 (0.5); 7.2618 (20.5);7.1986 (1.5); 7.1928 (1.7); 7.1865 (2.1); 7.1805 (3.2); 7.1788 (2.8);7.1730 (2.1); 7.1714 (1.9); 7.1668 (2.4); 7.1609 (2.6); 7.1549 (1.1);6.9277 (0.5); 6.9218 (0.6); 6.9160 (1.0); 6.9104 (1.2); 6.9062 (1.0);6.9001 (1.0); 6.8942 (1.4); 6.8927 (1.3); 6.8886 (1.0); 6.8784 (0.6);6.8724 (0.7); 6.8710 (0.6); 6.0235 (0.5); 6.0211 (0.7); 6.0167 (0.7);6.0142 (0.8); 6.0099 (0.9); 6.0072 (0.9); 6.0036 (1.1); 6.0007 (1.1);5.9975 (1.1); 5.9943 (1.0); 5.9908 (1.0); 5.9872 (1.0); 5.9841 (1.1);5.9804 (1.1); 5.9777 (0.6); 5.9062 (0.6); 5.9006 (1.0); 5.8950 (0.6);5.8868 (0.8); 5.8632 (0.8); 5.8493 (0.6); 5.8288 (0.9); 5.8231 (0.5);5.8150 (0.8); 5.8095 (0.8); 5.8039 (0.8); 5.7900 (0.6); 4.3164 (0.9);4.3081 (1.1); 4.3050 (1.4); 4.2959 (1.7); 4.2927 (1.1); 4.2848 (1.1);4.2806 (1.0); 4.2701 (1.7); 4.2677 (1.4); 4.2583 (1.8); 4.2563 (2.4);4.2546 (1.9); 4.2517 (1.0); 4.2460 (2.1); 4.2407 (1.6); 4.2345 (0.9);4.2319 (1.1); 4.2278 (0.9); 4.2211 (0.6); 4.0430 (1.5); 4.0260 (1.0);4.0166 (1.4); 4.0129 (2.8); 3.9960 (1.8); 3.9866 (2.6); 3.9532 (2.7);3.9514 (3.0); 3.9437 (1.7); 3.9336 (1.6); 3.9233 (1.4); 3.9214 (1.3);3.9136 (0.9); 3.9036 (0.9); 3.7902 (0.5); 3.7838 (0.6); 3.7777 (0.6);3.7285 (1.1); 3.7248 (1.2); 3.7211 (2.2); 3.6843 (1.7); 3.6806 (2.0);3.6771 (3.5); 3.6426 (1.6); 3.6321 (1.9); 3.6295 (1.9); 3.6185 (1.3);3.6108 (1.4); 3.6078 (1.4); 3.6042 (1.8); 3.5997 (1.8); 3.5963 (2.4);3.5914 (3.3); 3.5874 (1.8); 3.5843 (2.0); 3.5798 (3.1); 3.5672 (1.9);3.5559 (3.6); 3.5290 (1.3); 3.5119 (1.9); 3.4848 (0.8); 3.4018 (14.3);3.3923 (0.7); 3.3855 (11.7); 3.3814 (1.7); 3.3773 (16.0); 3.3734 (12.0);2.5469 (0.6); 2.5117 (0.7); 2.4841 (0.7); 2.4490 (0.8); 2.0083 (0.6);1.9734 (0.6); 1.9644 (0.6); 1.9390 (0.8); 1.9293 (0.6); 1.9036 (0.6);1.5761 (1.1); 0.0079 (0.8); −0.0002 (21.8); −0.0085 (0.7) I-125:¹H-NMR(400.0 MHz, CDCl3): δ = 7.3185 (0.6); 7.2621 (16.2); 7.1990 (1.6);7.1932 (1.9); 7.1870 (1.9); 7.1808 (3.3); 7.1792 (3.6); 7.1746 (2.5);7.1673 (2.2); 7.1653 (2.4); 7.1613 (2.6); 7.1553 (1.2); 6.9315 (0.5);6.9284 (0.5); 6.9246 (0.6); 6.9224 (0.7); 6.9186 (0.8); 6.9162 (1.0);6.9126 (1.0); 6.9100 (1.2); 6.9067 (1.0); 6.9029 (1.1); 6.9008 (1.2);6.8970 (1.4); 6.8948 (1.4); 6.8911 (1.0); 6.8889 (1.0); 6.8851 (0.6);6.8811 (0.6); 6.8791 (0.6); 6.8753 (0.8); 6.8732 (0.7); 6.0063 (0.5);6.0046 (0.6); 6.0004 (0.9); 5.9964 (1.0); 5.9943 (0.8); 5.9903 (1.4);5.9865 (1.5); 5.9825 (1.4); 5.9803 (1.4); 5.9762 (1.7); 5.9726 (1.2);5.9694 (1.2); 5.9660 (1.1); 5.9623 (0.7); 5.9587 (0.6); 5.9071 (0.7);5.9016 (1.2); 5.8959 (0.7); 5.8935 (0.6); 5.8878 (0.9); 5.8602 (0.8);5.8545 (0.5); 5.8463 (0.7); 5.8405 (0.5); 5.8381 (0.6); 5.8325 (1.0);5.8268 (0.6); 5.8245 (0.5); 5.8187 (0.9); 5.8131 (0.5); 5.8025 (0.8);5.7886 (0.7); 5.0257 (0.7); 5.0229 (0.7); 4.0444 (2.2); 4.0274 (1.1);4.0202 (1.4); 4.0144 (3.9); 3.9974 (2.0); 3.9902 (3.1); 3.9562 (3.5);3.9544 (3.1); 3.9433 (1.8); 3.9342 (1.7); 3.9261 (1.5); 3.9242 (1.6);3.9133 (0.9); 3.9043 (1.1); 3.7718 (0.7); 3.7652 (0.7); 3.7574 (14.7);3.7501 (1.0); 3.7439 (1.0); 3.7377 (0.8); 3.7301 (1.8); 3.7278 (2.2);3.7234 (16.0); 3.7177 (2.7); 3.7103 (0.7); 3.7009 (9.3); 3.6882 (10.0);3.6841 (2.4); 3.6736 (3.2); 3.5624 (2.4); 3.5536 (2.0); 3.5495 (2.5);3.5382 (0.8); 3.5292 (2.1); 3.5221 (0.8); 3.5184 (1.8); 3.5095 (1.4);3.5055 (1.5); 3.4851 (0.9); 2.5442 (0.7); 2.5301 (0.5); 2.5091 (0.8);2.4795 (0.8); 2.4654 (0.6); 2.4445 (0.9); 2.0028 (0.7); 1.9762 (0.7);1.9676 (0.7); 1.9364 (0.5); 1.9275 (0.9); 1.9186 (0.7); 1.8924 (0.7);1.5781 (1.3); 0.0080 (0.6); −0.0002 (17.2); −0.0085 (0.6) I-126:¹H-NMR(400.0 MHz, CDCl3): δ = 7.6640 (1.4); 7.6598 (1.7); 7.6579 (1.9);7.6537 (2.0); 7.6497 (1.2); 7.6470 (1.5); 7.6447 (1.5); 7.6398 (2.5);7.6337 (1.7); 7.4334 (0.8); 7.4303 (1.0); 7.4179 (4.3); 7.4130 (1.9);7.4117 (1.9); 7.4050 (1.3); 7.4012 (2.1); 7.3999 (2.3); 7.3875 (0.5);7.3861 (0.6); 7.2606 (14.4); 6.2299 (1.7); 6.2032 (1.8); 6.1868 (2.0);6.1600 (2.1); 5.9565 (0.5); 5.9544 (0.6); 5.9504 (0.5); 5.9465 (0.8);5.9449 (0.8); 5.9407 (1.1); 5.9367 (0.8); 5.9311 (0.6); 5.9270 (0.6);5.9249 (0.6); 5.9209 (0.6); 5.8801 (0.6); 5.8746 (1.1); 5.8690 (0.6);5.8607 (0.8); 5.8237 (0.6); 5.8180 (1.0); 5.8123 (0.6); 5.8099 (0.5);5.8042 (0.8); 5.5783 (1.4); 5.5764 (1.4); 5.5611 (1.4); 5.5591 (1.4);5.5352 (1.2); 5.5333 (1.2); 5.5179 (1.2); 5.5160 (1.2); 5.3356 (1.2);5.3338 (1.2); 5.3220 (1.2); 5.3202 (1.2); 5.3089 (1.2); 5.3071 (1.2);5.2979 (2.5); 5.2953 (1.3); 5.2934 (1.2); 5.0307 (0.6); 5.0265 (0.6);3.9885 (1.7); 3.9839 (1.7); 3.9456 (2.0); 3.9410 (2.0); 3.7614 (1.4);3.7592 (0.9); 3.7550 (1.0); 3.7508 (1.7); 3.7447 (16.0); 3.7387 (1.5);3.7344 (1.1); 3.7276 (14.0); 3.7141 (2.2); 3.5239 (0.5); 3.5213 (0.5);3.5162 (0.5); 3.5133 (0.6); 3.5079 (0.5); 3.5056 (0.5); 3.5028 (0.5);3.3940 (1.7); 3.3889 (1.7); 3.3511 (1.5); 3.3460 (1.5); 2.5606 (0.7);2.5468 (0.5); 2.5390 (0.7); 2.5257 (0.8); 2.5173 (0.7); 2.5038 (0.7);2.4824 (0.8); 1.9372 (0.6); 1.9023 (1.0); 1.8917 (1.0); 1.8680 (1.6);1.8603 (1.2); 1.8566 (1.4); 1.8514 (3.7); 1.8465 (1.2); 1.8424 (1.2);1.8348 (1.3); 1.3282 (0.5); 1.0206 (0.7); 1.0032 (1.0); 0.0079 (0.5);−0.0002 (18.5); −0.0085 (0.7) I-127: ¹H-NMR(400.0 MHz, CDCl3): δ =7.2607 (21.7); 7.2167 (1.5); 7.2150 (1.8); 7.2131 (1.9); 7.2112 (2.0);7.2095 (1.7); 7.2006 (0.7); 7.1907 (0.9); 7.1674 (0.8); 6.9571 (0.8);6.9357 (0.7); 6.9337 (0.8); 6.2123 (1.3); 6.1856 (1.4); 6.1692 (1.6);6.1425 (1.7); 5.9625 (0.5); 5.9586 (0.5); 5.9563 (0.5); 5.9523 (0.5);5.9489 (0.9); 5.9450 (1.0); 5.9427 (1.0); 5.9388 (0.9); 5.9355 (0.6);5.9314 (0.6); 5.9293 (0.6); 5.9253 (0.5); 5.8789 (0.5); 5.8734 (1.0);5.8678 (0.6); 5.8596 (0.7); 5.8249 (0.5); 5.8192 (0.9); 5.8135 (0.5);5.8054 (0.8); 5.5702 (1.3); 5.5683 (1.3); 5.5516 (1.3); 5.5498 (1.3);5.5270 (1.1); 5.5252 (1.1); 5.5085 (1.1); 5.5067 (1.1); 5.3404 (1.1);5.3387 (1.2); 5.3261 (1.2); 5.3243 (1.2); 5.3137 (1.1); 5.3120 (1.1);5.2985 (4.0); 5.0227 (0.5); 3.9486 (1.5); 3.9446 (1.5); 3.9056 (1.7);3.9017 (1.8); 3.7665 (0.6); 3.7617 (1.7); 3.7596 (1.2); 3.7553 (1.2);3.7514 (2.2); 3.7503 (2.0); 3.7450 (16.0); 3.7389 (2.0); 3.7365 (1.6);3.7320 (12.5); 3.7284 (2.6); 3.7246 (0.8); 3.7139 (3.5); 3.7029 (0.7);3.5241 (0.5); 3.5187 (0.5); 3.5131 (0.5); 3.5077 (0.5); 3.3475 (1.5);3.3424 (1.5); 3.3046 (1.3); 3.2994 (1.3); 2.5526 (0.6); 2.5313 (0.8);2.5176 (0.7); 2.5100 (0.7); 2.4963 (0.8); 2.4751 (0.8); 2.3690 (8.8);1.9362 (0.6); 1.9019 (0.7); 1.8928 (0.8); 1.8684 (2.0); 1.8605 (1.6);1.8588 (1.7); 1.8518 (4.8); 1.8472 (1.4); 1.8428 (1.6); 1.8351 (1.7);1.3514 (0.6); 1.3332 (1.3); 1.3149 (0.6); 1.0196 (1.0); 1.0033 (1.4);0.9862 (0.6); 0.0079 (0.8); −0.0002 (27.8); −0.0068 (0.7); −0.0085 (1.1)I-128: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.6545 (1.4); 7.6510 (2.2); 7.6473(1.8); 7.6410 (1.1); 7.6308 (2.0); 7.6274 (1.5); 7.4291 (1.3); 7.4231(1.5); 7.4189 (3.2); 7.4157 (3.4); 7.4103 (1.7); 7.3989 (1.7); 7.2612(11.7); 6.2244 (0.8); 6.2206 (0.8); 6.1977 (0.8); 6.1938 (0.8); 6.1814(0.9); 6.1774 (0.8); 6.1546 (0.9); 6.1507 (0.9); 5.9982 (0.6); 5.9878(0.8); 5.9832 (1.0); 5.9694 (0.6); 5.8939 (0.9); 5.8800 (0.7); 5.8403(0.8); 5.8345 (0.5); 5.8265 (0.7); 5.5716 (1.1); 5.5699 (1.1); 5.5592(1.2); 5.5575 (1.1); 5.5284 (1.0); 5.5268 (1.0); 5.5161 (1.0); 5.5143(0.9); 5.3353 (1.1); 5.3260 (1.0); 5.3086 (1.0); 5.2992 (1.0); 4.1497(1.2); 4.1318 (3.5); 4.1140 (3.6); 4.0961 (1.2); 3.9947 (1.2); 3.9890(1.3); 3.9517 (1.4); 3.9461 (1.5); 3.4001 (1.3); 3.3946 (1.3); 3.3570(1.1); 3.3516 (1.1); 2.5702 (0.6); 2.5600 (0.5); 2.5251 (0.6); 2.1729(0.8); 2.0459 (16.0); 1.9564 (0.6); 1.9472 (0.6); 1.2772 (4.5); 1.2593(9.1); 1.2414 (4.4); −0.0002 (14.0); −0.0086 (0.6) I-129: ¹H-NMR(400.0MHz, CDCl3): δ = 7.2610 (6.0); 7.2253 (2.7); 7.1971 (0.8); 7.0092 (0.8);6.9861 (0.8); 6.0072 (0.6); 6.0038 (0.7); 6.0009 (0.7); 5.9974 (0.7);5.9935 (0.9); 5.9901 (0.9); 5.9871 (0.9); 5.9838 (0.8); 5.9269 (0.8);5.9213 (1.4); 5.9157 (0.9); 5.9076 (1.0); 5.9021 (0.6); 5.0678 (0.6);4.0009 (1.2); 3.9559 (1.8); 3.7784 (2.8); 3.7401 (16.0); 3.7337 (2.4);3.5496 (0.6); 3.5434 (0.6); 3.5358 (0.5); 3.5288 (0.6); 3.5223 (0.6);2.5040 (0.5); 2.4831 (1.0); 2.4688 (0.7); 2.4623 (0.6); 2.4479 (1.2);2.4271 (0.6); 2.3878 (9.8); 1.9655 (0.6); 1.9570 (1.1); 1.9485 (0.6);1.9303 (0.5); 1.9218 (0.9); 1.9133 (0.5); 1.5615 (2.4); −0.0002 (7.4)I-130: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.3755 (0.5); 7.3542 (0.5); 7.2606(9.1); 7.2162 (2.6); 7.1873 (0.8); 7.0075 (0.8); 6.9843 (0.8); 5.9969(0.7); 5.9934 (0.7); 5.9905 (0.8); 5.9870 (0.7); 5.9831 (0.8); 5.9797(0.9); 5.9768 (0.8); 5.9734 (0.8); 5.8616 (0.7); 5.8561 (1.3); 5.8503(0.9); 5.8423 (1.1); 5.8368 (0.6); 5.0772 (0.6); 4.0001 (1.2); 3.9551(1.8); 3.7714 (2.8); 3.7593 (16.0); 3.7509 (0.7); 3.7264 (1.8); 3.5610(0.6); 3.5543 (0.6); 3.5471 (0.5); 3.5396 (0.6); 3.5333 (0.6); 2.5667(0.5); 2.5458 (1.0); 2.5314 (0.7); 2.5248 (0.6); 2.5105 (1.1); 2.4895(0.6); 2.3849 (9.8); 2.0107 (0.6); 2.0026 (1.0); 1.9945 (0.6); 1.9754(0.5); 1.9673 (0.9); 1.9592 (0.5); 1.5521 (3.5); −0.0002 (11.1) I-131:¹H-NMR(400.0 MHz, CDCl3): δ = 7.6797 (1.6); 7.6764 (1.9); 7.6724 (1.0);7.6651 (0.7); 7.6599 (2.3); 7.6556 (1.9); 7.4837 (1.0); 7.4703 (0.9);7.4664 (1.5); 7.4621 (1.0); 7.4558 (2.2); 7.4521 (1.0); 7.4411 (1.1);7.4374 (2.2); 7.4205 (0.8); 7.4154 (0.6); 7.2602 (15.8); 6.0056 (0.6);6.0021 (0.6); 5.9993 (0.6); 5.9957 (0.6); 5.9918 (0.8); 5.9883 (0.8);5.9855 (0.8); 5.9820 (0.7); 5.9279 (0.7); 5.9224 (1.3); 5.9167 (0.8);5.9087 (0.9); 5.2992 (0.5); 5.0739 (0.5); 4.0375 (1.0); 3.9926 (1.5);3.8224 (2.5); 3.7775 (1.7); 3.7367 (14.8); 2.4914 (0.9); 2.4771 (0.6);2.4704 (0.5); 2.4562 (1.0); 2.4353 (0.5); 1.9641 (0.5); 1.9553 (0.9);1.9466 (0.5); 1.9202 (0.8); 1.5474 (1.4); 1.5274 (16.0); 1.4322 (0.6);1.2556 (0.6); 0.0078 (0.8); −0.0002 (19.8); −0.0084 (0.8) I-132:¹H-NMR(400.0 MHz, CDCl3): δ = 7.6716 (1.6); 7.6682 (2.0); 7.6642 (1.0);7.6570 (0.7); 7.6517 (2.4); 7.6474 (2.0); 7.4824 (1.1); 7.4690 (0.9);7.4651 (1.5); 7.4607 (1.0); 7.4536 (2.3); 7.4501 (1.0); 7.4389 (1.1);7.4354 (2.3); 7.4184 (0.8); 7.4134 (0.5); 7.2605 (7.7); 5.9941 (0.6);5.9906 (0.6); 5.9878 (0.7); 5.9842 (0.6); 5.9804 (0.7); 5.9768 (0.8);5.9740 (0.8); 5.9705 (0.7); 5.8608 (0.7); 5.8553 (1.2); 5.8496 (0.8);5.8473 (0.7); 5.8415 (1.0); 5.8359 (0.6); 5.2990 (2.7); 5.0809 (0.5);4.0375 (1.0); 3.9925 (1.6); 3.8160 (2.6); 3.7711 (2.0); 3.7595 (16.0);3.5384 (0.5); 3.5322 (0.5); 2.5749 (0.5); 2.5540 (0.9); 2.5397 (0.6);2.5329 (0.6); 2.5187 (1.0); 2.4977 (0.5); 2.0126 (0.5); 2.0043 (1.0);1.9958 (0.5); 1.9690 (0.8); 1.2571 (0.8); −0.0002 (9.6) I-133:¹H-NMR(400.0 MHz, CDCl3): δ = 7.2604 (37.8); 7.2313 (0.6); 7.2004 (5.0);7.1806 (1.5); 6.9541 (1.3); 6.9334 (1.2); 6.2080 (1.4); 6.2034 (1.2);6.1813 (1.6); 6.1766 (1.3); 6.1649 (1.7); 6.1602 (1.4); 6.1382 (1.7);6.1335 (1.4); 6.0080 (0.8); 6.0040 (1.0); 5.9943 (1.6); 5.9901 (1.9);5.9840 (1.4); 5.9806 (0.8); 5.9760 (0.9); 5.9704 (0.7); 5.9036 (0.7);5.8980 (1.3); 5.8922 (0.8); 5.8842 (1.1); 5.8789 (0.7); 5.8545 (0.7);5.8489 (1.4); 5.8431 (0.9); 5.8351 (1.1); 5.8295 (0.6); 5.5628 (2.0);5.5500 (2.1); 5.5197 (1.7); 5.5069 (1.8); 5.3399 (2.2); 5.3295 (1.7);5.3132 (2.1); 5.3027 (1.6); 5.0338 (0.5); 5.0120 (0.9); 5.0073 (0.9);3.9639 (0.5); 3.9501 (2.2); 3.9449 (2.1); 3.9207 (0.6); 3.9071 (2.5);3.9020 (2.4); 3.5857 (0.9); 3.5799 (0.9); 3.5758 (0.9); 3.3590 (0.8);3.3518 (2.2); 3.3464 (2.2); 3.3155 (0.6); 3.3088 (1.9); 3.3033 (1.9);2.6011 (0.9); 2.5873 (0.6); 2.5795 (0.7); 2.5660 (1.0); 2.5561 (0.9);2.5424 (0.7); 2.5349 (0.5); 2.5209 (0.9); 2.3664 (16.0); 1.9983 (0.5);1.9873 (0.9); 1.9762 (0.5); 1.9525 (1.2); 1.9420 (1.2); 1.9071 (0.8);0.0078 (1.6); −0.0002 (48.0); −0.0086 (1.7) I-134: ¹H-NMR(400.0 MHz,CDCl3): δ = 7.5192 (0.5); 7.3269 (0.7); 7.3047 (0.7); 7.2602 (94.9);7.2073 (2.5); 7.2016 (3.4); 7.1909 (2.0); 7.1880 (3.2); 7.1823 (2.8);6.9963 (0.6); 6.9706 (0.5); 6.9511 (1.3); 6.9493 (1.2); 6.9353 (1.2);6.9295 (2.0); 6.9238 (1.0); 6.9138 (0.6); 6.9080 (1.0); 6.0648 (1.2);6.0586 (1.3); 6.0547 (1.2); 6.0510 (1.5); 6.0446 (1.7); 6.0410 (1.3);5.9669 (1.0); 5.9615 (1.9); 5.9557 (1.2); 5.9476 (1.5); 5.9420 (0.8);5.9106 (0.8); 5.8968 (0.7); 5.2997 (0.7); 5.0789 (0.7); 4.1268 (1.3);4.1189 (0.9); 4.1090 (1.3); 4.1011 (2.5); 4.0833 (2.5); 4.0712 (0.8);4.0655 (0.9); 4.0534 (2.5); 4.0357 (2.5); 4.0277 (1.2); 4.0179 (1.0);4.0100 (1.8); 3.9922 (0.5); 3.9834 (1.5); 3.9654 (0.8); 3.9381 (2.2);3.8172 (0.8); 3.7681 (1.7); 3.7566 (4.1); 3.7229 (1.1); 3.7116 (2.7);3.6122 (0.7); 3.6065 (0.7); 3.5998 (0.7); 3.5908 (0.8); 3.5852 (0.8);2.5433 (0.8); 2.5224 (1.5); 2.5080 (1.0); 2.5015 (0.8); 2.4871 (1.6);2.4662 (0.8); 1.9964 (0.8); 1.9881 (1.3); 1.9795 (0.7); 1.9611 (0.6);1.9527 (1.2); 1.9442 (0.8); 1.8572 (0.8); 1.4322 (2.8); 1.3567 (7.9);1.3390 (16.0); 1.3212 (7.8); 1.2545 (0.6); 1.2466 (0.6); 1.2228 (0.7);0.0080 (3.9); −0.0002 (120.6); −0.0085 (3.9) I-135: ¹H-NMR(400.0 MHz,CDCl3): δ = 7.2613 (28.8); 7.2070 (0.5); 7.2014 (1.0); 7.1890 (4.9);7.1835 (6.0); 7.1726 (3.9); 7.1691 (6.1); 7.1636 (4.9); 7.1514 (1.0);7.0983 (1.6); 7.0766 (1.6); 6.9100 (1.2); 6.9042 (2.0); 6.8984 (1.2);6.8883 (2.4); 6.8825 (4.1); 6.8767 (2.1); 6.8666 (1.2); 6.8608 (2.1);6.8552 (1.1); 6.1989 (3.8); 6.1721 (4.2); 6.1557 (4.4); 6.1290 (4.6);6.1162 (1.0); 6.1061 (2.1); 6.0960 (1.0); 5.9783 (3.7); 5.9684 (6.2);5.9639 (3.3); 5.9584 (5.3); 5.9541 (3.0); 5.9171 (2.8); 5.9117 (5.0);5.9060 (2.9); 5.8979 (3.3); 5.8924 (1.8); 5.8412 (1.0); 5.8311 (2.1);5.8210 (1.0); 5.5520 (7.1); 5.5088 (6.2); 5.3456 (6.7); 5.3188 (6.3);5.0577 (0.9); 5.0541 (1.0); 5.0367 (1.7); 5.0326 (1.7); 5.0151 (1.0);4.3601 (3.4); 4.3500 (3.4); 4.3260 (6.8); 4.3160 (6.6); 4.2919 (3.5);4.2819 (3.3); 3.9373 (7.2); 3.8943 (8.2); 3.7355 (0.8); 3.5980 (1.6);3.5922 (1.5); 3.5888 (1.6); 3.5832 (1.6); 3.5767 (1.6); 3.3331 (7.6);3.2901 (6.6); 3.1120 (0.5); 2.5721 (1.7); 2.5510 (3.2); 2.5369 (2.2);2.5299 (1.9); 2.5158 (3.6); 2.4947 (1.8); 2.1712 (16.0); 1.9347 (1.9);1.9247 (3.4); 1.9146 (1.9); 1.8996 (1.7); 1.8895 (3.0); 1.8796 (1.7);1.4348 (1.1); 1.3199 (0.7); 1.3018 (1.3); 1.2832 (0.8); 1.2567 (2.2);0.8821 (0.6); 0.0077 (1.3); −0.0002 (34.2); −0.0084 (1.2) I-136:¹H-NMR(400.0 MHz, CDCl3): δ = 7.2610 (75.0); 7.1988 (0.9); 7.1931 (2.0);7.1872 (1.9); 7.1806 (9.2); 7.1749 (11.2); 7.1718 (6.7); 7.1640 (6.4);7.1609 (10.8); 7.1552 (8.7); 7.1485 (1.4); 7.1427 (1.5); 7.1370 (0.6);6.9205 (2.4); 6.9148 (4.1); 6.9089 (2.2); 6.8988 (4.7); 6.8931 (8.0);6.8872 (4.0); 6.8772 (2.4); 6.8714 (3.9); 6.8655 (1.9); 6.7513 (3.1);6.7308 (3.1); 6.1937 (7.7); 6.1669 (8.6); 6.1505 (9.1); 6.1238 (9.4);6.0735 (2.1); 6.0634 (4.2); 6.0533 (2.0); 5.9889 (4.4); 5.9845 (5.1);5.9829 (5.0); 5.9785 (4.7); 5.9750 (5.7); 5.9706 (6.7); 5.9690 (6.5);5.9646 (5.5); 5.9359 (4.3); 5.9258 (8.8); 5.9158 (4.2); 5.8888 (5.2);5.8832 (9.4); 5.8774 (5.6); 5.8750 (4.5); 5.8693 (7.2); 5.8635 (3.9);5.7983 (2.1); 5.7883 (4.4); 5.7783 (2.1); 5.6419 (0.6); 5.5989 (0.5);5.5504 (12.9); 5.5491 (12.7); 5.5073 (11.5); 5.5059 (11.1); 5.4236(0.5); 5.3554 (12.0); 5.3544 (11.5); 5.3287 (11.0); 5.3275 (11.0);5.1494 (0.6); 5.1439 (1.2); 5.1383 (1.6); 5.1326 (1.8); 5.1282 (2.3);5.1228 (2.9); 5.1179 (3.1); 5.1124 (3.1); 5.1072 (2.9); 5.1019 (2.2);5.0974 (1.7); 5.0919 (1.6); 5.0863 (1.1); 5.0808 (0.6); 4.3204 (7.7);4.3103 (7.8); 4.2862 (16.0); 4.2762 (15.4); 4.2520 (8.1); 4.2420 (7.7);3.9611 (0.6); 3.9493 (13.4); 3.9184 (0.7); 3.9061 (15.3); 3.8287 (1.1);3.8227 (2.8); 3.8168 (3.8); 3.8108 (4.1); 3.8049 (3.6); 3.8006 (3.6);3.7947 (4.1); 3.7887 (3.9); 3.7828 (2.8); 3.7768 (1.1); 3.4155 (0.5);3.3360 (13.7); 3.2928 (11.8); 3.1201 (0.6); 3.0986 (0.6); 2.7004 (3.7);2.6885 (3.7); 2.6797 (3.9); 2.6677 (4.4); 2.6651 (4.7); 2.6532 (4.2);2.6444 (4.0); 2.6325 (3.8); 1.9085 (3.8); 1.8972 (3.8); 1.8864 (4.0);1.8747 (5.0); 1.8619 (3.7); 1.8511 (3.5); 1.8398 (3.4); 1.5654 (0.5);1.5516 (0.5); 1.5356 (0.5); 1.5165 (0.5); 1.4634 (1.3); 1.4206 (1.3);1.4026 (2.5); 1.3843 (1.3); 1.2563 (2.6); 0.9484 (0.6); 0.9327 (0.6);0.9058 (0.7); 0.8901 (0.9); 0.8798 (1.0); 0.0080 (3.1); −0.0002 (93.9);−0.0085 (3.1) I-137: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.2623 (45.5); 7.2059(0.9); 7.2002 (1.9); 7.1943 (1.7); 7.1878 (9.1); 7.1821 (11.0); 7.1790(6.5); 7.1711 (6.3); 7.1680 (10.9); 7.1623 (9.2); 7.1558 (1.8); 7.1500(1.8); 7.1442 (1.0); 7.1222 (2.7); 7.0999 (2.8); 6.9082 (2.4); 6.9024(4.0); 6.8966 (2.2); 6.8865 (4.6); 6.8807 (8.0); 6.8749 (4.1); 6.8648(2.4); 6.8590 (4.0); 6.8532 (1.9); 6.1990 (7.8); 6.1722 (8.8); 6.1559(9.4); 6.1291 (9.5); 5.9551 (3.4); 5.9513 (3.9); 5.9490 (3.9); 5.9452(3.6); 5.9413 (5.1); 5.9375 (5.8); 5.9351 (5.7); 5.9314 (5.3); 5.8944(5.3); 5.8889 (9.7); 5.8833 (5.4); 5.8807 (3.8); 5.8751 (6.3); 5.8696(3.5); 5.5510 (13.0); 5.5494 (13.2); 5.5078 (11.4); 5.5063 (11.5);5.3445 (11.7); 5.3432 (11.6); 5.3177 (11.0); 5.3164 (10.8); 5.0527(1.6); 5.0495 (1.7); 5.0464 (1.4); 5.0435 (1.5); 5.0401 (1.8); 5.0316(2.9); 5.0277 (3.0); 5.0157 (1.4); 5.0129 (1.4); 5.0099 (1.7); 5.0066(1.6); 4.4017 (0.6); 4.3857 (1.3); 4.3722 (8.3); 4.3682 (8.8); 4.3619(2.0); 4.3560 (14.2); 4.3529 (15.6); 4.3407 (8.8); 4.3369 (8.8); 4.3232(1.2); 4.3073 (0.8); 3.9394 (14.0); 3.8965 (16.0); 3.8420 (0.5); 3.8386(0.8); 3.5544 (1.1); 3.5485 (2.1); 3.5445 (2.6); 3.5387 (2.8); 3.5356(2.6); 3.5328 (2.7); 3.5299 (2.7); 3.5271 (2.6); 3.5241 (2.8); 3.5174(2.7); 3.5142 (2.2); 3.5083 (1.2); 3.3315 (14.1); 3.2885 (12.3); 3.1171(0.9); 3.1015 (0.9); 2.5660 (1.9); 2.5503 (3.3); 2.5400 (9.1); 2.5348(2.7); 2.5242 (10.0); 2.5191 (7.4); 2.5138 (7.0); 2.5086 (6.5); 2.5051(5.4); 2.4980 (13.4); 2.4875 (3.4); 2.4832 (9.5); 2.4720 (3.6); 2.4628(3.7); 2.4564 (2.2); 1.9130 (3.3); 1.9032 (5.9); 1.8934 (3.3); 1.8778(3.0); 1.8681 (5.3); 1.8583 (3.1); 1.4348 (0.5); 1.4207 (1.3); 1.4042(2.5); 1.3871 (1.2); 1.2561 (1.7); 0.8809 (0.7); 0.0080 (1.6); −0.0002(56.4); −0.0085 (2.1) I-138: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.5193 (0.6);7.2605 (108.3); 7.1929 (0.8); 7.1870 (0.7); 7.1805 (4.2); 7.1747 (5.1);7.1716 (3.0); 7.1639 (2.9); 7.1607 (5.0); 7.1550 (4.1); 7.1482 (0.7);7.1425 (0.7); 6.9964 (0.6); 6.9198 (1.1); 6.9140 (1.9); 6.9082 (1.0);6.8981 (2.2); 6.8923 (3.7); 6.8865 (1.9); 6.8764 (1.1); 6.8706 (1.9);6.8648 (0.9); 6.7368 (1.5); 6.7158 (1.5); 6.1936 (3.7); 6.1668 (4.1);6.1505 (4.4); 6.1237 (4.5); 5.9694 (2.0); 5.9650 (2.4); 5.9634 (2.4);5.9591 (2.2); 5.9556 (2.6); 5.9512 (3.0); 5.9495 (3.0); 5.9452 (2.6);5.8653 (2.5); 5.8597 (4.6); 5.8539 (2.6); 5.8515 (2.2); 5.8457 (3.5);5.8400 (1.9); 5.5490 (6.1); 5.5476 (6.1); 5.5059 (5.4); 5.5044 (5.4);5.3535 (5.6); 5.3523 (5.6); 5.3267 (5.2); 5.3256 (5.3); 5.1329 (0.6);5.1274 (0.8); 5.1215 (0.8); 5.1171 (1.1); 5.1118 (1.4); 5.1065 (1.5);5.1008 (1.4); 5.0963 (1.4); 5.0908 (1.1); 5.0863 (0.8); 5.0805 (0.7);5.0751 (0.6); 4.3401 (0.6); 4.3264 (3.8); 4.3221 (4.0); 4.3103 (7.0);4.3069 (7.4); 4.2950 (4.1); 4.2910 (3.9); 3.9494 (6.5); 3.9062 (7.4);3.9024 (2.6); 3.7668 (0.5); 3.7608 (1.3); 3.7549 (1.8); 3.7489 (2.0);3.7430 (1.7); 3.7388 (1.7); 3.7328 (2.0); 3.7268 (1.9); 3.7209 (1.3);3.7149 (0.5); 3.3338 (6.5); 3.2907 (5.7); 2.6828 (1.8); 2.6708 (1.7);2.6621 (1.8); 2.6501 (2.1); 2.6476 (2.2); 2.6356 (2.0); 2.6269 (1.9);2.6149 (1.8); 2.5128 (0.9); 2.4971 (1.6); 2.4867 (2.8); 2.4816 (1.2);2.4710 (4.5); 2.4607 (3.0); 2.4555 (2.9); 2.4450 (4.6); 2.4346 (1.2);2.4294 (2.7); 2.4189 (1.5); 2.4034 (0.9); 1.8743 (1.8); 1.8630 (1.8);1.8523 (1.8); 1.8407 (2.3); 1.8278 (1.7); 1.8170 (1.6); 1.8057 (1.6);1.5420 (16.0); 1.2563 (0.7); 0.0080 (4.3); −0.0002 (135.2); −0.0085(4.8) I-139: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.9410 (3.0); 7.9376 (3.8);7.9337 (2.9); 7.9291 (2.4); 7.9251 (1.5); 7.8776 (0.8); 7.8745 (1.0);7.8702 (0.9); 7.8676 (1.0); 7.8645 (1.2); 7.8602 (1.1); 7.8575 (1.4);7.8536 (2.2); 7.8503 (1.8); 7.8477 (1.6); 7.8447 (1.4); 7.8404 (1.1);7.8365 (1.0); 7.8338 (1.2); 7.8319 (1.3); 7.8299 (1.1); 7.8273 (0.7);7.7284 (0.7); 7.7253 (1.4); 7.7218 (1.5); 7.7185 (1.5); 7.7156 (1.7);7.7120 (1.7); 7.7091 (1.7); 7.7059 (1.9); 7.7024 (1.8); 7.6991 (1.7);7.6963 (2.0); 7.6926 (1.9); 7.6898 (1.0); 7.5669 (1.1); 7.5649 (1.1);7.5569 (1.6); 7.5473 (1.8); 7.5452 (1.8); 7.5373 (2.6); 7.5276 (0.8);7.5256 (0.8); 7.5177 (1.1); 7.2627 (18.6); 7.1017 (0.7); 6.7924 (0.6);6.7727 (0.6); 6.1338 (0.7); 6.0973 (0.7); 6.0872 (0.5); 6.0064 (0.7);5.9964 (1.5); 5.9861 (1.3); 5.9805 (1.5); 5.9759 (1.7); 5.9701 (2.1);5.9673 (1.5); 5.9614 (2.2); 5.9600 (2.2); 5.9567 (1.3); 5.9497 (1.5);5.9437 (0.9); 5.9379 (1.7); 5.9326 (1.9); 5.9295 (0.8); 5.9270 (0.9);5.9233 (1.3); 5.9187 (0.9); 5.9131 (0.9); 5.9078 (0.6); 5.9021 (1.0);5.8964 (0.6); 5.8882 (0.7); 5.8589 (0.7); 5.8474 (0.9); 5.8417 (1.4);5.8359 (0.9); 5.8330 (1.3); 5.8275 (1.9); 5.8222 (1.6); 5.8129 (1.1);5.1042 (0.5); 5.0983 (0.5); 5.0283 (0.7); 5.0240 (0.7); 5.0202 (0.7);5.0161 (0.7); 4.3888 (1.3); 4.3788 (1.3); 4.3546 (2.6); 4.3486 (1.3);4.3446 (2.7); 4.3386 (1.2); 4.3352 (1.0); 4.3251 (1.0); 4.3203 (1.6);4.3184 (1.2); 4.3144 (2.0); 4.3103 (1.7); 4.3083 (1.3); 4.3043 (2.0);4.3010 (1.9); 4.2908 (1.6); 4.2840 (1.8); 4.2803 (1.1); 4.2740 (1.7);4.2702 (1.0); 4.2668 (1.0); 4.2567 (0.8); 4.2499 (0.9); 4.2398 (0.8);3.8620 (1.5); 3.8543 (2.6); 3.8475 (2.6); 3.8428 (0.8); 3.8188 (2.0);3.8111 (3.2); 3.8042 (3.0); 3.6017 (0.7); 3.5967 (0.7); 3.2436 (2.0);3.2417 (2.1); 3.2376 (2.5); 3.2296 (2.2); 3.2002 (1.8); 3.1983 (1.8);3.1944 (2.3); 3.1864 (2.0); 2.6261 (0.5); 2.6050 (0.9); 2.5910 (0.6);2.5838 (0.6); 2.5698 (1.0); 2.5574 (0.5); 2.5487 (0.6); 2.5363 (0.9);2.5223 (0.6); 2.5152 (0.6); 2.5012 (1.0); 2.4801 (0.6); 1.9855 (0.9);1.9755 (0.5); 1.9603 (0.8); 1.9499 (1.0); 1.9384 (0.6); 1.9097 (0.6);1.8997 (1.0); 1.8896 (0.5); 1.8745 (0.6); 1.8677 (0.6); 1.8646 (0.8);1.8570 (0.5); 1.8548 (0.5); 1.8456 (0.5); 1.7392 (12.7); 1.7337 (16.0);1.7274 (13.0); 1.5801 (2.2); 0.0080 (0.8); −0.0002 (23.0); −0.0085 (0.7)I-140: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.2614 (12.6); 7.2221 (0.5); 7.2096(1.3); 7.2038 (1.5); 7.2006 (0.9); 7.1930 (0.9); 7.1898 (1.5); 7.1841(1.2); 6.9155 (0.6); 6.8995 (0.6); 6.8937 (1.1); 6.8879 (0.5); 6.8720(0.6); 5.9845 (0.5); 5.9817 (0.5); 5.9782 (0.5); 5.9744 (0.7); 5.9708(0.8); 5.9680 (0.7); 5.9645 (0.7); 5.9114 (0.7); 5.9059 (1.2); 5.9003(0.7); 5.8978 (0.6); 5.8921 (0.9); 4.2182 (1.1); 4.2004 (3.7); 4.1825(3.8); 4.1647 (1.2); 3.8589 (1.9); 3.8135 (2.2); 3.3748 (16.0); 3.3587(2.4); 3.3133 (2.0); 2.5536 (0.8); 2.5396 (0.6); 2.5185 (1.0); 1.9950(0.8); 1.9599 (0.7); 1.5572 (3.3); 1.3157 (4.1); 1.2979 (8.5); 1.2800(4.0); −0.0002 (15.0); −0.0085 (0.5) I-141: ¹H-NMR(400.0 MHz, CDCl3): δ= 7.2603 (69.5); 7.2124 (1.2); 7.2067 (1.4); 7.1959 (0.8); 7.1927 (1.4);7.1869 (1.2); 6.9162 (0.6); 6.9003 (0.6); 6.8945 (1.1); 6.8727 (0.5);5.9852 (0.5); 5.9777 (0.7); 5.9744 (0.7); 5.9715 (0.7); 5.9682 (0.7);5.9322 (0.7); 5.9268 (1.2); 5.9213 (0.7); 5.9130 (0.8); 4.2021 (0.7);4.1857 (2.2); 4.1842 (2.2); 4.1678 (2.3); 4.1665 (2.1); 4.1498 (0.8);3.8654 (1.8); 3.8202 (2.1); 3.3667 (16.0); 3.3540 (2.3); 3.3088 (1.9);2.5293 (0.9); 2.5152 (0.5); 2.4941 (0.9); 1.9868 (0.8); 1.9519 (0.7);1.5445 (10.7); 1.3029 (4.2); 1.2851 (8.6); 1.2672 (4.1); 0.0080 (2.4);−0.0002 (82.0); −0.0085 (2.6) I-142: ¹H-NMR(400.0 MHz, CDCl3): δ =7.2773 (2.4); 7.2612 (45.7); 7.2160 (0.8); 7.2103 (1.3); 7.2043 (1.2);7.1977 (5.8); 7.1922 (7.3); 7.1813 (4.8); 7.1780 (7.4); 7.1725 (6.1);7.1602 (1.3); 6.9272 (1.4); 6.9215 (2.4); 6.9157 (1.4); 6.9055 (2.9);6.8997 (4.8); 6.8940 (2.6); 6.8838 (1.6); 6.8781 (2.5); 6.8723 (1.3);6.0125 (2.4); 6.0089 (2.8); 6.0063 (2.9); 6.0026 (2.8); 5.9988 (3.5);5.9951 (3.9); 5.9925 (3.8); 5.9890 (3.5); 5.9281 (3.1); 5.9225 (5.7);5.9168 (3.7); 5.9088 (4.4); 5.9032 (2.5); 5.0540 (1.3); 5.0329 (2.4);5.0141 (1.4); 4.4015 (0.6); 4.3856 (5.3); 4.3821 (5.5); 4.3720 (10.4);4.3675 (9.4); 4.3571 (6.3); 4.3542 (6.2); 4.3378 (0.7); 4.0221 (5.7);3.9921 (13.2); 3.9517 (12.8); 3.9217 (5.6); 3.7288 (1.7); 3.7234 (7.2);3.7169 (11.3); 3.7027 (16.0); 3.6888 (10.6); 3.6795 (11.4); 3.5902(2.2); 3.5871 (2.1); 3.5841 (2.3); 3.5755 (2.2); 3.5687 (2.7); 3.5590(11.8); 3.5149 (6.3); 2.5316 (2.0); 2.5106 (3.9); 2.4964 (2.7); 2.4895(2.4); 2.4753 (4.4); 2.4543 (2.2); 1.9712 (2.2); 1.9623 (4.0); 1.9533(2.3); 1.9361 (2.0); 1.9271 (3.6); 1.9182 (2.1); 1.5666 (1.9); 1.2565(2.0); 0.8801 (0.6); 0.8526 (0.6); 0.0079 (2.0); −0.0002 (55.2); −0.0083(3.2) I-143: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.2729 (2.1); 7.2610 (60.3);7.2050 (0.6); 7.1993 (1.1); 7.1868 (5.1); 7.1811 (6.1); 7.1779 (3.8);7.1703 (3.8); 7.1671 (6.0); 7.1615 (4.8); 7.1547 (0.8); 7.1490 (0.8);6.9254 (1.2); 6.9196 (2.1); 6.9138 (1.2); 6.9037 (2.5); 6.8979 (4.1);6.8921 (2.1); 6.8820 (1.3); 6.8762 (2.0); 6.8704 (1.0); 6.0052 (2.2);6.0015 (2.4); 5.9989 (2.5); 5.9951 (2.4); 5.9915 (2.7); 5.9877 (2.9);5.9851 (2.8); 5.9814 (2.5); 5.8567 (2.5); 5.8510 (4.4); 5.8453 (2.8);5.8431 (2.5); 5.8372 (3.8); 5.8317 (2.1); 5.0661 (1.0); 5.0474 (1.9);5.0264 (1.0); 4.4427 (0.6); 4.4266 (4.5); 4.4221 (4.7); 4.4127 (7.6);4.4083 (6.9); 4.3982 (5.1); 4.3944 (4.9); 4.3779 (0.6); 4.0495 (5.9);4.0194 (10.6); 3.9532 (10.1); 3.9232 (5.7); 3.7570 (9.2); 3.7481 (2.1);3.7429 (16.0); 3.7382 (2.4); 3.7289 (7.5); 3.7181 (5.9); 3.6741 (9.3);3.6070 (1.7); 3.6042 (1.6); 3.6012 (1.8); 3.5945 (1.6); 3.5923 (1.6);3.5856 (1.9); 3.5825 (1.7); 3.5798 (1.8); 3.5537 (8.7); 3.5096 (5.3);2.5958 (1.7); 2.5747 (3.1); 2.5605 (2.2); 2.5534 (1.9); 2.5393 (3.5);2.5182 (1.8); 2.0420 (1.8); 2.0333 (3.2); 2.0245 (1.8); 2.0068 (1.7);1.9980 (2.8); 1.9892 (1.6); 1.5643 (1.8); 1.2564 (1.9); 0.8812 (0.6);0.8527 (0.6); 0.0080 (2.5); −0.0002 (76.7); −0.0085 (3.2) I-144:¹H-NMR(400.0 MHz, CDCl3): δ = 7.2610 (65.5); 7.2126 (1.4); 7.2068 (1.7);7.2037 (1.2); 7.1929 (2.0); 7.1871 (2.0); 7.1822 (4.4); 7.1765 (5.1);7.1735 (3.2); 7.1659 (3.1); 7.1627 (4.9); 7.1570 (4.0); 7.1504 (0.6);7.1444 (0.7); 6.9372 (1.1); 6.9314 (1.8); 6.9256 (1.0); 6.9221 (0.7);6.9156 (2.5); 6.9098 (3.8); 6.9039 (2.0); 6.9005 (1.1); 6.8943 (2.1);6.8882 (2.4); 6.8823 (1.3); 6.8728 (1.8); 6.8501 (1.5); 6.0321 (2.1);6.0278 (2.5); 6.0261 (2.5); 6.0219 (2.3); 6.0182 (2.4); 6.0139 (2.8);6.0122 (2.8); 6.0080 (2.3); 5.9879 (0.6); 5.9853 (0.6); 5.9818 (0.6);5.9778 (0.8); 5.9744 (0.8); 5.9715 (0.8); 5.9683 (0.7); 5.9322 (0.8);5.9268 (1.3); 5.9213 (0.8); 5.9130 (0.8); 5.8305 (2.2); 5.8246 (4.0);5.8188 (2.5); 5.8167 (2.2); 5.8108 (3.5); 5.8050 (1.9); 5.1409 (0.6);5.1361 (0.9); 5.1305 (1.0); 5.1259 (1.3); 5.1203 (1.6); 5.1154 (1.7);5.1099 (1.8); 5.1052 (1.8); 5.0996 (1.4); 5.0952 (1.1); 5.0893 (1.0);5.0844 (0.8); 4.3686 (5.2); 4.3552 (6.8); 4.3524 (5.6); 4.3407 (6.7);4.2021 (0.8); 4.1857 (2.3); 4.1843 (2.3); 4.1677 (2.4); 4.1666 (2.4);4.1499 (0.9); 4.0480 (5.3); 4.0181 (8.8); 3.9353 (8.2); 3.9053 (5.0);3.8660 (2.0); 3.8341 (0.5); 3.8280 (1.4); 3.8210 (3.4); 3.8157 (2.0);3.8096 (1.7); 3.8061 (1.7); 3.8000 (1.9); 3.7938 (1.8); 3.7877 (1.3);3.7817 (0.5); 3.7318 (5.0); 3.6996 (8.2); 3.6875 (12.5); 3.6854 (10.9);3.6714 (7.2); 3.5306 (7.1); 3.4863 (4.5); 3.3667 (16.0); 3.3545 (2.5);3.3092 (2.1); 2.7537 (1.7); 2.7412 (1.6); 2.7332 (1.8); 2.7207 (2.1);2.7185 (2.2); 2.7060 (1.9); 2.6980 (1.8); 2.6855 (1.8); 2.5293 (0.9);2.5153 (0.6); 2.5082 (0.5); 2.4941 (1.0); 1.9997 (1.7); 1.9889 (2.1);1.9779 (2.1); 1.9671 (2.1); 1.9646 (2.0); 1.9536 (2.0); 1.9427 (1.8);1.9319 (1.5); 1.5596 (3.2); 1.3030 (4.5); 1.2852 (8.9); 1.2673 (4.9);1.2564 (2.4); 0.8798 (0.8); 0.8535 (0.7); 0.0080 (2.9); −0.0002 (83.5);−0.0085 (2.9) I-145: ¹H-NMR(400.0 MHz, CDCl3): δ = 8.0232 (2.1); 7.5211(0.6); 7.2622 (86.8); 7.2118 (0.6); 7.2061 (0.7); 7.2003 (1.4); 7.1876(7.0); 7.1820 (8.3); 7.1788 (5.3); 7.1712 (5.2); 7.1681 (8.3); 7.1624(6.6); 7.1556 (1.2); 7.1499 (1.2); 6.9981 (0.5); 6.9413 (1.8); 6.9356(3.0); 6.9298 (1.7); 6.9197 (3.6); 6.9139 (6.0); 6.9082 (3.4); 6.8980(3.1); 6.8923 (5.3); 6.8866 (3.0); 6.8708 (2.4); 6.0240 (3.2); 6.0196(3.9); 6.0179 (3.8); 6.0135 (3.6); 6.0101 (4.1); 6.0057 (4.7); 6.0040(4.5); 5.9996 (3.9); 5.8889 (3.7); 5.8832 (6.7); 5.8774 (4.2); 5.8751(3.5); 5.8693 (5.5); 5.8636 (3.0); 5.1677 (0.9); 5.1620 (1.2); 5.1562(1.3); 5.1518 (1.7); 5.1465 (2.2); 5.1412 (2.3); 5.1360 (2.3); 5.1307(2.2); 5.1254 (1.7); 5.1211 (1.2); 5.1152 (1.1); 5.1099 (0.9); 4.3566(7.8); 4.3449 (10.4); 4.3438 (10.6); 4.3406 (9.0); 4.3290 (10.0); 4.1581(0.6); 4.1401 (0.6); 4.0348 (7.9); 4.0047 (14.5); 3.9451 (13.6); 3.9150(7.4); 3.8093 (1.2); 3.8031 (2.2); 3.7972 (2.9); 3.7913 (3.1); 3.7855(2.8); 3.7810 (2.8); 3.7752 (3.3); 3.7693 (3.2); 3.7634 (2.6); 3.7575(1.2); 3.7359 (7.8); 3.7125 (0.9); 3.6916 (14.5); 3.6894 (16.0); 3.6750(14.8); 3.6612 (11.6); 3.5570 (11.0); 3.5127 (7.0); 3.4968 (0.8); 2.7188(4.2); 2.7071 (4.2); 2.6981 (4.3); 2.6863 (4.8); 2.6836 (4.9); 2.6718(4.5); 2.6626 (5.0); 2.6511 (4.2); 1.8973 (2.8); 1.8857 (2.8); 1.8752(2.9); 1.8633 (3.8); 1.8505 (2.7); 1.8400 (2.5); 1.8285 (2.5); 1.7288(0.9); 1.7203 (1.7); 1.3060 (0.9); 1.2881 (1.2); 1.2738 (1.6); 1.2560(4.3); 1.2382 (1.4); 0.8803 (1.3); 0.8529 (1.2); 0.0080 (3.8); −0.0002(109.7); −0.0085 (4.1) I-146: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.6650(1.5); 7.6607 (1.8); 7.6465 (1.4); 7.6408 (2.0); 7.5189 (0.7); 7.4331(0.7); 7.4211 (3.0); 7.4031 (1.6); 7.2601 (113.7); 6.9960 (0.7); 6.2306(1.1); 6.2039 (1.2); 6.1875 (1.3); 6.1607 (1.4); 5.9436 (0.9); 5.9376(0.7); 5.8809 (0.8); 5.8753 (1.3); 5.8697 (0.8); 5.8615 (1.0); 5.8559(0.6); 5.5613 (1.7); 5.5183 (1.6); 5.3235 (1.6); 5.2969 (1.4); 3.9845(1.9); 3.9416 (2.3); 3.7290 (16.0); 3.5050 (0.5); 3.3961 (2.0); 3.3531(1.8); 2.5180 (0.9); 2.5041 (0.6); 2.4969 (0.6); 2.4831 (1.1); 2.4620(0.6); 1.8921 (0.9); 1.8821 (0.5); 1.8571 (0.8); 1.8471 (0.6); 1.7054(4.6); 0.1461 (0.6); 0.0080 (4.9); −0.0002 (140.9); −0.0085 (4.9);−0.1498 (0.6) I-147: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.6588 (1.6); 7.6547(1.7); 7.6506 (0.8); 7.6484 (0.7); 7.6450 (0.7); 7.6401 (1.4); 7.6347(1.9); 7.4356 (0.5); 7.4321 (0.6); 7.4235 (1.4); 7.4194 (3.0); 7.4149(1.4); 7.4130 (1.1); 7.4057 (0.9); 7.4017 (1.5); 7.4006 (1.4); 7.2609(14.1); 6.2304 (1.0); 6.2036 (1.2); 6.1872 (1.3); 6.1605 (1.3); 5.9468(0.5); 5.9427 (0.6); 5.9407 (0.6); 5.9366 (0.6); 5.9330 (0.7); 5.9289(0.7); 5.9269 (0.7); 5.9228 (0.6); 5.8248 (0.6); 5.8191 (1.2); 5.8134(0.7); 5.8111 (0.6); 5.8053 (1.0); 5.7997 (0.5); 5.5793 (1.7); 5.5774(1.6); 5.5362 (1.5); 5.5343 (1.5); 5.3383 (1.5); 5.3365 (1.5); 5.3116(1.4); 5.3098 (1.4); 3.9898 (2.0); 3.9469 (2.3); 3.7523 (0.8); 3.7464(16.0); 3.7293 (0.6); 3.3934 (2.0); 3.3504 (1.7); 2.5609 (0.8); 2.5471(0.6); 2.5398 (0.5); 2.5260 (0.9); 2.5049 (0.5); 1.9392 (0.8); 1.9044(0.7); 0.0080 (0.6); −0.0002 (18.5); −0.0085 (0.7) I-148: ¹H-NMR(400.0MHz, CDCl3): δ = 7.9797 (7.7); 7.9762 (10.6); 7.9722 (8.2); 7.9680(6.0); 7.9038 (2.1); 7.9006 (2.8); 7.8961 (2.9); 7.8919 (2.9); 7.8877(2.6); 7.8806 (5.8); 7.8766 (4.9); 7.8721 (3.4); 7.8681 (2.6); 7.8599(3.2); 7.7854 (2.9); 7.7825 (3.1); 7.7788 (3.7); 7.7757 (4.8); 7.7730(4.5); 7.7694 (3.6); 7.7660 (3.9); 7.7630 (4.0); 7.7593 (4.4); 7.7563(5.6); 7.7536 (5.1); 7.6131 (2.7); 7.6053 (4.4); 7.5942 (4.4); 7.5856(7.1); 7.5748 (2.0); 7.5659 (3.1); 7.2626 (32.9); 7.2400 (2.0); 6.8252(0.9); 6.8033 (1.4); 6.7812 (0.8); 6.1338 (0.7); 6.1238 (1.4); 6.1139(0.8); 6.1076 (0.8); 6.0976 (1.5); 6.0932 (0.6); 6.0876 (0.9); 6.0831(1.1); 6.0710 (0.9); 6.0504 (1.1); 6.0456 (1.5); 6.0394 (1.8); 6.0303(3.3); 6.0262 (3.4); 6.0201 (3.1); 6.0154 (4.2); 6.0127 (4.2); 6.0097(4.0); 6.0064 (3.7); 6.0018 (2.4); 5.9964 (3.4); 5.9920 (2.0); 5.9866(3.2); 5.9766 (1.8); 5.9684 (2.6); 5.9610 (4.5); 5.9565 (3.1); 5.9496(3.4); 5.9456 (2.9); 5.9335 (1.8); 5.9235 (1.0); 5.9188 (1.1); 5.9132(1.8); 5.9072 (1.2); 5.8993 (3.0); 5.8937 (3.7); 5.8879 (2.0); 5.8800(2.3); 5.8744 (1.3); 5.8627 (1.2); 5.8571 (2.2); 5.8493 (2.6); 5.8431(1.9); 5.8387 (1.3); 5.8330 (0.9); 5.8229 (1.6); 5.8182 (0.6); 5.8130(0.8); 5.8082 (1.0); 5.7962 (0.9); 5.3001 (16.0); 5.1841 (0.7); 5.1784(0.8); 5.1723 (0.9); 5.1675 (0.9); 5.1557 (0.9); 5.1509 (1.1); 5.1455(1.0); 5.1407 (0.8); 5.1352 (0.6); 5.1300 (0.7); 5.1242 (0.9); 5.1197(1.0); 5.1001 (1.9); 5.0799 (2.0); 4.4328 (0.5); 4.3943 (2.9); 4.3843(2.4); 4.3638 (2.4); 4.3600 (5.6); 4.3563 (3.0); 4.3541 (2.9); 4.3501(5.2); 4.3443 (2.3); 4.3323 (5.7); 4.3257 (3.8); 4.3222 (5.5); 4.3160(3.2); 4.3100 (3.9); 4.2984 (5.9); 4.2880 (4.6); 4.2758 (1.9); 4.2654(2.3); 4.2537 (1.4); 4.0606 (2.2); 4.0502 (5.3); 4.0152 (3.2); 4.0051(7.4); 3.8758 (0.6); 3.8696 (0.9); 3.8635 (1.0); 3.8574 (1.1); 3.8534(1.4); 3.8476 (1.7); 3.8415 (1.8); 3.8355 (1.5); 3.8307 (1.1); 3.8253(1.1); 3.8123 (7.4); 3.8072 (7.3); 3.8005 (6.4); 3.7927 (1.0); 3.7812(2.3); 3.7670 (5.1); 3.7620 (5.0); 3.7553 (4.3); 3.7343 (2.0); 3.6409(1.8); 3.6343 (2.2); 3.6274 (2.4); 3.6200 (2.3); 3.6137 (1.9); 3.6076(1.4); 2.7795 (0.8); 2.7671 (0.8); 2.7590 (0.9); 2.7463 (1.1); 2.7441(1.1); 2.7355 (0.8); 2.7315 (1.0); 2.7236 (1.6); 2.7147 (0.9); 2.7112(1.0); 2.7031 (0.9); 2.7004 (0.9); 2.6886 (0.8); 2.6794 (0.8); 2.6677(0.8); 2.6274 (1.2); 2.6063 (2.1); 2.5919 (1.4); 2.5852 (1.2); 2.5708(2.3); 2.5524 (1.6); 2.5318 (2.4); 2.5173 (1.6); 2.5109 (1.4); 2.4964(2.6); 2.4755 (1.3); 2.0361 (1.2); 2.0278 (2.2); 2.0186 (1.6); 2.0066(1.4); 2.0002 (2.4); 1.9918 (4.2); 1.9835 (3.1); 1.9708 (1.0); 1.9645(1.3); 1.9560 (2.3); 1.9476 (2.2); 1.9353 (0.8); 1.9248 (0.7); 1.9127(1.1); 1.8998 (0.7); 1.8893 (0.6); 1.8778 (0.6); 1.5759 (2.6); 0.0080(1.5); −0.0002 (39.7); −0.0080 (1.4) I-149: ¹H-NMR(400.0 MHz, CDCl3): δ= 7.2602 (7.0); 7.1930 (0.7); 7.1873 (0.7); 7.1819 (0.7); 7.1761 (0.9);7.1732 (0.9); 7.1674 (0.7); 7.1620 (0.6); 6.8898 (0.7); 4.0055 (0.9);3.9869 (1.2); 3.9574 (1.7); 3.9274 (0.7); 3.7187 (0.5); 3.6748 (0.9);3.6647 (0.7); 3.5579 (1.3); 3.5139 (0.7); 1.5524 (0.8); 1.4957 (0.5);1.4842 (0.9); 1.4761 (12.9); 1.4418 (1.9); 1.4313 (16.0); −0.0002 (8.7)I-150: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.3854 (0.9); 7.3636 (0.9); 7.2608(12.3); 7.2238 (4.8); 7.1960 (1.4); 7.0071 (1.4); 6.9839 (1.3); 6.0074(1.1); 6.0040 (1.2); 6.0010 (1.2); 5.9975 (1.2); 5.9937 (1.5); 5.9902(1.6); 5.9873 (1.6); 5.9839 (1.4); 5.9210 (1.4); 5.9155 (2.5); 5.9099(1.6); 5.9018 (1.8); 5.8962 (1.0); 5.0862 (0.6); 5.0652 (1.1); 5.0456(0.5); 4.2165 (2.2); 4.1986 (6.7); 4.1808 (6.9); 4.1630 (2.3); 4.0036(2.0); 3.9585 (2.9); 3.7762 (4.7); 3.7312 (3.3); 3.5297 (1.0); 3.5269(0.9); 3.5236 (1.0); 3.5155 (0.9); 3.5086 (1.0); 3.5056 (0.9); 3.5026(1.0); 2.4954 (1.0); 2.4745 (1.8); 2.4602 (1.2); 2.4536 (1.1); 2.4393(2.1); 2.4182 (1.3); 2.3863 (16.0); 1.9642 (1.0); 1.9558 (1.8); 1.9475(1.1); 1.9290 (0.9); 1.9206 (1.6); 1.9122 (0.9); 1.5578 (5.9); 1.3024(7.7); 1.2846 (15.3); 1.2667 (7.7); 0.0079 (0.7); −0.0002 (18.3);−0.0084 (0.8) I-151: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.3727 (0.9); 7.3503(0.9); 7.2612 (10.0); 7.2148 (4.4); 7.1868 (1.4); 7.0061 (1.4); 6.9829(1.3); 5.9976 (1.2); 5.9941 (1.3); 5.9911 (1.3); 5.9876 (1.3); 5.9839(1.4); 5.9804 (1.5); 5.9774 (1.4); 5.9740 (1.3); 5.8512 (1.4); 5.8457(2.4); 5.8400 (1.5); 5.8378 (1.4); 5.8319 (1.9); 5.8264 (1.1); 5.1078(0.6); 5.0857 (1.1); 5.0650 (0.6); 4.2371 (2.3); 4.2192 (7.1); 4.2014(7.3); 4.1835 (2.5); 4.0016 (2.0); 3.9566 (2.9); 3.7710 (4.8); 3.7260(3.4); 3.5473 (0.5); 3.5411 (1.0); 3.5347 (1.0); 3.5273 (0.9); 3.5198(1.0); 3.5136 (1.0); 2.5604 (1.0); 2.5394 (1.8); 2.5251 (1.2); 2.5183(1.1); 2.5040 (2.0); 2.4830 (1.0); 2.3838 (16.0); 2.0047 (1.0); 1.9967(1.8); 1.9888 (1.0); 1.9694 (0.9); 1.9614 (1.6); 1.9535 (0.9); 1.5633(5.0); 1.3255 (7.9); 1.3076 (15.8); 1.2960 (0.8); 1.2897 (7.7); 1.2575(0.8); 1.2528 (0.7); 0.0080 (0.6); −0.0002 (15.2); −0.0084 (0.6) I-152:¹H-NMR(400.0 MHz, CDCl3): δ = 7.2605 (20.1); 7.2107 (5.2); 7.1900 (1.4);7.0210 (1.4); 6.9975 (1.4); 6.8092 (1.0); 6.7896 (0.9); 6.0269 (1.3);6.0225 (1.6); 6.0210 (1.6); 6.0166 (1.5); 6.0131 (1.6); 6.0086 (1.8);6.0071 (1.7); 6.0027 (1.4); 5.8702 (1.4); 5.8645 (2.5); 5.8586 (1.6);5.8565 (1.4); 5.8506 (2.1); 5.8449 (1.2); 5.1827 (0.5); 5.1769 (0.6);5.1723 (0.7); 5.1669 (0.9); 5.1620 (1.0); 5.1566 (1.0); 5.1512 (0.9);5.1460 (0.7); 5.1415 (0.5); 5.1355 (0.5); 4.1677 (2.2); 4.1623 (0.6);4.1499 (6.7); 4.1321 (6.7); 4.1143 (2.2); 4.0105 (1.9); 3.9653 (2.8);3.7862 (4.6); 3.7522 (0.5); 3.7461 (1.2); 3.7409 (4.1); 3.7345 (1.4);3.7286 (1.1); 3.7244 (1.2); 3.7184 (1.2); 3.7125 (1.1); 3.7065 (0.8);2.7113 (1.1); 2.6994 (1.1); 2.6906 (1.2); 2.6785 (1.4); 2.6762 (1.4);2.6642 (1.2); 2.6553 (1.1); 2.6434 (1.1); 2.3919 (16.0); 1.8873 (1.1);1.8760 (1.1); 1.8654 (1.1); 1.8537 (1.5); 1.8408 (1.0); 1.8301 (1.0);1.8188 (1.0); 1.5464 (11.0); 1.3255 (0.6); 1.3077 (1.1); 1.2959 (0.6);1.2899 (0.9); 1.2817 (1.0); 1.2704 (7.9); 1.2639 (2.1); 1.2526 (15.7);1.2347 (7.3); 0.0079 (1.4); −0.0002 (29.3); −0.0084 (1.0) I-153:¹H-NMR(400.0 MHz, CDCl3): δ = 7.2609 (13.2); 7.2112 (4.4); 7.2086 (4.7);7.1915 (1.1); 7.1872 (1.3); 7.0186 (1.4); 6.9967 (1.3); 6.9948 (1.3);6.8319 (0.9); 6.8117 (0.9); 6.0372 (1.3); 6.0330 (1.6); 6.0313 (1.5);6.0270 (1.4); 6.0233 (1.5); 6.0191 (1.7); 6.0174 (1.7); 6.0132 (1.5);5.8166 (1.3); 5.8108 (2.4); 5.8048 (1.5); 5.8029 (1.4); 5.7969 (2.0);5.7911 (1.1); 5.2993 (10.6); 5.1546 (0.6); 5.1488 (0.6); 5.1443 (0.7);5.1386 (0.9); 5.1340 (1.0); 5.1283 (1.0); 5.1237 (0.8); 5.1180 (0.6);4.1799 (2.1); 4.1620 (6.4); 4.1498 (0.9); 4.1442 (6.5); 4.1320 (0.6);4.1264 (2.1); 4.0069 (1.8); 3.9617 (2.7); 3.7842 (4.6); 3.7701 (0.9);3.7639 (1.1); 3.7576 (1.2); 3.7515 (1.1); 3.7483 (1.2); 3.7391 (3.5);3.7297 (0.9); 2.7458 (1.0); 2.7332 (1.0); 2.7253 (1.1); 2.7125 (1.4);2.7107 (1.4); 2.6979 (1.2); 2.6900 (1.2); 2.6774 (1.1); 2.3892 (15.0);1.9665 (1.0); 1.9560 (1.0); 1.9447 (1.0); 1.9341 (1.2); 1.9313 (1.1);1.9207 (1.0); 1.9094 (0.9); 1.8989 (0.9); 1.5524 (1.7); 1.2817 (7.7);1.2701 (1.7); 1.2638 (16.0); 1.2526 (2.5); 1.2460 (7.6); 1.2347 (0.9);0.8801 (0.6); 0.8533 (0.5); 0.0079 (0.8); −0.0002 (20.2); −0.0085 (0.7)I-154: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.6783 (2.8); 7.6748 (3.4); 7.6706(1.6); 7.6637 (1.2); 7.6582 (3.9); 7.6541 (3.4); 7.5000 (0.5); 7.4817(1.6); 7.4747 (0.7); 7.4682 (1.6); 7.4643 (2.7); 7.4599 (1.8); 7.4554(2.9); 7.4535 (3.8); 7.4499 (1.8); 7.4407 (1.4); 7.4388 (1.6); 7.4353(3.8); 7.4337 (2.4); 7.4300 (0.7); 7.4228 (0.6); 7.4188 (1.2); 7.4133(1.0); 7.3963 (0.6); 7.3760 (0.6); 7.2604 (24.4); 6.0055 (0.9); 6.0020(1.0); 5.9992 (1.0); 5.9957 (1.0); 5.9918 (1.2); 5.9883 (1.3); 5.9854(1.3); 5.9819 (1.2); 5.9216 (1.2); 5.9162 (2.2); 5.9105 (1.3); 5.9080(1.0); 5.9024 (1.6); 5.8968 (0.9); 5.0726 (0.8); 4.2138 (2.1); 4.1960(6.8); 4.1781 (7.0); 4.1603 (2.3); 4.0401 (1.5); 3.9953 (2.3); 3.8204(4.6); 3.7754 (3.1); 3.5277 (0.7); 3.5249 (0.7); 3.5221 (0.7); 3.5155(0.7); 3.5131 (0.7); 3.5065 (0.8); 3.5037 (0.7); 3.5009 (0.7); 2.5052(0.8); 2.4842 (1.6); 2.4701 (1.1); 2.4633 (0.9); 2.4491 (1.8); 2.4281(0.9); 1.9629 (0.8); 1.9541 (1.5); 1.9453 (0.8); 1.9277 (0.7); 1.9189(1.3); 1.9101 (0.7); 1.5512 (11.8); 1.2990 (7.8); 1.2811 (16.0); 1.2702(0.8); 1.2633 (7.8); 1.2524 (1.2); 1.2346 (0.6); 0.0080 (0.9); −0.0002(31.0); −0.0085 (1.1) I-155: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.6708 (2.9);7.6673 (3.6); 7.6631 (1.8); 7.6561 (1.2); 7.6507 (4.2); 7.6466 (3.6);7.4996 (0.6); 7.4813 (1.8); 7.4743 (0.8); 7.4677 (1.7); 7.4638 (2.8);7.4595 (1.6); 7.4542 (3.0); 7.4524 (4.0); 7.4488 (1.8); 7.4395 (1.6);7.4377 (1.8); 7.4343 (4.0); 7.4326 (2.5); 7.4289 (0.8); 7.4216 (0.6);7.4175 (1.2); 7.4122 (0.9); 7.3843 (0.6); 7.3619 (0.6); 7.2608 (14.6);5.9948 (1.0); 5.9912 (1.1); 5.9883 (1.1); 5.9848 (1.1); 5.9810 (1.2);5.9775 (1.3); 5.9746 (1.2); 5.9710 (1.1); 5.8498 (1.2); 5.8442 (2.1);5.8386 (1.3); 5.8362 (1.1); 5.8305 (1.7); 5.8249 (1.0); 5.0916 (0.8);5.0898 (0.8); 4.2375 (2.2); 4.2197 (7.1); 4.2018 (7.3); 4.1840 (2.4);4.0394 (1.6); 3.9936 (2.4); 3.8155 (4.6); 3.7705 (3.2); 3.5399 (0.8);3.5372 (0.7); 3.5343 (0.8); 3.5271 (0.7); 3.5184 (0.8); 3.5154 (0.7);3.5128 (0.8); 2.5693 (0.8); 2.5482 (1.6); 2.5340 (1.1); 2.5271 (0.9);2.5129 (1.7); 2.4918 (0.9); 2.0062 (0.9); 1.9979 (1.5); 1.9896 (0.8);1.9709 (0.7); 1.9626 (1.4); 1.9544 (0.8); 1.5608 (6.0); 1.3261 (7.8);1.3083 (16.0); 1.2904 (7.7); 1.2629 (0.5); 0.0079 (0.5); −0.0002 (17.5);−0.0085 (0.7) I-156: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.6706 (3.1); 7.6673(4.0); 7.6632 (2.1); 7.6559 (1.4); 7.6505 (4.8); 7.6464 (4.0); 7.5138(0.6); 7.4952 (2.1); 7.4887 (0.8); 7.4816 (1.8); 7.4778 (2.8); 7.4738(1.5); 7.4702 (1.0); 7.4640 (4.4); 7.4607 (2.1); 7.4494 (2.0); 7.4459(4.3); 7.4329 (0.8); 7.4286 (1.4); 7.4239 (1.0); 7.2605 (24.2); 6.8512(0.8); 6.8316 (0.8); 6.0240 (1.3); 6.0196 (1.5); 6.0180 (1.6); 6.0136(1.4); 6.0101 (1.6); 6.0058 (1.8); 6.0040 (1.7); 5.9997 (1.5); 5.8736(1.4); 5.8679 (2.5); 5.8621 (1.5); 5.8598 (1.3); 5.8540 (2.1); 5.8482(1.2); 5.1755 (0.7); 5.1700 (0.8); 5.1648 (0.9); 5.1595 (0.9); 5.1545(0.8); 5.1490 (0.7); 5.1446 (0.5); 4.1657 (2.2); 4.1618 (0.7); 4.1479(6.9); 4.1301 (7.0); 4.1122 (2.3); 4.0455 (1.8); 4.0002 (2.8); 3.8305(4.8); 3.7854 (3.3); 3.7447 (0.8); 3.7387 (1.1); 3.7328 (1.2); 3.7268(1.0); 3.7227 (1.0); 3.7168 (1.2); 3.7108 (1.1); 3.7048 (0.8); 2.7091(1.1); 2.6972 (1.1); 2.6883 (1.1); 2.6764 (1.3); 2.6739 (1.4); 2.6619(1.2); 2.6530 (1.1); 2.6412 (1.1); 1.8910 (1.0); 1.8797 (1.1); 1.8690(1.1); 1.8575 (1.3); 1.8444 (1.0); 1.8337 (1.0); 1.8225 (1.0); 1.5467(12.5); 1.3084 (0.6); 1.2815 (0.8); 1.2686 (7.8); 1.2637 (2.0); 1.2508(16.0); 1.2330 (7.5); 0.0080 (0.9); −0.0002 (29.6); −0.0085 (1.1) I-157:¹H-NMR(400.0 MHz, CDCl3): δ = 7.6683 (3.0); 7.6649 (3.8); 7.6608 (1.9);7.6535 (1.3); 7.6482 (4.5); 7.6441 (3.6); 7.5110 (0.6); 7.4925 (2.0);7.4859 (0.8); 7.4788 (1.7); 7.4750 (2.7); 7.4709 (1.4); 7.4670 (1.0);7.4629 (3.0); 7.4610 (4.1); 7.4575 (1.8); 7.4476 (1.9); 7.4463 (2.0);7.4428 (4.1); 7.4412 (2.8); 7.4298 (0.7); 7.4257 (1.3); 7.4209 (0.9);7.2604 (28.3); 6.8690 (0.7); 6.8497 (0.7); 6.0324 (1.2); 6.0282 (1.4);6.0264 (1.4); 6.0222 (1.4); 6.0185 (1.5); 6.0143 (1.7); 6.0125 (1.6);6.0083 (1.4); 5.8185 (1.2); 5.8127 (2.3); 5.8068 (1.4); 5.8048 (1.3);5.7988 (2.1); 5.7930 (1.1); 5.1581 (0.5); 5.1523 (0.5); 5.1479 (0.7);5.1421 (0.8); 5.1375 (0.9); 5.1318 (0.9); 5.1272 (0.8); 5.1214 (0.6);4.1794 (2.0); 4.1616 (6.2); 4.1438 (6.5); 4.1260 (2.1); 4.0418 (1.7);3.9972 (2.5); 3.8279 (4.6); 3.7828 (3.2); 3.7700 (0.8); 3.7638 (1.0);3.7575 (1.1); 3.7513 (1.0); 3.7481 (1.0); 3.7420 (1.1); 3.7356 (1.0);3.7295 (0.8); 2.7453 (1.0); 2.7327 (1.0); 2.7248 (1.1); 2.7120 (1.3);2.7101 (1.4); 2.6974 (1.2); 2.6895 (1.1); 2.6768 (1.1); 1.9702 (1.0);1.9598 (1.0); 1.9484 (1.0); 1.9378 (1.1); 1.9350 (1.1); 1.9244 (0.9);1.9130 (0.9); 1.9026 (0.9); 1.5441 (8.2); 1.2815 (7.5); 1.2636 (16.0);1.2508 (1.5); 1.2458 (7.5); 1.2330 (0.6); 0.0079 (1.0); −0.0002 (35.6);−0.0085 (1.4) I-158: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.8680 (1.3); 7.8639(1.9); 7.8592 (1.7); 7.8545 (1.4); 7.8504 (1.9); 7.8458 (1.6); 7.8187(1.6); 7.8150 (2.6); 7.8113 (1.4); 7.8050 (1.7); 7.8014 (2.7); 7.7977(1.4); 7.6749 (1.7); 7.6717 (2.9); 7.6701 (2.3); 7.6684 (2.3); 7.6668(2.7); 7.6636 (1.5); 7.2619 (21.7); 7.1857 (0.8); 5.9800 (0.5); 5.9764(0.6); 5.9736 (0.7); 5.9700 (0.7); 5.9664 (0.9); 5.9626 (1.0); 5.9597(1.1); 5.9565 (1.3); 5.9536 (1.1); 5.9504 (0.8); 5.9469 (0.7); 5.9431(0.7); 5.9394 (0.8); 5.9368 (0.7); 5.9331 (0.6); 5.9050 (0.8); 5.8995(1.4); 5.8939 (0.8); 5.8915 (0.6); 5.8858 (0.9); 5.8802 (0.5); 5.8155(0.6); 5.8099 (1.2); 5.8043 (0.7); 5.8019 (0.6); 5.7962 (1.0); 5.7905(0.6); 5.7338 (0.6); 5.3289 (0.6); 5.0057 (0.8); 3.8330 (1.9); 3.8276(2.0); 3.7898 (2.2); 3.7844 (2.3); 3.7703 (0.8); 3.7584 (15.9); 3.7315(16.0); 3.7262 (6.4); 3.7009 (0.6); 3.5464 (0.6); 3.5401 (0.7); 3.5376(0.7); 3.5310 (0.9); 3.5279 (0.9); 3.5252 (1.0); 3.5188 (0.8); 3.2073(2.0); 3.1968 (1.9); 3.1641 (1.7); 3.1536 (1.7); 2.5419 (0.8); 2.5279(0.6); 2.5069 (0.9); 2.4859 (0.5); 2.4716 (0.9); 2.4576 (0.7); 2.4506(0.5); 2.4366 (0.9); 1.9682 (2.2); 1.9658 (2.0); 1.9643 (2.0); 1.9619(1.7); 1.9436 (0.6); 1.9340 (0.7); 1.8893 (0.5); 1.8802 (0.8); 1.8453(0.7); 1.7419 (10.4); 1.7287 (10.6); 1.7117 (0.6); 1.5709 (10.0); 0.0079(0.7); −0.0002 (21.4); −0.0085 (0.8) I-159: ¹H-NMR(400.0 MHz, CDCl3): δ= 8.1375 (3.6); 8.1338 (3.8); 8.1211 (3.7); 8.1173 (3.8); 7.9588 (1.0);7.9553 (2.5); 7.9517 (2.4); 7.9481 (1.0); 7.2603 (55.0); 5.9705 (0.5);5.9676 (0.5); 5.9639 (0.6); 5.9033 (0.8); 5.8977 (0.5); 5.8896 (0.6);5.8102 (0.8); 5.7964 (0.7); 3.8686 (1.3); 3.8601 (1.3); 3.8254 (1.4);3.8170 (1.5); 3.7619 (11.0); 3.7344 (10.6); 3.5294 (0.5); 3.2227 (1.3);3.2095 (1.3); 3.1794 (1.2); 3.1662 (1.2); 2.5340 (0.5); 2.4990 (0.6);2.4776 (0.6); 2.4563 (0.6); 2.4213 (0.6); 1.9754 (0.6); 1.8820 (0.6);1.8473 (0.5); 1.7605 (7.0); 1.7468 (7.2); 1.5405 (16.0); 0.0080 (2.0);−0.0002 (69.4); −0.0085 (2.6) I-160: ¹H-NMR(400.0 MHz, CDCl3): δ =7.8495 (0.8); 7.8428 (1.7); 7.8388 (3.1); 7.8341 (3.5); 7.8298 (3.7);7.8259 (4.9); 7.8220 (1.7); 7.8153 (0.7); 7.8116 (0.8); 7.8063 (1.1);7.8018 (2.4); 7.7981 (3.6); 7.7944 (1.8); 7.6808 (0.7); 7.6686 (2.4);7.6652 (3.4); 7.6634 (3.7); 7.6612 (3.2); 7.6579 (2.1); 7.2620 (27.6);7.2372 (0.8); 7.2146 (1.4); 7.1929 (0.8); 6.0385 (0.8); 6.0349 (0.8);6.0323 (1.0); 6.0285 (0.9); 6.0246 (1.1); 6.0211 (1.2); 6.0184 (1.4);6.0148 (1.2); 6.0071 (1.0); 6.0034 (1.1); 6.0010 (1.1); 5.9971 (1.0);5.9934 (1.0); 5.9874 (1.5); 5.9822 (2.3); 5.9400 (0.9); 5.9344 (1.7);5.9287 (1.0); 5.9263 (0.9); 5.9206 (1.3); 5.9150 (0.8); 5.8569 (0.8);5.8512 (1.6); 5.8454 (1.0); 5.8432 (1.0); 5.8374 (1.4); 5.8316 (0.8);5.7264 (0.8); 5.7241 (1.0); 5.7216 (0.8); 5.3380 (0.7); 5.3346 (0.8);5.3312 (0.7); 5.3000 (0.6); 5.0154 (1.0); 3.8341 (4.7); 3.8215 (0.6);3.8093 (0.6); 3.7908 (5.5); 3.6069 (0.8); 3.6040 (0.9); 3.6010 (0.9);3.5950 (1.3); 3.5895 (1.3); 3.5829 (1.0); 3.5709 (0.6); 3.5680 (0.6);3.2255 (0.7); 3.2188 (2.6); 3.2092 (2.6); 3.1820 (0.7); 3.1755 (2.3);3.1658 (2.2); 2.5862 (1.0); 2.5721 (0.7); 2.5650 (0.7); 2.5548 (0.7);2.5510 (1.1); 2.5304 (1.0); 2.5197 (0.6); 2.5099 (1.0); 2.4959 (0.8);2.4889 (0.6); 2.4748 (1.1); 2.4539 (0.5); 2.0466 (0.6); 2.0264 (0.6);2.0168 (1.0); 2.0073 (0.6); 1.9919 (0.8); 1.9817 (1.0); 1.9721 (0.6);1.9639 (0.7); 1.9577 (0.9); 1.9509 (2.5); 1.9485 (3.1); 1.9473 (3.1);1.9449 (2.4); 1.9201 (0.7); 1.9110 (1.1); 1.9014 (0.7); 1.8850 (0.6);1.8757 (0.9); 1.8665 (0.6); 1.7384 (16.0); 1.7308 (15.2); 1.7215 (2.3);1.7121 (1.0); 1.2886 (0.7); 1.2610 (0.8); 0.0080 (1.0); −0.0002 (34.6);−0.0084 (1.3) I-169: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.2718 (1.1); 7.2612(18.4); 7.2111 (1.9); 7.2094 (1.9); 7.1914 (1.2); 7.1679 (1.1); 6.9564(0.8); 6.9329 (0.8); 6.2133 (1.1); 6.1866 (1.2); 6.1702 (1.3); 6.1434(1.3); 5.9500 (0.7); 5.9460 (0.8); 5.9440 (0.8); 5.9399 (0.8); 5.9363(0.8); 5.9323 (0.9); 5.9262 (0.7); 5.8256 (0.8); 5.8200 (1.3); 5.8143(0.8); 5.8120 (0.8); 5.8062 (1.1); 5.8006 (0.6); 5.5707 (1.8); 5.5691(1.7); 5.5275 (1.6); 5.5260 (1.5); 5.3423 (1.7); 5.3409 (1.7); 5.3154(1.6); 5.0235 (0.5); 3.9487 (2.0); 3.9057 (2.3); 3.7679 (0.6); 3.7563(1.1); 3.7511 (1.7); 3.7463 (16.0); 3.7334 (1.3); 3.5201 (0.5); 3.5168(0.5); 3.3457 (2.2); 3.3028 (1.8); 2.7057 (0.6); 2.5739 (0.6); 2.5529(1.0); 2.5390 (0.8); 2.5316 (0.7); 2.5179 (1.1); 2.4968 (0.6); 2.3983(0.5); 2.3689 (8.6); 1.9478 (0.6); 1.9376 (0.9); 1.9273 (0.5); 1.9128(0.5); 1.9027 (0.8); 1.2564 (0.5); 0.0103 (1.1); 0.0079 (1.2); −0.0002(21.0); −0.0084 (1.2) I-170: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.2626 (6.3);7.2155 (2.2); 7.2006 (1.2); 7.1958 (1.1); 7.1724 (0.8); 6.9578 (0.8);6.9345 (0.8); 6.2125 (1.1); 6.1857 (1.2); 6.1693 (1.3); 6.1426 (1.4);5.9633 (0.6); 5.9593 (0.8); 5.9571 (0.8); 5.9533 (0.8); 5.9495 (0.9);5.9455 (1.0); 5.9434 (1.0); 5.9395 (0.9); 5.8799 (0.8); 5.8744 (1.4);5.8687 (0.9); 5.8664 (0.8); 5.8606 (1.1); 5.8550 (0.6); 5.5518 (1.7);5.5504 (1.8); 5.5086 (1.5); 5.5073 (1.6); 5.3264 (1.7); 5.2996 (1.6);5.0236 (0.5); 3.9453 (2.1); 3.9024 (2.4); 3.7529 (0.6); 3.7456 (1.2);3.7332 (16.0); 3.5186 (0.5); 3.5150 (0.5); 3.5080 (0.6); 3.5041 (0.5);3.3506 (2.2); 3.3076 (1.9); 2.5311 (0.6); 2.5100 (1.0); 2.4961 (0.7);2.4889 (0.6); 2.4751 (1.1); 2.4540 (0.6); 2.3708 (8.9); 1.9046 (0.6);1.8944 (1.0); 1.8841 (0.6); 1.8697 (0.6); 1.8595 (0.9); 1.8492 (0.5);1.2558 (0.6); −0.0002 (7.1); −0.0081 (0.5) I-171: ¹H-NMR(400.0 MHz,CDCl3): δ = 8.4246 (0.6); 8.1386 (4.5); 8.1349 (4.8); 8.1244 (3.2);8.1219 (5.6); 8.1183 (7.2); 8.1147 (3.0); 7.9709 (1.3); 7.9654 (1.4);7.9617 (0.9); 7.9580 (1.5); 7.9545 (2.6); 7.9518 (2.6); 7.2616 (44.6);7.1807 (0.8); 6.0124 (0.7); 6.0021 (1.0); 5.9983 (1.0); 5.9877 (1.0);5.9087 (0.7); 5.9031 (1.1); 5.8973 (0.7); 5.8891 (0.8); 5.8839 (0.5);5.8696 (0.6); 5.8558 (0.6); 5.8138 (0.6); 5.8083 (1.0); 5.7945 (0.9);5.0152 (0.7); 4.3226 (1.0); 4.3106 (2.4); 4.2990 (2.5); 4.2905 (1.2);4.2803 (1.4); 4.2670 (1.7); 4.2569 (1.4); 4.2527 (1.1); 4.2471 (1.2);3.9781 (1.2); 3.8831 (0.9); 3.8747 (1.7); 3.8603 (1.6); 3.8399 (1.0);3.8316 (2.0); 3.8173 (1.7); 3.7478 (0.5); 3.6472 (2.1); 3.6364 (2.4);3.6238 (2.8); 3.6126 (2.1); 3.6058 (1.9); 3.5941 (2.3); 3.5895 (1.8);3.5823 (2.1); 3.5777 (2.4); 3.5661 (1.4); 3.4327 (3.9); 3.4072 (16.0);3.3894 (14.9); 3.3872 (11.0); 3.3825 (3.3); 3.3725 (7.8); 3.3699 (2.3);3.2223 (2.1); 3.2067 (1.5); 3.1793 (1.7); 3.1635 (1.4); 2.5352 (0.7);2.5002 (0.8); 2.4609 (0.7); 2.4259 (0.7); 1.9839 (0.7); 1.9490 (0.6);1.9406 (0.5); 1.8911 (0.7); 1.8561 (0.7); 1.8471 (0.6); 1.7594 (8.6);1.7543 (3.7); 1.7495 (9.1); 1.7441 (9.9); 1.5665 (2.1); 1.3434 (1.3);0.0080 (2.4); −0.0002 (60.3); −0.0085 (2.4) I-174: ¹H-NMR(400.0 MHz,CDCl3): δ = 7.2612 (16.3); 7.2091 (1.8); 7.2058 (2.4); 7.2033 (2.4);7.2001 (2.4); 7.1895 (2.2); 7.1863 (2.1); 7.1838 (2.0); 7.1805 (1.4);6.9232 (0.5); 6.9173 (0.9); 6.9115 (0.5); 6.9014 (1.1); 6.8956 (1.9);6.8898 (1.0); 6.8797 (0.6); 6.8739 (1.0); 6.0224 (0.8); 6.0161 (0.9);6.0123 (1.1); 6.0086 (1.3); 6.0026 (1.3); 5.9985 (0.8); 5.9728 (0.7);5.9675 (1.2); 5.9619 (0.7); 5.9508 (1.3); 5.9453 (0.8); 5.9370 (0.8);5.1010 (0.7); 3.8644 (3.1); 3.8191 (3.6); 3.6059 (0.7); 3.5997 (0.8);3.5933 (0.7); 3.3645 (14.3); 3.3596 (16.0); 3.3136 (1.9); 3.3107 (2.0);2.6014 (0.7); 2.5801 (0.5); 2.5764 (0.8); 2.5661 (0.8); 2.5624 (0.6);2.5412 (0.8); 2.0303 (1.0); 2.0211 (1.0); 2.0082 (0.8); 1.9949 (0.9);1.9858 (0.9); 0.0080 (0.8); −0.0002 (21.4); −0.0085 (1.0) I-175:¹H-NMR(400.0 MHz, CDCl3): δ = 7.6635 (3.6); 7.6578 (5.0); 7.6536 (4.8);7.6497 (3.2); 7.6444 (3.9); 7.6394 (6.3); 7.6337 (4.1); 7.4503 (0.6);7.4463 (0.8); 7.4338 (2.1); 7.4303 (2.8); 7.4217 (5.7); 7.4179 (11.6);7.4136 (5.8); 7.4112 (5.1); 7.4042 (3.9); 7.4001 (6.0); 7.3908 (1.4);7.3865 (1.8); 7.3821 (0.9); 7.3778 (1.1); 7.2609 (29.9); 7.2283 (0.8);7.2018 (1.2); 7.1756 (0.8); 6.2275 (3.3); 6.2008 (3.7); 6.1844 (3.9);6.1577 (4.1); 5.9612 (1.1); 5.9551 (1.3); 5.9477 (2.0); 5.9431 (2.7);5.9377 (2.2); 5.9313 (1.6); 5.9250 (1.3); 5.8739 (1.4); 5.8683 (2.5);5.8627 (1.5); 5.8545 (1.9); 5.8489 (1.1); 5.8145 (1.3); 5.8088 (2.4);5.8031 (1.4); 5.7951 (2.0); 5.7893 (1.0); 5.5755 (3.3); 5.5737 (3.3);5.5579 (3.3); 5.5560 (3.4); 5.5324 (2.9); 5.5305 (2.9); 5.5147 (2.9);5.5128 (2.9); 5.3344 (3.0); 5.3327 (3.0); 5.3204 (3.0); 5.3186 (2.9);5.3077 (2.8); 5.3060 (2.9); 5.2937 (2.8); 5.2918 (2.8); 5.0298 (1.4);4.2221 (2.1); 4.2043 (7.3); 4.1869 (9.4); 4.1698 (7.4); 4.1521 (2.3);3.9908 (4.2); 3.9859 (4.3); 3.9479 (4.7); 3.9430 (4.8); 3.4928 (1.6);3.3944 (4.3); 3.3899 (4.1); 3.3515 (3.6); 3.3469 (3.6); 2.5731 (0.8);2.5520 (1.6); 2.5381 (1.3); 2.5307 (1.1); 2.5168 (2.1); 2.5009 (1.3);2.4959 (1.2); 2.4936 (1.2); 2.4797 (1.8); 2.4587 (0.9); 1.9431 (1.0);1.9328 (1.5); 1.9224 (0.9); 1.9084 (0.9); 1.8985 (1.9); 1.8890 (2.0);1.8787 (1.0); 1.8652 (0.9); 1.8545 (1.5); 1.8441 (0.8); 1.3429 (0.6);1.3251 (1.6); 1.3190 (7.7); 1.3012 (15.7); 1.2931 (8.2); 1.2833 (7.9);1.2752 (16.0); 1.2574 (7.5); 0.0079 (1.6); −0.0002 (38.2); −0.0085 (1.6)I-176: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.6790 (1.0); 7.6637 (7.1); 7.6596(8.4); 7.6574 (9.3); 7.6533 (10.4); 7.6495 (6.0); 7.6466 (7.3); 7.6447(6.9); 7.6396 (12.5); 7.6333 (8.6); 7.4536 (1.3); 7.4495 (1.6); 7.4369(4.2); 7.4334 (5.8); 7.4247 (10.7); 7.4206 (23.5); 7.4024 (11.1); 7.3886(2.9); 7.3805 (1.8); 7.2610 (68.5); 7.1989 (1.7); 7.1809 (2.5); 6.2296(4.8); 6.2273 (4.8); 6.2029 (5.4); 6.2005 (5.1); 6.1864 (5.8); 6.1841(6.0); 6.1597 (5.9); 6.1574 (5.7); 5.9820 (2.3); 5.9782 (2.6); 5.9758(2.6); 5.9720 (2.3); 5.9682 (3.2); 5.9643 (5.2); 5.9620 (4.1); 5.9581(5.0); 5.9540 (2.6); 5.9504 (2.9); 5.9463 (2.9); 5.9443 (2.9); 5.9402(2.6); 5.9014 (2.8); 5.8958 (5.0); 5.8901 (2.7); 5.8876 (2.2); 5.8820(3.7); 5.8763 (2.2); 5.8434 (2.8); 5.8377 (4.9); 5.8321 (3.0); 5.8296(2.8); 5.8239 (4.2); 5.8183 (2.1); 5.6173 (0.7); 5.5776 (6.9); 5.5758(7.5); 5.5591 (7.3); 5.5572 (7.4); 5.5345 (6.2); 5.5327 (6.1); 5.5159(6.4); 5.5140 (6.4); 5.4034 (0.7); 5.3767 (0.6); 5.3399 (6.2); 5.3381(6.5); 5.3252 (5.9); 5.3233 (5.9); 5.3132 (6.0); 5.3114 (6.4); 5.2984(5.4); 5.2966 (5.5); 5.0421 (2.8); 4.4837 (0.7); 4.4527 (0.7); 4.4459(0.6); 4.4319 (1.2); 4.4163 (4.5); 4.4072 (4.8); 4.4023 (7.3); 4.3922(6.7); 4.3874 (10.4); 4.3790 (5.5); 4.3751 (8.5); 4.3727 (7.0); 4.3713(7.4); 4.3593 (8.1); 4.3465 (1.3); 4.3315 (1.2); 4.0129 (0.8); 3.9887(13.8); 3.9705 (1.0); 3.9523 (1.6); 3.9457 (16.0); 3.7461 (6.0); 3.7442(6.2); 3.7319 (9.4); 3.7300 (11.8); 3.7194 (12.4); 3.7155 (6.5); 3.7049(10.0); 3.6909 (8.6); 3.6787 (1.4); 3.6648 (1.3); 3.6517 (0.5); 3.5906(1.2); 3.5696 (2.6); 3.5659 (2.8); 3.5588 (2.7); 3.5552 (2.6); 3.4491(0.8); 3.4066 (1.1); 3.3971 (8.6); 3.3943 (9.0); 3.3542 (7.4); 3.3513(7.7); 2.6056 (1.8); 2.5844 (3.1); 2.5705 (2.4); 2.5631 (3.7); 2.5495(3.5); 2.5417 (3.2); 2.5280 (3.9); 2.5206 (2.0); 2.5067 (3.5); 2.4855(1.7); 1.9811 (1.8); 1.9709 (3.2); 1.9607 (1.7); 1.9462 (1.8); 1.9353(4.0); 1.9244 (4.2); 1.9135 (2.2); 1.8992 (1.7); 1.8889 (3.0); 1.8785(1.9); 0.0080 (2.9); −0.0002 (85.9); −0.0085 (3.7) I-177: ¹H-NMR(400.0MHz, CDCl3): δ = 7.6642 (1.8); 7.6577 (2.2); 7.6536 (2.5); 7.6401 (2.8);7.6335 (2.0); 7.4302 (1.7); 7.4180 (5.6); 7.4002 (2.9); 7.3866 (0.8);7.3779 (0.7); 7.2602 (61.1); 7.2137 (0.8); 6.2269 (1.0); 6.2001 (1.2);6.1975 (1.1); 6.1837 (1.2); 6.1811 (1.2); 6.1569 (1.3); 6.1544 (1.2);5.9609 (1.0); 5.9566 (1.2); 5.9508 (1.1); 5.8724 (1.0); 5.8670 (0.7);5.8585 (0.8); 5.8116 (1.1); 5.7978 (0.9); 5.5756 (1.5); 5.5554 (1.5);5.5342 (1.4); 5.5142 (1.2); 5.3365 (1.4); 5.3211 (1.2); 5.3083 (1.2);5.2943 (1.1); 5.0335 (0.7); 4.3064 (1.2); 4.3024 (1.2); 4.2954 (2.0);4.2889 (2.0); 4.2785 (1.9); 4.2666 (1.2); 4.2568 (1.0); 3.9999 (0.5);3.9894 (1.9); 3.9853 (1.7); 3.9576 (0.6); 3.9464 (2.1); 3.9424 (2.0);3.6400 (2.6); 3.6268 (2.4); 3.6159 (2.5); 3.6019 (2.5); 3.5915 (1.5);3.4115 (1.0); 3.4009 (16.0); 3.3951 (2.7); 3.3849 (1.5); 3.3745 (14.4);3.3697 (4.8); 3.3522 (1.6); 3.3486 (1.8); 2.5665 (0.9); 2.5527 (0.7);2.5456 (0.6); 2.5315 (0.9); 2.5265 (0.8); 2.5108 (0.5); 2.4914 (0.7);1.9455 (0.7); 1.9102 (0.9); 1.9036 (1.0); 1.8691 (0.8); 0.9257 (0.6);0.0080 (2.9); −0.0002 (79.0); −0.0085 (3.6) I-178: ¹H-NMR(400.0 MHz,CDCl3): δ = 7.8970 (1.6); 7.8929 (2.5); 7.8883 (2.2); 7.8845 (2.0);7.8804 (2.6); 7.8757 (1.9); 7.8574 (2.0); 7.8538 (2.9); 7.8502 (2.0);7.8461 (2.3); 7.8425 (2.9); 7.7326 (3.6); 7.3978 (1.3); 7.3774 (1.3);7.2621 (10.4); 6.0012 (1.8); 5.9371 (0.8); 5.9319 (1.3); 5.9260 (1.0);5.9180 (1.0); 5.8657 (1.3); 5.8601 (1.0); 5.8521 (1.1); 5.3006 (1.0);5.0832 (1.2); 5.0651 (1.1); 4.0395 (2.2); 3.9943 (3.0); 3.7775 (2.9);3.7655 (16.0); 3.7457 (14.6); 3.7326 (2.2); 3.7237 (1.9); 3.5589 (1.3);2.5517 (0.5); 2.5308 (0.9); 2.5165 (0.6); 2.5100 (0.6); 2.4955 (1.0);2.4792 (0.6); 2.4747 (0.6); 2.4584 (0.9); 2.4440 (0.6); 2.4377 (0.5);2.4233 (1.0); 2.0199 (0.6); 2.0127 (1.0); 2.0056 (0.6); 1.9778 (1.4);1.9707 (1.6); 1.9355 (0.9); 1.9278 (0.6); −0.0002 (13.6) I-184:¹H-NMR(599.7 MHz, CDCl3): δ = 7.2625 (19.6); 7.2071 (8.8); 7.1841 (6.6);7.1690 (7.9); 7.1518 (3.5); 7.1364 (2.0); 6.9536 (7.0); 6.9397 (5.2);6.7989 (2.2); 6.7857 (2.2); 6.1980 (3.7); 6.1802 (4.0); 6.1696 (4.1);6.1516 (4.1); 5.9779 (5.5); 5.9652 (4.3); 5.9541 (3.1); 5.8913 (3.2);5.8635 (1.7); 5.8287 (3.9); 5.5618 (3.5); 5.5422 (7.2); 5.5337 (3.4);5.5137 (6.4); 5.3369 (6.4); 5.3210 (8.1); 5.3053 (3.2); 5.1085 (1.9);5.0395 (3.8); 4.4120 (2.2); 4.4027 (4.8); 4.3908 (6.7); 4.3798 (7.6);4.3703 (4.2); 4.3566 (2.3); 4.3461 (5.0); 4.3360 (4.8); 3.9499 (3.4);3.9426 (6.4); 3.9213 (3.7); 3.9143 (6.9); 3.7804 (1.9); 3.7390 (3.8);3.7302 (6.6); 3.7200 (7.0); 3.7097 (7.3); 3.7010 (3.9); 3.6886 (2.4);3.6794 (5.6); 3.6696 (5.3); 3.5685 (3.8); 3.3441 (8.2); 3.3155 (7.4);2.7015 (0.8); 2.6885 (1.4); 2.6771 (1.4); 2.6654 (1.3); 2.6533 (0.7);2.5870 (0.9); 2.5727 (1.7); 2.5615 (1.6); 2.5478 (2.2); 2.5324 (2.1);2.5190 (1.6); 2.5075 (1.8); 2.4929 (0.9); 2.4767 (0.4); 2.3957 (2.0);2.3718 (50.0); 1.9638 (1.9); 1.9387 (1.8); 1.9205 (2.4); 1.8973 (2.2);1.8575 (0.9); 1.5871 (39.3); 1.2853 (0.5); 1.2571 (1.9); 0.8949 (0.5);0.0704 (3.5); −0.0001 (14.0) I-185: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.2607(75.8); 7.2098 (1.3); 7.1682 (0.8); 6.9548 (0.6); 6.2120 (0.5); 6.2093(0.5); 6.1852 (0.6); 6.1826 (0.6); 6.1689 (0.7); 6.1662 (0.6); 6.1421(0.7); 6.1395 (0.6); 5.9753 (0.5); 5.9722 (0.5); 5.9574 (0.6); 5.8714(0.6); 5.8136 (0.7); 5.8081 (0.5); 5.7997 (0.6); 5.5687 (0.7); 5.5670(0.8); 5.5464 (1.5); 5.5256 (0.7); 5.5239 (0.7); 5.5032 (1.3); 5.3377(1.1); 5.3233 (0.7); 5.3109 (1.0); 5.2950 (0.6); 4.3061 (0.6); 4.3015(0.6); 4.2952 (1.0); 4.2887 (1.0); 4.2826 (1.4); 4.2782 (0.7); 4.2694(1.0); 4.2596 (0.7); 4.2483 (0.6); 4.2397 (0.8); 4.2352 (0.6); 3.9554(0.8); 3.9517 (1.0); 3.9476 (0.9); 3.9124 (1.0); 3.9089 (1.1); 3.9047(1.0); 3.6380 (1.1); 3.6274 (0.9); 3.6249 (1.1); 3.6185 (0.9); 3.6145(1.1); 3.6053 (1.2); 3.6003 (0.7); 3.5930 (0.8); 3.5884 (1.4); 3.5766(1.4); 3.5649 (0.8); 3.4004 (8.6); 3.3840 (4.6); 3.3791 (8.0); 3.3728(4.3); 3.3461 (1.0); 3.3421 (1.0); 3.3032 (1.0); 3.2991 (0.8); 2.3688(6.5); 1.5479 (16.0); 0.0079 (1.6); −0.0002 (54.5); −0.0085 (1.6) I-186:¹H-NMK (599.7 MHz, CDCl3): δ = 7.2609 (30.0); 7.2190 (1.6); 7.2107(1.6); 7.2015 (1.7); 7.1827 (1.6); 7.1674 (1.5); 7.1208 (0.4); 7.1061(0.8); 7.0900 (0.4); 7.0842 (0.3); 6.9554 (1.4); 6.9420 (1.1); 6.8020(0.4); 6.7889 (0.4); 6.1964 (1.3); 6.1922 (0.8); 6.1785 (1.4); 6.1744(0.9); 6.1676 (1.5); 6.1634 (0.9); 6.1498 (1.5); 6.1456 (0.8); 6.0798(0.4); 6.0598 (0.4); 5.9948 (0.4); 5.9880 (0.8); 5.9811 (0.5); 5.9730(0.9); 5.9676 (1.5); 5.9616 (1.5); 5.9507 (1.0); 5.9420 (0.8); 5.9355(0.9); 5.9295 (0.3); 5.9240 (0.4); 5.9095 (0.5); 5.9059 (0.9); 5.9023(0.8); 5.8966 (1.0); 5.8835 (0.4); 5.8803 (0.6); 5.8763 (0.7); 5.8707(0.5); 5.8547 (0.5); 5.8510 (1.0); 5.8457 (0.9); 5.8417 (1.2); 5.8379(0.8); 5.8322 (0.6); 5.5605 (1.4); 5.5420 (2.4); 5.5317 (1.3); 5.5132(2.2); 5.3411 (1.5); 5.3363 (1.2); 5.3235 (1.7); 5.3185 (1.1); 5.3084(1.3); 5.1051 (0.4); 5.0362 (0.7); 4.3624 (0.8); 4.3557 (0.8); 4.3399(2.1); 4.3332 (2.0); 4.3173 (2.1); 4.3105 (2.0); 4.3042 (0.5); 4.2940(1.2); 4.2872 (1.1); 4.2814 (0.8); 4.2746 (0.8); 4.2708 (0.4); 4.2641(0.4); 4.2587 (0.4); 4.2519 (0.3); 3.9495 (0.8); 3.9460 (0.9); 3.9408(1.5); 3.9383 (1.6); 3.9209 (0.9); 3.9174 (1.0); 3.9122 (1.7); 3.9098(1.8); 3.8067 (0.4); 3.8027 (0.4); 3.5922 (0.7); 3.3475 (1.7); 3.3446(1.8); 3.3414 (1.6); 3.3189 (1.5); 3.3161 (1.6); 3.3129 (1.4); 2.6821(0.4); 2.6573 (0.3); 2.6101 (0.3); 2.5960 (0.6); 2.5866 (0.4); 2.5819(0.4); 2.5726 (0.7); 2.5644 (0.4); 2.5584 (0.4); 2.5502 (0.6); 2.5409(0.4); 2.5361 (0.4); 2.5268 (0.7); 2.5129 (0.3); 2.3983 (0.5); 2.3709(13.0); 1.9550 (0.4); 1.9479 (0.7); 1.9409 (0.4); 1.9312 (0.5); 1.9242(0.8); 1.9170 (0.7); 1.9097 (0.7); 1.9028 (0.4); 1.8936 (0.5); 1.8864(0.8); 1.8795 (0.5); 1.8713 (0.3); 1.5586 (50.0); 1.2558 (0.3); 0.0694(4.6); −0.0001 (22.8) I-187: ¹H-NMK (599.7 MHz, CDCl3): δ = 7.2611(23.0); 7.2113 (3.3); 7.1863 (2.2); 7.1724 (2.2); 6.9519 (2.2); 6.9367(1.8); 6.1988 (1.3); 6.1813 (1.4); 6.1703 (1.5); 6.1524 (1.5); 5.9459(2.0); 5.8655 (1.1); 5.8081 (1.1); 5.7995 (1.2); 5.5601 (1.5); 5.5412(2.2); 5.5313 (1.5); 5.5124 (2.0); 5.3339 (2.1); 5.3179 (2.7); 5.3017(1.4); 5.0286 (1.2); 4.2134 (1.0); 4.2014 (3.1); 4.1892 (4.3); 4.1770(2.8); 4.1647 (0.8); 4.1491 (0.7); 4.1371 (1.0); 4.1254 (0.7); 3.9417(2.2); 3.9132 (2.4); 3.4997 (1.3); 3.3395 (2.2); 3.3110 (1.9); 2.5520(0.4); 2.5382 (0.7); 2.5279 (0.5); 2.5145 (1.1); 2.5002 (1.1); 2.4900(0.5); 2.4767 (0.8); 2.4626 (0.4); 2.3944 (0.4); 2.3695 (16.4); 1.9268(0.8); 1.9033 (0.8); 1.8952 (0.6); 1.8860 (0.8); 1.8798 (0.6); 1.8627(0.8); 1.5620 (50.0); 1.3128 (2.7); 1.3009 (5.0); 1.2910 (4.4); 1.2795(4.8); 1.2678 (3.1); 1.2565 (2.2); 1.2445 (1.6); 1.2333 (0.6); 0.0701(3.8); −0.0001 (17.2) I-188: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.4124 (0.8);7.4090 (1.0); 7.4076 (1.0); 7.4050 (1.1); 7.4026 (0.8); 7.3894 (1.6);7.3876 (1.8); 7.3849 (1.4); 7.3830 (1.8); 7.3791 (3.7); 7.3767 (2.2);7.3748 (2.7); 7.3723 (2.2); 7.3706 (1.6); 7.3668 (1.0); 7.3642 (1.5);7.2627 (19.6); 7.2100 (0.5); 7.1885 (0.5); 7.1476 (0.5); 7.1409 (0.6);7.1390 (0.5); 7.1332 (0.7); 7.1257 (0.8); 7.1180 (0.8); 5.9743 (0.8);5.9704 (0.8); 5.9682 (0.8); 5.9643 (0.8); 5.9605 (1.0); 5.9566 (1.1);5.9544 (1.0); 5.9505 (1.0); 5.8908 (1.0); 5.8853 (1.8); 5.8797 (1.0);5.8771 (0.8); 5.8714 (1.3); 5.8659 (0.7); 5.0118 (0.5); 5.0077 (0.5);4.0890 (3.1); 4.0721 (6.3); 4.0552 (3.1); 3.8201 (2.8); 3.7770 (3.2);3.7233 (0.5); 3.5160 (0.5); 3.5103 (0.5); 3.5069 (0.6); 3.4999 (0.5);3.4965 (0.5); 3.2291 (3.0); 3.1859 (2.6); 2.5248 (0.7); 2.5037 (1.2);2.4900 (0.8); 2.4826 (0.7); 2.4689 (1.3); 2.4477 (0.6); 1.8855 (0.7);1.8751 (1.2); 1.8647 (0.6); 1.8507 (0.6); 1.8402 (1.0); 1.8298 (0.6);1.7231 (0.9); 1.7095 (16.0); 1.6915 (1.5); 1.6744 (2.7); 1.6560 (2.7);1.6388 (1.4); 1.5989 (1.9); 0.9466 (4.8); 0.9281 (9.7); 0.9095 (4.3);−0.0002 (11.6) I-189: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.4098 (1.0); 7.4058(1.4); 7.3879 (2.2); 7.3863 (2.3); 7.3829 (2.2); 7.3781 (3.5); 7.3756(2.8); 7.3738 (3.1); 7.3713 (2.9); 7.3664 (1.5); 7.3628 (1.9); 7.2616(36.1); 7.1953 (0.7); 7.1729 (0.7); 7.1460 (0.6); 7.1395 (0.6); 7.1368(0.7); 7.1316 (0.8); 7.1246 (1.0); 7.1169 (1.0); 7.1095 (0.7); 7.1046(0.5); 7.1018 (0.6); 5.9563 (0.8); 5.9524 (0.9); 5.9502 (1.0); 5.9463(0.9); 5.9425 (1.1); 5.9386 (1.2); 5.9363 (1.3); 5.9325 (1.2); 5.8825(1.0); 5.8770 (1.8); 5.8714 (1.1); 5.8688 (0.9); 5.8632 (1.4); 5.8576(0.8); 5.0533 (0.6); 5.0376 (1.5); 5.0219 (2.2); 5.0062 (2.0); 4.9905(0.9); 3.8255 (2.8); 3.7824 (3.2); 3.7235 (0.7); 3.4695 (0.6); 3.4640(0.6); 3.4607 (0.6); 3.4534 (0.7); 3.4477 (0.6); 3.4443 (0.6); 3.2296(3.0); 3.1865 (2.7); 2.5087 (0.7); 2.4875 (1.3); 2.4739 (0.8); 2.4664(0.8); 2.4527 (1.4); 2.4316 (0.7); 1.8648 (0.7); 1.8545 (1.2); 1.8442(0.7); 1.8299 (0.7); 1.8196 (1.1); 1.8092 (0.7); 1.7251 (0.7); 1.7175(1.2); 1.7098 (16.0); 1.5727 (2.9); 1.2835 (0.7); 1.2716 (0.6); 1.2673(0.7); 1.2546 (8.3); 1.2488 (8.7); 1.2390 (8.7); 1.2331 (8.8); 1.2215(1.4); 1.2059 (1.0); 0.0080 (0.6); −0.0002 (21.6); −0.0085 (1.3) I-190:¹H-NMR(400.0 MHz, CDCl3): δ = 7.3853 (0.7); 7.3754 (1.4); 7.3727 (1.1);7.3708 (1.1); 7.3622 (0.6); 7.2636 (6.2); 7.2623 (6.3); 7.1161 (0.6);5.8494 (0.6); 3.8223 (0.8); 3.7792 (0.9); 3.2292 (0.9); 3.1861 (0.8);1.7080 (4.9); 1.4796 (0.8); 1.4400 (16.0); 1.4247 (1.0); 0.0009 (3.6);−0.0002 (3.7) I-191: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.4073 (1.2); 7.4031(1.2); 7.3914 (1.6); 7.3815 (4.5); 7.3761 (4.3); 7.3675 (2.2); 7.2628(15.5); 7.1836 (0.7); 7.1622 (0.9); 7.1511 (0.7); 7.1433 (0.9); 7.1362(0.9); 7.1286 (1.1); 7.1216 (1.1); 7.1153 (0.6); 5.9898 (0.8); 5.9852(1.1); 5.9762 (1.2); 5.9715 (1.5); 5.9669 (1.2); 5.9195 (1.0); 5.9142(1.8); 5.9077 (1.2); 5.9005 (1.3); 5.8949 (0.8); 5.0253 (0.8); 4.3819(2.7); 4.3684 (3.8); 4.3665 (3.4); 4.3536 (3.0); 3.8262 (2.6); 3.7831(3.0); 3.7222 (0.9); 3.7165 (3.1); 3.7018 (4.2); 3.6880 (2.8); 3.5663(0.7); 3.5559 (0.7); 3.5508 (0.7); 3.5450 (0.7); 3.2313 (3.0); 3.1881(2.6); 2.5485 (0.6); 2.5273 (1.2); 2.5136 (0.8); 2.5062 (0.7); 2.4922(1.4); 2.4711 (0.7); 1.9147 (0.7); 1.9047 (1.3); 1.8949 (0.7); 1.8797(0.7); 1.8698 (1.3); 1.8598 (0.7); 1.7266 (0.7); 1.7128 (16.0); 1.5899(3.7); −0.0002 (9.1); −0.0082 (0.6) I-192: ¹H-NMR(400.0 MHz, CDCl3): δ =7.4078 (1.2); 7.3882 (2.2); 7.3793 (3.1); 7.3752 (3.1); 7.3733 (3.0);7.3648 (1.7); 7.2637 (13.7); 7.2138 (0.6); 7.1924 (0.7); 7.1391 (0.6);7.1329 (0.7); 7.1248 (0.9); 7.1182 (0.9); 7.1106 (0.6); 5.9776 (1.0);5.9639 (1.3); 5.8979 (0.8); 5.8925 (1.5); 5.8855 (1.1); 5.8788 (1.2);5.8733 (0.7); 5.0136 (0.7); 4.4460 (1.3); 4.4343 (1.5); 4.4225 (1.4);4.2828 (1.2); 4.2730 (2.3); 4.2595 (2.4); 4.2503 (1.2); 3.8241 (2.2);3.7810 (2.5); 3.6955 (1.4); 3.6835 (1.5); 3.6719 (1.4); 3.6091 (1.7);3.5975 (3.1); 3.5881 (1.7); 3.5673 (0.8); 3.5573 (0.8); 3.5520 (0.7);3.5488 (0.7); 3.3992 (8.4); 3.3860 (1.2); 3.3744 (16.0); 3.2277 (2.5);3.1846 (2.2); 2.5309 (0.6); 2.5098 (1.0); 2.4960 (0.7); 2.4888 (0.6);2.4750 (1.2); 2.4539 (0.6); 1.8934 (0.6); 1.8830 (1.1); 1.8727 (0.7);1.8585 (0.6); 1.8481 (1.0); 1.8377 (0.6); 1.7535 (0.5); 1.7245 (0.6);1.7093 (13.2); 1.6141 (1.8); −0.0002 (8.2); −0.0078 (0.5) I-193:¹H-NMR(400.0 MHz, CDCl3): δ = 7.4717 (0.6); 7.4066 (1.7); 7.3887 (3.7);7.3803 (5.1); 7.3747 (4.4); 7.3641 (2.7); 7.3543 (4.1); 7.3438 (16.0);7.3361 (3.2); 7.3305 (1.8); 7.3142 (0.9); 7.2611 (17.4); 7.2257 (0.9);7.2045 (0.8); 7.1492 (0.6); 7.1428 (0.7); 7.1379 (0.8); 7.1283 (1.1);7.1212 (1.1); 7.1133 (0.8); 7.1059 (0.6); 5.9775 (1.0); 5.9732 (1.2);5.9672 (1.1); 5.9636 (1.3); 5.9596 (1.6); 5.9541 (1.1); 5.8963 (1.2);5.8910 (1.9); 5.8851 (1.3); 5.8773 (1.4); 5.8718 (0.8); 5.1843 (0.8);5.1544 (6.4); 5.1503 (5.7); 5.0133 (0.8); 3.8252 (2.7); 3.7821 (3.1);3.7231 (0.6); 3.5509 (0.8); 3.5451 (0.8); 3.5353 (0.7); 3.2323 (3.1);3.1892 (2.7); 2.5372 (0.6); 2.5161 (1.2); 2.5023 (0.9); 2.4953 (0.7);2.4814 (1.4); 2.4604 (0.7); 1.9116 (0.8); 1.9010 (1.4); 1.8901 (0.8);1.8768 (0.8); 1.8662 (1.3); 1.8553 (0.7); 1.7278 (0.5); 1.7097 (16.0);0.0004 (10.4); −0.0002 (10.4) I-194: ¹H-NMR(400.0 MHz, CDCl3): δ =7.4087 (1.2); 7.4045 (1.2); 7.3925 (1.5); 7.3817 (4.2); 7.3783 (4.2);7.3681 (2.4); 7.3488 (2.1); 7.3355 (2.3); 7.3278 (2.4); 7.3193 (1.1);7.3143 (2.2); 7.2615 (17.9); 7.2064 (0.7); 7.1852 (0.7); 7.1543 (0.6);7.1471 (0.8); 7.1399 (0.7); 7.1320 (1.0); 7.1249 (1.0); 7.1200 (0.6);7.1150 (0.7); 7.1106 (0.5); 7.0564 (0.6); 7.0498 (2.5); 7.0449 (1.3);7.0332 (1.2); 7.0282 (4.4); 7.0234 (1.2); 7.0116 (0.8); 7.0067 (2.0);5.9553 (0.8); 5.9508 (1.0); 5.9456 (0.9); 5.9417 (1.2); 5.9369 (1.5);5.9321 (1.2); 5.8953 (1.1); 5.8901 (2.0); 5.8843 (1.2); 5.8764 (1.3);5.8710 (0.8); 5.1450 (0.6); 5.1155 (4.5); 5.1099 (4.6); 5.0098 (0.8);5.0058 (0.8); 3.8247 (2.8); 3.7815 (3.2); 3.7230 (0.6); 3.5416 (0.7);3.5365 (0.7); 3.5314 (0.8); 3.5255 (0.8); 3.5204 (0.7); 3.5152 (0.7);3.2323 (3.1); 3.1892 (2.7); 2.5274 (0.6); 2.5063 (1.3); 2.4925 (0.8);2.4853 (0.7); 2.4714 (1.4); 2.4504 (0.7); 1.8919 (0.7); 1.8815 (1.3);1.8710 (0.8); 1.8571 (0.6); 1.8467 (1.2); 1.8361 (0.7); 1.7081 (16.0);1.5867 (4.5); −0.0002 (10.8); −0.0084 (0.6) I-199: ¹H-NMR(400.0 MHz,CDCl3): δ = 7.8665 (1.2); 7.8618 (1.8); 7.8577 (1.5); 7.8212 (1.3);7.8176 (2.4); 7.8139 (1.3); 7.6726 (1.2); 7.6690 (1.4); 7.6678 (1.6);7.6642 (1.2); 7.2633 (5.4); 5.9888 (0.5); 5.9815 (0.6); 5.9778 (0.6);5.9751 (0.6); 5.9715 (0.6); 5.9043 (0.6); 5.8988 (1.1); 5.8932 (0.6);5.8907 (0.5); 5.8850 (0.8); 4.2883 (0.8); 4.2781 (1.1); 4.2755 (1.8);4.2647 (1.7); 4.2623 (1.3); 4.2524 (0.9); 3.8289 (1.7); 3.7857 (1.9);3.6211 (1.1); 3.6181 (1.1); 3.6103 (1.2); 3.6071 (1.8); 3.5977 (1.0);3.5946 (1.1); 3.3848 (16.0); 3.2053 (1.8); 3.1621 (1.5); 2.4765 (0.7);2.4415 (0.8); 1.8899 (0.7); 1.8549 (0.6); 1.7254 (9.3); −0.0002 (7.2)I-200: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.8527 (1.2); 7.8483 (2.1); 7.8440(1.7); 7.8062 (1.5); 7.8026 (2.7); 7.7991 (1.6); 7.6704 (1.4); 7.6657(1.9); 7.6621 (1.5); 7.2631 (6.9); 7.1684 (0.5); 7.1470 (0.5); 5.9721(0.6); 5.9686 (0.6); 5.9660 (0.6); 5.9621 (0.6); 5.9585 (0.7); 5.9547(0.7); 5.9520 (0.8); 5.9484 (0.7); 5.8128 (0.6); 5.8073 (1.1); 5.8016(0.7); 5.7935 (1.0); 5.7879 (0.6); 4.3185 (1.0); 4.3070 (1.8); 4.2971(1.8); 4.2952 (1.7); 4.2862 (1.0); 3.8393 (1.9); 3.7961 (2.2); 3.6449(1.9); 3.6345 (2.2); 3.6321 (2.3); 3.6212 (1.7); 3.5939 (0.7); 3.5760(0.6); 3.4052 (16.0); 3.3850 (2.0); 3.3716 (0.6); 3.1929 (1.9); 3.1497(1.7); 2.5434 (0.8); 2.5294 (0.5); 2.5084 (0.9); 1.9773 (0.8); 1.9423(0.7); 1.7412 (10.2); 1.7326 (1.1); 1.7255 (1.2); −0.0002 (9.0) I-201:¹H-NMR(400.0 MHz, CDCl3): δ = 7.8436 (1.2); 7.8391 (2.0); 7.8349 (1.7);7.8053 (1.4); 7.8017 (2.6); 7.7980 (1.6); 7.6824 (1.3); 7.6778 (1.9);7.6741 (1.5); 7.2615 (10.3); 6.7283 (0.5); 6.7075 (0.5); 6.0027 (0.6);5.9968 (0.8); 5.9925 (0.7); 5.9889 (0.8); 5.9829 (0.9); 5.9787 (0.7);5.7944 (0.6); 5.7887 (1.1); 5.7829 (0.8); 5.7748 (1.1); 5.7691 (0.6);5.0857 (0.5); 4.2658 (0.9); 4.2547 (2.0); 4.2453 (1.8); 4.2423 (1.4);4.2344 (1.0); 3.8391 (1.7); 3.8093 (0.5); 3.8028 (0.6); 3.7958 (2.3);3.7873 (0.8); 3.7809 (0.6); 3.6045 (2.0); 3.5926 (3.1); 3.5811 (1.9);3.3865 (16.0); 3.2099 (1.8); 3.1665 (1.6); 2.7126 (0.5); 2.6979 (0.7);2.6855 (0.5); 2.6773 (0.6); 1.9042 (0.6); 1.7319 (9.5); −0.0002 (13.6)

Analytical data of Examples II-01-II-63 (see Table 1.2)

II-01: ¹H-NMR(400.6 MHz, CDCl3): δ = 9.2153 (1.0); 7.5272 (0.5); 7.3891(2.1); 7.3818 (3.5); 7.3737 (6.2); 7.3675 (6.8); 7.3588 (3.0); 7.2686(6.2); 7.1388 (0.8); 7.1303 (0.9); 7.1258 (1.0); 7.1177 (1.4); 7.1101(1.4); 7.1028 (0.9); 7.0955 (0.9); 7.0883 (0.5); 5.8967 (1.0); 5.8353(2.7); 4.9530 (0.6); 3.8217 (1.9); 3.8154 (3.0); 3.7890 (16.0); 3.7787(2.6); 3.7723 (4.4); 3.7664 (15.8); 3.7452 (0.9); 3.2931 (0.6); 3.2196(2.9); 3.2150 (2.3); 3.1766 (2.5); 3.1719 (2.0); 2.5155 (0.6); 2.0467(1.3); 1.8834 (1.2); 1.7148 (12.8); 1.7021 (12.4); 1.3339 (0.5); 1.2834(0.8); 1.2779 (0.6); 1.2599 (1.6); 1.2560 (1.8); −0.0002 (3.1) II-02:¹H-NMR(400.6 MHz, CDCl3): δ = 7.3902 (1.4); 7.3831 (2.2); 7.3736 (4.4);7.3678 (4.7); 7.3616 (2.1); 7.3583 (1.7); 7.2652 (8.1); 7.1401 (0.5);7.1326 (0.6); 7.1272 (0.7); 7.1190 (1.0); 7.1114 (1.0); 7.1042 (0.6);7.0975 (0.5); 5.8988 (0.7); 5.8383 (2.0); 3.8172 (1.5); 3.8120 (2.6);3.7898 (10.1); 3.7741 (2.2); 3.7669 (16.0); 3.2179 (2.3); 3.2134 (1.5);3.1749 (2.0); 3.1703 (1.3); 2.0463 (0.5); 1.7147 (9.9); 1.7024 (9.8);1.2596 (0.8); 1.2556 (0.9); −0.0002 (3.6) II-03: ¹H-NMR(400.6 MHz,CDCl3): δ = 9.0380 (1.4); 7.5374 (0.6); 7.5278 (0.6); 7.5157 (0.6);7.3907 (2.5); 7.3812 (4.5); 7.3736 (7.0); 7.3679 (8.8); 7.2691 (10.0);7.1375 (0.9); 7.1255 (1.3); 7.1164 (1.7); 7.1094 (1.7); 7.1021 (1.1);7.0943 (1.1); 7.0872 (0.6); 5.8928 (1.2); 5.8296 (3.3); 4.9593 (0.7);4.9417 (0.6); 4.1307 (0.7); 4.1128 (0.7); 3.9991 (1.5); 3.9744 (2.8);3.9566 (2.4); 3.9393 (1.0); 3.8209 (2.0); 3.8129 (3.3); 3.7779 (2.2);3.7699 (3.7); 3.2943 (0.8); 3.2170 (3.3); 3.2113 (2.8); 3.1740 (2.9);3.1683 (2.4); 2.5140 (0.7); 2.4921 (0.6); 2.0463 (2.9); 1.8946 (2.1);1.8590 (0.6); 1.7127 (16.0); 1.6988 (15.2); 1.2954 (2.4); 1.2777 (5.4);1.2598 (6.5); 1.2421 (2.5); 1.2273 (0.6); −0.0002 (3.9) II-04:¹H-NMR(400.6 MHz, CDCl3): δ = 7.5587 (0.5); 7.5376 (0.6); 7.5262 (0.6);7.4269 (0.7); 7.4113 (0.5); 7.4082 (0.6); 7.3787 (4.0); 7.3685 (7.2);7.3659 (6.9); 7.3631 (7.0); 7.3551 (4.3); 7.2677 (9.1); 7.1368 (0.9);7.1303 (1.1); 7.1232 (1.2); 7.1157 (1.7); 7.1081 (1.6); 7.1003 (1.1);7.0945 (0.9); 7.0871 (0.6); 5.8875 (1.0); 5.8263 (3.1); 4.9533 (0.6);4.0135 (0.5); 3.9963 (1.5); 3.9872 (1.6); 3.9789 (1.9); 3.9703 (3.0);3.9527 (2.8); 3.9350 (1.2); 3.8126 (1.8); 3.8054 (3.5); 3.7695 (2.1);3.7624 (3.9); 3.3038 (0.8); 3.2142 (3.4); 3.2089 (2.8); 3.1711 (3.0);3.1658 (2.4); 2.5129 (0.7); 2.4911 (0.5); 2.4813 (0.5); 2.0463 (1.0);1.8733 (0.8); 1.7085 (15.6); 1.6961 (16.0); 1.2835 (2.5); 1.2694 (3.8);1.2595 (4.2); 1.2567 (4.1); 1.2421 (2.6); 1.2324 (1.4); −0.0002 (4.0)II-05: ¹H-NMR(400.6 MHz, CDCl3): δ = 8.7642 (0.9); 8.7457 (0.9); 7.4812(0.5); 7.3905 (2.2); 7.3811 (4.0); 7.3691 (8.2); 7.2679 (10.5); 7.1361(0.8); 7.1264 (1.1); 7.1159 (1.5); 7.1094 (1.5); 7.0943 (0.9); 5.8883(1.1); 5.8298 (3.1); 4.9617 (0.6); 4.9415 (0.5); 4.1684 (0.6); 4.1532(0.6); 4.1485 (0.7); 4.1397 (0.5); 4.1306 (0.8); 4.1127 (0.7); 3.8195(1.7); 3.8102 (2.6); 3.7766 (1.9); 3.7672 (3.0); 3.3009 (0.8); 3.2150(2.8); 3.2079 (2.7); 3.1720 (2.5); 3.1649 (2.3); 2.5233 (0.6); 2.0459(2.4); 1.9249 (0.5); 1.8892 (0.9); 1.8804 (0.9); 1.8486 (2.2); 1.7115(15.3); 1.6969 (16.0); 1.2773 (4.5); 1.2654 (7.5); 1.2596 (8.4); 1.2505(8.2); 1.2422 (6.6); 1.2299 (5.1); 1.2140 (1.5); −0.0002 (4.7) II-06:¹H-NMR(400.0 MHz, CDCl3): δ = 7.6251 (0.6); 7.6056 (0.6); 7.5477 (0.6);7.5185 (3.2); 7.2924 (1.2); 7.2596 (533.2); 7.2500 (0.8); 7.2492 (0.8);7.2476 (0.6); 7.2095 (1.1); 7.1982 (0.7); 7.1914 (2.1); 7.1856 (2.5);7.1747 (2.4); 7.1712 (4.4); 7.1685 (3.7); 7.1655 (4.9); 7.1513 (3.0);7.1490 (2.6); 7.1455 (2.4); 6.9956 (3.0); 6.9010 (0.5); 6.8830 (0.9);6.8795 (1.6); 6.8736 (1.7); 6.8673 (0.9); 6.8577 (1.9); 6.8517 (2.6);6.8461 (1.3); 6.8358 (0.8); 6.8299 (1.2); 5.9612 (0.7); 5.9570 (0.8);5.9431 (0.6); 5.8986 (1.9); 5.8915 (1.8); 5.8867 (2.3); 5.8816 (1.8);5.8741 (1.1); 5.8539 (0.8); 5.8401 (0.5); 5.7964 (0.8); 5.7910 (1.6);5.7854 (1.5); 5.7772 (1.3); 5.7715 (1.0); 5.0162 (0.8); 4.9907 (0.8);4.0808 (0.8); 4.0636 (1.2); 4.0466 (1.2); 4.0309 (1.8); 4.0237 (2.0);4.0138 (2.7); 4.0096 (2.8); 4.0070 (3.3); 3.9972 (2.5); 3.9897 (2.0);3.9799 (2.3); 3.9607 (1.8); 3.9479 (1.4); 3.9427 (1.6); 3.9298 (1.3);3.8893 (1.9); 3.8203 (0.7); 3.8151 (1.3); 3.8016 (2.2); 3.7971 (3.4);3.7929 (4.3); 3.7824 (2.0); 3.7717 (2.3); 3.7624 (2.0); 3.7542 (5.0);3.7500 (3.9); 3.7451 (1.5); 3.7365 (2.8); 3.7178 (1.7); 3.7096 (1.0);3.6990 (0.8); 3.6912 (1.2); 3.6722 (0.8); 3.1958 (1.8); 3.1708 (3.0);3.1581 (3.0); 3.1525 (1.7); 3.1278 (2.6); 3.1151 (2.5); 3.1022 (0.5);2.6837 (0.7); 2.6480 (0.6); 2.4560 (0.6); 2.4350 (1.1); 2.4214 (0.9);2.4143 (0.8); 2.4008 (2.1); 2.3803 (2.4); 2.3667 (3.3); 2.3596 (1.3);2.3488 (4.8); 2.3316 (5.0); 2.3141 (3.4); 2.2965 (1.3); 2.0152 (0.7);2.0072 (1.1); 1.9801 (0.6); 1.9726 (0.9); 1.9315 (0.7); 1.9235 (1.2);1.9160 (0.7); 1.8971 (0.8); 1.8893 (1.2); 1.7856 (0.5); 1.7395 (3.6);1.7264 (16.0); 1.7220 (7.6); 1.7159 (6.8); 1.7061 (1.9); 1.6961 (16.0);1.5593 (11.7); 1.2559 (0.8); 0.3307 (0.6); 0.1573 (0.9); 0.1460 (0.7);0.0080 (8.3); −0.0002 (234.3); −0.0085 (6.3); −0.1496 (0.7) II-07:¹H-NMR(400.0 MHz, CDCl3): δ = 7.5191 (1.2); 7.3110 (0.6); 7.2601(216.8); 7.1915 (1.4); 7.1858 (1.8); 7.1827 (1.3); 7.1742 (1.9); 7.1709(3.5); 7.1681 (3.6); 7.1652 (4.0); 7.1621 (2.5); 7.1539 (2.3); 7.1507(2.8); 7.1483 (2.9); 7.1450 (2.2); 7.1424 (1.4); 6.9962 (1.2); 6.9016(0.6); 6.8893 (0.5); 6.8837 (1.0); 6.8794 (1.4); 6.8731 (1.4); 6.8672(0.8); 6.8620 (0.6); 6.8570 (1.6); 6.8511 (2.3); 6.8453 (1.1); 6.8351(0.7); 6.8292 (1.1); 6.8236 (0.5); 5.9496 (0.5); 5.9413 (0.7); 5.9374(1.1); 5.9317 (0.7); 5.9293 (0.6); 5.9252 (0.6); 5.9196 (0.6); 5.8910(1.1); 5.8868 (1.8); 5.8831 (1.7); 5.8790 (1.9); 5.8737 (1.4); 5.8701(0.9); 5.8663 (1.0); 5.8497 (0.8); 5.8358 (0.6); 5.7910 (0.8); 5.7857(1.5); 5.7806 (1.4); 5.7722 (1.2); 5.7668 (1.1); 5.2986 (2.4); 5.0936(0.5); 5.0884 (0.5); 5.0828 (0.5); 5.0175 (0.6); 4.9878 (0.6); 4.0818(0.9); 4.0693 (1.2); 4.0556 (1.1); 4.0237 (1.4); 4.0131 (1.8); 4.0017(1.6); 3.9949 (1.8); 3.9851 (1.9); 3.9771 (1.6); 3.9672 (2.2); 3.9573(1.8); 3.9507 (1.8); 3.9398 (1.7); 3.9310 (1.1); 3.9061 (0.7); 3.8933(0.6); 3.8801 (0.6); 3.8608 (0.5); 3.8475 (0.6); 3.8197 (1.6); 3.8014(1.8); 3.7932 (2.9); 3.7906 (2.8); 3.7764 (1.6); 3.7581 (1.7); 3.7502(3.0); 3.7476 (3.1); 3.6943 (1.1); 3.6792 (0.9); 3.6627 (0.9); 3.1983(1.6); 3.1949 (1.7); 3.1714 (2.2); 3.1590 (2.6); 3.1549 (1.6); 3.1516(1.6); 3.1284 (1.9); 3.1160 (2.1); 2.6736 (0.8); 2.6597 (0.5); 2.6372(0.7); 2.4331 (0.9); 2.4195 (0.7); 2.4125 (0.6); 2.3990 (1.1); 2.3782(0.6); 2.3741 (0.9); 2.3604 (0.5); 2.3399 (1.0); 2.0434 (0.5); 1.9976(0.5); 1.9898 (0.9); 1.9822 (0.5); 1.9556 (0.8); 1.9205 (0.5); 1.9125(0.9); 1.9052 (0.6); 1.8955 (0.6); 1.8861 (1.1); 1.8781 (1.4); 1.8705(1.3); 1.8650 (1.4); 1.8572 (1.7); 1.8475 (2.1); 1.8372 (2.3); 1.8299(2.2); 1.8243 (2.2); 1.8067 (1.8); 1.7968 (1.5); 1.7852 (1.3); 1.7757(1.6); 1.7721 (1.4); 1.7629 (2.2); 1.7499 (3.2); 1.7353 (3.4); 1.7254(16.0); 1.7227 (11.9); 1.7163 (8.8); 1.7094 (3.0); 1.7065 (2.6); 1.6958(12.0); 1.5578 (7.5); 1.2586 (0.9); 0.0080 (3.2); −0.0002 (90.6);−0.0085 (2.6) II-08: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.5187 (1.1); 7.3381(0.5); 7.2598 (194.2); 7.1811 (0.5); 7.1750 (1.2); 7.1689 (2.7); 7.1658(2.5); 7.1631 (2.7); 7.1599 (2.3); 7.1548 (1.7); 7.1521 (1.9); 7.1490(3.3); 7.1464 (2.3); 7.1432 (2.4); 6.9958 (1.1); 6.8938 (0.9); 6.8881(1.7); 6.8842 (0.9); 6.8823 (0.9); 6.8722 (1.1); 6.8664 (2.0); 6.8606(1.0); 6.8447 (0.8); 6.7572 (0.5); 5.9645 (0.5); 5.9556 (0.6); 5.9506(1.2); 5.9457 (0.8); 5.9356 (0.8); 5.9320 (1.0); 5.9272 (1.0); 5.9227(0.7); 5.9194 (0.8); 5.9139 (1.3); 5.9095 (1.2); 5.9051 (0.8); 5.8994(0.7); 5.8950 (1.1); 5.8900 (0.6); 5.8854 (0.6); 5.8811 (0.9); 5.8759(0.8); 5.8576 (3.9); 5.3512 (0.5); 5.2986 (0.6); 5.0812 (0.5); 4.9382(0.5); 4.9285 (0.5); 3.7992 (1.5); 3.7951 (1.3); 3.7741 (1.8); 3.7725(1.6); 3.7559 (1.7); 3.7518 (1.5); 3.7310 (2.1); 3.7294 (1.9); 3.3064(0.5); 3.2953 (0.7); 3.2849 (0.7); 3.2020 (1.4); 3.1995 (1.7); 3.1844(1.4); 3.1753 (1.7); 3.1586 (1.3); 3.1561 (1.5); 3.1413 (1.2); 3.1322(1.4); 2.5469 (0.6); 2.5420 (0.8); 2.5377 (0.5); 2.5283 (0.8); 2.5258(0.6); 2.5234 (0.6); 2.5208 (0.5); 2.5115 (0.5); 2.5071 (1.3); 2.5029(0.5); 2.4857 (0.7); 2.4720 (0.6); 2.0435 (1.4); 1.8929 (0.7); 1.8840(0.6); 1.8584 (0.7); 1.8489 (0.6); 1.8238 (0.6); 1.7153 (16.0); 1.7133(12.4); 1.7017 (7.7); 1.6109 (8.0); 1.5941 (3.7); 1.5785 (6.8); 1.5765(7.2); 1.5638 (7.6); 1.5429 (13.9); 1.3214 (0.6); 1.3042 (1.3); 1.2649(6.3); 1.2588 (4.5); 1.2408 (1.0); 0.8988 (3.4); 0.8819 (12.4); 0.8642(4.6); 0.0080 (2.2); −0.0002 (74.7); −0.0085 (2.2) II-09: ¹H-NMR(400.0MHz, CDCl3): δ = 7.5189 (1.3); 7.3494 (0.5); 7.3094 (0.6); 7.2778 (0.5);7.2770 (0.5); 7.2762 (0.6); 7.2754 (0.6); 7.2746 (0.6); 7.2738 (0.7);7.2730 (0.8); 7.2722 (0.9); 7.2714 (1.0); 7.2706 (1.0); 7.2698 (1.1);7.2690 (1.3); 7.2682 (1.5); 7.2674 (1.7); 7.2666 (1.9); 7.2658 (2.3);7.2650 (2.9); 7.2641 (3.7); 7.2600 (230.6); 7.1705 (1.2); 7.1676 (2.2);7.1649 (2.4); 7.1618 (2.7); 7.1554 (1.1); 7.1507 (2.3); 7.1478 (2.7);7.1452 (2.4); 7.1420 (1.9); 6.9960 (1.3); 6.8924 (0.6); 6.8888 (0.9);6.8867 (1.0); 6.8831 (1.4); 6.8773 (0.7); 6.8673 (1.0); 6.8649 (0.6);6.8615 (1.6); 6.8557 (0.7); 6.8398 (0.6); 6.7549 (0.6); 6.7341 (0.6);6.0524 (0.6); 6.0378 (0.6); 5.9563 (1.0); 5.9502 (2.5); 5.9472 (1.8);5.9425 (1.1); 5.9378 (0.9); 5.9322 (0.8); 5.9294 (0.6); 5.9248 (0.8);5.9206 (0.6); 5.9151 (0.5); 5.9120 (0.6); 5.8872 (0.8); 5.8818 (1.4);5.8763 (0.6); 5.8677 (0.8); 5.8617 (0.9); 5.2987 (3.7); 5.0879 (0.5);4.1306 (1.0); 4.1127 (1.0); 3.7989 (1.8); 3.7977 (1.8); 3.7872 (1.2);3.7770 (1.2); 3.7701 (0.6); 3.7612 (10.6); 3.7556 (2.3); 3.7543 (2.5);3.7430 (12.2); 3.7414 (15.3); 3.7339 (1.7); 3.7293 (14.2); 3.5647 (0.5);3.1991 (2.4); 3.1745 (1.1); 3.1655 (1.2); 3.1557 (2.1); 3.1314 (1.0);3.1224 (1.0); 2.5602 (0.7); 2.5440 (0.5); 2.5396 (0.8); 2.5276 (0.7);2.5256 (0.6); 2.5093 (0.6); 2.5059 (0.6); 2.4928 (0.7); 2.0436 (4.9);1.8668 (0.7); 1.8560 (0.7); 1.7159 (16.0); 1.7082 (6.7); 1.6978 (6.3);1.5877 (5.4); 1.5807 (5.4); 1.5651 (5.4); 1.5506 (12.3); 1.5439 (11.0);1.5376 (7.9); 1.5298 (7.1); 1.2766 (1.6); 1.2587 (3.3); 1.2408 (1.5);0.0079 (2.6); 0.0062 (0.8); 0.0054 (1.0); 0.0045 (1.2); −0.0002 (89.6);−0.0028 (4.1); −0.0044 (1.6); −0.0052 (1.2); −0.0061 (0.9); −0.0069(0.8); −0.0085 (2.5) II-10: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.5189 (1.3);7.3016 (0.5); 7.2985 (0.5); 7.2953 (0.6); 7.2931 (0.8); 7.2897 (0.5);7.2889 (0.6); 7.2865 (0.6); 7.2850 (0.6); 7.2818 (0.6); 7.2802 (0.6);7.2778 (0.8); 7.2770 (0.8); 7.2762 (0.9); 7.2730 (1.1); 7.2714 (1.3);7.2706 (1.4); 7.2682 (1.8); 7.2600 (227.8); 7.2098 (0.6); 7.1808 (1.1);7.1781 (1.4); 7.1751 (1.6); 7.1723 (1.7); 7.1692 (1.6); 7.1664 (1.7);7.1634 (2.2); 7.1609 (2.6); 7.1584 (2.2); 7.1554 (1.7); 7.1526 (1.7);7.1496 (1.5); 7.1466 (1.5); 7.1437 (1.3); 7.1410 (0.9); 6.9960 (1.3);6.9084 (0.7); 6.9025 (0.7); 6.8967 (0.7); 6.8910 (0.9); 6.8867 (1.3);6.8808 (1.3); 6.8750 (0.7); 6.8650 (0.6); 6.8591 (0.6); 5.9811 (0.5);5.9725 (0.5); 5.9672 (1.0); 5.9621 (0.6); 5.9431 (0.6); 5.9390 (0.7);5.9338 (0.6); 5.9203 (0.8); 5.9159 (1.0); 5.9137 (1.4); 5.9104 (1.2);5.9059 (0.6); 5.8988 (0.5); 5.8936 (0.8); 5.8849 (0.8); 5.8799 (1.4);5.8752 (1.0); 5.8611 (0.6); 5.8560 (1.2); 5.8498 (1.2); 5.8443 (0.6);5.8423 (0.6); 5.8359 (0.6); 5.2987 (6.1); 4.1305 (1.2); 4.1126 (1.2);3.7990 (1.3); 3.7949 (1.2); 3.7601 (1.4); 3.7556 (1.6); 3.7513 (2.6);3.7170 (1.5); 3.7078 (1.6); 3.3871 (0.5); 3.2042 (1.6); 3.1943 (1.6);3.1919 (1.6); 3.1608 (1.4); 3.1511 (1.4); 3.1487 (1.4); 2.6429 (0.6);2.6313 (0.8); 2.6184 (0.6); 2.6073 (0.8); 2.5962 (0.7); 2.5823 (0.6);2.5732 (0.6); 2.0437 (5.8); 1.9633 (0.6); 1.9326 (0.6); 1.9280 (0.6);1.9210 (0.6); 1.9097 (0.6); 1.8981 (0.6); 1.8859 (0.6); 1.7512 (0.6);1.7315 (7.4); 1.7241 (7.7); 1.7168 (15.8); 1.7142 (16.0); 1.7069 (2.8);1.7031 (8.8); 1.6986 (14.3); 1.6858 (9.6); 1.5428 (17.1); 1.2766 (1.8);1.2587 (4.0); 1.2409 (1.8); 0.0079 (2.4); 0.0062 (0.8); 0.0053 (0.9);0.0045 (1.0); −0.0002 (89.7); −0.0052 (1.4); −0.0061 (1.1); −0.0069(1.0); −0.0085 (2.7) II-11: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.5197 (1.4);7.4953 (0.7); 7.2810 (0.6); 7.2802 (0.6); 7.2794 (0.6); 7.2786 (0.6);7.2778 (0.6); 7.2770 (0.7); 7.2762 (0.8); 7.2754 (0.8); 7.2746 (0.9);7.2738 (0.9); 7.2730 (1.0); 7.2722 (1.2); 7.2714 (1.2); 7.2706 (1.3);7.2698 (1.6); 7.2690 (1.8); 7.2682 (2.0); 7.2674 (2.2); 7.2666 (2.6);7.2658 (3.3); 7.2649 (4.2); 7.2608 (208.3); 7.2561 (2.6); 7.2553 (1.8);7.2544 (1.4); 7.2536 (1.0); 7.2529 (0.7); 7.1803 (1.4); 7.1777 (1.7);7.1740 (2.8); 7.1666 (3.2); 7.1636 (3.2); 7.1605 (3.5); 7.1576 (3.2);7.1541 (3.3); 7.1479 (3.1); 7.1408 (1.3); 6.9968 (1.2); 6.9052 (0.5);6.8922 (0.5); 6.8893 (0.7); 6.8849 (1.4); 6.8792 (1.7); 6.8734 (0.8);6.8632 (1.9); 6.8574 (3.0); 6.8516 (1.4); 6.8415 (0.8); 6.8356 (1.4);6.8298 (0.7); 6.7486 (0.5); 6.0862 (0.7); 5.9800 (0.6); 5.9756 (0.6);5.9685 (2.5); 5.9633 (1.0); 5.9581 (0.7); 5.9498 (1.2); 5.9448 (1.5);5.9399 (1.4); 5.9360 (1.4); 5.9312 (1.8); 5.9262 (1.4); 5.9105 (0.9);5.9054 (1.3); 5.9032 (1.4); 5.9000 (1.4); 5.8921 (1.1); 5.8861 (0.8);5.8777 (0.7); 5.8697 (1.2); 5.8617 (1.2); 5.2988 (3.0); 4.9842 (0.8);4.6521 (0.8); 4.6398 (0.9); 4.6299 (0.9); 4.6178 (1.1); 4.6133 (1.0);4.6072 (0.8); 4.6004 (1.4); 4.5973 (0.8); 4.5910 (1.0); 4.5879 (0.8);4.5848 (0.8); 4.5782 (1.7); 4.5657 (1.0); 4.5628 (0.8); 4.5505 (0.7);4.5408 (0.7); 4.5286 (0.6); 4.1484 (0.7); 4.1305 (2.2); 4.1127 (2.2);4.0948 (0.7); 3.8166 (1.2); 3.8049 (0.8); 3.8016 (1.8); 3.7843 (1.9);3.7811 (1.9); 3.7783 (1.6); 3.7736 (1.7); 3.7602 (15.0); 3.7538 (11.0);3.7475 (11.6); 3.7422 (10.7); 3.7402 (16.0); 3.7333 (6.4); 3.7318 (7.0);3.3897 (0.9); 3.2013 (2.2); 3.1718 (2.8); 3.1653 (1.8); 3.1583 (2.4);3.1288 (2.5); 3.1222 (1.5); 3.1167 (1.1); 2.5605 (0.5); 2.5257 (0.7);2.5044 (0.7); 2.4985 (0.6); 2.4829 (0.8); 2.4696 (0.6); 2.4637 (0.9);2.4485 (0.7); 2.4413 (0.6); 2.4275 (0.7); 2.2063 (0.6); 2.1991 (0.6);2.1939 (0.9); 2.1890 (0.9); 2.1819 (0.8); 2.1767 (1.3); 2.1712 (1.0);2.1649 (0.8); 2.1594 (1.2); 2.1539 (0.8); 2.1479 (0.7); 2.1419 (0.8);2.0436 (10.7); 1.9396 (0.7); 1.9132 (0.7); 1.9048 (0.6); 1.8764 (0.6);1.8640 (0.7); 1.8380 (0.7); 1.8290 (0.7); 1.7187 (14.5); 1.7120 (10.1);1.7081 (7.8); 1.7002 (7.6); 1.6947 (9.4); 1.5719 (2.0); 1.2765 (3.2);1.2587 (6.7); 1.2408 (3.1); 0.9713 (3.6); 0.9542 (3.8); 0.9435 (7.1);0.9348 (4.4); 0.9313 (3.4); 0.9265 (10.8); 0.9207 (8.3); 0.9177 (9.1);0.9143 (3.9); 0.9095 (4.6); 0.9070 (3.5); 0.9033 (7.7); 0.9008 (9.7);0.8964 (3.4); 0.8864 (4.1); 0.8839 (5.4); 0.8790 (2.5); 0.8694 (3.1);0.0080 (2.2); −0.0002 (77.8); −0.0085 (2.3) II-12: ¹H-NMR(400.0 MHz,CDCl3): δ = 7.5187 (1.3); 7.4241 (0.7); 7.4031 (0.5); 7.3255 (0.6);7.3100 (0.8); 7.2598 (223.5); 7.1920 (1.2); 7.1875 (1.6); 7.1825 (1.7);7.1766 (2.0); 7.1655 (3.2); 7.1625 (3.0); 7.1566 (1.8); 7.1487 (2.3);7.1451 (2.1); 7.1396 (0.9); 6.9958 (1.3); 6.9127 (0.8); 6.8940 (1.3);6.8911 (1.6); 6.8882 (1.4); 6.8854 (1.3); 6.8824 (1.0); 6.8725 (1.2);6.8693 (1.4); 6.8637 (0.8); 6.7904 (0.6); 6.7693 (0.6); 5.9956 (0.8);5.9905 (0.8); 5.9594 (0.5); 5.9384 (1.2); 5.9358 (1.3); 5.9312 (1.2);5.9285 (1.2); 5.9222 (0.7); 5.9064 (0.6); 5.8920 (1.4); 5.8824 (3.5);5.8718 (1.3); 5.8670 (1.6); 5.8633 (1.2); 5.2985 (1.9); 4.8577 (0.8);4.8418 (0.9); 4.8333 (1.0); 4.8281 (1.1); 4.8186 (1.6); 4.8106 (1.8);4.8029 (1.8); 4.7957 (1.2); 4.7882 (1.4); 4.7801 (1.4); 4.7639 (0.8);3.9508 (0.9); 3.8435 (1.1); 3.7998 (1.7); 3.7969 (1.7); 3.7770 (1.2);3.7731 (1.2); 3.7670 (1.2); 3.7593 (0.9); 3.7534 (1.8); 3.7339 (1.2);3.7299 (1.3); 3.7240 (1.3); 3.4194 (0.8); 3.4144 (0.9); 3.2092 (1.6);3.2010 (1.3); 3.1919 (1.1); 3.1827 (1.3); 3.1793 (1.4); 3.1659 (1.5);3.1615 (0.9); 3.1576 (1.2); 3.1487 (1.0); 3.1391 (1.1); 3.1363 (1.2);2.6519 (0.5); 2.6391 (0.5); 2.6164 (0.9); 2.5941 (0.8); 2.5814 (0.6);2.5760 (0.8); 2.5590 (0.8); 2.5495 (0.6); 2.5404 (0.8); 2.0918 (0.6);2.0750 (1.1); 2.0689 (0.8); 2.0585 (1.4); 2.0519 (1.1); 2.0436 (3.0);2.0351 (1.0); 2.0251 (0.8); 2.0184 (0.7); 2.0033 (0.5); 1.9696 (0.6);1.9450 (0.6); 1.9353 (0.6); 1.9214 (0.9); 1.9108 (1.3); 1.9006 (0.6);1.8859 (0.6); 1.8752 (0.9); 1.7562 (0.5); 1.7278 (7.0); 1.7204 (16.0);1.7142 (8.1); 1.6934 (5.8); 1.5510 (5.9); 1.2765 (0.8); 1.2586 (2.0);1.2407 (0.7); 1.1320 (3.6); 1.1133 (8.1); 1.0964 (7.5); 1.0916 (6.1);1.0837 (4.9); 1.0741 (10.6); 1.0712 (7.2); 1.0676 (5.0); 1.0626 (3.1);1.0564 (8.2); 1.0542 (8.2); 1.0456 (2.1); 1.0373 (2.7); 0.0080 (3.3);−0.0002 (95.1); −0.0085 (3.0) II-13: ¹H-NMR(400.6 MHz, CDCl3): δ =7.4158 (1.8); 7.3963 (4.7); 7.3873 (2.8); 7.3827 (4.2); 7.3782 (6.6);7.3736 (6.1); 7.3702 (7.5); 7.3669 (7.3); 7.2641 (15.3); 7.1590 (1.1);7.1536 (1.4); 7.1411 (1.4); 7.1344 (1.8); 7.1322 (1.7); 7.1303 (1.7);7.1243 (1.2); 7.1165 (1.3); 7.1092 (0.6); 5.9624 (1.9); 5.9403 (1.3);5.9323 (1.7); 5.9269 (1.9); 5.9239 (1.7); 5.9190 (1.9); 5.9141 (1.1);5.8928 (1.3); 5.8879 (2.5); 5.8830 (2.3); 5.8743 (1.5); 5.8692 (1.3);4.7835 (0.9); 4.1316 (0.7); 4.1137 (0.7); 3.8381 (2.5); 3.8258 (2.2);3.7946 (2.8); 3.7824 (2.5); 3.5727 (0.8); 3.5603 (1.0); 3.5555 (1.0);3.5443 (0.8); 3.2886 (9.1); 3.2672 (11.9); 3.2492 (4.0); 3.2459 (3.2);3.2057 (3.2); 3.2023 (2.6); 2.7107 (0.6); 2.6877 (1.1); 2.6742 (1.0);2.6647 (0.9); 2.6520 (1.3); 2.6293 (0.7); 2.2836 (0.5); 2.0478 (3.6);2.0389 (0.9); 2.0341 (0.7); 2.0264 (0.7); 2.0211 (1.1); 2.0154 (0.7);2.0083 (0.7); 2.0031 (1.0); 1.9982 (0.7); 1.9905 (0.7); 1.9853 (1.0);1.9727 (0.6); 1.7198 (13.1); 1.7162 (16.0); 1.7110 (8.0); 1.6950 (0.7);1.3326 (1.6); 1.2983 (0.6); 1.2836 (2.5); 1.2779 (1.8); 1.2599 (5.4);1.2557 (6.8); 1.2422 (1.6); 0.8962 (0.6); 0.8799 (1.4); 0.8621 (0.7);−0.0002 (7.8) II-14: ¹H-NMR(400.0 MHz, CDCl3): δ = 9.5942 (0.8); 9.5645(0.9); 7.3118 (1.7); 7.2971 (1.9); 7.2786 (1.6); 7.2618 (76.0); 7.2014(0.7); 7.1972 (0.8); 7.1887 (3.1); 7.1848 (5.0); 7.1829 (4.9); 7.1792(5.2); 7.1760 (3.0); 7.1722 (3.1); 7.1690 (5.2); 7.1652 (5.1); 7.1634(5.0); 7.1595 (3.3); 7.1526 (0.8); 7.1471 (0.6); 6.9172 (1.1); 6.9153(1.1); 6.9114 (1.7); 6.9097 (1.6); 6.9056 (1.0); 6.8955 (2.0); 6.8937(2.1); 6.8897 (3.2); 6.8880 (3.1); 6.8840 (1.8); 6.8738 (1.0); 6.8721(1.0); 6.8680 (1.6); 6.8663 (1.5); 6.8623 (0.8); 6.1922 (2.5); 6.1846(2.5); 6.1654 (2.8); 6.1578 (2.8); 6.1491 (3.1); 6.1414 (2.9); 6.1222(3.0); 6.1147 (3.0); 5.9398 (1.0); 5.9347 (1.6); 5.9321 (1.5); 5.9264(2.5); 5.9209 (3.2); 5.9182 (2.8); 5.9163 (3.0); 5.9135 (3.5); 5.9092(2.5); 5.9025 (4.2); 5.8978 (6.5); 5.8926 (3.2); 5.8887 (1.5); 5.8838(2.8); 5.8787 (1.7); 5.5695 (4.4); 5.5682 (4.9); 5.5665 (4.8); 5.5652(4.5); 5.5264 (3.9); 5.5250 (4.3); 5.5234 (4.2); 5.5220 (3.8); 5.3657(3.8); 5.3649 (3.8); 5.3569 (4.0); 5.3389 (3.5); 5.3379 (3.6); 5.3301(3.7); 5.3291 (3.6); 5.2991 (8.6); 4.8195 (0.5); 4.8002 (1.1); 4.7937(1.2); 4.7888 (1.3); 4.7833 (1.2); 4.7787 (1.1); 4.7706 (1.0); 3.9516(4.0); 3.9401 (4.2); 3.9082 (4.6); 3.8967 (4.8); 3.5617 (1.0); 3.5571(1.4); 3.5523 (1.4); 3.5491 (1.5); 3.5443 (1.9); 3.5392 (2.0); 3.5341(1.9); 3.5292 (1.5); 3.5259 (1.4); 3.5214 (1.6); 3.5168 (1.0); 3.4518(0.6); 3.4357 (3.8); 3.4259 (2.6); 3.4228 (3.3); 3.4170 (5.7); 3.4121(3.4); 3.4065 (2.9); 3.4046 (3.1); 3.3966 (4.3); 3.3872 (2.2); 3.3761(0.9); 3.3699 (0.6); 3.3512 (0.5); 3.3392 (4.5); 3.3315 (4.3); 3.2958(3.8); 3.2881 (3.8); 2.7259 (1.0); 2.7232 (1.0); 2.7029 (2.1); 2.7002(2.0); 2.6898 (1.4); 2.6870 (1.4); 2.6799 (1.3); 2.6772 (1.2); 2.6668(2.3); 2.6641 (2.2); 2.6437 (1.1); 2.6413 (1.1); 2.0357 (1.0); 2.0273(1.2); 2.0233 (1.9); 2.0154 (1.9); 2.0109 (1.2); 2.0030 (1.1); 1.9999(1.1); 1.9912 (1.2); 1.9872 (1.8); 1.9793 (1.7); 1.9748 (1.1); 1.9671(0.9); 1.8925 (0.9); 1.8767 (3.0); 1.8736 (2.7); 1.8578 (5.7); 1.8547(4.4); 1.8467 (1.9); 1.8387 (6.0); 1.8352 (4.5); 1.8280 (2.1); 1.8196(3.9); 1.8160 (3.4); 1.8008 (1.8); 1.7973 (1.7); 1.0983 (1.0); 1.0899(7.6); 1.0814 (1.8); 1.0746 (9.0); 1.0714 (16.0); 1.0630 (1.6); 1.0561(15.4); 1.0527 (8.1); 1.0374 (6.2); 0.9033 (1.0); 0.8932 (0.5); 0.8875(1.0); 0.0080 (1.4); −0.0002 (44.4); −0.0085 (1.7) II-15: ¹H-NMR(400.0MHz, d₆-DMSO): δ = 7.8906 (0.9); 7.8742 (1.5); 7.8548 (1.4); 7.7920(1.1); 7.7714 (1.1); 7.5229 (3.9); 7.5034 (4.0); 7.4859 (2.8); 7.3286(1.2); 7.3093 (2.2); 7.2914 (1.0); 5.8650 (2.6); 5.6779 (1.8); 5.6699(1.2); 5.6643 (1.6); 5.6195 (1.6); 5.6058 (1.3); 4.7403 (1.1); 4.0385(1.2); 4.0205 (1.3); 3.7633 (4.3); 3.7195 (5.2); 3.3720 (3.4); 3.3677(2.9); 3.3572 (1.2); 3.3434 (0.8); 3.3282 (3.9); 3.3235 (4.0); 3.3093(256.8); 2.6743 (3.3); 2.6694 (4.4); 2.6650 (3.3); 2.5508 (3.5); 2.5461(3.4); 2.5227 (14.0); 2.5094 (278.6); 2.5050 (564.2); 2.5005 (753.6);2.4961 (546.5); 2.4918 (270.3); 2.4474 (4.0); 2.3318 (3.5); 2.3272(4.5); 2.3228 (3.5); 2.2409 (0.6); 2.2213 (1.3); 2.2030 (0.9); 2.1835(1.5); 2.1703 (1.2); 2.1502 (1.5); 2.1303 (0.7); 2.0724 (1.5); 1.9878(5.0); 1.7952 (0.9); 1.7835 (1.1); 1.7606 (0.7); 1.7506 (1.0); 1.7392(1.2); 1.7273 (1.3); 1.7154 (0.8); 1.6943 (1.2); 1.6821 (0.8); 1.5556(12.0); 1.5325 (16.0); 1.2377 (2.2); 1.1923 (1.4); 1.1745 (2.9); 1.1567(1.4); 0.8539 (0.6); 0.1464 (0.6); −0.0002 (147.9); −0.0085 (6.8);−0.1496 (0.6) II-16: ¹H-NMR(400.0 MHz, d₆-DMSO): δ = 7.8755 (1.8);7.8505 (1.7); 7.7928 (1.4); 7.5227 (5.8); 7.5027 (5.6); 7.4864 (4.2);7.3083 (2.9); 5.8644 (3.4); 5.6720 (2.4); 5.6195 (1.8); 4.7574 (1.6);3.7626 (4.2); 3.7196 (5.2); 3.3712 (4.4); 3.3078 (485.4); 2.6699 (7.9);2.5039 (1088.6); 2.5004 (1306.5); 2.3938 (2.6); 2.3271 (8.4); 2.2218(2.2); 2.1868 (2.0); 2.1701 (2.0); 2.0727 (1.2); 1.9884 (2.2); 1.7277(1.6); 1.5554 (12.9); 1.5325 (16.0); 1.2374 (2.2); 1.1744 (1.7); −0.0002(90.9) II-17: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.5187 (1.8); 7.4267 (1.0);7.3105 (1.4); 7.2956 (1.1); 7.2598 (331.5); 7.2117 (0.5); 7.1955 (2.4);7.1906 (2.4); 7.1844 (2.6); 7.1798 (3.4); 7.1748 (3.7); 7.1693 (2.8);7.1648 (2.0); 7.1549 (1.8); 6.9958 (1.8); 6.8999 (1.1); 6.8953 (1.3);6.8893 (1.2); 6.8837 (1.6); 6.8784 (1.8); 6.8735 (1.6); 6.8676 (1.0);6.8566 (0.8); 6.1977 (1.1); 6.1935 (1.8); 6.1807 (1.0); 6.1709 (1.3);6.1668 (2.0); 6.1543 (2.0); 6.1504 (2.1); 6.1376 (1.1); 6.1277 (1.3);6.1236 (2.1); 6.1108 (1.0); 5.9507 (0.9); 5.9010 (1.0); 5.8836 (6.3);5.8728 (1.9); 5.8686 (2.0); 5.5795 (1.4); 5.5717 (1.5); 5.5668 (1.7);5.5653 (1.7); 5.5502 (1.4); 5.5454 (1.6); 5.5439 (1.6); 5.5364 (1.3);5.5287 (1.3); 5.5237 (1.5); 5.5070 (1.1); 5.5023 (1.3); 5.3713 (1.4);5.3595 (2.1); 5.3471 (1.8); 5.3448 (1.6); 5.3331 (3.1); 5.3217 (1.4);5.3065 (1.2); 4.8516 (1.2); 4.8353 (3.0); 4.8293 (1.4); 4.8189 (2.4);4.8128 (3.0); 4.7965 (2.2); 4.7769 (0.6); 4.1485 (0.6); 4.1306 (1.8);4.1127 (2.0); 4.0949 (0.6); 3.9786 (1.6); 3.9417 (1.0); 3.9353 (2.0);3.9226 (1.5); 3.9179 (1.7); 3.9106 (1.5); 3.8986 (1.1); 3.8796 (1.7);3.8748 (1.9); 3.8676 (1.6); 3.5411 (0.9); 3.5269 (0.8); 3.4112 (1.2);3.3368 (1.2); 3.3324 (1.8); 3.3171 (3.0); 3.3122 (1.7); 3.2895 (1.7);3.2738 (2.5); 3.2694 (1.5); 2.6500 (0.8); 2.6373 (0.5); 2.6277 (0.7);2.6143 (0.9); 2.6058 (0.8); 2.5920 (1.1); 2.5838 (0.5); 2.5702 (1.6);2.5597 (0.7); 2.5566 (0.7); 2.5481 (0.9); 2.5349 (1.0); 2.0841 (0.9);2.0673 (1.6); 2.0505 (1.8); 2.0436 (9.4); 2.0336 (1.3); 2.0156 (0.6);1.9641 (1.0); 1.9564 (1.2); 1.9460 (0.6); 1.9228 (1.6); 1.9125 (1.4);1.8876 (0.9); 1.8770 (0.9); 1.5444 (16.0); 1.2765 (2.8); 1.2587 (5.6);1.2408 (2.6); 1.1280 (5.5); 1.1173 (6.1); 1.1150 (6.8); 1.1107 (8.4);1.0978 (10.4); 1.0928 (6.6); 1.0891 (11.1); 1.0805 (10.1); 1.0704(13.0); 1.0632 (5.8); 1.0531 (9.2); 1.0439 (1.5); 1.0402 (1.4); 0.9977(0.6); 0.8819 (0.7); 0.1460 (0.6); 0.0505 (0.6); 0.0080 (6.6); −0.0002(169.8); −0.0085 (6.8); −0.1495 (0.6) II-18: ¹H-NMR(400.6 MHz, CDCl3): δ= 7.3653 (0.5); 7.3554 (0.6); 7.3475 (0.6); 7.3377 (0.6); 7.2620 (30.5);7.1972 (1.1); 7.1914 (1.4); 7.1885 (0.8); 7.1779 (2.1); 7.1753 (1.6);7.1723 (2.2); 7.1619 (0.9); 7.1588 (1.6); 7.1531 (1.3); 6.9144 (0.8);6.9086 (0.7); 6.8986 (0.6); 6.8928 (1.6); 6.8870 (1.4); 6.8811 (0.5);6.8712 (0.8); 6.8653 (0.7); 6.1988 (1.1); 6.1912 (1.0); 6.1720 (1.3);6.1645 (1.1); 6.1557 (1.4); 6.1482 (1.2); 6.1289 (1.4); 6.1214 (1.2);5.9786 (0.6); 5.9700 (0.9); 5.9648 (1.5); 5.9598 (0.9); 5.9562 (0.7);5.9510 (1.1); 5.9461 (0.7); 5.9276 (0.7); 5.9224 (1.4); 5.9191 (1.6);5.9138 (1.1); 5.9086 (0.9); 5.9052 (0.9); 5.5807 (1.8); 5.5794 (1.9);5.5618 (1.6); 5.5605 (1.6); 5.5376 (1.6); 5.5363 (1.6); 5.5187 (1.4);5.5174 (1.4); 5.3609 (1.5); 5.3598 (1.5); 5.3520 (1.7); 5.3512 (1.7);5.3341 (1.4); 5.3330 (1.4); 5.3253 (1.6); 5.3243 (1.7); 4.7652 (0.5);4.7586 (0.6); 4.7532 (0.6); 4.4965 (1.4); 4.4652 (1.4); 4.4584 (2.3);4.4280 (3.0); 4.3818 (3.1); 4.3504 (2.4); 4.3446 (1.4); 4.3124 (1.5);4.1314 (0.5); 4.1136 (0.6); 3.9916 (1.6); 3.9481 (1.9); 3.9413 (2.0);3.8980 (2.2); 3.7724 (16.0); 3.6914 (13.4); 3.5917 (0.5); 3.5850 (0.6);3.5800 (0.6); 3.5746 (0.6); 3.5681 (0.6); 3.5625 (0.6); 3.3294 (2.2);3.3278 (2.1); 3.2861 (1.9); 3.2841 (1.8); 2.7413 (0.6); 2.7354 (0.7);2.7222 (0.5); 2.7047 (0.7); 2.6988 (0.8); 2.1548 (0.7); 2.1182 (0.7);2.1021 (0.7); 2.0655 (0.6); 2.0467 (2.6); 1.5910 (1.9); 1.2779 (1.0);1.2601 (2.3); 1.2532 (1.1); 1.2422 (0.9); 0.8819 (1.6); 0.8642 (0.6);0.0693 (1.4); 0.0079 (0.7); −0.0002 (27.3); −0.0085 (0.9) II-27:¹H-NMR(400.0 MHz, CDCl3): δ = 7.6172 (1.7); 7.5974 (1.6); 7.5544 (3.6);7.5320 (3.1); 7.3116 (1.8); 7.2797 (11.7); 7.2607 (138.2); 7.2109 (3.1);7.1920 (7.6); 7.1800 (12.1); 7.1752 (12.6); 7.1601 (9.0); 7.1426 (1.1);6.9970 (0.8); 6.8847 (3.4); 6.8791 (4.6); 6.8628 (5.5); 6.8573 (7.3);6.8516 (4.0); 6.8412 (2.7); 6.8356 (3.4); 6.2130 (4.8); 6.1978 (2.8);6.1863 (5.3); 6.1704 (6.7); 6.1547 (3.0); 6.1432 (5.4); 6.1280 (2.3);5.8981 (7.2); 5.8705 (2.8); 5.8653 (3.4); 5.8513 (1.9); 5.8145 (5.0);5.8092 (6.7); 5.8034 (4.7); 5.7955 (4.4); 5.5878 (9.4); 5.5448 (9.2);5.5049 (3.5); 5.3405 (9.5); 5.3142 (10.7); 5.2987 (1.8); 5.2897 (3.6);5.0311 (5.0); 5.0125 (3.4); 4.0475 (2.5); 4.0283 (8.6); 4.0206 (7.4);4.0114 (13.1); 4.0038 (10.2); 3.9945 (7.3); 3.9865 (6.4); 3.9643 (4.8);3.9327 (16.0); 3.8899 (13.3); 3.8158 (2.3); 3.7966 (4.6); 3.7884 (5.1);3.7698 (8.0); 3.7561 (5.3); 3.7507 (5.4); 3.7374 (7.3); 3.7189 (5.6);3.7104 (3.4); 3.6991 (2.0); 3.6913 (2.3); 3.6710 (0.6); 3.3094 (6.2);3.3022 (9.6); 3.2667 (5.3); 3.2593 (8.3); 2.4465 (2.5); 2.4259 (4.8);2.4120 (4.3); 2.4051 (3.7); 2.3914 (7.2); 2.3831 (5.0); 2.3658 (10.8);2.3538 (9.6); 2.3478 (12.8); 2.3301 (8.8); 2.3173 (3.8); 2.2994 (1.1);1.9934 (3.5); 1.9858 (5.0); 1.9778 (3.0); 1.9589 (3.6); 1.9516 (5.5);1.9441 (4.3); 1.9178 (1.4); 1.9103 (1.8); 1.9026 (1.0); 1.5907 (5.6);−0.0002 (79.8); −0.0500 (0.7) II-28: ¹H-NMR(400.0 MHz, CDCl3): δ =7.5183 (9.0); 7.3731 (1.4); 7.3097 (12.2); 7.2881 (3.0); 7.2594(1582.1); 7.2109 (3.7); 7.1847 (12.4); 7.1791 (19.2); 7.1747 (19.4);7.1650 (16.0); 7.1596 (17.5); 6.9954 (8.9); 6.9053 (3.9); 6.8976 (5.4);6.8911 (4.6); 6.8821 (6.1); 6.8762 (8.9); 6.8702 (5.0); 6.8607 (2.9);6.8546 (4.3); 6.7435 (1.9); 6.1965 (10.3); 6.1698 (11.6); 6.1534 (12.8);6.1266 (12.9); 6.0151 (6.5); 6.0092 (6.6); 6.0014 (8.5); 5.9957 (8.4);5.9914 (6.1); 5.9107 (4.5); 5.9053 (8.5); 5.8995 (5.0); 5.8914 (6.7);5.8858 (4.1); 5.8687 (2.6); 5.8613 (3.3); 5.8464 (3.5); 5.8317 (1.8);5.6515 (2.7); 5.6084 (2.5); 5.5642 (4.4); 5.5510 (16.0); 5.5213 (3.9);5.5079 (13.6); 5.4650 (2.6); 5.4379 (2.5); 5.3557 (8.2); 5.3436 (11.7);5.3291 (7.5); 5.3167 (11.0); 5.1225 (1.7); 5.0099 (3.9); 3.9857 (1.7);3.9523 (4.5); 3.9480 (3.8); 3.9344 (6.3); 3.9306 (13.4); 3.9091 (5.0);3.9046 (4.4); 3.8913 (6.8); 3.8876 (15.4); 3.7886 (2.4); 3.5799 (4.1);3.4260 (3.8); 3.3824 (2.9); 3.3368 (7.5); 3.3305 (15.1); 3.3256 (6.3);3.2936 (6.5); 3.2874 (13.2); 3.2823 (5.6); 3.2404 (1.5); 2.7040 (3.0);2.6933 (2.7); 2.6815 (2.6); 2.6175 (2.1); 2.5964 (3.1); 2.5697 (4.1);2.5607 (3.2); 2.5485 (6.8); 2.5345 (4.8); 2.5271 (4.0); 2.5135 (6.8);2.4922 (3.5); 2.0047 (1.8); 1.9891 (1.9); 1.9588 (3.6); 1.9487 (6.6);1.9388 (3.6); 1.9231 (3.0); 1.9135 (6.1); 1.9031 (3.5); 1.8794 (1.6);1.8669 (1.6); 1.6309 (1.7); 1.3486 (1.4); 1.3304 (2.7); 1.3116 (1.3);0.1460 (3.5); 0.0501 (6.4); 0.0079 (30.9); −0.0002 (897.7); −0.0085(29.5); −0.0495 (1.9); −0.0849 (1.5); −0.1497 (3.2) II-29: ¹H-NMR(400.0MHz, CDCl3): δ = 7.5187 (3.7); 7.3605 (1.4); 7.3499 (0.6); 7.3103 (3.2);7.2599 (652.6); 7.2261 (1.2); 7.2111 (1.2); 7.1957 (1.9); 7.1899 (2.6);7.1833 (8.3); 7.1776 (16.0); 7.1720 (11.6); 7.1678 (9.3); 7.1633 (12.1);7.1610 (11.6); 7.1578 (15.5); 7.1521 (8.2); 7.1456 (2.6); 7.1397 (1.8);6.9958 (3.6); 6.9153 (2.0); 6.9096 (3.9); 6.9059 (4.0); 6.9002 (2.1);6.8936 (4.3); 6.8879 (7.7); 6.8843 (7.8); 6.8785 (3.9); 6.8720 (2.5);6.8663 (3.9); 6.8625 (3.9); 6.8569 (1.7); 6.7382 (2.9); 6.7194 (5.0);6.7019 (3.0); 6.2089 (6.3); 6.1941 (6.4); 6.1821 (7.1); 6.1660 (9.5);6.1509 (7.8); 6.1390 (7.7); 6.1242 (7.8); 5.9475 (8.3); 5.9437 (5.6);5.9417 (5.5); 5.9392 (6.3); 5.9336 (10.2); 5.9298 (6.7); 5.8412 (3.9);5.8355 (7.3); 5.8296 (4.4); 5.8215 (5.7); 5.8159 (3.1); 5.8027 (3.7);5.7969 (6.8); 5.7910 (4.2); 5.7830 (5.6); 5.7772 (3.1); 5.5543 (10.7);5.5528 (10.7); 5.5471 (11.4); 5.5457 (11.2); 5.5111 (9.3); 5.5097 (9.2);5.5039 (9.8); 5.5026 (9.5); 5.3497 (11.0); 5.3473 (11.4); 5.3230 (10.2);5.3206 (10.7); 5.1241 (2.4); 5.1086 (4.1); 5.1031 (4.4); 5.0989 (4.4);5.0942 (4.0); 4.0926 (4.1); 4.0348 (1.6); 4.0201 (4.6); 4.0090 (5.3);3.9957 (5.9); 3.9878 (7.3); 3.9823 (4.8); 3.9716 (7.5); 3.9639 (14.1);3.9558 (4.9); 3.9459 (16.0); 3.9348 (2.0); 3.9278 (2.1); 3.9208 (13.4);3.9028 (13.1); 3.8899 (1.8); 3.8772 (3.1); 3.8650 (3.2); 3.8566 (3.0);3.8434 (4.4); 3.8325 (4.4); 3.7073 (2.0); 3.6934 (4.7); 3.6778 (4.8);3.6612 (3.7); 3.6440 (2.8); 3.6322 (1.3); 3.3306 (13.5); 3.3279 (13.3);3.2874 (11.9); 3.2848 (11.8); 2.6995 (2.8); 2.6861 (2.8); 2.6784 (5.1);2.6650 (8.4); 2.6569 (3.5); 2.6515 (3.6); 2.6436 (8.1); 2.6302 (5.4);2.6222 (3.1); 2.6089 (2.9); 2.0046 (1.0); 1.8846 (5.6); 1.8748 (6.1);1.8631 (6.7); 1.8535 (8.4); 1.8501 (8.3); 1.8395 (13.3); 1.8281 (15.5);1.8167 (11.3); 1.8035 (7.8); 1.7940 (6.0); 1.7819 (4.5); 1.7721 (4.2);1.7611 (3.8); 1.7479 (8.7); 1.7340 (11.2); 1.7225 (9.7); 1.7114 (5.2);1.7004 (3.5); 1.6879 (1.5); 1.5844 (1.1); 1.5413 (1.6); 1.2541 (1.3);0.9018 (0.8); 0.8971 (0.8); 0.8813 (0.8); 0.1462 (1.3); 0.1005 (0.8);0.0503 (1.7); 0.0079 (12.1); −0.0002 (388.3); −0.0085 (15.0); −0.0339(0.9); −0.0491 (0.9); −0.0992 (0.6); −0.1494 (1.3) II-30: ¹H-NMR(400.0MHz, CDCl3): δ = 7.6666 (2.3); 7.6446 (2.3); 7.5963 (2.3); 7.5743 (2.4);7.5192 (2.0); 7.3107 (0.6); 7.2914 (0.7); 7.2604 (343.8); 7.2157 (0.8);7.2101 (1.6); 7.2043 (1.3); 7.1978 (7.4); 7.1921 (9.5); 7.1890 (5.5);7.1797 (11.0); 7.1777 (12.6); 7.1740 (12.6); 7.1721 (11.4); 7.1628(5.4); 7.1597 (9.5); 7.1540 (7.4); 7.1477 (1.3); 7.1419 (1.2); 7.1364(0.5); 6.9963 (2.0); 6.8848 (3.1); 6.8791 (5.5); 6.8733 (3.0); 6.8631(6.2); 6.8573 (10.9); 6.8515 (5.6); 6.8413 (3.2); 6.8356 (5.4); 6.8298(2.7); 6.2128 (5.9); 6.1975 (5.9); 6.1860 (6.6); 6.1702 (10.7); 6.1544(7.0); 6.1429 (7.3); 6.1276 (7.1); 5.9028 (2.5); 5.8997 (2.6); 5.8889(7.2); 5.8859 (7.8); 5.8827 (7.7); 5.8797 (7.0); 5.8751 (4.8); 5.8720(4.5); 5.8689 (4.2); 5.8622 (4.5); 5.8572 (6.9); 5.8520 (4.1); 5.8434(3.6); 5.8382 (2.3); 5.8097 (3.5); 5.8043 (6.1); 5.7987 (3.9); 5.7905(4.5); 5.7852 (2.6); 5.5871 (10.0); 5.5855 (9.8); 5.5475 (10.5); 5.5457(11.8); 5.5441 (10.9); 5.5425 (9.3); 5.5044 (8.6); 5.5028 (8.3); 5.3406(9.5); 5.3393 (8.9); 5.3176 (9.8); 5.3159 (10.7); 5.3141 (10.6); 5.2985(0.8); 5.2909 (8.6); 5.2894 (8.2); 5.0296 (4.0); 5.0109 (4.1); 4.9894(1.5); 4.0486 (2.1); 4.0225 (5.5); 4.0178 (6.1); 4.0089 (6.7); 4.0013(5.9); 3.9916 (5.2); 3.9813 (6.7); 3.9694 (8.4); 3.9605 (6.8); 3.9486(8.0); 3.9299 (16.0); 3.9274 (15.6); 3.9156 (4.8); 3.9022 (4.3); 3.8871(15.6); 3.8845 (14.8); 3.7150 (1.8); 3.7031 (2.8); 3.6964 (3.5); 3.6854(3.1); 3.6634 (2.8); 3.6553 (2.2); 3.3131 (11.6); 3.3053 (11.8); 3.2703(10.1); 3.2624 (10.4); 2.4455 (2.5); 2.4249 (4.8); 2.4112 (3.4); 2.4048(4.2); 2.3906 (5.8); 2.3853 (5.2); 2.3710 (4.8); 2.3648 (3.1); 2.3510(5.5); 2.3305 (2.7); 2.2067 (0.7); 2.0050 (0.7); 1.9770 (2.7); 1.9694(4.7); 1.9616 (2.7); 1.9421 (4.4); 1.9345 (8.0); 1.9268 (4.6); 1.9074(2.6); 1.8997 (4.6); 1.8920 (3.3); 1.8683 (3.3); 1.8578 (4.6); 1.8497(6.2); 1.8375 (7.3); 1.8258 (6.4); 1.8146 (4.0); 1.8011 (2.5); 1.7884(2.2); 1.7766 (3.7); 1.7636 (6.9); 1.7505 (8.9); 1.7399 (8.8); 1.7294(6.0); 1.7109 (2.8); 1.6985 (1.2); 1.2556 (1.3); 0.8901 (0.7); 0.8767(0.9); 0.8612 (0.7); 0.1460 (0.8); 0.0079 (7.0); −0.0002 (201.5);−0.0084 (7.7); −0.1495 (0.7) II-31: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.9871(0.8); 7.5185 (0.8); 7.2596 (134.0); 7.2152 (1.8); 7.2096 (2.4); 7.2054(1.4); 7.1957 (3.2); 7.1919 (3.0); 7.1901 (2.8); 7.1810 (1.6); 7.1781(2.3); 7.1724 (1.8); 6.9956 (0.8); 6.9380 (0.6); 6.9339 (1.0); 6.9281(0.6); 6.9163 (1.2); 6.9122 (1.8); 6.9105 (1.8); 6.9064 (1.0); 6.8947(0.6); 6.8906 (0.9); 5.9428 (0.6); 5.9387 (0.6); 5.9290 (1.1); 5.9248(1.6); 5.9086 (1.0); 5.9042 (1.7); 5.8993 (1.6); 5.8939 (0.9); 5.8856(0.7); 5.8802 (0.5); 5.8422 (0.8); 5.8371 (1.2); 5.8317 (0.8); 5.8233(0.9); 5.8181 (0.6); 5.2982 (4.1); 5.0733 (0.7); 5.0591 (0.6); 5.0387(0.8); 4.0583 (0.6); 4.0430 (1.0); 4.0296 (1.8); 4.0192 (2.3); 4.0132(2.0); 4.0009 (2.5); 3.9945 (2.0); 3.9911 (2.3); 3.9813 (3.2); 3.9574(0.9); 3.9364 (3.0); 3.8919 (0.6); 3.7561 (0.7); 3.7352 (3.1); 3.7212(3.3); 3.7107 (1.0); 3.6903 (2.9); 3.6762 (2.9); 3.6611 (0.7); 2.4027(1.0); 2.3885 (0.6); 2.3823 (0.6); 2.3682 (1.1); 2.3480 (0.6); 2.3305(1.0); 2.3163 (0.7); 2.3102 (0.6); 2.2960 (1.2); 2.2757 (0.6); 2.0261(1.1); 2.0209 (0.6); 2.0014 (1.1); 1.9963 (1.1); 1.9914 (1.0); 1.9669(0.8); 1.9614 (0.5); 1.8777 (0.7); 1.8527 (1.3); 1.8423 (1.6); 1.8323(1.6); 1.8206 (1.1); 1.8088 (0.7); 1.7962 (0.6); 1.7809 (0.8); 1.7675(1.8); 1.7541 (2.2); 1.7404 (1.7); 1.7314 (1.3); 1.5465 (16.0); 1.2584(0.7); 0.8819 (0.6); 0.0080 (2.6); −0.0002 (77.7); −0.0085 (2.7) II-32:¹H-NMR(400.0 MHz, CDCl3): δ = 7.9588 (1.6); 7.9382 (1.0); 7.5190 (0.9);7.2601 (154.0); 7.2288 (0.6); 7.2162 (3.3); 7.2105 (4.3); 7.2071 (2.4);7.1987 (4.8); 7.1965 (5.6); 7.1931 (5.4); 7.1910 (5.0); 7.1823 (2.5);7.1791 (4.1); 7.1735 (3.2); 7.1667 (0.5); 7.1609 (0.5); 6.9960 (0.9);6.9405 (1.0); 6.9385 (1.1); 6.9348 (1.7); 6.9328 (1.7); 6.9290 (1.0);6.9189 (2.0); 6.9169 (2.1); 6.9131 (3.4); 6.9111 (3.3); 6.9074 (1.9);6.9054 (1.7); 6.8973 (1.0); 6.8952 (1.1); 6.8915 (1.7); 6.8895 (1.6);6.8858 (0.9); 5.9552 (1.1); 5.9486 (1.1); 5.9394 (2.1); 5.9337 (3.1);5.9201 (1.7); 5.9133 (3.2); 5.9080 (2.7); 5.9027 (1.7); 5.8943 (1.4);5.8891 (1.0); 5.8490 (1.4); 5.8439 (2.2); 5.8383 (1.6); 5.8301 (1.6);5.8247 (1.0); 5.2984 (6.4); 5.0944 (0.7); 5.0743 (1.4); 5.0546 (1.2);5.0382 (1.4); 5.0180 (0.7); 4.0615 (0.7); 4.0419 (3.7); 4.0359 (2.3);4.0254 (7.5); 4.0188 (4.6); 4.0087 (6.8); 4.0016 (3.5); 3.9863 (5.5);3.9724 (2.0); 3.9416 (5.1); 3.8390 (0.8); 3.8204 (1.1); 3.8119 (1.4);3.8017 (1.0); 3.7930 (2.8); 3.7867 (0.8); 3.7752 (2.2); 3.7573 (3.6);3.7515 (1.6); 3.7387 (3.9); 3.7340 (7.7); 3.7206 (7.3); 3.7137 (2.0);3.6891 (4.4); 3.6757 (4.2); 2.4277 (1.0); 2.4072 (1.9); 2.3927 (2.4);2.3869 (1.9); 2.3834 (1.2); 2.3730 (4.6); 2.3666 (2.9); 2.3570 (5.3);2.3496 (4.5); 2.3461 (2.4); 2.3376 (4.9); 2.3326 (3.1); 2.3290 (2.1);2.3221 (2.2); 2.3164 (1.8); 2.3023 (2.4); 2.2821 (1.1); 2.0426 (1.4);2.0362 (2.0); 2.0307 (1.2); 2.0224 (1.2); 2.0169 (2.1); 2.0113 (1.4);2.0070 (1.1); 2.0015 (1.7); 1.9961 (1.0); 1.9879 (1.0); 1.9823 (1.7);1.9771 (1.0); 1.5632 (16.0); 1.2845 (0.6); 1.2583 (1.3); 0.8818 (0.8);0.0080 (2.8); −0.0002 (91.2); −0.0085 (3.2) II-33: ¹H-NMR(400.0 MHz,CDCl3): δ = 7.5185 (0.9); 7.4005 (0.5); 7.3769 (0.5); 7.2596 (167.8);7.2007 (2.6); 7.1906 (2.5); 7.1856 (2.6); 6.9956 (1.2); 6.9574 (0.8);6.9515 (1.0); 6.9409 (0.9); 6.9368 (1.0); 6.9303 (0.8); 5.9650 (2.2);5.9409 (1.0); 4.5183 (1.2); 4.1066 (0.9); 4.0005 (0.8); 3.9905 (0.9);3.9554 (1.2); 3.9453 (1.2); 3.9355 (0.7); 3.7755 (0.8); 3.7672 (1.2);3.7579 (1.4); 3.7478 (1.3); 3.7309 (0.6); 3.7221 (0.8); 3.7128 (1.0);3.7027 (0.9); 3.5481 (0.6); 3.5072 (0.5); 3.4930 (1.0); 3.4867 (0.9);3.4678 (1.6); 3.4559 (1.4); 3.4489 (1.8); 3.4355 (1.6); 3.4310 (1.6);3.4243 (1.2); 3.4108 (1.7); 3.3970 (1.0); 3.3781 (0.5); 3.3707 (0.6);3.1249 (3.5); 3.1112 (2.2); 3.1052 (3.5); 3.0988 (2.1); 3.0856 (3.8);2.6306 (0.5); 2.6036 (0.6); 2.0460 (0.6); 2.0096 (0.5); 1.9419 (3.8);1.9284 (2.5); 1.9228 (4.8); 1.9165 (2.9); 1.9101 (3.2); 1.9031 (4.2);1.8841 (2.7); 1.8762 (1.3); 1.8655 (1.3); 1.8568 (1.4); 1.8374 (1.1);1.8194 (0.7); 1.7260 (1.4); 1.7175 (2.0); 1.7068 (1.7); 1.6931 (1.8);1.6828 (2.3); 1.6738 (1.7); 1.6152 (1.2); 1.5835 (1.5); 1.5473 (16.0);1.4023 (0.6); 1.3934 (0.9); 1.3726 (1.4); 1.3641 (2.3); 1.3324 (2.2);1.3091 (1.0); 1.3010 (1.4); 1.2925 (1.0); 1.2577 (3.0); 1.2096 (0.8);1.2009 (1.0); 1.1925 (0.7); 1.1716 (1.5); 1.1559 (1.3); 1.1473 (1.6);1.1253 (2.4); 1.1077 (7.3); 1.0972 (4.4); 1.0891 (14.7); 1.0788 (4.6);1.0703 (7.4); 1.0602 (2.7); 1.0491 (1.7); 1.0346 (0.6); 0.8799 (1.0);0.1456 (0.6); 0.0080 (4.4); −0.0002 (125.5); −0.0085 (5.1) II-34:¹H-NMR(400.0 MHz, CDCl3): δ = 7.5189 (0.7); 7.2600 (94.7); 7.2093 (1.5);7.1962 (2.4); 7.1832 (1.9); 6.9959 (0.6); 6.9475 (0.8); 6.9399 (0.7);6.9338 (0.9); 6.9299 (0.9); 6.9182 (0.5); 5.9697 (1.0); 5.9183 (2.0);5.8964 (0.7); 5.2984 (0.5); 3.9522 (1.0); 3.9235 (0.7); 3.9050 (0.9);3.7625 (1.4); 3.7556 (1.3); 3.7470 (1.1); 3.7370 (0.6); 3.7321 (0.5);3.7172 (1.0); 3.7106 (0.9); 3.7019 (0.7); 3.3862 (0.5); 3.1389 (0.8);3.1203 (2.6); 3.1091 (2.8); 3.1022 (2.8); 3.0908 (2.6); 3.0727 (1.0);2.9561 (2.3); 2.8831 (1.9); 2.5466 (0.5); 1.9957 (0.6); 1.9851 (0.7);1.9750 (0.6); 1.9592 (0.6); 1.9490 (0.8); 1.9397 (0.6); 1.7717 (4.5);1.7552 (0.8); 1.7433 (4.0); 1.7262 (4.0); 1.7075 (5.1); 1.7046 (5.6);1.6981 (7.3); 1.5520 (3.7); 1.4316 (8.8); 1.4132 (16.0); 1.3948 (7.4);1.2548 (0.6); 0.0080 (3.7); −0.0002 (120.0); −0.0085 (4.5) II-35:¹H-NMR(400.0 MHz, CDCl3): δ = 7.2603 (69.8); 7.2197 (0.7); 7.1951 (2.4);7.1865 (1.7); 7.1822 (1.9); 6.9548 (0.7); 6.9489 (1.0); 6.9343 (0.8);6.9298 (1.0); 6.9186 (0.5); 5.9954 (1.0); 5.9521 (0.7); 5.9448 (0.8);5.9261 (1.4); 5.9092 (0.7); 5.8917 (0.7); 5.2987 (3.3); 4.8485 (0.5);4.0009 (0.6); 3.9767 (0.9); 3.9558 (0.8); 3.9306 (0.8); 3.9263 (0.5);3.7658 (1.3); 3.7549 (0.9); 3.7465 (0.9); 3.7384 (1.2); 3.7206 (1.0);3.7098 (0.7); 3.7014 (0.6); 3.6934 (1.1); 3.6562 (0.8); 3.4420 (1.7);3.4227 (1.2); 3.1428 (0.7); 3.1246 (1.9); 3.1133 (1.9); 3.1062 (2.0);3.0950 (2.0); 3.0784 (0.9); 3.0535 (1.2); 3.0030 (0.9); 2.9955 (1.1);2.9581 (2.9); 2.9420 (0.6); 2.8846 (2.3); 2.0637 (0.9); 2.0471 (1.4);2.0413 (1.0); 2.0303 (1.7); 2.0241 (1.3); 2.0148 (1.8); 2.0101 (1.4);1.9980 (1.1); 1.9933 (0.8); 1.9809 (0.7); 1.4320 (1.4); 1.4240 (5.3);1.4057 (11.0); 1.3873 (5.3); 1.2557 (0.8); 1.1413 (8.1); 1.1308 (9.3);1.1245 (8.7); 1.1129 (16.0); 1.1076 (13.5); 1.0955 (13.0); 1.0909(13.1); 1.0804 (4.3); 1.0775 (4.5); 1.0718 (2.9); 1.0684 (2.3); 1.0634(3.2); 1.0606 (4.0); 1.0549 (2.4); 1.0514 (1.9); 1.0469 (1.5); 1.0437(1.5); 0.0978 (2.4); 0.0690 (1.4); 0.0648 (0.7); 0.0080 (2.1); −0.0002(90.0); −0.0085 (3.9) II-36: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.2597(60.0); 7.1944 (1.4); 7.1836 (1.1); 7.1804 (1.2); 7.1749 (1.1); 5.9553(0.7); 5.9470 (0.5); 5.2984 (13.2); 3.9288 (0.6); 3.9249 (0.7); 3.7660(13.5); 3.7493 (5.3); 3.7456 (4.2); 3.7369 (3.4); 3.7334 (1.1); 3.7249(0.8); 3.7116 (0.5); 3.6883 (0.5); 3.1050 (0.8); 3.0919 (0.8); 2.9553(0.7); 2.8840 (0.5); 1.6105 (1.2); 1.5977 (16.0); 1.5902 (5.8); 1.5697(3.3); 1.5549 (4.8); 1.5520 (4.4); 1.5482 (4.8); 1.5410 (8.9); 1.4346(2.8); 1.4163 (5.4); 1.3979 (2.6); 0.0079 (2.6); −0.0002 (76.9); −0.0085(2.6) II-37: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.2612 (34.4); 7.2101 (0.7);7.2041 (1.4); 7.1963 (1.8); 7.1906 (1.6); 7.1850 (1.8); 7.1800 (1.4);7.1773 (1.3); 7.1714 (0.6); 6.9448 (0.6); 6.9387 (0.6); 6.9220 (0.7);6.9161 (0.9); 5.9626 (1.6); 5.9532 (0.7); 5.9488 (0.6); 5.9387 (0.6);5.9351 (0.6); 5.9076 (1.3); 5.2988 (3.8); 4.6423 (0.5); 4.6306 (0.8);4.6188 (0.6); 4.5688 (0.6); 4.5114 (1.0); 4.5074 (1.0); 4.4986 (1.0);4.4946 (1.0); 4.4880 (1.0); 4.4841 (1.0); 4.4752 (1.0); 4.4712 (1.0);3.9574 (0.6); 3.9388 (0.6); 3.9266 (0.5); 3.9217 (0.7); 3.7660 (7.6);3.7644 (15.3); 3.7573 (16.0); 3.7542 (6.9); 3.7477 (3.7); 3.7458 (8.0);3.7389 (4.4); 3.7295 (1.1); 3.7270 (1.1); 3.7224 (1.2); 3.7151 (0.6);3.6911 (0.7); 3.6846 (0.8); 3.6820 (0.8); 3.6776 (0.7); 3.4105 (0.6);3.3902 (0.7); 3.1272 (0.6); 3.1090 (1.9); 3.0906 (1.9); 3.0722 (0.7);2.9559 (2.5); 2.8845 (2.0); 2.8831 (2.1); 2.2519 (0.6); 2.2457 (0.6);2.2393 (0.6); 2.2331 (0.7); 2.2285 (0.5); 2.2221 (0.6); 2.2158 (0.6);2.1925 (0.5); 2.1755 (0.6); 2.1582 (0.5); 1.5762 (0.7); 1.4333 (3.8);1.4151 (7.5); 1.3967 (3.5); 0.9857 (4.8); 0.9755 (5.8); 0.9683 (6.3);0.9664 (6.6); 0.9580 (7.5); 0.9565 (8.4); 0.9490 (5.6); 0.9429 (3.4);0.9391 (6.2); 0.9328 (4.8); 0.9261 (3.3); 0.9159 (7.0); 0.9090 (2.2);0.9049 (2.6); 0.8992 (3.8); 0.8945 (2.0); 0.8877 (2.2); 0.8773 (1.4);0.0079 (1.2); −0.0002 (43.6); −0.0085 (1.7) II-38: ¹H-NMR(400.0 MHz,CDCl3): δ = 7.2595 (87.1); 7.1926 (1.2); 7.1819 (1.1); 7.1740 (0.8);6.9955 (0.5); 6.9457 (0.5); 6.9245 (0.6); 5.9609 (0.9); 5.9017 (1.2);5.2982 (16.0); 3.7589 (0.8); 3.7417 (0.7); 3.7339 (0.7); 3.7138 (0.7);3.6968 (0.5); 1.9468 (0.7); 1.9249 (0.9); 1.7145 (0.7); 1.7042 (0.6);1.6808 (0.8); 1.6708 (0.6); 1.6131 (2.5); 1.5833 (4.5); 1.5731 (2.0);1.5418 (5.9); 1.3771 (0.6); 1.3685 (0.8); 1.3352 (0.8); 1.3054 (0.6);1.2587 (2.4); 1.1672 (0.5); 1.1444 (0.6); 1.1359 (0.7); 1.1072 (0.8);1.0795 (0.6); 0.8804 (0.8); 0.0079 (1.9); −0.0002 (62.8); −0.0085 (2.3)II-40: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.7425 (2.3); 7.7396 (2.7); 7.7366(1.5); 7.6488 (0.8); 7.6449 (1.1); 7.6427 (1.0); 7.6391 (0.8); 7.6271(0.8); 7.6231 (1.1); 7.6210 (0.9); 7.6173 (0.8); 7.4992 (0.6); 7.4964(1.0); 7.4933 (1.1); 7.4903 (1.0); 7.4873 (0.7); 7.4802 (0.6); 7.4775(1.1); 7.4743 (1.2); 7.4713 (1.0); 7.4683 (0.7); 7.2619 (27.7); 6.7355(0.6); 5.9963 (0.5); 5.9919 (0.7); 5.9908 (0.7); 5.9865 (0.6); 5.9823(0.8); 5.9781 (1.0); 5.9769 (1.0); 5.9726 (0.8); 5.9634 (3.5); 5.9094(0.7); 5.9039 (1.3); 5.8983 (0.7); 5.8956 (0.6); 5.8899 (1.0); 5.8844(0.5); 5.4066 (0.9); 5.3907 (0.6); 5.2991 (1.6); 5.1520 (0.5); 5.1420(0.5); 5.1374 (0.6); 5.1318 (0.6); 4.0485 (1.1); 4.0032 (1.5); 3.7811(3.3); 3.7358 (2.5); 3.5919 (0.6); 3.5862 (0.6); 3.5825 (0.6); 3.5769(0.7); 3.5702 (0.7); 3.5645 (0.6); 2.6340 (0.5); 2.6216 (0.6); 2.6194(0.7); 2.6069 (0.6); 2.5989 (0.6); 2.5865 (0.6); 2.0055 (16.0); 1.9990(0.9); 1.9875 (0.6); 1.9770 (0.6); 1.9741 (0.6); 1.9415 (0.6); 1.5828(7.5); 1.5727 (7.8); −0.0002 (15.8); −0.0085 (0.7) II-41: ¹H-NMR(400.0MHz, CDCl3): δ = 7.7407 (1.2); 7.7374 (2.3); 7.7334 (2.0); 7.7290 (2.1);7.7256 (1.2); 7.6722 (0.6); 7.6684 (0.7); 7.6659 (0.8); 7.6640 (0.8);7.6623 (0.8); 7.6604 (0.7); 7.6579 (0.7); 7.6541 (0.6); 7.6502 (0.7);7.6464 (0.7); 7.6439 (0.8); 7.6420 (0.8); 7.6403 (0.8); 7.6384 (0.7);7.6359 (0.6); 7.6321 (0.5); 7.4773 (0.8); 7.4743 (1.0); 7.4715 (1.1);7.4685 (0.9); 7.4659 (0.6); 7.4583 (0.8); 7.4553 (1.0); 7.4526 (1.1);7.4494 (0.9); 7.4469 (0.6); 7.2628 (15.9); 5.9653 (0.5); 5.9567 (0.6);5.9516 (1.0); 5.9467 (0.7); 5.9293 (0.7); 5.9267 (0.8); 5.9233 (0.8);5.9205 (0.8); 5.9128 (0.5); 5.9058 (3.5); 5.9034 (3.2); 5.6381 (1.1);5.2995 (16.0); 4.0136 (1.0); 4.0109 (0.9); 3.9685 (1.4); 3.9659 (1.3);3.7672 (2.0); 3.7580 (1.7); 3.7221 (1.5); 3.7128 (1.3); 3.3100 (0.8);3.3052 (0.8); 3.2894 (0.8); 2.4646 (0.6); 2.4297 (0.7); 2.4059 (0.8);2.3710 (0.8); 2.1701 (0.6); 1.9317 (0.9); 1.9246 (0.9); 1.8968 (0.8);1.8897 (0.8); 1.6175 (5.1); 1.6139 (5.2); 1.5878 (5.4); 1.5809 (5.5);−0.0002 (9.1) II-42: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.5941 (2.1); 7.5730(2.1); 7.2603 (74.4); 7.2459 (0.7); 7.2400 (1.2); 7.2341 (1.0); 7.2273(6.2); 7.2216 (7.6); 7.2185 (4.6); 7.2110 (4.7); 7.2079 (7.6); 7.2022(6.3); 7.1953 (1.1); 7.1894 (1.2); 7.1836 (0.6); 6.9586 (1.6); 6.9528(2.8); 6.9470 (1.5); 6.9369 (3.2); 6.9312 (5.5); 6.9254 (2.8); 6.9153(1.8); 6.9095 (3.0); 6.9036 (4.9); 6.8972 (3.9); 6.8898 (4.2); 6.8850(4.1); 6.6724 (2.8); 6.6687 (3.0); 6.6643 (3.1); 6.6601 (4.3); 6.6555(2.8); 6.6511 (2.6); 6.6474 (2.4); 5.9795 (2.5); 5.9727 (2.7); 5.9657(3.8); 5.9609 (3.8); 5.9160 (3.3); 5.9105 (5.4); 5.9048 (3.5); 5.8968(3.7); 5.8913 (2.2); 5.2985 (16.0); 5.2861 (1.0); 5.0450 (1.5); 5.0247(2.9); 5.0046 (1.5); 4.5206 (1.2); 4.5149 (3.0); 4.5091 (3.0); 4.5017(1.9); 4.4947 (3.0); 4.4889 (2.9); 4.4833 (1.2); 4.0017 (4.7); 3.9567(6.7); 3.7501 (11.3); 3.7051 (8.2); 3.4874 (3.4); 3.4832 (4.6); 3.4814(5.0); 3.4795 (4.6); 3.4753 (3.4); 2.3485 (3.8); 2.3455 (3.8); 2.3411(2.3); 2.3278 (7.0); 2.3233 (5.9); 2.3192 (3.6); 2.3134 (3.1); 2.3076(2.4); 2.2930 (4.7); 2.2726 (2.3); 2.2592 (3.8); 2.2556 (6.5); 2.2520(3.9); 2.2372 (2.4); 2.2335 (4.1); 2.2300 (2.4); 2.0052 (2.5); 1.9996(4.3); 1.9941 (2.5); 1.9702 (2.0); 1.9647 (3.5); 1.9591 (2.1); 0.0079(2.1); −0.0002 (62.8); −0.0085 (2.3) II-43: ¹H-NMR(400.0 MHz, CDCl3): δ= 7.4903 (0.7); 7.4824 (0.8); 7.4721 (0.8); 7.4638 (0.7); 7.2611 (54.2);7.1986 (1.6); 7.1928 (1.8); 7.1896 (1.5); 7.1854 (2.3); 7.1822 (2.5);7.1794 (3.6); 7.1735 (2.1); 7.1696 (1.8); 7.1660 (2.4); 7.1603 (1.8);6.9359 (0.6); 6.9304 (0.9); 6.9250 (0.8); 6.9195 (0.6); 6.9143 (1.1);6.9088 (1.8); 6.9034 (1.6); 6.8978 (0.8); 6.8927 (0.6); 6.8872 (0.9);6.8818 (0.8); 6.0096 (1.8); 6.0013 (1.0); 5.9970 (1.3); 5.9922 (1.6);5.9874 (1.4); 5.9825 (1.3); 5.9776 (0.8); 5.9581 (1.0); 5.9529 (1.8);5.9504 (1.3); 5.9449 (1.9); 5.9392 (1.6); 5.9337 (0.8); 5.9311 (1.0);5.9256 (0.5); 5.2990 (7.0); 4.8212 (0.7); 4.8165 (0.7); 4.8091 (0.7);4.8037 (0.7); 4.4992 (1.5); 4.4671 (1.7); 4.4609 (2.8); 4.4295 (3.0);4.4156 (1.9); 4.4056 (1.2); 4.4014 (1.1); 4.3862 (2.9); 4.3594 (3.0);4.3479 (1.6); 4.3218 (1.6); 4.0736 (1.9); 4.0649 (2.0); 4.0437 (2.9);4.0348 (2.8); 4.0140 (0.7); 3.9266 (2.6); 3.9160 (0.9); 3.9114 (2.4);3.8965 (1.8); 3.8861 (0.6); 3.8814 (1.7); 3.8051 (4.9); 3.8005 (2.4);3.7963 (4.9); 3.7797 (16.0); 3.7559 (2.5); 3.7374 (15.5); 3.7325 (2.2);3.7083 (1.2); 3.6880 (2.3); 3.6128 (0.6); 3.6074 (0.7); 3.6010 (0.8);3.5958 (0.9); 3.5904 (0.9); 3.5846 (0.7); 3.5783 (0.7); 3.5445 (0.7);3.5395 (2.2); 3.5204 (0.6); 3.5116 (2.0); 3.5002 (0.5); 3.4950 (1.4);3.4669 (1.5); 2.7727 (0.8); 2.7596 (0.6); 2.7495 (0.6); 2.7439 (0.8);2.7363 (0.9); 2.7307 (0.7); 2.7208 (0.6); 2.7131 (0.6); 2.7075 (0.9);2.6843 (0.5); 2.1611 (0.8); 2.1245 (0.8); 2.1203 (0.7); 2.1123 (0.6);2.1080 (0.8); 2.0715 (0.7); 1.2556 (0.5); 0.0079 (1.0); −0.0002 (30.6);−0.0085 (1.0) II-44: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.9734 (5.0); 7.8730(2.4); 7.8707 (2.7); 7.8662 (1.8); 7.8532 (2.6); 7.8509 (3.0); 7.8464(1.8); 7.7827 (2.6); 7.7792 (2.8); 7.7763 (1.5); 7.7632 (3.2); 7.7597(3.4); 7.7568 (1.8); 7.6099 (2.3); 7.5901 (3.8); 7.5705 (1.7); 7.5181(0.6); 7.2593 (103.2); 6.9953 (0.5); 6.7782 (0.9); 6.7569 (1.4); 6.7342(0.7); 5.9912 (1.1); 5.9859 (1.4); 5.9815 (1.4); 5.9773 (1.6); 5.9722(2.2); 5.9674 (3.6); 5.9641 (8.0); 5.9131 (1.4); 5.9075 (2.6); 5.9020(1.6); 5.8937 (2.0); 5.8881 (1.1); 5.3761 (1.9); 5.1679 (0.8); 5.1568(1.1); 5.1473 (1.1); 5.1415 (1.1); 5.1369 (1.2); 5.1317 (1.1); 5.1270(0.9); 5.1211 (0.6); 5.1169 (0.5); 4.0547 (2.4); 4.0094 (3.3); 3.8011(7.2); 3.7559 (5.4); 3.6006 (0.8); 3.5948 (0.9); 3.5882 (1.2); 3.5826(1.3); 3.5790 (1.6); 3.5732 (1.5); 3.5668 (1.6); 3.5607 (1.2); 3.5575(0.9); 3.5458 (0.7); 2.6516 (0.9); 2.6392 (0.9); 2.6312 (1.0); 2.6188(1.7); 2.6078 (0.8); 2.6039 (1.2); 2.5959 (1.2); 2.5838 (1.7); 2.5726(0.7); 2.5634 (0.8); 2.5518 (0.7); 2.0120 (1.0); 2.0018 (1.0); 1.9903(1.0); 1.9798 (1.2); 1.9770 (1.1); 1.9666 (0.9); 1.9551 (0.9); 1.9445(1.4); 1.9328 (0.7); 1.9222 (0.7); 1.9092 (0.9); 1.8976 (0.7); 1.8870(0.6); 1.8757 (0.6); 1.6283 (0.5); 1.5834 (16.0); 1.5719 (15.7); 1.5388(1.1); 1.2574 (0.8); 1.2397 (0.9); 1.2275 (0.8); 1.1291 (0.7); 1.1071(0.6); 0.0080 (4.0); −0.0002 (124.2); −0.0084 (4.5) II-45: ¹H-NMR(400.0MHz, CDCl3): δ = 7.9710 (1.9); 7.9670 (3.2); 7.9628 (3.0); 7.9587 (2.8);7.9547 (1.8); 7.8978 (1.3); 7.8949 (1.7); 7.8935 (1.6); 7.8909 (2.0);7.8884 (1.7); 7.8840 (1.2); 7.8780 (1.6); 7.8750 (1.9); 7.8736 (1.9);7.8710 (2.3); 7.8686 (1.8); 7.8642 (1.3); 7.7642 (1.7); 7.7599 (2.7);7.7447 (2.2); 7.7407 (3.3); 7.7364 (1.9); 7.6984 (0.7); 7.6770 (0.7);7.5920 (3.2); 7.5723 (5.0); 7.5526 (2.2); 7.2597 (53.0); 5.9692 (0.7);5.9640 (1.1); 5.9589 (0.7); 5.9554 (1.2); 5.9503 (1.9); 5.9453 (1.3);5.9247 (1.3); 5.9219 (1.4); 5.9189 (1.6); 5.9011 (6.6); 5.6102 (1.9);5.0443 (0.8); 5.0380 (0.8); 5.0181 (0.8); 4.9977 (0.9); 4.0248 (1.7);4.0204 (1.6); 3.9798 (2.4); 3.9757 (2.2); 3.7858 (4.0); 3.7771 (3.5);3.7408 (2.8); 3.7321 (2.5); 3.3042 (1.4); 3.2831 (1.6); 2.5012 (0.6);2.4805 (1.2); 2.4663 (0.8); 2.4597 (0.7); 2.4456 (1.9); 2.4248 (2.0);2.4106 (0.9); 2.4040 (0.8); 2.3898 (1.5); 2.3691 (0.7); 1.9367 (0.7);1.9303 (1.7); 1.9238 (1.9); 1.9169 (0.8); 1.9018 (0.6); 1.8953 (1.5);1.8889 (1.6); 1.8821 (0.7); 1.6171 (10.7); 1.6146 (10.8); 1.5830 (16.0);0.0080 (2.0); −0.0002 (67.4); −0.0085 (2.3) II-46: ¹H-NMR(400.0 MHz,CDCl3): δ = 7.9420 (2.1); 7.9380 (2.1); 7.8514 (0.7); 7.8487 (1.1);7.8468 (1.2); 7.8446 (1.0); 7.8423 (0.7); 7.8315 (0.8); 7.8288 (1.2);7.8270 (1.3); 7.8248 (1.1); 7.8224 (0.7); 7.7281 (0.6); 7.7247 (1.3);7.7213 (1.3); 7.7180 (0.6); 7.7087 (0.8); 7.7052 (1.6); 7.7019 (1.5);7.6986 (0.7); 7.5680 (0.9); 7.5667 (1.0); 7.5642 (0.9); 7.5471 (1.6);7.5445 (1.5); 7.5287 (0.6); 7.5274 (0.7); 7.5249 (0.6); 7.2620 (12.6);6.7675 (0.7); 6.7470 (0.7); 5.9683 (0.6); 5.9594 (0.7); 5.9543 (1.3);5.9495 (0.8); 5.9379 (0.8); 5.9339 (1.0); 5.9289 (1.0); 5.9240 (0.7);5.9201 (0.7); 5.9151 (1.0); 5.9102 (0.8); 5.9063 (0.7); 5.8947 (0.6);5.8899 (1.1); 5.8847 (0.6); 5.8760 (0.5); 5.3830 (0.6); 5.3638 (0.6);5.2992 (1.6); 5.0901 (0.5); 5.0850 (0.5); 3.8578 (1.6); 3.8530 (1.4);3.8145 (1.8); 3.8097 (1.6); 3.5542 (0.6); 3.5485 (0.6); 3.2396 (1.8);3.2366 (1.8); 3.1962 (1.6); 3.1932 (1.6); 2.5600 (0.5); 2.5393 (0.5);2.5271 (0.5); 2.5248 (0.6); 1.8574 (0.5); 1.7291 (16.0); 1.7209 (1.5);1.5788 (8.0); 1.5770 (8.1); 1.5623 (8.6); 1.3049 (0.5); 1.2847 (0.6);−0.0002 (16.2); −0.0085 (0.6) II-47: ¹H-NMR(400.0 MHz, CDCl3): δ =7.9338 (1.4); 7.9297 (3.2); 7.9254 (3.4); 7.9213 (1.6); 7.8750 (1.0);7.8719 (1.2); 7.8680 (1.6); 7.8653 (1.4); 7.8610 (1.0); 7.8551 (1.1);7.8509 (1.4); 7.8482 (1.9); 7.8454 (1.5); 7.8412 (1.0); 7.7081 (1.7);7.7048 (2.4); 7.7013 (1.7); 7.6887 (2.2); 7.6852 (3.0); 7.6819 (1.9);7.5487 (2.5); 7.5291 (4.0); 7.5094 (1.7); 7.3762 (0.6); 7.3639 (0.8);7.3440 (0.7); 7.2618 (18.6); 5.9352 (0.6); 5.9300 (0.9); 5.9248 (0.6);5.9215 (0.9); 5.9162 (1.6); 5.9111 (1.0); 5.8870 (1.0); 5.8831 (1.1);5.8775 (1.0); 5.8733 (0.8); 5.8695 (0.8); 5.8561 (5.6); 5.8509 (1.5);5.7297 (0.8); 5.7031 (0.9); 5.2991 (2.1); 4.9427 (0.9); 4.9334 (0.9);4.9215 (0.8); 4.9184 (0.7); 4.9127 (0.7); 3.8297 (3.0); 3.8272 (2.7);3.7866 (3.4); 3.7841 (3.1); 3.3205 (0.5); 3.3102 (0.7); 3.3073 (0.7);3.2988 (1.0); 3.2887 (1.1); 3.2753 (0.5); 3.2720 (0.5); 3.2228 (2.5);3.2129 (2.8); 3.1796 (2.2); 3.1697 (2.4); 2.5579 (0.6); 2.5366 (1.1);2.5231 (0.8); 2.5158 (0.8); 2.5020 (1.3); 2.4960 (1.1); 2.4821 (0.9);2.4747 (0.6); 2.4613 (1.1); 2.4400 (0.5); 1.9068 (0.6); 1.8969 (1.0);1.8871 (0.6); 1.8722 (0.5); 1.8623 (1.0); 1.8525 (0.5); 1.8376 (0.5);1.8276 (1.0); 1.8176 (0.5); 1.7930 (0.9); 1.7830 (0.5); 1.7269 (14.7);1.7153 (13.4); 1.6140 (15.8); 1.6121 (16.0); 1.5916 (7.0); 1.5707 (6.8);0.0079 (0.7); −0.0002 (23.8); −0.0085 (0.9) II-48: ¹H-NMR(400.0 MHz,CDCl3): δ = 7.5674 (0.6); 7.5434 (1.0); 7.5200 (0.9); 7.2612 (45.9);7.1974 (0.6); 7.1922 (2.1); 7.1851 (2.9); 7.1821 (2.4); 7.1791 (2.6);7.1758 (2.4); 7.1725 (2.7); 7.1697 (2.4); 7.1666 (2.9); 7.1655 (2.8);7.1595 (2.0); 7.1544 (0.6); 6.9151 (0.9); 6.9093 (1.6); 6.9035 (0.8);6.8934 (1.8); 6.8876 (3.1); 6.8818 (1.6); 6.8717 (0.9); 6.8658 (1.6);6.8600 (0.8); 5.9417 (0.6); 5.9366 (1.0); 5.9315 (0.6); 5.9279 (1.1);5.9227 (1.9); 5.9178 (1.3); 5.9003 (1.2); 5.8949 (1.6); 5.8913 (1.3);5.8864 (0.8); 5.8774 (7.0); 5.8733 (1.8); 5.6760 (1.1); 5.6592 (1.1);5.2988 (2.3); 4.9670 (1.0); 4.9596 (1.0); 4.9453 (0.9); 4.9419 (0.9);4.9389 (1.0); 4.0257 (2.0); 4.0116 (2.0); 3.9957 (4.1); 3.9816 (4.7);3.9474 (6.1); 3.9176 (2.5); 3.6992 (2.2); 3.6931 (2.0); 3.6553 (3.9);3.6492 (3.6); 3.5539 (3.8); 3.5499 (3.6); 3.5100 (2.2); 3.5059 (2.0);3.3135 (0.6); 3.3058 (1.0); 3.2991 (0.9); 3.2925 (1.3); 3.2845 (1.2);3.2781 (0.8); 2.5298 (0.6); 2.5088 (1.2); 2.4951 (0.8); 2.4877 (0.8);2.4849 (0.8); 2.4741 (1.3); 2.4638 (1.3); 2.4530 (0.7); 2.4501 (0.9);2.4428 (0.7); 2.4290 (1.4); 2.4080 (0.6); 1.9360 (0.6); 1.9272 (1.1);1.9185 (0.6); 1.9012 (0.5); 1.8925 (1.0); 1.8835 (1.2); 1.8744 (1.2);1.8654 (0.6); 1.8485 (0.6); 1.8396 (1.1); 1.8307 (0.6); 1.6082 (15.6);1.6064 (16.0); 1.5858 (2.5); 1.5757 (8.7); 1.5621 (8.5); 0.0079 (0.8);−0.0002 (26.7); −0.0085 (0.9) II-49: ¹H-NMR(400.0 MHz, CDCl3): δ =7.9778 (4.3); 7.9737 (4.2); 7.8872 (2.8); 7.8701 (2.5); 7.8672 (2.8);7.7779 (2.3); 7.7750 (2.3); 7.7669 (1.2); 7.7584 (2.8); 7.7554 (2.7);7.6160 (0.7); 7.6090 (1.7); 7.6051 (1.7); 7.5965 (1.3); 7.5893 (2.8);7.5854 (2.9); 7.5697 (1.2); 7.5656 (1.5); 7.4731 (0.8); 7.4515 (1.4);7.4290 (0.9); 7.2616 (25.1); 6.0269 (1.0); 6.0096 (2.4); 6.0047 (2.8);6.0004 (3.6); 5.9959 (2.2); 5.9859 (1.7); 5.9811 (2.3); 5.9759 (1.2);5.9672 (1.4); 5.9224 (0.8); 5.2999 (8.0); 4.9617 (1.1); 4.4817 (2.7);4.4438 (5.5); 4.4162 (2.2); 4.4089 (3.6); 4.4006 (1.1); 4.3707 (1.2);4.3562 (3.0); 4.3187 (1.7); 4.0943 (1.3); 4.0778 (0.6); 4.0611 (1.4);4.0488 (1.8); 4.0318 (1.0); 4.0158 (1.9); 3.8409 (0.6); 3.8217 (1.6);3.8066 (5.8); 3.7966 (6.2); 3.7861 (16.0); 3.7759 (1.3); 3.7587 (2.1);3.7506 (2.3); 3.7426 (14.9); 3.5981 (1.1); 3.5928 (1.0); 3.5749 (1.1);3.1497 (2.1); 3.0019 (1.7); 2.9853 (1.5); 2.7547 (0.7); 2.7322 (1.0);2.7186 (0.8); 2.7092 (0.6); 2.6953 (1.2); 2.6714 (1.1); 2.6568 (0.6);2.6484 (0.6); 2.6346 (1.0); 2.1748 (0.5); 2.1650 (0.9); 2.1545 (0.5);2.1286 (0.9); 2.1176 (0.9); 2.1065 (0.9); 2.0962 (0.5); 2.0805 (0.6);2.0701 (1.1); 2.0601 (0.7); 2.0464 (0.9); 2.0084 (1.7); 1.6197 (0.8);1.2596 (0.6); 0.0079 (1.3); −0.0002 (32.2); −0.0083 (1.1) II-50:¹H-NMR(400.0 MHz, CDCl3): δ = 7.9473 (4.8); 7.8521 (2.7); 7.8332 (2.8);7.7236 (2.6); 7.7056 (3.1); 7.5659 (2.1); 7.5479 (3.1); 7.5297 (1.6);7.4110 (2.3); 7.2628 (9.6); 5.9575 (3.2); 5.9172 (3.4); 5.3009 (0.6);4.7708 (1.8); 4.4562 (1.5); 4.4196 (3.3); 4.3636 (3.3); 4.3253 (1.5);3.8539 (2.5); 3.8102 (3.2); 3.7623 (14.8); 3.5826 (2.0); 3.2448 (3.1);3.2016 (2.5); 2.7205 (1.3); 2.6847 (1.6); 2.1275 (1.6); 2.0919 (1.5);1.9501 (0.6); 1.7317 (16.0); 1.5064 (0.7); 1.2571 (3.7); 0.8572 (1.5);−0.0002 (10.9) II-51: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.9615 (5.2); 7.8558(3.8); 7.7053 (4.0); 7.5436 (3.6); 7.4247 (3.8); 7.2645 (8.2); 5.9678(4.4); 5.9162 (4.4); 5.3020 (1.1); 4.7727 (2.8); 4.4788 (1.9); 4.4410(3.4); 4.3703 (3.5); 3.9090 (2.5); 3.8679 (3.2); 3.7078 (14.1); 3.5852(3.4); 3.3643 (0.7); 3.2400 (3.1); 3.1968 (2.7); 2.6985 (2.3); 2.0728(2.5); 1.7380 (16.0); 1.4947 (1.3); 1.2575 (10.2); 0.8679 (4.8); −0.0002(9.7) II-52: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.9376 (4.4); 7.8587 (2.3);7.8381 (2.5); 7.7254 (2.5); 7.7058 (3.0); 7.5681 (2.5); 7.5480 (3.7);7.5282 (1.7); 7.5193 (1.5); 7.2604 (229.7); 7.1779 (1.6); 6.9963 (1.4);6.8500 (1.7); 5.9791 (2.0); 5.9229 (1.5); 5.1059 (1.4); 4.3559 (4.3);4.1853 (0.7); 4.0492 (0.8); 4.0191 (1.3); 3.9349 (1.4); 3.9050 (0.9);3.8640 (2.6); 3.8205 (3.7); 3.7954 (9.6); 3.6996 (1.4); 3.6862 (2.1);3.6718 (1.2); 3.5303 (1.2); 3.3670 (3.2); 3.2495 (2.9); 3.2064 (2.6);2.9122 (0.7); 2.6865 (1.1); 2.6205 (1.4); 2.0075 (1.8); 1.9879 (1.4);1.7294 (16.0); 1.6024 (5.1); 1.5640 (4.4); 1.2848 (5.7); 1.2556 (15.0);0.8802 (5.8); 0.1465 (1.1); 0.0078 (13.4); −0.0002 (286.4); −0.0082(15.4); −0.1497 (1.3) II-53: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.9380 (4.9);7.8611 (2.7); 7.8458 (3.1); 7.7251 (2.7); 7.7092 (3.4); 7.5699 (2.2);7.5514 (3.2); 7.2607 (80.9); 6.8473 (2.0); 5.9782 (3.8); 5.1087 (1.7);4.3183 (3.6); 3.8732 (2.0); 3.8288 (2.6); 3.7738 (9.7); 3.7004 (1.9);3.2452 (2.6); 3.2032 (2.2); 2.6199 (1.5); 1.8699 (1.8); 1.7262 (16.0);1.5647 (3.4); 1.2579 (11.5); 0.8590 (5.2); −0.0002 (102.1); −0.1500(1.0) II-54: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.2611 (59.3); 7.1908 (0.5);7.1825 (2.1); 7.1781 (3.3); 7.1769 (3.1); 7.1726 (3.2); 7.1677 (1.9);7.1629 (3.3); 7.1586 (3.2); 7.1574 (3.2); 7.1530 (2.0); 6.9392 (0.5);6.9358 (0.6); 6.9334 (0.9); 6.9301 (1.0); 6.9278 (0.6); 6.9243 (0.5);6.9175 (1.0); 6.9142 (1.3); 6.9118 (1.9); 6.9085 (1.9); 6.9061 (1.1);6.9028 (1.0); 6.8959 (0.6); 6.8926 (0.7); 6.8901 (1.0); 6.8869 (1.0);6.8522 (0.8); 6.8407 (0.9); 6.8320 (0.9); 6.8213 (0.8); 5.9682 (0.6);5.9634 (0.9); 5.9566 (1.1); 5.9542 (1.7); 5.9495 (3.0); 5.9454 (2.2);5.9419 (2.6); 5.9385 (3.4); 5.9375 (3.4); 5.9334 (2.6); 5.9236 (0.6);5.9196 (0.6); 5.9018 (1.2); 5.8964 (2.1); 5.8910 (1.2); 5.8879 (0.8);5.8825 (1.3); 5.8771 (0.7); 5.3811 (1.4); 5.3699 (1.2); 5.1332 (0.5);5.1288 (0.8); 5.1240 (0.8); 5.1187 (0.9); 5.1140 (0.9); 5.1083 (1.0);5.1036 (0.9); 5.0981 (0.9); 5.0935 (0.8); 5.0878 (0.6); 4.0436 (2.5);4.0261 (2.2); 4.0137 (4.0); 3.9961 (4.0); 3.9362 (3.7); 3.9266 (3.7);3.9061 (2.0); 3.8966 (2.3); 3.7288 (2.4); 3.7246 (2.2); 3.6847 (3.6);3.6805 (3.4); 3.5853 (0.6); 3.5795 (0.7); 3.5731 (0.8); 3.5674 (0.8);3.5633 (1.0); 3.5577 (1.2); 3.5461 (3.7); 3.5391 (1.0); 3.5330 (0.8);3.5223 (3.5); 3.5019 (1.9); 3.4782 (2.0); 2.6213 (0.7); 2.6090 (0.7);2.6009 (0.8); 2.5888 (1.2); 2.5863 (1.1); 2.5781 (0.8); 2.5739 (0.9);2.5690 (0.9); 2.5659 (0.9); 2.5573 (0.9); 2.5543 (1.3); 2.5430 (0.8);2.5340 (0.7); 2.5224 (0.7); 2.0149 (0.7); 2.0044 (0.7); 1.9930 (0.8);1.9825 (0.9); 1.9800 (0.8); 1.9694 (0.7); 1.9580 (0.6); 1.9475 (0.6);1.9160 (0.7); 1.9046 (0.7); 1.8939 (0.7); 1.8821 (1.0); 1.8696 (0.7);1.8588 (0.6); 1.8475 (0.6); 1.5798 (14.5); 1.5673 (16.0); 0.0079 (1.1);−0.0002 (34.0); −0.0085 (1.2) II-55: ¹H-NMR(400.6 MHz, CDCl3): δ =7.8433 (1.2); 7.8393 (2.0); 7.8385 (1.9); 7.8370 (1.9); 7.8346 (1.8);7.8321 (1.4); 7.8110 (1.4); 7.8075 (2.9); 7.8045 (2.6); 7.8010 (1.2);7.6898 (1.3); 7.6863 (2.5); 7.6852 (1.8); 7.6826 (1.6); 7.6815 (2.4);7.6779 (1.1); 7.2634 (13.2); 6.7266 (0.6); 6.7066 (0.6); 5.9660 (0.5);5.9570 (0.7); 5.9520 (1.4); 5.9476 (0.9); 5.9414 (0.9); 5.9367 (1.2);5.9326 (0.9); 5.9220 (0.8); 5.9177 (0.9); 5.9164 (0.9); 5.9124 (0.7);5.8928 (0.7); 5.8876 (1.1); 5.8823 (0.6); 5.8737 (0.6); 5.3904 (0.7);5.3729 (0.7); 5.3012 (1.8); 3.8426 (1.6); 3.8371 (1.4); 3.7993 (1.8);3.7938 (1.6); 3.2154 (1.6); 3.2123 (1.7); 3.1721 (1.4); 3.1690 (1.5);2.5656 (0.8); 2.5451 (0.8); 2.5309 (0.5); 1.8509 (0.6); 1.7308 (16.0);1.7144 (1.0); 1.5947 (0.9); 1.5795 (8.3); 1.5779 (8.7); 1.5647 (8.5);−0.0002 (16.7); −0.0084 (0.5) II-56: ¹H-NMR(400.6 MHz, CDCl3): δ =7.8646 (1.8); 7.8605 (2.7); 7.8560 (3.8); 7.8521 (2.8); 7.8475 (2.2);7.8043 (2.1); 7.8006 (3.8); 7.7974 (3.5); 7.7941 (4.0); 7.7904 (2.0);7.6683 (3.6); 7.6644 (4.4); 7.6599 (3.3); 7.3915 (1.0); 7.3709 (1.0);7.2632 (20.5); 5.9377 (0.6); 5.9325 (1.0); 5.9274 (0.6); 5.9239 (1.0);5.9187 (1.7); 5.9136 (1.1); 5.8898 (1.0); 5.8861 (1.1); 5.8842 (1.1);5.8804 (1.0); 5.8763 (0.8); 5.8725 (0.8); 5.8665 (0.8); 5.8583 (6.0);5.8535 (1.6); 5.7132 (0.9); 5.6836 (0.9); 5.3012 (5.0); 4.9472 (0.9);4.9388 (0.8); 4.9261 (0.9); 4.9234 (0.8); 4.9178 (0.7); 3.8102 (2.9);3.8071 (2.8); 3.7672 (3.3); 3.7641 (3.3); 3.3159 (0.5); 3.3086 (0.7);3.3013 (0.5); 3.2944 (1.0); 3.2874 (1.0); 3.2728 (0.5); 3.1981 (2.7);3.1869 (2.8); 3.1550 (2.4); 3.1438 (2.5); 2.5344 (0.6); 2.5133 (1.2);2.4997 (0.8); 2.4918 (1.0); 2.4787 (1.2); 2.4700 (1.1); 2.4568 (1.1);2.4488 (0.6); 2.4353 (1.2); 2.4142 (0.6); 1.9106 (0.6); 1.9015 (1.1);1.8923 (0.6); 1.8760 (0.6); 1.8669 (1.0); 1.8579 (0.5); 1.8351 (0.6);1.8260 (1.0); 1.8168 (0.6); 1.7913 (0.9); 1.7821 (0.5); 1.7294 (15.2);1.7179 (14.6); 1.7117 (1.2); 1.6999 (0.5); 1.6145 (16.0); 1.5940 (7.6);1.5766 (7.6); 0.0080 (0.7); −0.0002 (25.9); −0.0085 (0.7) II-57:¹H-NMR(400.6 MHz, CDCl3): δ = 7.8503 (1.2); 7.8457 (2.7); 7.8415 (3.1);7.8368 (1.4); 7.8139 (1.4); 7.8101 (3.4); 7.8063 (3.4); 7.8024 (1.4);7.6897 (1.3); 7.6860 (2.8); 7.6812 (2.6); 7.6775 (1.3); 7.2631 (20.2);6.7397 (0.6); 6.7209 (0.7); 6.0096 (0.6); 5.9983 (0.8); 5.9945 (0.8);5.9844 (1.5); 5.9798 (2.0); 5.9769 (1.6); 5.9749 (1.6); 5.9712 (2.1);5.9663 (1.5); 5.9605 (0.8); 5.9009 (0.6); 5.8954 (1.1); 5.8900 (0.6);5.8816 (0.8); 5.1156 (0.5); 5.1103 (0.5); 5.1050 (0.6); 5.1004 (0.5);4.0504 (2.9); 4.0366 (4.1); 4.0227 (2.8); 3.8464 (1.6); 3.8426 (1.6);3.8031 (1.8); 3.7993 (1.9); 3.7889 (1.2); 3.7814 (0.5); 3.7749 (1.3);3.7690 (12.2); 3.7598 (12.0); 3.6643 (0.6); 3.6587 (0.5); 3.2137 (2.7);3.1704 (2.4); 2.6246 (0.5); 2.6051 (0.6); 2.5933 (0.6); 1.9718 (0.5);1.8806 (0.6); 1.7334 (16.0); 1.7268 (1.5); 1.7166 (0.9); 0.0080 (0.7);−0.0002 (26.3); −0.0085 (0.8) II-58: ¹H-NMR(400.6 MHz, CDCl3): δ =7.8724 (1.6); 7.8684 (2.4); 7.8637 (3.2); 7.8598 (2.3); 7.8550 (1.8);7.8215 (1.8); 7.8179 (3.1); 7.8140 (2.0); 7.8124 (2.0); 7.8087 (3.1);7.8050 (1.6); 7.6629 (2.4); 7.6621 (2.3); 7.6583 (3.7); 7.6546 (2.4);7.6309 (0.6); 7.6183 (0.7); 7.6102 (0.7); 7.5968 (0.6); 7.2646 (15.8);6.1914 (0.5); 5.9549 (0.5); 5.9461 (0.8); 5.9412 (1.4); 5.9368 (1.0);5.9288 (1.1); 5.9268 (1.0); 5.9238 (1.0); 5.9211 (0.8); 5.9073 (0.8);5.8937 (0.8); 5.8908 (0.9); 5.8880 (1.0); 5.8854 (1.0); 5.8737 (0.9);5.8691 (1.3); 5.8640 (0.8); 5.8552 (0.6); 5.3019 (3.6); 4.9973 (0.7);4.9895 (0.7); 4.1128 (1.9); 4.1054 (2.0); 4.0997 (2.0); 4.0926 (2.0);4.0862 (2.7); 4.0733 (2.6); 3.8395 (2.1); 3.8234 (2.2); 3.7965 (2.4);3.7882 (15.6); 3.7777 (16.0); 3.7630 (0.8); 3.4174 (0.5); 3.4083 (0.7);3.4037 (0.9); 3.3975 (0.8); 3.3899 (0.6); 3.1884 (2.2); 3.1774 (2.2);3.1453 (2.0); 3.1344 (1.9); 2.5059 (0.8); 2.4922 (0.6); 2.4713 (0.9);2.4424 (0.8); 2.4285 (0.6); 2.4078 (0.9); 1.9490 (0.8); 1.9144 (0.7);1.8723 (0.8); 1.8378 (0.8); 1.7337 (11.7); 1.7184 (11.7); 1.7006 (0.6);1.6503 (1.0); 0.0080 (0.5); −0.0002 (20.2); −0.0084 (0.6) II-59:¹H-NMR(400.6 MHz, CDCl3): δ = 7.8604 (1.2); 7.8564 (2.2); 7.8515 (2.6);7.8488 (1.7); 7.8448 (2.5); 7.8407 (2.7); 7.8373 (3.1); 7.8336 (1.4);7.8263 (2.1); 7.8226 (3.6); 7.8188 (2.0); 7.6932 (0.5); 7.6896 (0.7);7.6865 (2.2); 7.6825 (3.5); 7.6781 (3.0); 7.6739 (1.5); 7.3462 (0.8);7.3333 (0.8); 7.3274 (0.7); 7.2630 (22.6); 6.0064 (1.7); 5.9941 (0.7);5.9889 (0.9); 5.9832 (0.8); 5.9803 (0.8); 5.9753 (1.3); 5.9696 (1.2);5.9639 (1.2); 5.9589 (0.8); 5.9301 (1.3); 5.9247 (2.2); 5.9192 (1.2);5.9163 (0.8); 5.9107 (1.4); 5.9055 (0.8); 5.3014 (13.1); 4.7960 (0.5);4.7908 (0.6); 4.7836 (0.6); 4.7786 (0.6); 4.7737 (0.5); 4.4997 (1.5);4.4771 (1.5); 4.4617 (2.8); 4.4397 (2.8); 4.4179 (1.0); 4.4155 (1.0);4.4051 (1.1); 4.4015 (1.1); 4.3933 (2.9); 4.3781 (2.9); 4.3553 (1.5);4.3406 (1.5); 3.8942 (1.7); 3.8505 (2.1); 3.8402 (1.8); 3.8188 (0.7);3.8049 (4.2); 3.7949 (5.2); 3.7784 (15.8); 3.7520 (0.7); 3.7376 (15.3);3.6771 (0.7); 3.6058 (0.6); 3.5994 (0.6); 3.5937 (0.7); 3.5883 (0.7);3.5829 (0.6); 3.5767 (0.6); 3.2350 (0.5); 3.2306 (0.6); 3.2231 (1.9);3.2152 (1.9); 3.1871 (0.6); 3.1794 (1.7); 3.1714 (1.7); 2.7425 (0.7);2.7302 (0.9); 2.7179 (0.7); 2.7066 (1.0); 2.6947 (0.8); 2.1242 (0.7);2.0879 (0.6); 2.0718 (0.7); 2.0354 (0.7); 1.7373 (11.8); 1.7345 (16.0);1.7209 (0.9); 1.7177 (1.0); 0.0079 (0.7); −0.0002 (29.7); −0.0085 (0.8)II-60: ¹H-NMR(400.0 MHz, CDCl3): δ = 8.1441 (6.0); 8.1404 (6.6); 8.1340(6.2); 8.1303 (6.5); 7.9457 (3.9); 7.6763 (1.3); 7.6544 (1.4); 7.2756(0.6); 7.2643 (13.3); 6.2546 (0.7); 6.1913 (0.7); 5.9576 (0.7); 5.9487(1.0); 5.9439 (1.7); 5.9398 (1.4); 5.9324 (1.5); 5.9281 (1.4); 5.9089(0.7); 5.9026 (0.7); 5.8922 (1.2); 5.8886 (1.2); 5.8713 (1.1); 5.8664(1.5); 5.8616 (1.0); 5.8529 (0.8); 5.8479 (0.6); 5.3016 (10.2); 4.9998(1.2); 4.1491 (0.7); 4.1310 (1.8); 4.1169 (2.4); 4.1133 (2.6); 4.1067(2.7); 4.1041 (2.7); 4.0945 (2.9); 4.0858 (4.6); 4.0730 (4.4); 3.9750(1.6); 3.8752 (2.1); 3.8576 (2.1); 3.8321 (2.3); 3.8145 (2.4); 3.8042(1.0); 3.7930 (16.0); 3.7847 (15.7); 3.7772 (1.9); 3.4207 (0.8); 3.4060(1.4); 3.3895 (0.8); 3.2065 (2.3); 3.1934 (2.3); 3.1633 (2.0); 3.1502(2.0); 2.4898 (0.9); 2.4759 (0.7); 2.4689 (0.6); 2.4549 (1.0); 2.4412(0.6); 2.4341 (0.6); 2.4204 (0.9); 2.4064 (0.6); 2.3996 (0.6); 2.3857(1.0); 2.0457 (7.7); 1.9612 (0.6); 1.9545 (1.0); 1.9474 (0.6); 1.9264(0.6); 1.9199 (0.9); 1.9127 (0.6); 1.8772 (0.6); 1.8705 (1.0); 1.8635(0.6); 1.8424 (0.5); 1.8359 (0.9); 1.8289 (0.5); 1.7519 (12.0); 1.7363(11.9); 1.2777 (2.0); 1.2598 (4.1); 1.2420 (2.1); 0.0112 (0.8); 0.0080(1.0); −0.0002 (17.4); −0.0081 (1.0) II-61: ¹H-NMR(400.6 MHz, CDCl3): δ= 8.1254 (5.3); 8.1222 (8.0); 8.1187 (5.1); 7.9784 (1.4); 7.9748 (3.5);7.9712 (3.3); 7.9675 (1.2); 7.2637 (14.2); 6.7054 (0.5); 6.6983 (0.6);6.6853 (0.6); 6.6776 (0.5); 5.9596 (0.7); 5.9548 (1.5); 5.9506 (1.0);5.9461 (1.0); 5.9428 (1.6); 5.9379 (1.2); 5.9330 (0.5); 5.9289 (1.0);5.9242 (1.1); 5.9193 (0.7); 5.8858 (0.6); 5.8805 (1.1); 5.8752 (0.6);5.8667 (0.7); 5.3937 (0.7); 5.3758 (0.7); 5.3015 (14.2); 5.0945 (0.5);5.0892 (0.6); 5.0846 (0.6); 3.8853 (1.5); 3.8787 (1.5); 3.8420 (1.7);3.8353 (1.7); 3.5653 (0.5); 3.5594 (0.6); 3.5542 (0.6); 3.2328 (1.7);3.2296 (1.7); 3.1895 (1.5); 3.1862 (1.5); 2.5739 (0.5); 2.5365 (0.5);1.9438 (0.5); 1.8435 (0.6); 1.7481 (16.0); 1.6125 (0.5); 1.5800 (9.0);1.5650 (8.6); −0.0002 (19.8); −0.0085 (0.6) II-62: ¹H-NMR(400.6 MHz,CDCl3): δ = 8.1314 (6.8); 8.1277 (7.4); 8.1232 (7.1); 8.1194 (7.4);7.9555 (2.9); 7.9518 (5.3); 7.9481 (2.8); 7.4298 (0.6); 7.4197 (0.7);7.4083 (0.8); 7.3992 (0.7); 7.2644 (15.4); 5.9439 (0.6); 5.9388 (0.9);5.9338 (0.6); 5.9302 (0.9); 5.9250 (1.5); 5.9200 (1.0); 5.8953 (0.8);5.8918 (1.0); 5.8895 (1.0); 5.8860 (1.0); 5.8783 (0.9); 5.8722 (0.7);5.8598 (4.2); 5.8539 (1.2); 5.6768 (1.4); 5.3019 (16.0); 4.9537 (0.8);4.9457 (0.7); 4.9344 (0.8); 4.9281 (0.6); 3.9831 (0.6); 3.9814 (0.6);3.9773 (1.9); 3.8480 (2.2); 3.8419 (2.4); 3.8049 (2.5); 3.7989 (2.6);3.3096 (0.6); 3.3065 (0.5); 3.2934 (1.0); 3.2885 (1.0); 3.2802 (0.6);3.2722 (0.6); 3.2158 (2.4); 3.2028 (2.3); 3.1727 (2.1); 3.1597 (2.0);2.4928 (0.9); 2.4791 (0.6); 2.4719 (0.5); 2.4628 (0.6); 2.4582 (1.0);2.4418 (1.0); 2.4374 (0.6); 2.4281 (0.6); 2.4208 (0.6); 2.4071 (1.0);1.9095 (0.9); 1.8749 (0.8); 1.8272 (1.0); 1.8188 (0.5); 1.7925 (0.9);1.7841 (0.6); 1.7469 (12.8); 1.7353 (12.8); 1.6183 (13.5); 1.6165(14.0); 1.5898 (7.1); 1.5823 (7.6); 1.5643 (0.9); 0.0079 (0.5); −0.0002(20.7); −0.0085 (0.6) II-63: ¹H-NMR(400.6 MHz, CDCl3): δ = 8.1537 (1.8);8.1499 (1.9); 8.1461 (0.5); 8.1424 (0.6); 8.1383 (1.9); 8.1346 (1.9);7.9725 (0.6); 7.9691 (1.2); 7.9658 (1.2); 7.9623 (0.5); 7.2618 (10.4);5.9727 (0.5); 5.9352 (0.5); 5.9332 (0.5); 5.3011 (16.0); 4.4548 (0.9);4.4481 (0.8); 4.4143 (0.9); 4.3766 (1.1); 3.8936 (0.6); 3.8751 (0.5);3.8315 (0.6); 3.8056 (1.1); 3.7947 (1.2); 3.7910 (4.5); 3.7613 (4.6);3.2406 (0.5); 3.2271 (0.5); 1.7520 (4.8); −0.0002 (13.6)

Analytical data of Examples III-01-III-28 (see Table 1.1)

III-01: 1H-NMR(400.0 MHz, CDCl3): δ = 7.5186 (1.1); 7.4156 (0.6); 7.3960(2.5); 7.3913 (2.0); 7.3836 (4.1); 7.3791 (4.3); 7.3763 (4.7); 7.3703(4.9); 7.3680 (5.6); 7.2597 (200.4); 7.1603 (0.9); 7.1543 (1.3); 7.1497(0.8); 7.1422 (1.0); 7.1393 (1.1); 7.1356 (1.2); 7.1307 (1.4); 7.1252(1.2); 7.1171 (1.2); 7.1095 (0.7); 7.0532 (1.0); 7.0352 (1.0); 6.9957(1.1); 6.8617 (1.1); 6.8568 (1.5); 6.8351 (1.1); 6.8299 (1.5); 6.8250(1.1); 4.6414 (0.8); 4.6310 (1.2); 4.6214 (1.4); 4.6113 (1.4); 4.6017(1.1); 4.5913 (0.7); 3.8286 (2.7); 3.8202 (2.6); 3.7853 (3.1); 3.7769(3.1); 3.2432 (2.9); 3.2356 (3.0); 3.1999 (2.5); 3.1923 (2.6); 3.0747(0.7); 3.0638 (0.6); 3.0417 (1.2); 3.0363 (0.9); 3.0216 (1.0); 3.0066(0.9); 2.9932 (1.0); 2.9875 (1.0); 2.5412 (0.6); 2.5369 (0.6); 2.5311(0.6); 2.4989 (0.9); 2.4934 (1.0); 2.4694 (0.6); 2.4543 (0.8); 2.4329(0.6); 2.4266 (0.7); 2.4156 (0.8); 2.3569 (0.6); 1.7191 (16.0); 1.7118(15.6); 1.2555 (1.5); 0.0080 (2.1); −0.0002 (67.7); −0.0084 (2.2)III-02: 1H-NMR(400.0 MHz, CDCl3): δ = 7.5187 (1.0); 7.3959 (2.4); 7.3914(2.0); 7.3835 (4.0); 7.3790 (4.3); 7.3763 (4.9); 7.3703 (5.1); 7.3680(5.7); 7.2598 (180.1); 7.2100 (0.5); 7.1603 (1.0); 7.1542 (1.3); 7.1496(0.9); 7.1423 (1.1); 7.1392 (1.1); 7.1356 (1.3); 7.1309 (1.5); 7.1252(1.3); 7.1170 (1.2); 7.1096 (0.8); 7.0523 (1.0); 7.0406 (1.1); 6.9957(1.1); 6.8622 (1.1); 6.8570 (1.5); 6.8359 (1.1); 6.8305 (1.5); 6.8255(1.1); 4.6414 (0.7); 4.6309 (1.2); 4.6215 (1.4); 4.6111 (1.4); 4.6017(1.1); 4.5913 (0.7); 3.8289 (2.7); 3.8206 (2.6); 3.7856 (3.0); 3.7773(3.1); 3.2433 (2.9); 3.2357 (2.8); 3.2000 (2.6); 3.1924 (2.6); 3.0626(0.6); 3.0412 (1.2); 3.0355 (1.0); 3.0209 (0.9); 3.0063 (0.9); 2.9931(1.0); 2.9868 (1.0); 2.9589 (0.5); 2.9342 (0.5); 2.5463 (0.5); 2.5412(0.6); 2.5360 (0.6); 2.4987 (0.9); 2.4930 (1.1); 2.4691 (0.7); 2.4641(0.6); 2.4339 (0.7); 2.4264 (0.7); 2.4157 (0.8); 2.3623 (0.5); 1.7191(15.6); 1.7118 (16.0); 1.4468 (1.4); 1.4318 (0.6); 1.2553 (1.4); 1.2433(0.5); 0.0079 (1.9); −0.0002 (62.7); −0.0085 (2.2) III-03: 1H-NMR(400.0MHz, d6-DMSO): δ = 8.3222 (1.1); 8.3041 (1.1); 7.5252 (2.2); 7.5160(2.8); 7.4971 (1.8); 7.4908 (1.2); 7.4652 (1.0); 7.4619 (0.8); 7.3384(0.7); 7.3307 (0.7); 7.3232 (1.0); 7.3175 (0.8); 7.3124 (0.5); 7.2993(0.6); 6.6795 (0.9); 6.6747 (1.3); 6.6686 (1.0); 6.6634 (0.7); 6.6572(0.9); 6.6524 (0.5); 4.4258 (0.7); 4.4053 (0.7); 3.7794 (2.4); 3.7356(2.8); 3.6626 (9.0); 3.6449 (16.0); 3.3703 (2.7); 3.3584 (0.7); 3.3264(3.1); 3.3086 (119.5); 2.7817 (0.8); 2.7606 (0.8); 2.7449 (0.6); 2.7241(0.5); 2.6741 (0.8); 2.6695 (1.1); 2.6649 (0.8); 2.5502 (1.1); 2.5229(5.4); 2.5182 (7.3); 2.5095 (63.0); 2.5050 (127.5); 2.5004 (173.8);2.4958 (120.3); 2.4913 (55.7); 2.4646 (1.2); 2.4616 (1.3); 2.4559 (1.0);2.4480 (0.7); 2.4420 (0.6); 2.4195 (0.5); 2.4141 (0.6); 2.4072 (0.6);2.3319 (0.8); 2.3271 (1.1); 2.3226 (0.8); 1.5450 (7.2); 1.5404 (11.0);0.0080 (1.1); −0.0002 (32.1); −0.0085 (1.0) III-04: 1H-NMR(400.0 MHz,d6-DMSO): δ = 8.3218 (1.0); 8.3041 (1.0); 7.5155 (2.3); 7.4952 (1.5);7.4647 (1.0); 7.3157 (0.9); 6.6572 (1.6); 3.7787 (2.1); 3.7345 (2.5);3.6625 (16.0); 3.6449 (4.4); 3.3694 (2.3); 3.3251 (2.5); 3.3088 (186.6);2.7615 (0.8); 2.6694 (1.2); 2.5228 (4.6); 2.5182 (6.4); 2.5094 (83.3);2.5049 (176.8); 2.5003 (247.5); 2.4957 (172.4); 2.4912 (79.4); 2.3269(1.5); 1.5449 (10.8); 0.0080 (1.4); −0.0002 (39.9); −0.0086 (1.2)III-05: 1H-NMR(400.0 MHz, CDCl3): δ = 7.5184 (4.3); 7.3764 (4.6); 7.3675(5.2); 7.2595 (761.0); 7.1539 (1.5); 7.1301 (1.6); 7.1245 (1.3); 6.9955(4.7); 6.7228 (2.0); 6.6957 (1.5); 4.6043 (1.3); 4.5942 (1.5); 4.5845(1.6); 4.5746 (1.6); 4.5644 (1.0); 4.2408 (1.1); 4.2225 (3.3); 4.2025(3.9); 4.1843 (3.5); 4.1654 (1.2); 3.8201 (2.6); 3.8148 (2.7); 3.7771(2.8); 3.7714 (3.3); 3.2355 (3.0); 3.2287 (2.7); 3.1921 (2.7); 3.1855(2.4); 3.0062 (1.2); 2.9651 (1.2); 2.4446 (1.5); 2.4053 (1.2); 1.7137(13.9); 1.7055 (16.0); 1.5332 (206.1); 1.3216 (4.4); 1.3036 (9.3);1.3008 (6.2); 1.2857 (5.3); 1.2829 (11.2); 1.2651 (5.3); 0.1462 (1.3);0.0080 (9.1); −0.0002 (261.5); −0.0085 (7.0); −0.1492 (1.1) III-06:1H-NMR(400.0 MHz, CDCl3): δ = 7.5184 (1.5); 7.3955 (2.5); 7.3833 (2.2);7.3764 (4.2); 7.3723 (4.1); 7.3677 (4.9); 7.3656 (4.5); 7.2880 (0.6);7.2596 (271.7); 7.1591 (0.8); 7.1535 (1.1); 7.1488 (0.8); 7.1299 (1.5);7.1241 (0.9); 7.1160 (0.8); 7.1084 (0.6); 7.0045 (0.9); 6.9956 (2.2);6.9860 (1.0); 6.7229 (1.6); 6.7009 (1.0); 6.6955 (1.4); 6.6904 (1.0);4.6143 (0.8); 4.6044 (1.3); 4.5945 (1.7); 4.5845 (1.6); 4.5746 (1.4);4.5645 (0.8); 4.2404 (1.0); 4.2226 (3.3); 4.2047 (3.7); 4.2025 (3.5);4.1843 (3.3); 4.1663 (1.0); 3.8203 (2.5); 3.8148 (2.8); 3.7770 (2.8);3.7715 (3.3); 3.2353 (3.0); 3.2286 (2.7); 3.1920 (2.6); 3.1853 (2.4);3.0311 (0.6); 3.0258 (0.8); 3.0205 (0.7); 3.0112 (0.9); 3.0067 (1.1);3.0011 (0.8); 2.9838 (0.6); 2.9790 (0.6); 2.9595 (1.1); 2.9461 (0.6);2.9410 (0.7); 2.5163 (0.6); 2.5110 (0.6); 2.4684 (0.5); 2.4447 (1.2);2.4055 (0.8); 2.3952 (1.0); 2.3892 (0.6); 2.3562 (0.6); 1.7137 (14.1);1.7055 (16.0); 1.5347 (49.7); 1.3214 (4.5); 1.3036 (9.7); 1.3007 (5.9);1.2857 (5.2); 1.2828 (11.0); 1.2650 (5.1); 1.2547 (0.7); 0.0080 (3.2);−0.0002 (101.2); −0.0085 (3.2) III-07: 1H-NMR(400.0 MHz, CDCl3): δ =7.2618 (43.0); 7.1694 (2.0); 7.1666 (2.9); 7.1637 (3.3); 7.1609 (3.2);7.1497 (3.1); 7.1469 (3.2); 7.1440 (2.9); 7.1412 (2.0); 6.9655 (1.0);6.9465 (1.0); 6.9114 (0.6); 6.9094 (0.6); 6.9056 (1.0); 6.9036 (1.0);6.8999 (0.6); 6.8979 (0.5); 6.8897 (1.1); 6.8876 (1.1); 6.8839 (1.9);6.8819 (1.8); 6.8781 (1.0); 6.8761 (1.0); 6.8680 (0.6); 6.8659 (0.6);6.8622 (0.9); 6.8602 (0.9); 6.7281 (0.9); 6.7233 (1.5); 6.7192 (1.0);6.7033 (1.1); 6.6983 (1.4); 6.6930 (1.1); 5.2988 (5.2); 4.6136 (0.8);4.6037 (1.4); 4.5937 (1.7); 4.5838 (1.7); 4.5737 (1.4); 4.5638 (0.8);4.2409 (1.1); 4.2232 (4.4); 4.2053 (6.6); 4.1873 (4.3); 4.1693 (1.1);3.7912 (2.8); 3.7863 (2.8); 3.7480 (3.2); 3.7431 (3.2); 3.2021 (2.8);3.1958 (3.0); 3.1588 (2.5); 3.1525 (2.6); 3.0337 (0.7); 3.0286 (0.9);3.0232 (0.7); 3.0193 (0.7); 3.0142 (0.9); 3.0090 (1.1); 3.0039 (0.7);2.9994 (0.5); 2.9905 (0.6); 2.9874 (0.6); 2.9820 (0.6); 2.9724 (0.5);2.9671 (1.1); 2.9620 (1.1); 2.9547 (0.6); 2.9481 (0.7); 2.9426 (0.6);2.5214 (0.5); 2.5161 (0.7); 2.5113 (0.7); 2.5060 (0.5); 2.4737 (0.6);2.4689 (0.6); 2.4521 (0.6); 2.4449 (1.1); 2.4419 (0.9); 2.4345 (0.9);2.4053 (0.7); 2.3992 (0.9); 2.3952 (0.9); 2.3891 (0.6); 2.3625 (0.6);2.3567 (0.6); 2.3156 (0.5); 2.3097 (0.5); 1.7241 (0.6); 1.7143 (16.0);1.7063 (15.7); 1.5698 (2.4); 1.3216 (5.5); 1.3037 (15.2); 1.2855 (14.9);1.2675 (5.3); 0.0079 (0.7); −0.0002 (23.7); −0.0085 (0.9) III-08:1H-NMR(400.0 MHz, CDCl3): δ = 7.2600 (56.1); 7.1756 (2.2); 7.1721 (2.8);7.1563 (2.8); 7.1526 (2.3); 6.9242 (0.9); 6.9084 (1.6); 6.8944 (1.1);6.8923 (1.2); 6.8886 (1.7); 6.8867 (1.6); 6.8829 (1.0); 6.8709 (0.5);6.8668 (0.8); 6.7312 (1.0); 6.7251 (1.2); 6.7208 (1.3); 6.7149 (1.2);6.7095 (1.3); 6.7042 (1.0); 6.1885 (1.1); 6.1805 (1.1); 6.1617 (1.2);6.1537 (1.2); 6.1454 (1.4); 6.1373 (1.3); 6.1186 (1.4); 6.1106 (1.4);5.5461 (2.2); 5.5402 (2.2); 5.5030 (1.9); 5.4971 (1.8); 5.3537 (2.0);5.3434 (2.0); 5.3268 (1.9); 5.3166 (1.8); 4.6304 (0.5); 4.6202 (0.9);4.6085 (1.0); 4.6001 (1.0); 4.5886 (1.0); 4.5784 (0.6); 3.9363 (2.1);3.9267 (2.2); 3.8934 (2.3); 3.8836 (2.5); 3.7539 (15.2); 3.7418 (16.0);3.3321 (2.3); 3.3251 (2.3); 3.2890 (2.0); 3.2820 (2.0); 3.0327 (0.6);3.0276 (0.6); 3.0226 (0.7); 3.0172 (0.6); 3.0124 (0.9); 3.0070 (0.9);2.9945 (0.7); 2.9738 (0.7); 2.9638 (0.8); 2.9590 (0.7); 2.9531 (0.6);2.5042 (0.6); 2.4991 (0.6); 2.4741 (0.6); 2.4672 (0.7); 2.4566 (0.6);2.4336 (1.0); 2.4268 (0.9); 2.4234 (1.0); 2.3890 (0.8); 1.5747 (2.1);0.0079 (1.4); −0.0002 (40.7); −0.0084 (1.8) III-09: 1H-NMR(400.0 MHz,CDCl3): δ = 7.5184 (1.3); 7.2596 (202.0); 7.2255 (2.5); 7.1914 (3.4);7.1792 (13.1); 7.1736 (16.0); 7.1627 (10.3); 7.1594 (15.9); 7.1539(12.9); 7.1415 (2.9); 6.9956 (1.4); 6.9611 (4.2); 6.9481 (4.4); 6.9161(4.2); 6.9104 (6.5); 6.9047 (4.1); 6.8945 (8.1); 6.8887 (12.2); 6.8829(7.2); 6.8728 (5.0); 6.8670 (7.9); 6.8612 (6.9); 6.8575 (8.4); 6.8479(6.3); 6.8425 (6.4); 6.8376 (4.5); 6.7697 (0.8); 6.1941 (5.8); 6.1839(5.2); 6.1673 (6.4); 6.1570 (6.4); 6.1509 (7.0); 6.1407 (6.4); 6.1241(7.1); 6.1139 (6.5); 5.6506 (0.7); 5.6076 (0.7); 5.5505 (10.7); 5.5462(10.9); 5.5074 (9.0); 5.5043 (9.7); 5.4579 (0.8); 5.4315 (0.6); 5.3592(8.7); 5.3490 (9.3); 5.3324 (8.4); 5.3230 (8.9); 5.2982 (16.0); 4.7429(0.8); 4.7235 (0.7); 4.7131 (0.6); 4.6652 (1.4); 4.6562 (2.1); 4.6456(3.8); 4.6335 (4.5); 4.6255 (4.4); 4.6137 (4.2); 4.6031 (2.5); 4.5936(1.7); 3.9451 (9.2); 3.9340 (10.3); 3.9271 (1.7); 3.9252 (2.5); 3.9239(1.6); 3.9195 (0.6); 3.9083 (1.6); 3.9020 (10.5); 3.8908 (12.0); 3.7542(1.1); 3.4180 (0.9); 3.3771 (2.1); 3.3621 (1.8); 3.3394 (11.0); 3.3314(10.4); 3.3189 (2.2); 3.3118 (2.8); 3.2962 (9.6); 3.2882 (8.8); 3.0814(1.9); 3.0611 (3.1); 3.0496 (5.1); 3.0292 (5.6); 3.0104 (5.6); 2.9904(4.7); 2.9740 (2.6); 2.9537 (1.8); 2.5710 (1.2); 2.5214 (3.3); 2.5160(3.0); 2.4815 (5.8); 2.4746 (5.4); 2.4437 (4.3); 2.4393 (4.5); 2.4286(4.0); 2.3852 (2.2); 2.3538 (1.1); 2.3450 (0.9); 1.5524 (1.3); 1.5361(1.3); 1.2560 (2.1); 0.9050 (4.3); 0.9016 (4.6); 0.8893 (4.4); 0.8858(4.6); 0.1459 (0.9); 0.0080 (9.2); −0.0002 (251.2); −0.0085 (10.8);−0.0499 (1.3); −0.1497 (0.9) III-10: 1H-NMR(599.7 MHz, CDCl3): δ =7.2876 (0.6); 7.2666 (2.5); 7.2610 (48.2); 7.2400 (0.6); 7.2205 (0.4);7.1842 (0.3); 7.1568 (15.6); 7.1460 (14.8); 7.0839 (0.3); 6.9510 (5.7);6.9390 (5.6); 6.8928 (3.9); 6.8786 (7.4); 6.8643 (3.8); 6.7278 (6.5);6.7032 (6.4); 5.2959 (8.9); 4.5993 (4.0); 4.5926 (4.9); 4.5862 (5.1);4.5795 (4.4); 4.0394 (2.2); 3.7809 (7.0); 3.7747 (6.9); 3.7562 (39.3);3.7460 (9.4); 3.7370 (38.2); 3.7173 (1.0); 3.6965 (0.8); 3.6806 (0.6);3.4847 (3.5); 3.1906 (7.2); 3.1848 (8.5); 3.1619 (6.6); 3.1560 (7.7);3.0597 (2.0); 3.0464 (2.0); 3.0311 (2.3); 3.0174 (3.5); 3.0013 (3.7);2.9861 (3.6); 2.9717 (4.0); 2.9559 (3.3); 2.9394 (1.9); 2.9209 (2.2);2.9080 (2.1); 2.5087 (3.2); 2.4801 (2.9); 2.4376 (5.8); 2.4064 (5.0);2.3552 (3.2); 2.3239 (2.9); 2.0397 (0.3); 1.9435 (6.9); 1.9225 (7.2);1.8108 (0.3); 1.7367 (0.3); 1.7101 (45.0); 1.7039 (50.0); 1.6823 (7.8);1.6077 (4.0); 1.5859 (6.4); 1.3825 (2.2); 1.3621 (6.4); 1.3404 (7.1);1.3204 (3.0); 1.2594 (3.3); 1.1846 (1.7); 1.1636 (3.6); 1.1431 (3.2);1.1231 (3.8); 1.1042 (7.1); 1.0858 (6.7); 1.0654 (2.4); 0.8907 (0.8);0.8807 (1.5); 0.8690 (1.0); −0.0001 (22.5); −0.0218 (0.4) III-11:1H-NMR(599.7 MHz, CDCl3): δ = 7.2592 (50.0); 7.1594 (5.5); 7.1482 (5.4);6.9514 (1.8); 6.9392 (1.8); 6.8931 (1.4); 6.8787 (2.8); 6.8643 (1.4);6.6923 (2.3); 6.6672 (2.3); 5.2954 (21.2); 5.0969 (0.5); 5.0865 (1.4);5.0763 (2.0); 5.0662 (2.2); 5.0565 (1.9); 5.0468 (1.3); 5.0365 (0.5);4.6000 (0.8); 4.5935 (1.3); 4.5870 (1.6); 4.5806 (1.9); 4.5743 (1.6);4.5678 (1.3); 4.5615 (0.8); 4.0336 (0.5); 3.7792 (3.9); 3.7504 (4.3);3.5007 (0.8); 3.4835 (1.6); 3.4663 (0.9); 3.1900 (3.0); 3.1842 (3.2);3.1613 (2.8); 3.1555 (3.0); 3.0528 (0.7); 3.0393 (0.8); 3.0247 (0.8);3.0100 (1.2); 2.9909 (1.2); 2.9774 (1.4); 2.9626 (1.2); 2.9445 (1.2);2.9306 (0.7); 2.9097 (0.8); 2.8992 (0.8); 2.4911 (1.0); 2.4658 (1.0);2.4233 (1.8); 2.3915 (1.6); 2.3399 (1.0); 2.3069 (0.9); 1.9430 (3.0);1.9275 (3.2); 1.9222 (3.1); 1.7776 (1.0); 1.7656 (1.0); 1.7128 (19.7);1.7036 (18.8); 1.6897 (2.9); 1.6829 (3.5); 1.6768 (2.4); 1.6087 (1.8);1.6019 (1.6); 1.5936 (1.8); 1.5866 (2.2); 1.3827 (1.3); 1.3769 (0.9);1.3681 (2.8); 1.3625 (3.3); 1.3580 (3.1); 1.3404 (3.8); 1.3260 (1.0);1.3200 (1.9); 1.3082 (0.8); 1.2818 (13.5); 1.2713 (13.8); 1.2669 (11.4);1.2613 (10.9); 1.2561 (10.6); 1.2511 (9.8); 1.2366 (0.9); 1.2199 (0.6);1.2095 (0.6); 1.1849 (1.0); 1.1788 (0.8); 1.1645 (2.0); 1.1439 (1.8);1.1296 (1.6); 1.1238 (1.8); 1.1087 (3.0); 1.0866 (2.7); 1.0715 (1.0);1.0656 (1.0); 0.8913 (0.4); 0.8806 (0.6); 0.8685 (0.5); −0.0001 (25.6)III-12: 1H-NMR(599.7 MHz, CDCl3): δ = 7.4289 (0.4); 7.4021 (1.1); 7.3746(9.5); 7.3704 (17.8); 7.3606 (10.1); 7.3517 (7.2); 7.3306 (1.5); 7.3239(1.5); 7.3163 (1.3); 7.3078 (1.5); 7.3030 (1.6); 7.2982 (1.7); 7.2932(1.9); 7.2884 (1.6); 7.2838 (1.6); 7.2572 (41.5); 7.1535 (3.0); 7.1439(2.7); 6.9493 (1.2); 6.9367 (1.1); 6.8913 (0.9); 6.8769 (1.4); 6.8626(0.7); 6.7722 (1.5); 6.7481 (1.2); 5.2940 (50.0); 5.2216 (0.5); 5.2009(4.0); 5.1921 (2.0); 5.1829 (3.0); 5.1768 (2.8); 5.1560 (0.4); 4.7023(9.4); 4.6007 (0.9); 4.5936 (1.0); 4.5874 (0.9); 3.7731 (1.6); 3.7663(1.6); 3.7443 (1.8); 3.7374 (1.6); 3.4806 (0.8); 3.1838 (1.9); 3.1778(1.6); 3.1550 (1.6); 3.1491 (1.4); 3.0765 (0.5); 3.0616 (0.6); 3.0446(0.8); 3.0297 (0.4); 3.0021 (0.8); 2.9748 (0.6); 2.9611 (0.7); 2.9434(0.4); 2.9253 (0.4); 2.9122 (0.4); 2.5316 (0.6); 2.5031 (0.5); 2.4618(0.7); 2.4355 (1.2); 2.4032 (0.5); 2.3561 (0.6); 2.3247 (0.5); 1.9480(1.5); 1.9273 (1.4); 1.7044 (11.1); 1.6976 (10.0); 1.6836 (1.7); 1.6090(1.4); 1.5870 (1.5); 1.5489 (1.9); 1.3824 (0.6); 1.3626 (1.5); 1.3412(1.4); 1.3202 (0.7); 1.2579 (0.8); 1.1852 (0.5); 1.1654 (0.8); 1.1443(0.8); 1.1298 (0.9); 1.1243 (0.9); 1.1094 (1.5); 1.0912 (1.3); 1.0719(0.5); −0.0001 (15.1) III-13: 1H-NMR(400.6 MHz, CDCl3): δ = 7.5195(1.4); 7.2898 (0.6); 7.2757 (0.5); 7.2734 (0.7); 7.2709 (0.7); 7.2693(0.8); 7.2611 (264.4); 7.1805 (2.4); 7.1777 (2.7); 7.1748 (3.4); 7.1720(2.7); 7.1638 (1.7); 7.1609 (3.4); 7.1583 (2.9); 7.1552 (3.0); 7.1526(1.5); 6.9974 (1.5); 6.9441 (0.9); 6.9253 (1.0); 6.9179 (1.2); 6.9121(1.4); 6.9063 (0.7); 6.8962 (1.3); 6.8904 (2.2); 6.8847 (1.2); 6.8746(0.7); 6.8688 (1.1); 6.8630 (0.6); 6.6986 (1.4); 6.6938 (1.6); 6.6882(1.6); 6.6823 (0.9); 6.6766 (1.0); 6.6715 (0.7); 6.1900 (2.0); 6.1855(1.1); 6.1632 (2.3); 6.1587 (1.3); 6.1469 (2.5); 6.1424 (1.4); 6.1201(2.5); 6.1156 (1.4); 5.5500 (1.9); 5.5487 (2.0); 5.5421 (3.3); 5.5407(3.3); 5.5069 (1.6); 5.5057 (1.7); 5.4990 (2.8); 5.4976 (2.8); 5.3570(1.6); 5.3461 (2.9); 5.3448 (2.9); 5.3312 (1.5); 5.3193 (2.7); 5.3181(2.7); 5.0928 (0.7); 5.0893 (1.0); 5.0772 (1.8); 5.0736 (1.4); 5.0616(2.4); 5.0581 (1.1); 5.0460 (1.8); 5.0303 (0.7); 4.6133 (0.7); 4.6103(0.8); 4.6003 (1.2); 4.5934 (0.8); 4.5905 (1.2); 4.5806 (1.2); 4.5705(0.7); 3.9366 (2.0); 3.9308 (3.7); 3.8936 (2.3); 3.8878 (4.2); 3.3367(3.6); 3.3303 (2.0); 3.3118 (0.6); 3.2936 (3.1); 3.2872 (1.8); 3.0253(0.6); 3.0200 (0.6); 3.0151 (0.6); 3.0095 (0.7); 3.0048 (0.8); 3.0001(0.8); 2.9958 (0.8); 2.9878 (0.8); 2.9824 (0.9); 2.9768 (0.8); 2.9674(0.9); 2.9615 (0.9); 2.9545 (0.8); 2.9497 (0.6); 2.9350 (0.6); 2.4660(0.5); 2.4605 (0.8); 2.4562 (0.9); 2.4518 (0.8); 2.4467 (0.6); 2.4236(0.9); 2.4199 (1.4); 2.4132 (1.2); 2.4098 (1.3); 2.3725 (0.9); 2.3661(0.8); 2.3624 (0.5); 1.6425 (5.8); 1.2844 (5.8); 1.2810 (5.8); 1.2731(11.2); 1.2691 (16.0); 1.2655 (6.9); 1.2575 (10.9); 1.2536 (10.8);1.2247 (0.7); 1.2092 (0.7); 0.0080 (3.5); −0.0002 (135.6); −0.0085 (4.1)III-14: 1H-NMR(599.7 MHz, CDCl3): δ = 7.2575 (50.0); 7.1688 (2.7);7.1576 (2.6); 6.9144 (1.0); 6.9013 (0.9); 6.8862 (1.3); 6.8719 (0.7);6.7941 (1.5); 6.7814 (0.7); 6.1771 (0.7); 6.1594 (0.8); 6.1489 (1.0);6.1305 (0.8); 5.5373 (1.7); 5.5086 (1.5); 5.3510 (0.7); 5.3409 (1.6);5.3230 (1.5); 4.6102 (0.8); 4.4145 (0.7); 4.4029 (2.4); 4.3923 (3.2);4.3833 (1.5); 3.9288 (0.7); 3.9208 (1.5); 3.9000 (0.7); 3.8921 (1.7);3.7251 (0.7); 3.7136 (2.7); 3.7038 (3.5); 3.6941 (1.6); 3.3250 (1.7);3.2964 (1.5); 3.0474 (0.7); 3.0338 (0.6); 3.0182 (1.0); 3.0051 (1.0);2.9844 (0.7); 2.9719 (0.7); 2.5126 (0.3); 2.4826 (1.0); 2.4440 (0.8);2.4063 (0.9); 1.5549 (3.5); −0.0001 (16.1) III-15: 1H-NMR(599.7 MHz,CDCl3): δ = 7.2939 (0.3); 7.2832 (0.4); 7.2721 (0.4); 7.2575 (50.0);7.2487 (0.4); 7.1705 (1.9); 7.1586 (1.9); 7.0806 (0.3); 6.8988 (1.0);6.8840 (1.1); 6.8695 (0.5); 6.7628 (1.0); 6.7465 (0.8); 6.1751 (0.6);6.1675 (0.5); 6.1573 (0.7); 6.1465 (0.8); 6.1387 (0.5); 6.1285 (0.7);6.1208 (0.6); 5.5407 (1.1); 5.5341 (1.4); 5.5118 (1.0); 5.5053 (1.2);5.3472 (1.0); 5.3368 (1.3); 5.3294 (1.0); 5.3190 (1.3); 4.6222 (0.3);4.6153 (0.5); 4.6087 (0.7); 4.6021 (0.8); 4.5955 (0.7); 4.5891 (0.6);4.5823 (0.4); 4.3069 (1.2); 4.3026 (1.7); 4.2954 (2.0); 4.2904 (1.4);4.2833 (0.8); 3.9256 (1.0); 3.9174 (1.3); 3.8970 (1.1); 3.8887 (1.5);3.6408 (1.1); 3.6326 (2.0); 3.6296 (1.9); 3.6216 (2.5); 3.6137 (1.4);3.3960 (6.8); 3.3843 (8.7); 3.3218 (1.5); 3.3144 (1.1); 3.2931 (1.3);3.2857 (1.1); 3.0420 (0.5); 3.0287 (0.5); 3.0110 (0.3); 2.9976 (0.6);2.9642 (0.5); 2.9513 (0.5); 2.5103 (0.3); 2.4824 (0.7); 2.4548 (0.4);2.4230 (0.4); 2.3885 (0.6); 2.3522 (0.3); −0.0001 (25.2) III-16:1H-NMR(599.7 MHz, CDCl3): δ = 7.2579 (50.0); 7.1702 (2.2); 7.1602 (2.1);6.8984 (1.1); 6.8836 (1.3); 6.8692 (0.6); 6.7563 (1.2); 6.7404 (0.8);6.1765 (0.8); 6.1684 (0.5); 6.1586 (0.8); 6.1478 (1.0); 6.1396 (0.6);6.1298 (0.9); 6.1216 (0.6); 5.5409 (1.2); 5.5348 (1.7); 5.5121 (1.1);5.5060 (1.6); 5.3469 (1.2); 5.3371 (1.6); 5.3290 (1.1); 5.3192 (1.6);4.6225 (0.3); 4.6156 (0.6); 4.6093 (0.7); 4.6026 (0.9); 4.5961 (0.8);4.5895 (0.7); 4.5827 (0.4); 4.3071 (0.8); 4.3043 (0.7); 4.2993 (1.3);4.2955 (1.9); 4.2880 (2.3); 4.2828 (1.7); 4.2753 (0.9); 3.9271 (1.2);3.9182 (1.6); 3.8984 (1.3); 3.8896 (1.8); 3.6774 (1.2); 3.6690 (2.2);3.6658 (2.1); 3.6575 (3.1); 3.6495 (1.7); 3.5637 (0.6); 3.5519 (2.7);3.5402 (4.4); 3.5285 (3.2); 3.5168 (0.9); 3.3220 (1.7); 3.3146 (1.2);3.2933 (1.6); 3.2859 (1.1); 3.0388 (0.6); 3.0254 (0.6); 3.0077 (0.4);2.9972 (0.6); 2.9648 (0.6); 2.9519 (0.5); 2.5043 (0.4); 2.4795 (0.8);2.4763 (0.8); 2.4517 (0.4); 2.4224 (0.5); 2.3882 (0.7); 2.3528 (0.3);1.5720 (1.6); 1.2274 (1.8); 1.2155 (6.0); 1.2035 (6.9); 1.1918 (2.7);−0.0001 (16.3) III-17: 1H-NMR(400.0 MHz, CDCl3): δ = 7.5181 (2.9);7.3094 (1.6); 7.2592 (503.4); 7.2480 (3.3); 7.2092 (0.8); 7.1764 (3.7);7.1708 (4.3); 7.1568 (4.5); 6.9953 (2.7); 6.9076 (2.7); 6.8921 (2.0);6.8863 (2.8); 6.8645 (1.5); 6.7114 (1.8); 6.7050 (1.8); 6.6998 (2.2);6.6946 (1.6); 6.2184 (1.8); 6.1893 (1.7); 6.1829 (2.0); 6.1625 (1.8);6.1562 (2.4); 6.1462 (1.9); 6.1397 (2.4); 6.1193 (2.0); 6.1130 (2.5);5.8282 (2.1); 5.5474 (3.7); 5.5418 (2.8); 5.5042 (3.3); 5.4987 (2.4);5.3541 (3.3); 5.3439 (2.4); 5.3279 (3.1); 5.3159 (2.3); 4.6282 (1.1);4.6175 (1.8); 4.6076 (1.5); 4.5978 (1.8); 4.5872 (1.3); 4.5757 (0.8);4.2370 (1.9); 4.2192 (5.6); 4.2072 (4.1); 4.2014 (6.0); 4.1895 (4.1);4.1837 (2.1); 4.1718 (1.4); 3.9366 (3.7); 3.9287 (3.0); 3.8935 (4.3);3.8855 (3.3); 3.7938 (12.5); 3.3318 (3.0); 3.3252 (3.9); 3.2887 (2.7);3.2821 (3.3); 3.0645 (0.8); 3.0227 (1.2); 3.0079 (1.2); 3.0018 (1.2);2.9746 (1.3); 2.9078 (0.7); 2.5006 (1.0); 2.4629 (1.2); 2.4195 (1.4);2.3765 (1.2); 2.3412 (0.8); 1.5342 (10.7); 1.4033 (5.8); 1.3871 (5.8);1.3825 (1.2); 1.3285 (0.7); 1.3175 (7.6); 1.3105 (2.0); 1.3056 (6.3);1.2997 (16.0); 1.2878 (11.9); 1.2819 (8.0); 1.2699 (5.6); 0.9005 (1.0);0.8851 (1.1); 0.1461 (1.1); 0.1032 (1.1); 0.0985 (0.9); 0.0955 (0.7);0.0919 (1.1); 0.0775 (1.2); 0.0696 (0.8); 0.0501 (0.9); 0.0080 (10.3);−0.0002 (282.2); −0.0085 (10.1); −0.1493 (1.0) III-18: 1H-NMR(400.0 MHz,CDCl3): δ = 7.3780 (11.2); 7.3749 (8.0); 7.3668 (35.5); 7.3558 (31.0);7.3483 (6.7); 7.3397 (6.1); 7.3342 (2.8); 7.3319 (3.4); 7.3289 (2.6);7.3268 (3.4); 7.3184 (2.6); 7.3116 (1.1); 7.3056 (0.9); 7.2593 (73.6);7.1854 (1.4); 7.1727 (6.9); 7.1675 (8.7); 7.1567 (5.6); 7.1527 (8.4);7.1478 (6.6); 7.1411 (1.1); 7.1353 (1.2); 6.9330 (2.4); 6.9112 (3.7);6.9070 (4.0); 6.9011 (2.0); 6.8909 (3.0); 6.8894 (3.1); 6.8851 (5.1);6.8837 (4.9); 6.8793 (2.7); 6.8692 (1.6); 6.8678 (1.6); 6.8634 (2.5);6.8577 (1.3); 6.7818 (1.0); 6.7757 (2.8); 6.7698 (3.4); 6.7656 (3.8);6.7597 (3.0); 6.7547 (3.6); 6.7496 (2.6); 6.7434 (0.9); 6.1840 (3.8);6.1750 (3.7); 6.1572 (4.3); 6.1482 (4.2); 6.1409 (4.6); 6.1318 (4.4);6.1141 (4.6); 6.1050 (4.4); 5.5416 (6.5); 5.5402 (6.8); 5.5369 (6.6);5.5354 (6.5); 5.4984 (5.7); 5.4971 (5.8); 5.4938 (5.8); 5.4923 (5.5);5.3479 (5.7); 5.3467 (5.6); 5.3400 (5.8); 5.3387 (5.5); 5.3211 (5.3);5.3200 (5.2); 5.3132 (5.3); 5.3119 (5.1); 5.2164 (0.9); 5.1963 (16.0);5.1853 (13.2); 5.1817 (13.0); 5.1681 (0.5); 5.1650 (0.5); 5.1505 (0.7);5.1168 (0.5); 4.6412 (0.9); 4.6317 (1.4); 4.6213 (2.7); 4.6096 (2.8);4.6012 (2.9); 4.5898 (2.6); 4.5795 (1.4); 4.5699 (0.9); 3.9311 (6.4);3.9209 (6.5); 3.8880 (7.2); 3.8778 (7.5); 3.3337 (1.9); 3.3292 (6.9);3.3222 (6.6); 3.2861 (6.0); 3.2791 (5.6); 3.2730 (0.8); 3.2507 (0.5);3.0967 (1.0); 3.0917 (1.1); 3.0767 (1.1); 3.0713 (1.3); 3.0652 (1.4);3.0596 (1.6); 3.0543 (1.7); 3.0494 (1.7); 3.0444 (1.7); 3.0395 (1.6);3.0342 (1.6); 3.0288 (1.5); 3.0229 (1.5); 3.0165 (1.9); 3.0079 (1.3);3.0026 (1.5); 2.9969 (1.9); 2.9884 (1.0); 2.9799 (1.1); 2.9733 (1.2);2.9669 (1.5); 2.9608 (1.8); 2.9553 (1.4); 2.9477 (1.3); 2.9417 (1.2);2.9329 (1.2); 2.9275 (1.1); 2.9184 (0.6); 2.9129 (1.0); 2.9076 (1.0);2.5323 (1.2); 2.5271 (1.5); 2.5222 (1.6); 2.5167 (1.3); 2.5018 (1.4);2.4967 (1.6); 2.4909 (2.2); 2.4859 (2.0); 2.4799 (1.6); 2.4745 (1.1);2.4599 (1.1); 2.4550 (1.4); 2.4492 (1.5); 2.4444 (1.5); 2.4375 (1.3);2.4325 (1.3); 2.4261 (1.4); 2.3942 (1.8); 2.3884 (2.2); 2.3841 (2.2);2.3781 (1.6); 2.3518 (0.9); 2.3468 (1.2); 2.3413 (1.2); 2.3366 (0.8);1.7792 (0.7); 0.8777 (0.5); 0.0079 (3.0); −0.0002 (93.3); −0.0085 (3.0)III-19: 1H-NMR(400.0 MHz, CDCl3): δ = 7.2609 (16.0); 7.2019 (1.8);7.1992 (2.5); 7.1963 (2.6); 7.1938 (2.3); 7.1830 (2.5); 7.1803 (2.5);7.1775 (2.0); 7.1747 (1.3); 6.9733 (1.0); 6.9676 (1.1); 6.9619 (0.8);6.9518 (1.0); 6.9460 (1.6); 6.9404 (1.0); 6.9245 (1.0); 6.9188 (0.9);6.7538 (0.7); 6.7475 (1.1); 6.7430 (0.6); 6.7266 (0.7); 6.7216 (0.9);6.7162 (0.7); 5.2988 (8.3); 4.6740 (0.8); 4.6636 (0.9); 4.6539 (0.9);4.6436 (0.8); 4.6337 (0.5); 3.9905 (1.2); 3.9436 (1.3); 3.9404 (1.3);3.7649 (16.0); 3.7612 (3.9); 3.7529 (14.0); 3.7417 (0.6); 3.7297 (1.0);3.7199 (1.6); 3.7160 (1.6); 3.6852 (0.8); 3.0616 (0.6); 3.0562 (0.8);3.0367 (0.6); 3.0165 (0.6); 3.0128 (0.6); 2.9971 (0.8); 2.9930 (0.6);2.5182 (0.7); 2.5140 (0.7); 2.5083 (0.8); 2.4801 (0.6); 2.4748 (0.5);2.4707 (0.5); 2.4382 (0.7); 2.4344 (0.7); 2.4281 (0.5); 1.4321 (2.7);0.0079 (0.6); −0.0002 (20.5); −0.0085 (0.8) III-20: 1H-NMR(400.0 MHz,CDCl3): δ = 7.2600 (12.6); 7.1697 (0.7); 7.1663 (1.0); 7.1635 (0.9);7.1605 (1.1); 7.1561 (0.7); 7.1499 (1.0); 7.1465 (0.9); 7.1441 (0.8);7.1408 (0.6); 6.8666 (0.6); 3.8038 (0.5); 3.7982 (0.6); 3.7963 (0.6);3.7605 (0.6); 3.7549 (0.7); 3.7532 (0.7); 3.7479 (0.5); 3.1958 (0.8);3.1913 (0.5); 3.1525 (0.7); 1.7219 (2.9); 1.7151 (4.3); 1.7072 (2.6);1.5457 (0.6); 1.4790 (10.7); 1.4408 (16.0); 1.4257 (11.4); −0.0002(14.6); −0.0085 (0.6) III-21: 1H-NMR(400.0 MHz, CDCl3): δ = 7.2595(81.0); 7.1805 (0.7); 7.1699 (2.5); 7.1677 (3.0); 7.1643 (3.6); 7.1620(3.4); 7.1503 (3.2); 7.1481 (3.5); 7.1446 (2.9); 7.1425 (2.2); 7.1321(0.5); 6.9955 (0.5); 6.9725 (1.1); 6.9537 (1.1); 6.9115 (0.7); 6.9055(1.1); 6.9015 (0.7); 6.8914 (1.2); 6.8896 (1.4); 6.8857 (2.0); 6.8839(2.0); 6.8799 (1.2); 6.8680 (0.7); 6.8639 (1.0); 6.8581 (0.6); 6.8074(1.7); 6.7945 (0.6); 6.7881 (1.1); 6.7830 (1.5); 6.7780 (1.1); 4.6250(0.8); 4.6146 (1.2); 4.6053 (1.4); 4.5948 (1.5); 4.5855 (1.2); 4.5750(0.8); 4.5390 (0.5); 4.5244 (0.7); 4.4253 (2.9); 4.4112 (3.9); 4.4088(3.0); 4.4000 (1.2); 4.3966 (3.9); 4.3938 (3.4); 4.3916 (2.8); 4.3782(2.3); 3.7881 (3.0); 3.7829 (2.8); 3.7714 (0.8); 3.7567 (0.7); 3.7534(0.7); 3.7448 (3.4); 3.7395 (4.2); 3.7377 (4.6); 3.7230 (4.6); 3.7198(4.4); 3.7088 (4.4); 3.7051 (4.7); 3.6910 (3.3); 3.2049 (2.9); 3.1987(3.0); 3.1616 (2.5); 3.1554 (2.6); 3.0750 (0.6); 3.0553 (1.2); 3.0485(0.8); 3.0358 (1.0); 3.0162 (0.6); 3.0118 (0.7); 3.0062 (1.1); 2.9920(1.1); 2.9874 (1.2); 2.9730 (0.7); 2.9683 (0.7); 2.5420 (0.6); 2.5369(0.7); 2.5320 (0.7); 2.5269 (0.6); 2.4945 (0.6); 2.4897 (0.6); 2.4838(0.6); 2.4689 (1.1); 2.4628 (1.0); 2.4582 (0.9); 2.4289 (0.8); 2.4245(0.8); 2.4183 (1.1); 2.4142 (0.8); 2.3894 (0.6); 2.3836 (0.6); 1.7768(0.6); 1.7257 (1.8); 1.7151 (16.0); 1.7074 (15.4); 1.5369 (6.1); 1.4511(3.8); 0.0080 (3.5); −0.0002 (105.7); −0.0085 (3.4) III-22: 1H-NMR(400.0MHz, CDCl3): δ = 7.2611 (21.8); 7.2160 (0.6); 7.2136 (0.7); 7.2031(3.1); 7.2005 (4.1); 7.1974 (4.8); 7.1949 (4.4); 7.1840 (4.4); 7.1815(4.7); 7.1784 (3.9); 7.1759 (2.8); 7.1652 (0.5); 6.9719 (2.0); 6.9663(2.5); 6.9607 (1.7); 6.9503 (2.1); 6.9448 (3.2); 6.9392 (1.7); 6.9293(1.1); 6.9234 (1.6); 6.9177 (0.8); 6.7486 (0.6); 6.7430 (1.5); 6.7367(2.0); 6.7284 (0.7); 6.7210 (0.6); 6.7149 (1.5); 6.7097 (2.0); 6.7046(1.5); 5.2986 (8.4); 4.6911 (0.6); 4.6812 (1.1); 4.6712 (2.0); 4.6613(2.2); 4.6514 (2.4); 4.6414 (1.8); 4.6316 (1.2); 4.6216 (0.6); 4.2468(1.6); 4.2347 (1.8); 4.2292 (5.2); 4.2171 (5.4); 4.2114 (5.6); 4.1993(5.8); 4.1936 (2.1); 4.1814 (2.2); 3.9868 (2.2); 3.9416 (3.3); 3.7650(4.7); 3.7614 (4.9); 3.7198 (3.2); 3.7162 (3.4); 3.1176 (0.6); 3.1126(0.6); 3.0977 (0.6); 3.0925 (0.6); 3.0750 (0.7); 3.0699 (0.8); 3.0604(0.8); 3.0553 (1.5); 3.0502 (1.2); 3.0449 (0.7); 3.0334 (1.0); 3.0174(0.6); 3.0137 (1.0); 3.0088 (0.8); 3.0033 (0.9); 2.9980 (1.3); 2.9937(1.5); 2.9785 (0.7); 2.9727 (0.6); 2.9510 (0.6); 2.9456 (0.6); 2.9312(0.6); 2.9259 (0.6); 2.5578 (0.7); 2.5526 (0.9); 2.5478 (0.9); 2.5425(0.7); 2.5190 (0.8); 2.5147 (1.5); 2.5103 (1.5); 2.5049 (1.5); 2.5004(0.9); 2.4773 (1.4); 2.4736 (1.3); 2.4676 (1.2); 2.4635 (0.9); 2.4424(0.6); 2.4358 (1.0); 2.4318 (1.4); 2.4263 (1.4); 2.4217 (1.0); 2.3899(0.5); 2.3852 (0.7); 2.3794 (0.7); 1.3237 (7.5); 1.3139 (7.4); 1.3059(16.0); 1.2961 (15.1); 1.2881 (7.9); 1.2783 (7.3); 1.2717 (0.8); 1.2680(0.9); 1.2646 (1.1); 1.2556 (1.9); 1.2468 (0.5); 0.0080 (0.7); −0.0002(26.3); −0.0085 (1.0) III-23: 1H-NMR(400.0 MHz, CDCl3): δ = 7.5185(0.5); 7.2596 (87.9); 7.2026 (3.1); 7.1998 (4.2); 7.1969 (4.9); 7.1941(4.8); 7.1836 (4.7); 7.1808 (4.7); 7.1780 (4.3); 7.1751 (3.1); 6.9955(0.8); 6.9718 (1.9); 6.9671 (2.6); 6.9613 (1.9); 6.9513 (2.6); 6.9454(3.4); 6.9397 (2.0); 6.9299 (1.3); 6.9240 (1.6); 6.9184 (1.0); 6.7161(1.4); 6.7102 (2.0); 6.6890 (1.3); 6.6839 (1.7); 6.6787 (1.3); 5.2984(2.4); 5.1143 (0.7); 5.0986 (1.7); 5.0830 (2.5); 5.0694 (2.8); 5.0538(2.1); 5.0381 (1.0); 4.6751 (0.9); 4.6644 (1.4); 4.6556 (1.6); 4.6454(1.6); 4.6361 (1.3); 4.6264 (0.9); 3.9857 (2.5); 3.9570 (0.6); 3.9403(3.6); 3.7635 (4.3); 3.7600 (4.4); 3.7510 (0.9); 3.7461 (1.1); 3.7347(1.7); 3.7183 (3.0); 3.7148 (3.2); 3.7061 (0.6); 3.7010 (0.7); 3.1089(0.5); 3.1037 (0.5); 3.0887 (0.6); 3.0835 (0.5); 3.0662 (0.6); 3.0609(0.8); 3.0462 (1.6); 3.0262 (1.1); 3.0067 (1.1); 2.9963 (0.9); 2.9872(1.4); 2.9790 (0.9); 2.9708 (0.6); 2.9650 (0.5); 2.9432 (0.6); 2.9379(0.6); 2.9233 (0.6); 2.9183 (0.6); 2.5372 (0.8); 2.5324 (0.8); 2.5275(0.6); 2.5001 (1.4); 2.4957 (1.3); 2.4902 (1.3); 2.4619 (1.3); 2.4194(1.3); 2.4138 (1.2); 2.3726 (0.7); 1.7120 (0.5); 1.5828 (0.6); 1.3639(0.7); 1.3481 (0.9); 1.2881 (14.6); 1.2813 (13.4); 1.2768 (14.2); 1.2727(16.0); 1.2657 (14.0); 1.2614 (12.0); 1.2524 (2.7); 1.2489 (2.3); 1.2419(1.5); 1.2302 (1.5); 1.2261 (1.2); 1.2184 (0.9); 0.0080 (2.9); −0.0002(107.2); −0.0084 (4.6) III-24: 1H-NMR(400.0 MHz, CDCl3): δ = 7.2598(60.4); 7.2025 (2.2); 7.2002 (2.8); 7.1969 (3.5); 7.1947 (3.1); 7.1836(3.0); 7.1813 (3.4); 7.1779 (2.7); 6.9957 (0.8); 6.9739 (1.5); 6.9682(1.9); 6.9624 (1.3); 6.9525 (1.7); 6.9467 (2.5); 6.9410 (1.4); 6.9310(0.8); 6.9250 (1.2); 6.9193 (0.7); 6.8287 (1.0); 6.8228 (1.4); 6.7989(1.0); 6.7938 (1.4); 6.7888 (1.0); 4.6948 (0.6); 4.6841 (1.0); 4.6775(1.0); 4.6744 (0.9); 4.6674 (1.0); 4.6642 (1.0); 4.6578 (0.9); 4.6479(0.6); 4.5686 (12.9); 4.5541 (15.8); 4.5523 (9.8); 4.5393 (13.9); 4.4313(2.0); 4.4194 (4.8); 4.4057 (3.8); 4.4032 (4.7); 4.3912 (3.1); 3.9874(1.7); 3.9415 (2.4); 3.9301 (0.7); 3.7889 (14.0); 3.7759 (10.1); 3.7741(16.0); 3.7669 (4.1); 3.7628 (4.7); 3.7597 (13.4); 3.7396 (3.3); 3.7298(3.9); 3.7250 (4.6); 3.7219 (3.4); 3.7177 (4.8); 3.7155 (4.4); 3.7110(3.7); 3.7013 (3.1); 3.1003 (0.5); 3.0953 (0.6); 3.0803 (1.2); 3.0602(0.8); 3.0547 (0.7); 3.0410 (0.8); 3.0312 (0.6); 3.0253 (0.8); 3.0211(1.1); 3.0071 (0.9); 2.5750 (0.7); 2.5698 (0.6); 2.5643 (0.5); 2.5360(0.9); 2.5321 (1.1); 2.5263 (0.9); 2.5219 (0.7); 2.4985 (0.9); 2.4942(0.8); 2.4883 (0.7); 2.4601 (0.9); 2.4547 (1.0); 1.5359 (5.9); 0.0080(2.4); −0.0002 (74.2); −0.0085 (2.5) III-25: 1H-NMR(400.0 MHz, CDCl3): δ= 7.3806 (8.4); 7.3774 (6.2); 7.3694 (24.6); 7.3599 (21.6); 7.3515(4.5); 7.3425 (4.2); 7.3353 (2.9); 7.3315 (2.0); 7.3293 (2.3); 7.3243(1.4); 7.3221 (1.7); 7.3172 (0.9); 7.3145 (1.0); 7.3078 (0.6); 7.2586(30.8); 7.2082 (1.0); 7.2023 (1.1); 7.1952 (5.0); 7.1905 (6.5); 7.1800(4.3); 7.1759 (6.3); 7.1713 (4.9); 7.1643 (0.9); 7.1582 (0.9); 6.9681(2.9); 6.9623 (3.5); 6.9568 (2.5); 6.9465 (2.9); 6.9408 (4.6); 6.9351(2.4); 6.9250 (1.5); 6.9192 (2.2); 6.9136 (1.2); 6.8010 (0.7); 6.7950(2.0); 6.7902 (2.4); 6.7847 (2.1); 6.7711 (0.7); 6.7650 (1.9); 6.7598(2.6); 6.7548 (1.9); 6.7487 (0.7); 5.3025 (0.6); 5.2965 (12.6); 5.2380(0.6); 5.2069 (9.3); 5.2033 (9.2); 5.1905 (16.0); 5.1722 (0.6); 4.6924(0.7); 4.6833 (1.3); 4.6727 (2.0); 4.6637 (2.4); 4.6534 (2.3); 4.6441(1.9); 4.6341 (1.2); 4.6245 (0.6); 3.9815 (2.3); 3.9757 (2.4); 3.9363(3.3); 3.9304 (3.5); 3.7588 (6.6); 3.7556 (6.4); 3.7136 (4.5); 3.7104(4.4); 3.1428 (0.7); 3.1379 (0.7); 3.1228 (0.8); 3.1177 (0.8); 3.1002(0.9); 3.0952 (0.9); 3.0899 (0.7); 3.0847 (1.1); 3.0797 (1.5); 3.0748(1.2); 3.0699 (0.8); 3.0643 (1.2); 3.0595 (1.2); 3.0506 (0.6); 3.0419(1.6); 3.0368 (1.6); 3.0274 (0.5); 3.0215 (1.0); 3.0156 (1.3); 3.0084(1.2); 3.0025 (1.1); 2.9959 (1.2); 2.9888 (1.1); 2.9827 (0.8); 2.9767(0.7); 2.9549 (0.8); 2.9497 (0.8); 2.9350 (0.8); 2.9298 (0.7); 2.5837(0.9); 2.5785 (1.1); 2.5735 (1.1); 2.5682 (0.9); 2.5410 (1.6); 2.5361(2.0); 2.5311 (2.0); 2.5261 (1.5); 2.4989 (0.9); 2.4932 (1.0); 2.4899(1.6); 2.4846 (1.5); 2.4801 (1.8); 2.4748 (1.1); 2.4692 (0.8); 2.4470(0.5); 2.4365 (1.7); 2.4305 (1.8); 2.4270 (1.6); 2.3940 (0.6); 2.3892(0.9); 2.3835 (0.8); 2.3787 (0.6); 2.0424 (1.7); 1.2757 (0.8); 1.2578(2.6); 1.2399 (0.6); 0.8818 (0.9); 0.0080 (1.2); −0.0002 (36.3); −0.0085(1.2) III-26: 1H-NMR(400.0 MHz, CDCl3): δ = 7.2607 (9.4); 7.2048 (0.9);7.1991 (1.6); 7.1953 (1.5); 7.1898 (1.3); 7.1839 (1.4); 7.1799 (1.5);6.9668 (0.6); 6.9502 (0.8); 6.9450 (0.9); 6.9286 (0.8); 6.9229 (0.6);3.9865 (0.8); 3.9547 (0.5); 3.9412 (1.2); 3.7642 (1.1); 3.7604 (1.0);3.7494 (0.6); 3.7442 (0.7); 3.7189 (0.7); 3.7152 (0.7); 1.5551 (0.6);1.4993 (13.0); 1.4900 (16.0); 1.4794 (12.2); 1.4497 (10.6); 1.4452(5.7); 1.4339 (4.2); 1.2864 (0.6); 1.2647 (1.9); 0.8986 (1.0); 0.8818(3.2); 0.8640 (1.3); −0.0002 (12.1) III-27: 1H-NMR(400.0 MHz, CDCl3): δ= 7.2609 (15.6); 7.2044 (1.2); 7.2011 (1.9); 7.1985 (2.0); 7.1955 (2.1);7.1852 (1.9); 7.1820 (2.0); 7.1796 (1.8); 7.1763 (1.3); 6.9718 (1.0);6.9661 (1.2); 6.9602 (0.8); 6.9503 (1.2); 6.9445 (1.6); 6.9388 (0.8);6.9288 (0.5); 6.9230 (0.8); 6.7948 (0.6); 6.7905 (0.7); 6.7846 (0.6);6.7642 (0.7); 6.7590 (1.0); 6.7539 (0.7); 5.2985 (7.5); 4.6725 (0.8);4.6628 (0.9); 4.6528 (0.9); 4.6431 (0.7); 4.4442 (0.6); 4.4324 (0.6);4.4205 (0.7); 4.3295 (1.0); 4.3267 (1.1); 4.3181 (1.5); 4.3147 (2.3);4.3058 (2.0); 4.3031 (2.0); 4.3001 (1.1); 4.2915 (1.3); 3.9840 (1.0);3.9388 (1.4); 3.7645 (1.8); 3.7601 (2.2); 3.7193 (1.2); 3.7149 (1.5);3.6937 (0.7); 3.6817 (0.7); 3.6700 (0.7); 3.6512 (2.0); 3.6462 (0.6);3.6414 (2.9); 3.6394 (2.5); 3.6323 (1.4); 3.6275 (2.9); 3.6179 (1.5);3.4000 (16.0); 3.3979 (6.0); 3.3897 (12.4); 3.3842 (1.3); 3.0721 (0.5);3.0087 (0.6); 2.5327 (0.6); 2.5272 (0.6); 2.5227 (0.5); 2.4902 (0.6);2.4805 (0.6); 2.4374 (0.6); 2.4323 (0.6); 1.5584 (1.2); 0.0080 (0.6);−0.0002 (19.0); −0.0085 (0.6) III-28: 1H-NMR(400.0 MHz, CDCl3): δ =7.2627 (6.0); 7.1713 (0.8); 7.1675 (1.4); 7.1654 (1.4); 7.1620 (1.4);7.1546 (0.8); 7.1513 (1.4); 7.1479 (1.4); 7.1459 (1.4); 7.1422 (0.9);6.9639 (0.5); 6.9443 (0.5); 6.8879 (0.5); 6.8836 (0.8); 6.8823 (0.9);6.7747 (0.7); 6.7699 (0.5); 6.7493 (0.7); 5.2993 (16.0); 4.6060 (0.6);4.5960 (0.7); 4.5861 (0.7); 4.5761 (0.6); 4.3233 (0.7); 4.3212 (0.8);4.3121 (1.0); 4.3089 (1.0); 4.3068 (1.0); 4.3053 (1.2); 4.3021 (1.0);4.2995 (1.1); 4.2976 (1.2); 4.2947 (1.2); 4.2888 (0.9); 4.2813 (0.8);4.2787 (0.8); 3.7887 (1.2); 3.7837 (1.2); 3.7455 (1.3); 3.7404 (1.4);3.6503 (1.2); 3.6383 (1.4); 3.6330 (1.6); 3.6266 (1.4); 3.6211 (1.5);3.6094 (1.2); 3.4005 (9.4); 3.3841 (9.5); 3.2025 (1.2); 3.1956 (1.2);3.1591 (1.1); 3.1523 (1.1); 1.7133 (6.7); 1.7055 (6.8); −0.0002 (7.8)

Analytical data of Examples IV-01-IV-07 (see Table 1.2)

IV-01: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.5185 (3.2); 7.3946 (2.9); 7.3751(5.2); 7.3667(5.3); 7.3183 (1.0); 7.2822 (1.9); 7.2595 (613.7); 7.2269(1.1); 7.1511 (1.1); 7.1282 (1.3); 7.1147 (1.0); 7.0275 (1.1); 6.9955(3.5); 5.8829 (1.6); 5.8591 (1.7); 4.5792 (1.1); 4.5682 (1.3); 4.5600(1.2); 4.5481 (1.4); 3.8296 (2.3); 3.8108 (2.5); 3.7864 (2.4); 3.7678(2.7); 3.2319 (2.8); 3.2262 (2.5); 3.1886 (2.4); 3.1828 (2.3); 2.9973(3.5); 1.7137 (16.0); 1.7109 (15.6); 1.5423 (20.1); 1.3324 (1.2); 1.2841(1.8); 1.2556 (4.3); 0.1458 (0.9); 0.0081 (7.0); −0.0002 (213.1);−0.0084 (6.3); −0.1499 (0.8) IV-02: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.8094(0.7); 7.6103 (0.7); 7.5185 (2.4); 7.5098 (0.6); 7.4131 (0.6); 7.3945(2.8); 7.3809 (3.5); 7.3756 (5.0); 7.3703 (4.0); 7.3669 (5.3); 7.3641(4.0); 7.3573 (1.6); 7.3090 (0.9); 7.3051 (0.9); 7.2970 (1.4); 7.2922(1.9); 7.2852 (1.1); 7.2822 (1.1); 7.2788 (1.1); 7.2752 (3.3); 7.2696(3.5); 7.2671 (5.5); 7.2597 (437.4); 7.2510 (2.6); 7.2469 (2.1); 7.2419(1.9); 7.2388 (0.8); 7.2249 (0.9); 7.2084 (0.8); 7.1572 (0.9); 7.1512(1.2); 7.1333 (1.3); 7.1297 (1.4); 7.1236 (1.0); 7.1146 (1.1); 7.1076(1.0); 7.0597 (0.8); 7.0267 (0.9); 7.0118 (1.0); 7.0072 (1.0); 6.9957(2.6); 5.8883 (1.1); 5.8832 (1.5); 5.8783 (1.1); 5.8642 (1.2); 5.8594(1.6); 4.5800 (1.1); 4.5681 (1.2); 4.5597 (1.2); 4.5483 (1.1); 4.5398(0.6); 3.8298 (2.3); 3.8110 (2.5); 3.7867 (2.6); 3.7678 (2.9); 3.2322(2.6); 3.2263 (2.6); 3.1889 (2.3); 3.1830 (2.2); 3.0504 (1.9); 3.0018(3.3); 2.8947 (0.5); 2.5923 (1.1); 2.5346 (0.5); 2.4876 (0.6); 2.4567(0.6); 2.4132 (0.6); 2.3693 (0.7); 2.3526 (0.7); 2.3025 (0.5); 1.7327(0.8); 1.7140 (16.0); 1.7110 (15.5); 1.5481 (6.3); 1.4445 (1.6); 1.3330(2.9); 1.2843 (4.0); 1.2551 (7.8); 0.8958 (0.6); 0.8803 (1.2); 0.8626(0.5); 0.0154 (1.0); 0.0079 (4.8); −0.0002 (151.0); −0.0086 (4.7);−0.0180 (0.8) IV-03: ¹H-NMR(400.0 MHz, CDCl3): δ = 8.2043 (0.8); 8.1666(0.8); 7.5187 (1.7); 7.3829 (3.9); 7.3780 (3.7); 7.3731 (4.1); 7.3701(3.8); 7.3662 (3.3); 7.2598 (298.6); 7.2297 (0.5); 7.1733 (0.8); 7.1581(1.6); 7.1342 (1.2); 7.1288 (0.9); 7.1206 (0.7); 7.0164 (0.8); 6.9958(2.5); 6.5143 (1.0); 6.4858 (1.0); 4.6151 (0.7); 4.6052 (1.2); 4.5946(1.2); 4.5853 (1.3); 4.5749 (0.9); 3.8758 (3.1); 3.8379 (3.3); 3.8199(16.0); 3.8094 (2.5); 3.7952 (15.8); 3.7805 (0.6); 3.7737 (2.5); 3.7661(2.7); 3.2397 (2.1); 3.2334 (2.2); 3.1964 (1.9); 3.1900 (2.0); 3.1790(0.5); 3.0021 (0.8); 2.9664 (0.6); 2.9560 (0.8); 2.9507 (1.1); 2.9307(0.7); 2.4963 (0.5); 2.4456 (0.6); 2.4245 (0.6); 2.3810 (0.7); 1.7129(12.1); 1.7074 (14.6); 1.5415 (26.6); 1.2842 (0.8); 1.2559 (1.6); 0.0080(3.1); −0.0002 (102.3); −0.0085 (3.1) IV-04: ¹H-NMR(400.0 MHz, CDCl3): δ= 8.1901 (1.0); 8.1543 (1.0); 7.5185 (1.9); 7.3866 (2.7); 7.3830 (4.3);7.3781 (4.3); 7.3732 (4.6); 7.3702 (4.6); 7.3663 (4.1); 7.2943 (0.7);7.2596 (343.5); 7.1718 (1.0); 7.1565 (1.8); 7.1346 (1.4); 7.1205 (0.8);7.1113 (0.6); 7.0138 (1.0); 6.9956 (3.0); 6.5139 (1.2); 6.4855 (1.1);4.6250 (0.5); 4.6149 (0.9); 4.6053 (1.4); 4.5953 (1.4); 4.5857 (1.5);4.5753 (1.0); 4.5656 (0.5); 3.8759 (3.0); 3.8381 (3.0); 3.8202 (15.8);3.8093 (2.9); 3.7955 (15.6); 3.7805 (0.7); 3.7737 (2.6); 3.7661 (3.0);3.2397 (2.4); 3.2333 (2.4); 3.2222 (0.5); 3.1964 (2.0); 3.1901 (2.1);3.0020 (0.9); 2.9829 (0.7); 2.9613 (0.7); 2.9563 (0.9); 2.9512 (1.2);2.9459 (1.0); 2.9366 (0.8); 2.9311 (0.8); 2.8996 (0.6); 2.5013 (0.5);2.4957 (0.5); 2.4406 (0.6); 2.4169 (0.7); 2.3736 (0.8); 2.3200 (0.6);2.1359 (0.6); 1.7131 (13.1); 1.7075 (16.0); 1.5386 (24.0); 1.4428 (1.2);1.3326 (0.5); 1.3051 (0.6); 1.2843 (1.2); 1.2650 (2.7); 0.8986 (1.4);0.8819 (4.3); 0.8641 (1.8); 0.1459 (0.5); 0.0079 (4.2); −0.0002 (125.5);−0.0085 (4.4); −0.1498 (0.5) IV-05: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.3960(1.7); 7.3910 (2.0); 7.3862 (3.0); 7.3834 (4.1); 7.3786 (4.6); 7.3739(3.8); 7.3703 (5.0); 7.3670 (3.9); 7.3639 (2.4); 7.2620 (87.0); 7.1609(0.7); 7.1558 (1.1); 7.1510 (0.7); 7.1419 (1.0); 7.1323 (1.4); 7.1260(0.9); 7.1172 (0.9); 7.1102 (0.5); 7.0242 (0.8); 7.0064 (0.7); 6.9980(1.0); 6.4684 (0.7); 6.4395 (0.7); 4.5935 (0.8); 4.5836 (0.8); 4.5744(0.8); 4.5638 (0.6); 3.8179 (2.6); 3.8155 (2.4); 3.7746 (3.0); 3.7723(2.7); 3.2377 (2.8); 3.2334 (2.9); 3.1945 (2.4); 3.1902 (2.6); 2.9779(0.6); 2.9578 (0.6); 2.9321 (0.7); 2.9128 (0.7); 2.6484 (6.7); 2.6229(6.9); 2.4992 (0.5); 2.4184 (0.9); 2.3714 (0.7); 2.3481 (0.6); 2.3430(0.6); 1.7146 (15.5); 1.7079 (16.0); 1.6088 (0.7); 1.2580 (0.6); 0.8817(0.9); 0.0079 (0.9); −0.0002 (31.0); −0.0085 (0.9) IV-06: ¹H-NMR(400.0MHz, CDCl3): δ = 7.3961 (1.8); 7.3911 (2.2); 7.3836 (4.3); 7.3787 (4.7);7.3741 (4.1); 7.3705 (5.1); 7.3672 (4.2); 7.3640 (2.6); 7.2622 (81.8);7.1612 (0.7); 7.1560 (1.1); 7.1510 (0.7); 7.1418 (1.0); 7.1326 (1.5);7.1262 (0.9); 7.1174 (0.9); 7.1104 (0.6); 7.0226 (0.8); 7.0055 (0.8);6.9982 (1.0); 6.4689 (0.8); 6.4390 (0.8); 4.6039 (0.6); 4.5940 (0.9);4.5843 (0.9); 4.5745 (0.9); 4.5641 (0.6); 3.8181 (2.8); 3.7748 (3.2);3.2380 (2.7); 3.2338 (3.1); 3.1947 (2.3); 3.1905 (2.7); 2.9784 (0.7);2.9585 (0.6); 2.9328 (0.8); 2.9180 (0.6); 2.9129 (0.8); 2.9085 (0.6);2.8873 (0.5); 2.8820 (0.5); 2.6490 (7.8); 2.6237 (7.4); 2.4998 (0.6);2.4231 (0.9); 2.4128 (0.8); 2.3715 (0.8); 2.3534 (0.5); 2.3485 (0.6);2.3431 (0.6); 2.3022 (0.5); 2.2975 (0.5); 1.7148 (16.0); 1.7081 (15.0);1.6149 (0.6); 1.4442 (1.6); 1.2562 (1.5); 0.0079 (0.9); −0.0002 (25.8);−0.0084 (1.0) IV-07: ¹H-NMR(400.0 MHz, CDCl3): δ = 8.2847 (1.2); 8.2381(1.1); 7.4014 (1.5); 7.3870 (3.2); 7.3812 (4.7); 7.3773 (3.8); 7.3731(4.4); 7.3674 (3.0); 7.3626 (2.2); 7.3598 (2.3); 7.2606 (78.9); 7.1662(0.8); 7.1610 (1.1); 7.1553 (0.7); 7.1451 (1.2); 7.1387 (1.7); 7.1327(0.8); 7.1292 (0.6); 7.1220 (1.0); 7.1157 (0.6); 7.0540 (1.2); 7.0363(1.2); 6.6811 (1.0); 6.6765 (1.4); 6.6648 (0.6); 6.6579 (1.0); 6.6529(1.4); 6.6484 (1.0); 4.6340 (0.5); 4.6245 (0.9); 4.6144 (1.4); 4.6045(1.3); 4.5946 (1.4); 4.5844 (0.9); 3.8252 (2.3); 3.8139 (2.3); 3.7819(2.6); 3.7706 (2.6); 3.3685 (16.0); 3.3485 (15.7); 3.2511 (2.5); 3.2408(2.6); 3.2078 (2.2); 3.1975 (2.2); 3.0867 (0.6); 3.0821 (0.6); 3.0607(1.1); 3.0370 (1.1); 3.0188 (0.9); 3.0138 (1.0); 2.5832 (0.6); 2.5783(0.6); 2.5468 (0.9); 2.5417 (1.0); 2.5367 (0.9); 2.5117 (0.6); 2.5052(0.8); 2.4877 (0.5); 2.4755 (0.9); 2.4701 (1.0); 2.4652 (0.8); 1.7158(14.0); 1.7085 (13.7); 1.5737 (5.3); 1.2651 (0.9); 0.8820 (1.3); 0.8643(0.5); 0.0080 (0.9); −0.0002 (28.1); −0.0084 (0.9) IV-08: ¹H-NMR(400.0MHz, CDCl3): δ = 7.5184 (3.1); 7.2596 (547.1); 7.2473 (0.8); 7.1773(2.1); 7.1714 (2.4); 7.1604 (3.6); 7.1575 (3.8); 7.1516 (2.9); 7.1460(2.5); 7.0590 (0.7); 6.9956 (3.0); 6.9084 (1.3); 6.8868 (2.3); 6.8650(1.2); 6.6661 (1.0); 5.4101 (1.2); 5.2985 (2.0); 4.6118 (0.8); 3.8159(2.6); 3.8038 (1.0); 3.7912 (1.6); 3.7727 (3.0); 3.7606 (1.2); 3.7481(1.8); 3.2199 (3.8); 3.2090 (1.2); 3.1813 (1.9); 3.1768 (3.1); 3.1657(1.3); 3.0441 (2.4); 3.0284 (1.4); 2.9399 (0.6); 2.5382 (0.8); 2.4685(0.8); 2.0498 (1.5); 1.9543 (1.0); 1.7916 (1.0); 1.7583 (16.0); 1.7179(8.0); 1.7104 (10.7); 1.2553 (1.0); 0.1459 (1.1); 0.0079 (10.7); −0.0002(307.0); −0.0085 (9.4); −0.1495 (1.0) IV-09: ¹H-NMR(400.0 MHz, CDCl3): δ= 7.5189 (1.0); 7.2600 (181.8); 7.1973 (2.5); 7.1829 (2.5); 6.9960(1.5); 6.9702 (1.2); 6.9541 (1.2); 6.9485 (1.7); 6.9268 (0.8); 6.8632(0.8); 6.8333 (0.9); 5.2995 (16.0); 4.6882 (0.8); 4.6681 (0.8); 3.9862(0.9); 3.9395 (1.2); 3.7702 (2.0); 3.7654 (1.7); 3.7250 (1.4); 3.0349(0.8); 2.5744 (2.4); 2.4870 (1.6); 2.0065 (1.0); 1.6417 (0.7); 1.2555(1.8); 1.0166 (1.4); 0.1460 (1.1); 0.0079 (8.0); −0.0002 (226.2);−0.0083 (9.4); −0.1493 (0.9) IV-11: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.5183(8.4); 7.2594 (1381.5); 7.2096 (12.1); 7.1794 (16.2); 7.1737 (19.7);7.1597 (20.3); 7.1540 (15.8); 6.9954 (8.3); 6.9569 (5.2); 6.9170 (5.2);6.9113 (7.7); 6.9058 (4.2); 6.8954 (9.2); 6.8896 (16.0); 6.8839 (8.1);6.8736 (4.9); 6.8680 (8.2); 6.8619 (5.7); 6.8497 (10.1); 6.8351 (7.5);6.1938 (8.4); 6.1832 (6.7); 6.1668 (9.3); 6.1564 (7.7); 6.1506 (10.4);6.1400 (7.8); 6.1238 (10.4); 6.1132 (8.3); 5.5505 (13.4); 5.5477 (14.8);5.5074 (11.0); 5.5046 (13.1); 5.3602 (11.1); 5.3494 (12.5); 5.3326(10.0); 5.3238 (11.8); 4.6458 (4.5); 4.6331 (5.2); 4.6260 (5.5); 4.6137(5.5); 4.6041 (3.2); 3.9429 (11.1); 3.9312 (14.2); 3.8999 (13.5); 3.8880(16.0); 3.3394 (14.0); 3.3313 (12.6); 3.2963 (12.6); 3.2883 (10.6);3.0848 (2.5); 3.0528 (5.8); 3.0327 (6.2); 3.0129 (6.0); 2.9925 (5.7);2.5120 (3.3); 2.4821 (6.9); 2.4390 (5.6); 2.3922 (2.7); 2.0052 (2.4);0.1459 (4.1); 0.0079 (37.0); −0.0002 (1177.9); −0.0085 (41.1); −0.0501(10.1); −0.1495 (3.6) IV-12: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.2617(46.8); 7.1803 (0.5); 7.1702 (2.2); 7.1676 (3.0); 7.1646 (3.5); 7.1620(3.3); 7.1507 (3.2); 7.1480 (3.4); 7.1451 (3.0); 7.1425 (2.1); 6.9976(1.2); 6.9807 (1.0); 6.9153 (0.5); 6.9129 (0.6); 6.9095 (1.0); 6.9072(1.0); 6.9039 (0.6); 6.9013 (0.5); 6.8936 (1.1); 6.8912 (1.2); 6.8878(1.9); 6.8855 (1.9); 6.8821 (1.1); 6.8798 (1.0); 6.8719 (0.6); 6.8695(0.6); 6.8661 (1.0); 6.8638 (0.9); 6.8605 (0.5); 6.4181 (1.1); 6.4127(1.8); 6.4021 (0.8); 6.3960 (1.2); 6.3910 (1.6); 6.3862 (1.1); 5.5605(1.2); 5.5351 (1.1); 5.2987 (1.3); 4.6152 (0.6); 4.6080 (1.0); 4.6043(1.0); 4.5975 (1.0); 4.5883 (1.1); 4.5845 (1.0); 4.5778 (0.7); 3.7901(2.8); 3.7862 (2.8); 3.7468 (3.2); 3.7429 (3.2); 3.2106 (2.8); 3.2044(2.9); 3.1672 (2.5); 3.1611 (2.5); 3.0222 (0.6); 3.0157 (0.9); 3.0101(1.1); 3.0025 (0.8); 2.9956 (0.9); 2.9902 (1.0); 2.9712 (1.0); 2.9677(1.0); 2.9634 (1.0); 2.9514 (1.1); 2.9437 (0.9); 2.4940 (0.6); 2.4890(0.7); 2.4838 (0.7); 2.4787 (0.6); 2.4426 (1.1); 2.4286 (0.6); 2.4187(0.8); 2.4144 (0.7); 2.4078 (0.8); 2.3991 (0.6); 2.3951 (0.6); 2.3875(0.7); 2.3825 (0.8); 2.3698 (1.0); 2.3644 (0.9); 2.3235 (0.6); 2.3183(0.6); 1.7196 (15.0); 1.7091 (15.1); 1.6382 (14.5); 1.6195 (15.6);1.6180 (16.0); 1.5765 (0.6); 1.5641 (0.5); 0.0079 (0.9); −0.0002 (26.2);−0.0084 (1.0) IV-13: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.2609 (6.7); 7.2013(0.6); 7.1982 (0.8); 7.1847 (0.7); 7.1826 (0.8); 7.1795 (0.6); 6.9492(0.6); 5.2996 (16.0); 3.9379 (0.6); 3.7701 (0.8); 3.7249 (0.6); 1.6404(3.8); 1.6391 (3.8); 1.6295 (3.8); −0.0002 (8.2)

Analytical data of Examples V-01-V-04 (see Table 1.1)

V-01: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.2607 (29.8); 7.1733 (1.8); 7.1675(2.2); 7.1644 (1.3); 7.1566 (1.3); 7.1535 (2.2); 7.1478 (1.8); 6.9165(1.2); 6.9109 (1.3); 6.9051 (0.7); 6.8949 (1.7); 6.8892 (2.0); 6.8834(0.9); 6.8733 (0.6); 6.8675 (0.8); 6.6565 (0.8); 6.6519 (2.1); 6.6465(1.8); 6.6420 (0.8); 5.2999 (2.6); 5.1266 (0.5); 5.1212 (0.6); 5.1061(0.6); 3.8051 (2.6); 3.7617 (3.0); 3.2223 (2.8); 3.1789 (2.4); 2.7298(0.6); 2.7242 (0.5); 2.5871 (0.7); 2.5674 (0.9); 2.5486 (1.0); 2.5451(1.5); 2.5380 (0.7); 2.5249 (0.6); 2.5165 (0.6); 1.7523 (0.8); 1.7447(0.9); 1.7294 (16.0); 1.7126 (0.6); 1.4322 (0.7); 0.0079 (1.2); −0.0002(38.1); −0.0085 (1.4) V-05: ¹H-NMR(400.6 MHz, CDCl3): δ = 7.2615 (30.2);7.2051 (1.2); 7.1994 (1.5); 7.1962 (0.9); 7.1892 (0.9); 7.1859 (1.5);7.1803 (1.3); 6.9720 (0.6); 6.9562 (0.6); 6.9505 (1.1); 6.9448 (0.6);6.9290 (0.6); 6.5558 (1.5); 6.5504 (1.3); 6.5456 (0.6); 3.9927 (0.9);3.9474 (1.3); 3.7747 (3.3); 3.7575 (16.0); 3.7293 (1.7); 2.5863 (0.6);2.5831 (0.5); 2.5665 (0.8); 2.5637 (1.0); −0.0002 (17.8); −0.0085 (0.6)V-02: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.2625 (20.6); 7.1731 (1.2); 7.1700(0.8); 7.1674 (1.4); 7.1643 (0.8); 7.1564 (0.8); 7.1533 (1.4); 7.1476(1.2); 6.9111 (0.6); 6.8952 (0.6); 6.8894 (1.1); 6.8836 (0.5); 6.8677(0.6); 6.5394 (0.5); 6.5341 (1.4); 6.5291 (1.1); 5.3005 (1.8); 3.7930(2.0); 3.7681 (0.7); 3.7496 (2.4); 3.7427 (16.0); 3.2154 (2.0); 3.1721(1.8); 2.6219 (1.0); 2.5432 (0.6); 2.5263 (0.8); 2.5230 (0.5); 1.7330(0.5); 1.7237 (11.9); −0.0002 (12.6) V-03: ¹H-NMR(400.0 MHz, CDCl3): δ =7.2633 (20.6); 7.1798 (1.0); 7.1740 (1.2); 7.1710 (0.7); 7.1631 (0.7);7.1600 (1.2); 7.1542 (1.0); 6.8951 (0.5); 6.8893 (0.9); 6.8676 (0.5);6.5767 (1.1); 6.5715 (0.9); 4.4461 (0.6); 4.4343 (0.5); 4.4224 (0.6);4.3059 (1.8); 4.2995 (0.6); 4.2974 (0.9); 4.2943 (1.7); 4.2908 (0.9);4.2887 (0.6); 4.2824 (1.9); 3.7952 (1.6); 3.7519 (1.9); 3.6955 (0.6);3.6836 (0.5); 3.6718 (0.6); 3.6266 (1.8); 3.6203 (0.6); 3.6182 (0.9);3.6147 (1.7); 3.6116 (0.9); 3.6096 (0.6); 3.6030 (1.7); 3.4040 (0.8);3.3991 (4.4); 3.3947 (0.7); 3.3746 (16.0); 3.2173 (1.7); 3.1740 (1.5);2.6163 (2.2); 2.5451 (0.7); 1.7238 (9.5); 1.7134 (0.8); 1.6802 (0.7);−0.0002 (12.2) V-04: ¹H-NMR(400.0 MHz, CDCl3): δ = 7.2601 (32.7); 7.2062(0.6); 7.2004 (0.7); 7.1870 (0.6); 7.1814 (0.5); 6.9786 (1.0); 5.2997(0.6); 5.0059 (0.5); 3.7802 (0.8); 3.7350 (0.6); 2.2715 (1.7); 1.4789(0.6); 1.4322 (16.0); 1.4218 (0.7); 1.2812 (0.8); 1.2546 (1.0); 1.2436(0.6); 1.2228 (3.0); 0.0080 (1.3); −0.0002 (40.1); −0.0085 (1.4)

In analogy to the preparation examples cited above and cited at theappropriate point, and taking account of the general details relating tothe preparation of substituted isoxazolinecarboxamides, the compoundscited below can be obtained:

Table 2.1: Compounds 2.1-1 to 2.1-240 according to the invention of thegeneral formula (I.1), where Z—(C═W)—O—R⁴ is as defined below.

TABLE 2.1 No.

2.1-1 

2.1-2 

2.1-3 

2.1-4 

2.1-5 

2.1-6 

2.1-7 

2.1-8 

2.1-9 

2.1-10 

2.1-11 

2.1-12 

2.1-13 

2.1-14 

2.1-15 

2.1-16 

2.1-17 

2.1-18 

2.1-19 

2.1-20 

2.1-21 

2.1-22 

2.1-23 

2.1-24 

2.1-25 

2.1-26 

2.1-27 

2.1-28 

2.1-29 

2.1-30 

2.1-31 

2.1-32 

2.1-33 

2.1-34 

2.1-35 

2.1-36 

2.1-37 

2.1-38 

2.1-39 

2.1-40 

2.1-41 

2.1-42 

2.1-43 

2.1-44 

2.1-45 

2.1-46 

2.1-47 

2.1-48 

2.1-49 

2.1-50 

2.1-51 

2.1-52 

2.1-53 

2.1-54 

2.1-55 

2.1-56 

2.1-57 

2.1-58 

2.1-59 

2.1-60 

2.1-61 

2.1-62 

2.1-63 

2.1-64 

2.1-65 

2.1-66 

2.1-67 

2.1-68 

2.1-69 

2.1-70 

2.1-71 

2.1-72 

2.1-73 

2.1-74 

2.1-75 

2.1-76 

2.1-77 

2.1-78 

2.1-79 

2.1-80 

2.1-81 

2.1-82 

2.1-83 

2.1-84 

2.1-85 

2.1-86 

2.1-87 

2.1-88 

2.1-89 

2.1-90 

2.1-91 

2.1-92 

2.1-93 

2.1-94 

2.1-95 

2.1-96 

2.1-97 

2.1-98 

2.1-99 

2.1-100

2.1-101

2.1-102

2.1-103

2.1-104

2.1-105

2.1-106

2.1-107

2.1-108

2.1-109

2.1-110

2.1-111

2.1-112

2.1-113

2.1-114

2.1-115

2.1-116

2.1-117

2.1-118

2.1-119

2.1-120

2.1-121

2.1-122

2.1-123

2.1-124

2.1-125

2.1-126

2.1-127

2.1-128

2.1-129

2.1-130

2.1-131

2.1-132

2.1-133

2.1-134

2.1-135

2.1-136

2.1-137

2.1-138

2.1-139

2.1-140

2.1-141

2.1-142

2.1-143

2.1-144

2.1-145

2.1-146

2.1-147

2.1-148

2.1-149

2.1-150

2.1-151

2.1-152

2.1-153

2.1-154

2.1-155

2.1-156

2.1-157

2.1-158

2.1-159

2.1-160

2.1-161

2.1-162

2.1-163

2.1-164

2.1-165

2.1-166

2.1-167

2.1-168

2.1-169

2.1-170

2.1-171

2.1-172

2.1-173

2.1-174

2.1-175

2.1-176

2.1-177

2.1-178

2.1-179

2.1-180

2.1-181

2.1-182

2.1-183

2.1-184

2.1-185

2.1-186

2.1-187

2.1-188

2.1-189

2.1-190

2.1-191

2.1-192

2.1-193

2.1-194

2.1-195

2.1-196

2.1-197

2.1-198

2.1-199

2.1-200

2.1-201

2.1-202

2.1-203

2.1-204

2.1-205

2.1-206

2.1-207

2.1-208

2.1-209

2.1-210

2.1-211

2.1-212

2.1-213

2.1-214

2.1-215

2.1-216

2.1-217

2.1-218

2.1-219

2.1-220

2.1-221

2.1-222

2.1-223

2.1-224

2.1-225

2.1-226

2.1-227

2.1-228

2.1-229

2.1-230

2.1-231

2.1-232

2.1-233

2.1-234

2.1-235

2.1-236

2.1-237

2.1-238

2.1-239

2.1-240

Table 2.2: Compounds 2.2-1 to 2.2-240 according to the invention of thegeneral formula (I.2), where Z—(C═W)—O—R⁴ is as defined in Table 2.1.

Table 2.3: Compounds 2.3-1 to 2.3-240 according to the invention of thegeneral formula (I.3), where Z—(C═W)—O—R⁴ is as defined in Table 2.1.

Table 2.4: Compounds 2.4-1 to 2.4-240 according to the invention of thegeneral formula (I.4), where Z—(C═W)—O—R⁴ is as defined in Table 2.1.

Table 2.5: Compounds 2.5-1 to 2.5-240 according to the invention of thegeneral formula (I.5),

Table 2.6: Compounds 2.6-1 to 2.6-240 according to the invention of thegeneral formula (I.6), where Z—(C═W)—O—R⁴ is as defined in Table 2.1.

Table 2.7: Compounds 2.7-1 to 2.7-240 according to the invention of thegeneral formula (I.7), where Z—(C═W)—O—R⁴ is as defined in Table 2.1.

Table 2.8: Compounds 2.8-1 to 2.8-240 according to the invention of thegeneral formula (I.8), where Z—(C═W)—O—R⁴ is as defined in Table 2.1.

Table 2.9: Compounds 2.9-1 to 2.9-240 according to the invention of thegeneral formula (I.9), where Z—(C═W)—O—R⁴ is as defined in Table 2.1.

Table 2.10: Compounds 2.10-1 to 2.10-240 according to the invention ofthe general formula (I.10),

Table 2.11: Compounds 2.11-1 to 2.11-240 according to the invention ofthe general formula (I.11), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.12: Compounds 2.12-1 to 2.12-240 according to the invention ofthe general formula (I.12), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.13: Compounds 2.13-1 to 2.13-240 according to the invention ofthe general formula (I.13), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.14: Compounds 2.14-1 to 2.14-240 according to the invention ofthe general formula (I.14), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.15: Compounds 2.15-1 to 2.15-240 according to the invention ofthe general formula (I.15),

Table 2.16: Compounds 2.16-1 to 2.16-240 according to the invention ofthe general formula (I.16), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.17: Compounds 2.17-1 to 2.17-240 according to the invention ofthe general formula (I.17), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.18: Compounds 2.18-1 to 2.18-240 according to the invention ofthe general formula (I.18), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.19: Compounds 2.19-1 to 2.19-240 according to the invention ofthe general formula (I.19), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.20: Compounds 2.20-1 to 2.20-240 according to the invention ofthe general formula (I.20),

Table 2.21: Compounds 2.21-1 to 2.21-240 according to the invention ofthe general formula (I.21), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.22: Compounds 2.22-1 to 2.22-240 according to the invention ofthe general formula (I.22), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.23: Compounds 2.23-1 to 2.23-240 according to the invention ofthe general formula (I.23), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.24: Compounds 2.24-1 to 2.24-240 according to the invention ofthe general formula (I.24), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.25: Compounds 2.25-1 to 2.25-240 according to the invention ofthe general formula (I.25), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.26: Compounds 2.26-1 to 2.26-240 according to the invention ofthe general formula (I.26), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.27: Compounds 2.27-1 to 2.27-240 according to the invention ofthe general formula (I.27), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.28: Compounds 2.28-1 to 2.28-240 according to the invention ofthe general formula (I.28),

Table 2.29: Compounds 2.29-1 to 2.29-240 according to the invention ofthe general formula (I.29), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.30: Compounds 2.30-1 to 2.30-240 according to the invention ofthe general formula (I.30), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.31: Compounds 2.31-1 to 2.31-240 according to the invention ofthe general formula (I.31), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.32: Compounds 2.32-1 to 2.32-240 according to the invention ofthe general formula (I.32), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.33: Compounds 2.33-1 to 2.33-240 according to the invention ofthe general formula (I.33), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.34: Compounds 2.34-1 to 2.34-240 according to the invention ofthe general formula (I.34), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.35: Compounds 2.35-1 to 2.35-240 according to the invention ofthe general formula (I.35), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.36: Compounds 2.36-1 to 2.36-240 according to the invention ofthe general formula (I.36),

Table 2.37: Compounds 2.37-1 to 2.37-240 according to the invention orme general formula (I.37), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.38: Compounds 2.38-1 to 2.38-240 according to the invention ofthe general formula (I.38), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.39: Compounds 2.39-1 to 2.39-240 according to the invention ofthe general formula (I.39), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.40: Compounds 2.40-1 to 2.40-240 according to the invention ofthe general formula (I.40),

Table 2.41: Compounds 2.41-1 to 2.41-240 according to the invention ofthe general formula (I.41), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.42: Compounds 2.42-1 to 2.42-240 according to the invention ofthe general formula (I.42), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.43: Compounds 2.43-1 to 2.43-240 according to the invention ofthe general formula (I.43), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.44: Compounds 2.44-1 to 2.44-240 according to the invention ofthe general formula (I.44),

Table 2.45: Compounds 2.45-1 to 2.45-240 according to the invention ofthe general formula (I.45), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.46: Compounds 2.46-1 to 2.46-240 according to the invention ofthe general formula (I.46), where Z—(C═W)—O—R⁴ is ac defined in Table 71

Table 2.47: Compounds 2.47 to 2.47-240 according to the invention of thegeneral formula (I.47), where Z—(C═W)—O—R⁴ is as defined in Table 2.1.

Table 2.48: Compounds 2.48-1 to 2.48-240 according to the invention ofthe general formula (I.48),

Table 2.49: Compounds 2.49-1 to 2.49-240 according to the invention ofthe general formula (I.49), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.50: Compounds 2.50-1 to 2.50-240 according to the invention ofthe general formula (I.50), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.51: Compounds 2.51-1 to 2.51-240 according to the invention ofthe general formula (I.51), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.52: Compounds 2.52-1 to 2.52-240 according to the invention ofthe general formula (I.52),

Table 2.53: Compounds 2.53-1 to 2.53-240 according to the invention ofthe general formula (I.53), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.54: Compounds 2.54-1 to 2.54-240 according to the invention ofthe general formula (I.54), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.55: Compounds 2.55-1 to 2.55-240 according to the invention ofthe general formula (I.55), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.56: Compounds 2.56-1 to 2.56-240 according to the invention ofthe general formula (I.56),

Table 2.57: Compounds 2.56-1 to 2.56-240 according to the invention ofthe general formula (I.57), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 2.58: Compounds 2.56-1 to 2.56-240 according to the invention ofthe general formula (I.58), where Z—(C═W)—O—R⁴ is as defined in Table2.1.

Table 3.1: Compounds 3.1-1 to 3.1-390 according to the invention of thegeneral formula (II.1), where Z—(C═W)—N(R¹¹)—R¹² is as defined below.

TABLE 3.1 No.

3.1-1 

3.1-2 

3.1-3 

3.1-4 

3.1-5 

3.1-6 

3.1-7 

3.1-8 

3.1-9 

3.1-10 

3.1-11 

3.1-12 

3.1-13 

3.1-14 

3.1-15 

3.1-16 

3.1-17 

3.1-18 

3.1-19 

3.1-20 

3.1-21 

3.1-22 

3.1-23 

3.1-24 

3.1-25 

3.1-26 

3.1-27 

3.1-28 

3.1-29 

3.1-30 

3.1-31 

3.1-32 

3.1-33 

3.1-34 

3.1-35 

3.1-36 

3.1-37 

3.1-38 

3.1-39 

3.1-40 

3.1-41 

3.1-42 

3.1-43 

3.1-44 

3.1-45 

3.1-46 

3.1-47 

3.1-48 

3.1-49 

3.1-50 

3.1-51 

3.1-52 

3.1-53 

3.1-54 

3.1-55 

3.1-56 

3.1-57 

3.1-58 

3.1-59 

3.1-60 

3.1-61 

3.1-62 

3.1-63 

3.1-64 

3.1-65 

3.1-66 

3.1-67 

3.1-68 

3.1-69 

3.1-70 

3.1-71 

3.1-72 

3.1-73 

3.1-74 

3.1-75 

3.1-76 

3.1-77 

3.1-78 

3.1-79 

3.1-80 

3.1-81 

3.1-82 

3.1-83 

3.1-84 

3.1-85 

3.1-86 

3.1-87 

3.1-88 

3.1-89 

3.1-90 

3.1-91 

3.1-92 

3.1-93 

3.1-94 

3.1-95 

3.1-96 

3.1-97 

3.1-98 

3.1-99 

3.1-100

3.1-101

3.1-102

3.1-103

3.1-104

3.1-105

3.1-106

3.1-107

3.1-108

3.1-109

3.1-110

3.1-111

3.1-112

3.1-113

3.1-114

3.1-115

3.1-116

3.1-117

3.1-118

3.1-119

3.1-120

3.1-121

3.1-122

3.1-123

3.1-124

3.1-125

3.1-126

3.1-127

3.1-128

3.1-129

3.1-130

3.1-131

3.1-132

3.1-133

3.1-134

3.1-135

3.1-136

3.1-137

3.1-138

3.1-139

3.1-140

3.1-141

3.1-142

3.1-143

3.1-144

3.1-145

3.1-146

3.1-147

3.1-148

3.1-149

3.1-150

3.1-151

3.1-152

3.1-153

3.1-154

3.1-155

3.1-156

3.1-157

3.1-158

3.1-159

3.1-160

3.1-161

3.1-162

3.1-163

3.1-164

3.1-165

3.1-166

3.1-167

3.1-168

3.1-169

3.1-170

3.1-171

3.1-172

3.1-173

3.1-174

3.1-175

3.1-176

3.1-177

3.1-178

3.1-179

3.1-180

3.1-181

3.1-182

3.1-183

3.1-184

3.1-185

3.1-186

3.1-187

3.1-188

3.1-189

3.1-190

3.1-191

3.1-192

3.1-193

3.1-194

3.1-195

3.1-196

3.1-197

3.1-198

3.1-199

3.1-200

3.1-201

3.1-202

3.1-203

3.1-204

3.1-205

3.1-206

3.1-207

3.1-208

3.1-209

3.1-210

3.1-211

3.1-212

3.1-213

3.1-214

3.1-215

3.1-216

3.1-217

3.1-218

3.1-219

3.1-220

3.1-221

3.1-222

3.1-223

3.1-224

3.1-225

3.1-226

3.1-227

3.1-228

3.1-229

3.1-230

3.1-231

3.1-232

3.1-233

3.1-234

3.1-235

3.1-236

3.1-237

3.1-238

3.1-239

3.1-240

3.1-241

3.1-242

3.1-243

3.1-244

3.1-245

3.1-246

3.1-247

3.1-248

3.1-249

3.1-250

3.1-251

3.1-252

3.1-253

3.1-254

3.1-255

3.1-256

3.1-257

3.1-258

3.1-259

3.1-260

3.1-261

3.1-262

3.1-263

3.1-264

3.1-265

3.1-266

3.1-267

3.1-268

3.1-269

3.1-270

3.1-271

3.1-272

3.1-273

3.1-274

3.1-275

3.1-276

3.1-277

3.1-278

3.1-279

3.1-280

3.1-281

3.1-282

3.1-283

3.1-284

3.1-285

3.1-286

3.1-287

3.1-288

3.1-289

3.1-290

3.1-291

3.1-292

3.1-293

3.1-294

3.1-295

3.1-296

3.1-297

3.1-298

3.1-299

3.1-300

3.1-301

3.1-302

3.1-303

3.1-304

3.1-305

3.1-306

3.1-307

3.1-308

3.1-309

3.1-310

3.1-311

3.1-312

3.1-313

3.1-314

3.1-315

3.1-316

3.1-317

3.1-318

3.1-319

3.1-320

3.1-321

3.1-322

3.1-323

3.1-324

3.1-325

3.1-326

3.1-327

3.1-328

3.1-329

3.1-330

3.1-331

3.1-332

3.1-333

3.1-334

3.1-335

3.1-336

3.1-337

3.1-338

3.1-339

3.1-340

3.1-341

3.1-342

3.1-343

3.1-344

3.1-345

3.1-346

3.1-347

3.1-348

3.1-349

3.1-350

3.1-351

3.1-352

3.1-353

3.1-354

3.1-355

3.1-356

3.1-357

3.1-358

3.1-359

3.1-360

3.1-361

3.1-362

3.1-363

3.1-364

3.1-365

3.1-366

3.1-367

3.1-368

3.1-369

3.1-370

3.1-371

3.1-372

3.1-373

3.1-374

3.1-375

3.1-376

3.1-377

3.1-378

3.1-379

3.1-380

3.1-381

3.1-382

3.1-383

3.1-384

3.1-385

3.1-386

3.1-387

3.1-388

3.1-389

3.1-390

Table 3.2: Compounds 3.2-1 to 3.2-390 according to the invention of thegeneral formula (II.2), where Z—(C═W)—N(R¹¹)—R¹² is as defined in Table3.1.

Table 3.3: Compounds 3.3-1 to 3.3-390 according to the invention of thegeneral formula (II.3), where Z—(C═W)—N(R¹¹)—R¹² is as defined in Table3.1.

Table 3.4: Compounds 3.4-1 to 3.4-390 according to the invention of thegeneral formula (II.4), where Z—(C═W)—N(R¹¹)—R¹² is as defined in Table3.1.

Table 3.5: Compounds 3.5-1 to 3.5-390 according to the invention of thegeneral formula (II.5), where Z—(C═W)—N(R¹¹)—R¹² is as defined in Table3.1.

Table 3.6: Compounds 3.6-1 to 3.6-390 according to the invention of thegeneral formula (II.6), where Z—(C═W)—N(R¹¹)—R¹² is as defined in Table3.1.

Table 3.7: Compounds 3.7-1 to 3.7-390 according to the invention of thegeneral formula (II.7), where Z—(C═W)—N(R¹¹)—R¹² is as defined in Table3.1.

Table 3.8: Compounds 3.8-1 to 3.8-390 according to the invention of thegeneral formula (II.8), where Z—(C═W)—N(R¹¹)—R¹² is as defined in Table3.1.

Table 3.9: Compounds 3.9-1 to 3.9-390 according to the invention of thegeneral formula (II.9), where Z—(C═W)—N(R¹¹)—R¹² is as defined in Table3.1.

Table 3.10: Compounds 3.10-1 to 3.10-390 according to the invention ofthe general formula (II.10), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.11: Compounds 3.11-1 to 3.11-390 according to the invention ofthe general formula (II.11), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.12: Compounds 3.12-1 to 3.12-390 according to the invention ofthe general formula (II.12), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.13: Compounds 3.13-1 to 3.13-390 according to the invention ofthe general formula (II.13), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.14: Compounds 3.14-1 to 3.14-390 according to the invention ofthe general formula (II.14), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.15: Compounds 3.15-1 to 3.15-390 according to the invention ofthe general formula (II.15), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.16: Compounds 3.16-1 to 3.16-390 according to the invention ofthe general formula (II.16), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.17: Compounds 3.17-1 to 3.17-390 according to the invention ofthe general formula (II.17), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.18: Compounds 3.18-1 to 3.18-390 according to the invention ofthe general formula (II.18), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.19: Compounds 3.19-1 to 3.19-390 according to the invention ofthe general formula (II.19), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.20: Compounds 3.20-1 to 3.20-390 according to the invention ofthe general formula (II.20), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.21: Compounds 3.21-1 to 3.21-390 according to the invention ofthe general formula (II.21), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.22: Compounds 3.22-1 to 3.22-390 according to the invention ofthe general formula (II.22), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.23: Compounds 3.23-1 to 3.23-390 according to the invention ofthe general formula (II.23), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.24: Compounds 3.24-1 to 3.24-390 of the general formula (II.24)in which Z—(C═W)—N(R¹¹)—R¹² is as defined in Table 3.1.

Table 3.25: Compounds 3.25-1 to 3.25-390 according to the invention ofthe general formula (II.25), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.26: Compounds 3.26-1 to 3.26-390 according to the invention ofthe general formula (II.26), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.27: Compounds 3.27-1 to 3.27-390 according to the invention ofthe general formula (II.27), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.28: Compounds 3.28-1 to 3.28-390 according to the invention ofthe general formula (II.28), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.29: Compounds 3.29-1 to 3.29-390 according to the invention ofthe general formula (II.29), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.30: Compounds 3.30-1 to 3.30-390 according to the invention ofthe general formula (II.30), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.31: Compounds 3.31-1 to 3.31-390 according to the invention ofthe general formula (II.31), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.32: Compounds 3.32-1 to 3.32-390 according to the invention ofthe general formula (II.32), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.33: Compounds 3.33-1 to 3.33-390 according to the invention ofthe general formula (II.33), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.34: Compounds 3.34-1 to 3.34-390 according to the invention ofthe general formula (II.34), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.35: Compounds 3.35-1 to 3.35-390 according to the invention ofthe general formula (II.35), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.36: Compounds 3.36-1 to 3.36-390 according to the invention ofthe general formula (II.36), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.37: Compounds 3.37-1 to 3.37-390 according to the invention ofthe general formula (II.37), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.38: Compounds 3.38-1 to 3.38-390 according to the invention ofthe general formula (II.38), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.39: Compounds 3.39-1 to 3.39-390 according to the invention ofthe general formula (II.39), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.40: Compounds 3.40-1 to 3.40-390 according to the invention ofthe general formula (II.40), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.41: Compounds 3.41-1 to 3.41-390 according to the invention ofthe general formula (II.41), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.42: Compounds 3.42-1 to 3.42-390 according to the invention ofthe general formula (II.42), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.43: Compounds 3.43-1 to 3.43-390 according to the invention ofthe general formula (II.43), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.44: Compounds 3.44-1 to 3.44-390 according to the invention ofthe general formula (II.44), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.45: Compounds 3.45-1 to 3.45-390 according to the invention ofthe general formula (II.45), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.46: Compounds 3.46-1 to 3.46-390 according to the invention ofthe general formula (II.46), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.47: Compounds 3.47 to 3.47-390 according to the invention of thegeneral formula (II.47), where Z—(C═W)—N(R¹¹)—R¹² is as defined in Table3.1.

Table 3.48: Compounds 3.48-1 to 3.48-390 according to the invention ofthe general formula (II.48), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.49: Compounds 3.49-1 to 3.49-390 according to the invention ofthe general formula (II.49), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.50: Compounds 3.50-1 to 3.50-390 according to the invention ofthe general formula (II.50), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.51: Compounds 3.51-1 to 3.51-390 according to the invention ofthe general formula (II.51), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.52: Compounds 3.52-1 to 3.52-390 according to the invention ofthe general formula (II.52), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.53: Compounds 3.53-1 to 3.53-390 according to the invention ofthe general formula (II.53), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.54: Compounds 3.54-1 to 3.54-390 according to the invention ofthe general formula (II.54), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.55: Compounds 3.55-1 to 3.55-390 according to the invention ofthe general formula (II.55), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.56: Compounds 3.56-1 to 3.56-390 according to the invention ofthe general formula (II.56), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.57: Compounds 3.56-1 to 3.56-390 according to the invention ofthe general formula (II.57), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

Table 3.58: Compounds 3.56-1 to 3.56-390 according to the invention ofthe general formula (II.58), where Z—(C═W)—N(R¹¹)—R¹² is as defined inTable 3.1.

B. Formulation Examples

1. Dusting products

A dusting product is obtained by mixing 10 parts by weight of a compoundof the formula (I) and 90 parts by weight of talc as an inert substanceand comminuting the mixture in a hammer mill.

2. Dispersible powder

A readily water-dispersible wettable powder is obtained by mixing 25parts by weight of a compound of the formula (I), 64 parts by weight ofkaolin-containing quartz as an inert substance, 10 parts by weight ofpotassium lignosulfonate and 1 part by weight of sodiumoleoylmethyltaurate as a wetting agent and dispersant, and grinding themixture in a pinned-disk mill.

3. Dispersion concentrate

A readily water-dispersible dispersion concentrate is obtained by mixing20 parts by weight of a compound of the formula (I), 6 parts by weightof alkylphenol polyglycol ether (®Triton X 207), 3 parts by weight ofisotridecanol polyglycol ether (8 EO) and 71 parts by weight ofparaffinic mineral oil (boiling range for example about 255 to more than277° C.) and grinding the mixture in a friction ball mill to a finenessof below 5 microns.

4. Emulsifiable concentrate

An emulsifiable concentrate is obtained from 15 parts by weight of acompound of the formula (I), 75 parts by weight of cyclohexanone as asolvent and 10 parts by weight of ethoxylated nonylphenol as anemulsifier.

5. Water-dispersible granules

Water-dispersible granules are obtained by mixing

75 parts by weight of a compound of the formula (I),

10″ of calcium lignosulfonate,

5″ of sodium laurylsulfate,

3″ of polyvinyl alcohol and

7″ of kaolin,

grinding the mixture in a pinned-disk mill, and granulating the powderin a fluidized bed by spray application of water as a granulatingliquid.

Water-dispersible granules are also obtained by homogenizing andprecomminuting, in a colloid mill, 25 parts by weight of a compound ofthe formula (I),

5″ of sodium 2,2′-dinaphthylmethane-6,6′-disulfonate,

2″ of sodium oleoylmethyltaurinate,

1″ of polyvinyl alcohol,

17″ of calcium carbonate and

50″ of water,

then grinding the mixture in a bead mill and atomizing and drying thesuspension thus obtained in a spray tower by means of a one-phasenozzle.

C. Biological Examples

Test Description

1. Pre-emergence herbicidal action against harmful plants and crop plantcompatibility

Seeds of monocotyledonous and dicotyledonous weed plants and crop plantsare placed in plastic or wood-fibre pots and covered with soil. Thecompounds of the invention, formulated in the form of wettable powders(WP) or as emulsion concentrates (EC), are then applied onto the surfaceof the covering soil as aqueous suspension or emulsion with addition of0.5% additive at a water application rate of 600 l/ha (converted). Afterthe treatment, the pots are placed in a greenhouse and kept under goodgrowth conditions for the trial plants. After about 3 weeks, the effectof the preparations is scored visually in comparison with untreatedcontrols as percentages. For example, 100% activity=the plants havedied, 0% activity=like control plants.

In the tables below, the following abbreviations are used:

Undesired plants/weeds:

ABUTH: Abutilon theophrasti ALOMY: Alopecurus myosuroides AMARE:Amaranthus retroflexus AVEFA: Avena fatua ECHCG: Echinochloa crus-galliHORMU: Hordeum murinum LOLRI: Lolium rigidum MATIN: Matricaria inodoraPHBPU: Pharbitis purpurea POLCO: Polygonum convolvulus SETVI: Setariaviridis STEME: Stellaria media VERPE: Veronica persica VIOTR: Violatricolor

TABLE 4.1 Pre-emergence herbicidal action against ALOMY in % Herbicidalaction Example Application against [%] number rate [g/ha] ALOMY I-002 8090 I-004 80 100 I-006 80 100 I-012 80 100 I-013 80 100 II-02 80 90 II-0480 100 II-06 80 90 II-07 80 100 II-12 80 90 II-16 80 100 III-02 80 100III-04 80 100 III-06 80 100 IV-01 80 90 IV-02 80 100 IV-03 80 90 IV-0480 90 IV-05 80 80 IV-06 80 100 IV-07 80 100

TABLE 4.2 Pre-emergence herbicidal action against AVEFA in % Herbicidalaction Example Application against [%] number rate [g/ha] AVEFA I-002 8080 I-004 80 90 I-006 80 90 I-012 80 90 I-013 80 100 II-02 80 90 II-04 8080 II-06 80 90 II-07 80 80 II-12 80 80 II-16 80 80 III-02 80 80 III-0480 90 III-06 80 80 IV-01 80 90 IV-02 80 90 IV-04 80 90 IV-05 80 80 IV-0780 80

TABLE 4.3 Pre-emergence herbicidal action against CYPRES in % Herbicidalaction Example Application against [%] number rate [g/ha] CYPES I-003 80100 I-006 80 100 II-16 80 100

TABLE 4.4 Pre-emergence herbicidal action against ECHCG in % Herbicidalaction Example Application against [%] number rate [g/ha] ECHCG I-002 8090 I-004 80 100 I-006 80 100 I-012 80 100 I-013 80 100 II-02 80 80 II-0480 90 II-06 80 90 II-07 80 90 II-16 80 100 III-04 80 90 III-06 80 90IV-02 80 90 IV-04 80 90 IV-06 80 90

TABLE 4.5 Pre-emergence herbicidal action against LOLRI in % Herbicidalaction Example Application against [%] number rate [g/ha] LOLRI I-002 80100 I-004 80 90 I-006 80 100 I-012 80 100 I-013 80 100 II-02 80 90 II-0480 90 II-06 80 100 II-07 80 100 II-12 80 90 II-16 80 100 III-02 80 100III-04 80 100 III-06 80 100 IV-01 80 100 IV-02 80 100 IV-04 80 100 IV-0680 100 IV-07 80 90

TABLE 4.6 Pre-emergence herbicidal action against SETVI in % Herbicidalaction Example Application against [%] number rate [g/ha] SETVI I-002 80100 I-004 80 100 I-006 80 100 I-012 80 100 I-013 80 100 II-02 80 100II-04 80 90 II-06 80 100 II-07 80 100 II-12 80 90 II-16 80 80 III-04 80100 III-06 80 100 IV-01 80 90 IV-02 80 90 IV-04 80 100 IV-06 80 100IV-07 80 100

TABLE 4.7 Pre-emergence herbicidal action against ABUTH in % Herbicidalaction Example Application against [%] number rate [g/ha] ABUTH I-012 8090 I-013 80 90 II-12 80 80 IV-02 80 80

TABLE 4.8 Pre-emergence herbicidal action against AMARE in % Herbicidalaction Example Application against [%] number rate [g/ha] AMARE I-002 8090 I-004 80 80 I-005 80 80 I-006 80 100 I-012 80 100 I-013 80 100 II-0280 100 II-04 80 100 II-06 80 100 II-07 80 100 II-12 80 90 II-16 80 90III-02 80 80 III-04 80 90 IV-01 80 90 IV-02 80 100 IV-04 80 90 IV-06 8080 IV-07 80 80

TABLE 4.9 Pre-emergence herbicidal action against MATIN in % Herbicidalaction Example Application against [%] number rate [g/ha] MATIN I-002 8080 I-004 80 80 I-006 80 90 I-012 80 90 I-013 80 100 II-02 80 90 II-04 8080 II-16 80 80 IV-07 80 80

TABLE 4.10 Pre-emergence herbicidal action against PHBPU in % Herbicidalaction Example Application against [%] number rate [g/ha] PHBPU I-002 8090 I-004 80 90 I-006 80 90 I-012 80 90 I-013 80 90 II-02 80 90 III-02 8080 III-04 80 90 III-06 80 80 IV-02 80 80 IV-06 80 90 IV-07 80 90

TABLE 4.11 Pre-emergence herbicidal action against POLCO in % Herbicidalaction Example Application against [%] number rate [g/ha] POLCO I-002 8090 I-003 80 80 I-004 80 100 I-006 80 80 I-012 80 90 I-013 80 90 II-02 80100 II-04 80 90 II-06 80 80 II-07 80 100 II-12 80 100 II-16 80 90 III-0480 100 III-06 80 100 IV-01 80 90 IV-02 80 100 IV-06 80 80 IV-07 80 80

TABLE 4.12 Pre-emergence herbicidal action against STEME in % Herbicidalaction Example Application against [%] number rate [g/ha] STEME I-002 80100 I-003 80 80 I-004 80 100 I-006 80 100 I-012 80 100 I-013 80 100II-02 80 100 II-04 80 100 II-05 80 90 II-06 80 90 II-07 80 100 II-12 8090 II-13 80 100 II-16 80 100 III-02 80 80 III-04 80 90 III-06 80 90IV-01 80 90 IV-02 80 90 IV-04 80 90 IV-05 80 90 IV-06 80 90 IV-07 80 100

TABLE 4.13 Pre-emergence herbicidal action against VIOTR in % Herbicidalaction Example Application against [%] number rate [g/ha] VIOTR I-002 8080 I-003 80 100 I-006 80 90 I-012 80 90 I-013 80 100 II-02 80 90 II-0380 90 II-06 80 100 II-07 80 100 II-12 80 80 II-16 80 80 III-04 80 90III-06 80 90 IV-02 80 90 IV-05 80 100 IV-06 80 100 IV-07 80 90

TABLE 4.14 Pre-emergence herbicidal action against VERPE in % Herbicidalaction Example Application against [%] number rate [g/ha] VERPE I-012 80100 I-013 80 90 II-06 80 90 II-07 80 100 III-01 80 90 III-02 80 90III-03 80 80 III-04 80 90 III-06 80 80 IV-02 80 90

TABLE 4.15 Pre-emergence herbicidal action against HORMU in % Herbicidalaction Example Application against [%] number rate [g/ha] HORMU I-002 8080 I-006 80 90 I-012 80 90 I-013 80 100 II-04 80 90 II-06 80 100 II-0780 90 III-01 80 80 III-02 80 100 III-04 80 100 III-05 80 80 III-06 80 90IV-01 80 90 IV-02 80 100 IV-04 80 90 IV-06 80 90 IV-07 80 90

As shown by the results, compounds according to the invention such as,for example, the compounds No. I-002 and other compounds from the tables(I-004, I-006, I-012, I-013, II-02, II-04, II-06, II-07, II-12, II-16,III-02, III-04, III-06, IV-01, IV-02, IV-04, IV-06, IV-07) have, whenused for pre-emergence treatment, very good activity (80% to 100%herbicidal action) against harmful plants such as Abufilon theophrasti,Alopecurus myosuroides, Amaranthus retroflexus, Echinochloa crus-galli,Hordeum murinum, Lolium rigidum, Matricaria inodora, Pharbitis purpurea,Polygonum convolvulus, Setaria viridis, Stellaria media, Veronicapersica and Viola tricolor at an application rate of 0.08 kg of activesubstance or less per hectare.

2. Post-emergence herbicidal action against harmful plants and cropplant compatibility

Seeds of monocotyledonous and dicotyledonous weeds and crop plants areplaced in sandy loam in plastic or wood-fibre pots, covered with soiland cultivated in a greenhouse under controlled growth conditions. 2 to3 weeks after sowing, the test plants are treated at the one-leaf stage.The compounds of the invention, formulated in the form of wettablepowders (WP) or as emulsion concentrates (EC), are then sprayed onto thegreen parts of the plants as aqueous suspension or emulsion withaddition of 0.5% additive at a water application rate of 600 l/ha(converted). After the test plants have been kept in the greenhouseunder optimum growth conditions for about 3 weeks, the activity of thepreparations is rated visually in comparison to untreated controls. Forexample, 100% activity=the plants have died, 0% activity=like controlplants.

TABLE 5.1 Post-emergence herbicidal action against ALOMY in % Herbicidalaction Example Application against [%] number rate [g/ha] ALOMY I-002 8090 I-004 80 80 I-006 80 80 I-007 80 90 I-008 80 100 I-009 80 90 I-010 8090 I-011 80 90 I-012 80 90 I-013 80 80 I-014 80 90 I-015 80 100 I-016 80100 I-017 80 100 I-018 80 100 I-019 80 90 I-020 80 90 I-021 80 90 I-02280 100 I-023 80 90 I-024 80 90 I-025 80 90 I-026 80 100 I-027 80 90I-028 80 90 I-029 80 90 I-030 80 90 I-031 80 90 I-032 80 90 I-033 80 90I-034 80 90 I-035 80 90 I-036 80 90 I-037 80 90 I-038 80 90 I-039 80 100I-040 80 90 I-042 80 100 I-043 80 90 I-045 80 100 I-046 80 90 I-048 80100 I-049 80 90 I-050 80 90 I-051 80 100 I-052 80 100 I-053 80 90 I-05480 90 I-055 80 90 I-056 80 100 I-057 80 90 I-058 80 100 I-059 80 90I-060 80 90 I-061 80 90 I-062 80 100 I-063 80 90 I-064 80 90 I-065 80 90I-066 80 90 I-067 80 90 I-068 80 90 I-069 80 90 I-070 80 90 I-071 80 90I-072 80 90 I-073 80 90 I-075 80 100 I-076 80 100 I-077 80 90 I-079 8090 I-080 80 90 I-082 80 100 I-083 80 100 I-084 80 100 I-085 80 90 I-08680 90 I-087 80 100 I-089 80 100 I-090 80 100 I-092 80 90 I-093 80 100I-094 80 100 I-095 80 90 I-096 80 100 I-097 80 100 I-098 80 100 I-099 8090 I-100 80 100 I-104 80 90 II-02 80 80 II-04 80 80 II-06 80 90 II-07 8080 II-08 80 80 II-10 80 90 II-11 80 90 II-12 80 90 II-14 80 100 II-17 8080 II-18 80 100 II-22 80 80 II-25 80 80 II-26 80 100 II-27 80 90 II-2880 100 II-30 80 100 II-31 80 90 II-32 80 90 II-34 80 90 II-35 80 90II-36 80 90 II-37 80 80 II-39 80 80 III-02 80 80 III-04 80 90 III-06 8090 III-07 80 90 III-08 80 90 III-09 80 90 III-10 80 100 III-12 80 100III-13 80 90 III-17 80 100 IV-04 80 90 IV-06 80 90 IV-07 80 90 V-01 80100 V-04 80 100

TABLE 5.2 Post-emergence herbicidal action against AVEFA in % Herbicidalaction Example Application against [%] number rate [g/ha] AVEFA I-002 8080 I-004 80 90 I-006 80 80 I-007 80 90 I-008 80 90 I-009 80 90 I-010 8090 I-011 80 90 I-012 80 100 I-013 80 90 I-014 80 90 I-015 80 100 I-01680 90 I-017 80 100 I-018 80 100 I-019 80 100 I-020 80 100 I-021 80 100I-022 80 100 I-023 80 90 I-024 80 100 I-025 80 90 I-026 80 100 I-027 8090 I-028 80 100 I-029 80 80 I-030 80 100 I-031 80 90 I-032 80 100 I-03380 90 I-034 80 90 I-035 80 90 I-036 80 80 I-037 80 90 I-038 80 100 I-03980 90 I-040 80 90 I-041 80 90 I-042 80 100 I-043 80 90 I-044 80 80 I-04580 90 I-046 80 90 I-048 80 90 I-049 80 90 I-050 80 90 I-051 80 90 I-05280 100 I-053 80 90 I-054 80 100 I-055 80 80 I-056 80 90 I-058 80 100I-059 80 100 I-060 80 90 I-061 80 100 I-062 80 100 I-063 80 100 I-064 80100 I-065 80 90 I-066 80 90 I-067 80 100 I-068 80 100 I-069 80 90 I-07080 100 I-071 80 100 I-072 80 100 I-073 80 100 I-076 80 100 I-077 80 100I-079 80 90 I-080 80 100 I-081 80 100 I-082 80 100 I-083 80 100 I-084 80100 I-085 80 100 I-086 80 90 I-087 80 100 I-088 80 100 I-089 80 100I-090 80 100 I-092 80 90 I-093 80 100 I-094 80 90 I-096 80 100 I-097 8090 I-098 80 100 I-099 80 90 I-100 80 100 I-104 80 80 II-02 80 80 II-0480 80 II-06 80 80 II-07 80 80 II-09 80 90 II-10 80 90 II-11 80 90 II-1280 80 II-14 80 100 II-18 80 100 II-20 80 100 II-22 80 90 II-25 80 90II-26 80 90 II-27 80 90 II-28 80 80 II-29 80 80 II-30 80 100 II-31 80100 II-32 80 90 II-33 80 100 II-34 80 100 II-35 80 100 II-36 80 100II-37 80 100 II-39 80 90 III-01 80 80 III-02 80 90 III-03 80 90 III-0480 100 III-06 80 80 III-07 80 90 III-08 80 100 III-09 80 100 III-10 80100 III-12 80 100 III-13 80 90 III-16 80 100 III-17 80 90 IV-04 80 90IV-06 80 90 IV-07 80 80 IV-10 80 90

TABLE 5.3 Post-emergence herbicidal action against ECHCG in % Herbicidalaction Example Application against [%] number rate [g/ha] ECHCG I-002 8080 I-004 80 80 I-006 80 80 I-007 80 90 I-008 80 90 I-009 80 90 I-010 8090 I-011 80 90 I-012 80 90 I-013 80 80 I-014 80 90 I-015 80 100 I-016 80100 I-017 80 100 I-018 80 100 I-019 80 80 I-020 80 80 I-021 80 80 I-02280 80 I-023 80 80 I-024 80 90 I-025 80 80 I-026 80 80 I-027 80 80 I-02880 80 I-030 80 80 I-031 80 80 I-033 80 90 I-034 80 80 I-035 80 90 I-03780 90 I-038 80 80 I-039 80 90 I-040 80 90 I-041 80 80 I-042 80 90 I-04380 80 I-044 80 90 I-045 80 80 I-046 80 90 I-048 80 80 I-051 80 80 I-05280 80 I-054 80 90 I-055 80 90 I-056 80 80 I-057 80 80 I-058 80 100 I-05980 100 I-060 80 90 I-061 80 100 I-062 80 90 I-063 80 90 I-064 80 90I-065 80 90 I-066 80 80 I-067 80 90 I-068 80 90 I-069 80 90 I-070 80 90I-071 80 90 I-072 80 90 I-073 80 100 I-075 80 90 I-076 80 90 I-077 80 80I-079 80 80 I-080 80 90 I-082 80 90 I-083 80 90 I-084 80 90 I-085 80 90I-086 80 90 I-087 80 80 I-088 80 90 I-089 80 90 I-090 80 80 I-092 80 80I-093 80 100 I-094 80 90 I-096 80 80 I-097 80 90 I-098 80 90 I-099 80 80I-100 80 90 I-104 80 80 II-02 80 80 II-04 80 80 II-06 80 80 II-07 80 80II-10 80 90 II-11 80 90 II-14 80 100 II-18 80 80 II-25 80 80 II-26 80 80II-27 80 90 II-28 80 90 II-29 80 90 II-30 80 90 II-31 80 90 II-32 80 90II-33 80 80 II-34 80 80 III-02 80 90 III-04 80 80 III-06 80 80 III-07 8090 III-08 80 90 III-09 80 90 III-10 80 90 III-13 80 90 III-16 80 90III-17 80 80 IV-04 80 80 IV-06 80 80 IV-07 80 80 IV-10 80 90 V-01 80 90V-04 80 80

TABLE 5.4 Post-emergence herbicidal action against LOLRI in % Herbicidalaction Example Application against [%] number rate [g/ha] LOLRI I-002 8080 I-004 80 80 I-006 80 80 I-007 80 90 I-008 80 90 I-009 80 90 I-010 8090 I-011 80 90 I-012 80 90 I-013 80 90 I-014 80 90 I-015 80 100 I-016 80100 I-017 80 100 I-018 80 100 I-019 80 90 I-020 80 90 I-021 80 90 I-02280 100 I-023 80 90 I-024 80 90 I-025 80 90 I-026 80 90 I-027 80 90 I-02880 90 I-029 80 90 I-030 80 100 I-031 80 100 I-032 80 90 I-033 80 90I-034 80 100 I-035 80 90 I-036 80 90 I-037 80 90 I-038 80 90 I-039 80100 I-040 80 90 I-041 80 80 I-042 80 100 I-043 80 90 I-045 80 80 I-04680 100 I-048 80 80 I-049 80 90 I-051 80 90 I-052 80 100 I-053 80 90I-054 80 100 I-055 80 90 I-056 80 90 I-057 80 90 I-058 80 90 I-059 80100 I-061 80 90 I-062 80 90 I-063 80 100 I-064 80 100 I-065 80 90 I-06680 90 I-067 80 90 I-068 80 90 I-069 80 90 I-070 80 80 I-071 80 90 I-07280 90 I-073 80 100 I-075 80 100 I-076 80 100 I-077 80 90 I-080 80 90I-081 80 100 I-082 80 100 I-083 80 100 I-084 80 100 I-085 80 100 I-08680 90 I-087 80 100 I-088 80 100 I-089 80 100 I-090 80 100 I-092 80 90I-093 80 100 I-094 80 90 I-096 80 100 I-097 80 100 I-098 80 90 I-099 80100 I-100 80 90 I-104 80 90 II-02 80 80 II-04 80 80 II-06 80 90 II-07 8080 II-09 80 80 II-10 80 90 II-11 80 90 II-12 80 80 II-14 80 100 II-16 8080 II-18 80 80 II-22 80 90 II-25 80 90 II-26 80 100 II-27 80 90 II-28 8090 II-29 80 90 II-30 80 90 II-31 80 90 II-32 80 90 II-33 80 90 II-34 8090 II-35 80 90 II-36 80 90 II-37 80 100 II-39 80 80 III-02 80 90 III-0380 80 III-04 80 90 III-05 80 80 III-06 80 90 III-07 80 90 III-08 80 90III-09 80 100 III-10 80 100 III-12 80 100 III-13 80 100 III-16 80 100III-17 80 90 IV-03 80 90 IV-04 80 90 IV-06 80 80 IV-07 80 90 IV-10 80 90V-01 80 100 V-04 80 90

TABLE 5.5 Post-emergence herbicidal action against SETVI in % Herbicidalaction Example Application against [%] number rate [g/ha] SETVI I-002 8080 I-004 80 80 I-007 80 90 I-008 80 90 I-009 80 90 I-010 80 90 I-011 8080 I-012 80 90 I-013 80 90 I-014 80 80 I-015 80 90 I-016 80 90 I-017 8090 I-018 80 90 I-019 80 90 I-020 80 90 I-021 80 90 I-022 80 100 I-023 8090 I-024 80 80 I-025 80 90 I-026 80 90 I-027 80 90 I-028 80 90 I-029 8080 I-030 80 90 I-031 80 90 I-032 80 90 I-033 80 90 I-034 80 80 I-035 8080 I-037 80 90 I-038 80 90 I-039 80 80 I-042 80 80 I-043 80 80 I-045 8080 I-046 80 80 I-052 80 90 I-054 80 80 I-055 80 90 I-056 80 80 I-058 8090 I-059 80 90 I-061 80 90 I-062 80 80 I-063 80 90 I-064 80 90 I-065 8090 I-066 80 90 I-067 80 90 I-068 80 90 I-069 80 80 I-070 80 90 I-071 8090 I-072 80 80 I-073 80 80 I-075 80 80 I-076 80 90 I-077 80 80 I-079 8090 I-080 80 80 I-081 80 80 I-082 80 90 I-083 80 80 I-084 80 90 I-085 8080 I-086 80 90 I-087 80 80 I-088 80 90 I-089 80 80 I-090 80 90 I-092 8080 I-093 80 80 I-094 80 80 I-096 80 80 I-097 80 90 I-098 80 80 I-099 8090 I-100 80 80 II-02 80 80 II-04 80 80 II-06 80 80 II-11 80 90 II-12 8080 II-14 80 90 II-16 80 80 II-18 80 90 II-26 80 80 II-27 80 80 II-28 8080 II-29 80 80 II-30 80 80 II-31 80 80 II-32 80 80 II-33 80 80 II-34 8080 II-35 80 80 II-37 80 80 III-02 80 80 III-04 80 80 III-06 80 80 III-0780 90 III-08 80 90 III-09 80 80 III-10 80 90 III-12 80 80 III-13 80 80III-16 80 80 III-17 80 80 IV-04 80 80 IV-06 80 80 IV-07 80 80 V-01 80 80V-04 80 80

TABLE 5.6 Post-emergence herbicidal action against ABUTH in % Herbicidalaction Example Application against [%] number rate [g/ha] ABUTH I-007 8080 I-008 80 90 I-009 80 90 I-010 80 80 I-012 80 80 I-013 80 80 I-015 8090 I-016 80 90 I-017 80 100 I-018 80 90 I-019 80 80 I-020 80 80 I-021 8080 I-022 80 90 I-023 80 80 I-024 80 80 I-027 80 80 I-028 80 80 I-033 8080 I-034 80 80 I-035 80 80 I-036 80 80 I-037 80 90 I-038 80 80 I-039 8080 I-040 80 80 I-041 80 80 I-042 80 80 I-043 80 80 I-044 80 90 I-045 8080 I-046 80 90 I-048 80 80 I-050 80 80 I-051 80 80 I-052 80 90 I-055 8080 I-058 80 90 I-061 80 80 I-062 80 80 I-063 80 90 I-064 80 80 I-065 8080 I-067 80 80 I-068 80 90 I-069 80 80 I-070 80 80 I-071 80 80 I-072 8080 I-073 80 80 I-075 80 80 I-076 80 80 I-079 80 80 I-081 80 80 I-082 8090 I-083 80 90 I-084 80 90 I-085 80 90 I-086 80 90 I-087 80 90 I-088 8090 I-089 80 90 I-090 80 90 I-092 80 90 I-093 80 80 I-094 80 90 I-096 8090 I-098 80 80 I-100 80 80 II-06 80 80 II-11 80 90 II-12 80 80 II-26 8080 II-28 80 90 II-30 80 80 II-31 80 90 II-32 80 80 II-33 80 80 II-34 8080 II-35 80 80 II-37 80 80 III-06 80 80 III-07 80 80 III-08 80 80 III-0980 80 III-10 80 90 III-12 80 90 III-13 80 80 III-16 80 80 III-17 80 80V-01 80 80 V-04 80 80

TABLE 5.7 Post-emergence herbicidal action against AMARE in % Herbicidalaction Example Application against [%] number rate [g/ha] AMARE I-004 8080 I-008 80 90 I-010 80 90 I-012 80 90 I-013 80 80 I-014 80 90 I-015 80100 I-016 80 90 I-017 80 90 I-018 80 90 I-019 80 90 I-020 80 100 I-02180 90 I-022 80 100 I-023 80 90 I-024 80 90 I-025 80 90 I-026 80 90 I-02780 80 I-028 80 90 I-029 80 90 I-030 80 90 I-031 80 90 I-032 80 90 I-03380 90 I-035 80 80 I-036 80 80 I-037 80 90 I-038 80 80 I-039 80 80 I-04380 80 I-044 80 80 I-046 80 80 I-049 80 90 I-050 80 80 I-052 80 90 I-05480 80 I-055 80 80 I-056 80 80 I-058 80 90 I-059 80 80 I-060 80 80 I-06180 90 I-062 80 80 I-063 80 90 I-064 80 90 I-065 80 80 I-066 80 90 I-06780 80 I-068 80 80 I-069 80 80 I-070 80 90 I-071 80 80 I-072 80 80 I-07380 80 I-075 80 90 I-076 80 90 I-077 80 80 I-079 80 90 I-080 80 90 I-08180 80 I-082 80 90 I-083 80 90 I-084 80 90 I-085 80 90 I-086 80 90 I-08780 90 I-088 80 90 I-089 80 90 I-090 80 90 I-092 80 90 I-093 80 80 I-09480 90 I-096 80 90 I-097 80 80 I-098 80 80 I-099 80 80 I-100 80 80 I-10480 80 II-02 80 80 II-06 80 80 II-10 80 80 II-11 80 90 II-12 80 80 II-1480 90 II-18 80 80 II-25 80 80 II-26 80 90 II-27 80 80 II-28 80 80 II-2980 80 II-30 80 80 II-31 80 80 II-32 80 80 II-33 80 90 II-34 80 90 II-3580 90 II-36 80 90 II-37 80 90 II-38 80 90 II-39 80 80 III-02 80 80III-04 80 80 III-06 80 80 III-07 80 90 III-08 80 80 III-09 80 90 III-1080 90 III-12 80 90 III-13 80 90 III-16 80 90 III-17 80 90 IV-04 80 80IV-06 80 80 IV-07 80 80 IV-10 80 80 V-01 80 80 V-04 80 80

TABLE 5.8 Post-emergence herbicidal action against MATIN in % Herbicidalaction Example Application against [%] number rate [g/ha] MATIN I-002 8080 I-008 80 90 I-009 80 90 I-011 80 80 I-012 80 90 I-013 80 90 I-015 8080 I-016 80 80 I-017 80 80 I-018 80 80 I-019 80 90 I-020 80 90 I-022 8080 I-023 80 90 I-024 80 80 I-027 80 90 I-028 80 80 I-031 80 80 I-032 8080 I-033 80 90 I-036 80 80 I-037 80 80 I-038 80 90 I-039 80 80 I-040 8080 I-041 80 80 I-042 80 80 I-046 80 80 I-048 80 80 I-053 80 80 I-055 8080 I-058 80 90 I-059 80 90 I-061 80 80 I-062 80 80 I-063 80 90 I-064 8090 I-065 80 80 I-067 80 80 I-068 80 90 I-071 80 80 I-076 80 80 I-077 8080 I-092 80 90 I-093 80 90 I-094 80 80 I-098 80 80 I-104 80 80 II-11 8090 II-14 80 90 V-01 80 80

TABLE 5.9 Post-emergence herbicidal action against PHBPU in % Herbicidalaction Example Application against [%] number rate [g/ha] PHBPU I-002 8080 I-006 80 80 I-007 80 90 I-008 80 90 I-009 80 90 I-010 80 90 I-012 8090 I-013 80 80 I-020 80 80 I-021 80 80 I-023 80 80 I-026 80 80 I-030 8080 I-031 80 80 I-033 80 80 I-037 80 80 I-038 80 80 I-039 80 80 I-044 8080 I-045 80 80 I-048 80 80 I-049 80 90 I-051 80 80 I-052 80 80 I-053 8080 I-054 80 80 I-058 80 80 I-059 80 80 I-060 80 80 I-061 80 80 I-062 8080 I-063 80 80 I-064 80 80 I-065 80 80 I-067 80 80 I-068 80 80 I-070 8080 I-073 80 80 I-075 80 90 I-076 80 80 I-077 80 80 I-080 80 90 I-082 8090 I-083 80 90 I-084 80 90 I-085 80 90 I-086 80 80 I-087 80 90 I-088 8090 I-090 80 90 I-092 80 80 I-093 80 80 I-094 80 90 I-095 80 90 I-096 8090 I-097 80 80 I-098 80 80 I-100 80 80 II-06 80 80 II-08 80 90 II-10 8090 II-11 80 90 II-12 80 80 II-18 80 80 II-19 80 90 II-24 80 80 II-26 8080 II-28 80 90 II-34 80 90 II-35 80 90 II-36 80 90 III-02 80 80 III-0480 90 III-07 80 80 III-08 80 80 III-09 80 90 III-10 80 90 III-12 80 90III-13 80 90 III-16 80 90 III-17 80 90 IV-07 80 80 IV-10 80 90 V-01 8090

TABLE 5.10 Post-emergence herbicidal action against POLCO in %Herbicidal action Example Application against [%] number rate [g/ha]POLCO I-003 80 80 I-007 80 80 I-008 80 90 I-009 80 90 I-010 80 90 I-01180 80 I-012 80 80 I-013 80 90 I-014 80 80 I-015 80 100 I-016 80 90 I-01780 90 I-018 80 100 I-019 80 100 I-021 80 90 I-022 80 100 I-023 80 100I-024 80 90 I-025 80 100 I-026 80 80 I-028 80 100 I-029 80 80 I-030 8090 I-031 80 90 I-032 80 100 I-033 80 100 I-034 80 80 I-035 80 80 I-03680 90 I-037 80 90 I-038 80 80 I-054 80 80 I-055 80 90 I-056 80 80 I-05780 80 I-058 80 90 I-059 80 80 I-061 80 90 I-062 80 80 I-063 80 90 I-06480 90 I-065 80 90 I-066 80 80 I-067 80 90 I-068 80 90 I-069 80 80 I-07080 90 I-071 80 90 I-072 80 90 I-073 80 90 I-075 80 90 I-076 80 90 I-07780 80 I-079 80 90 I-080 80 90 I-081 80 90 I-082 80 90 I-083 80 90 I-08480 90 I-085 80 80 I-086 80 80 I-087 80 90 I-088 80 90 I-089 80 90 I-09080 90 I-092 80 80 I-093 80 90 I-094 80 90 I-095 80 90 I-096 80 90 I-09780 80 I-098 80 80 I-099 80 80 I-100 80 90 I-104 80 90 II-06 80 80 II-0980 90 II-10 80 90 II-11 80 90 II-12 80 80 II-14 80 90 II-21 80 80 II-2280 80 II-25 80 80 II-26 80 80 II-27 80 90 II-28 80 80 II-29 80 80 II-3080 90 II-31 80 90 II-32 80 90 II-33 80 90 II-34 80 90 II-35 80 90 II-3680 90 II-37 80 100 III-04 80 80 III-06 80 80 III-07 80 80 III-08 80 80III-09 80 90 III-12 80 90 III-13 80 80 III-16 80 90 III-17 80 80 IV-0280 80 IV-04 80 80 IV-06 80 80 IV-07 80 80 V-01 80 90

TABLE 5.11 Post-emergence herbicidal action against STEME in %Herbicidal action Example Application against [%] number rate [g/ha]STEME I-002 80 90 I-004 80 80 I-006 80 80 I-007 80 90 I-008 80 90 I-00980 90 I-010 80 80 I-011 80 90 I-012 80 80 I-013 80 80 I-014 80 90 I-01580 100 I-016 80 100 I-017 80 100 I-019 80 90 I-020 80 80 I-021 80 80I-025 80 80 I-026 80 80 I-027 80 80 I-028 80 80 I-033 80 80 I-034 80 90I-035 80 90 I-037 80 90 I-038 80 90 I-039 80 90 I-040 80 90 I-041 80 80I-042 80 90 I-043 80 80 I-045 80 80 I-046 80 90 I-048 80 90 I-051 80 90I-052 80 80 I-053 80 90 I-054 80 80 I-055 80 90 I-056 80 90 I-057 80 80I-058 80 90 I-059 80 90 I-061 80 90 I-062 80 80 I-063 80 90 I-064 80 80I-065 80 90 I-067 80 90 I-068 80 90 I-069 80 80 I-070 80 80 I-071 80 90I-072 80 80 I-073 80 90 I-075 80 90 I-076 80 90 I-077 80 80 I-079 80 80I-080 80 90 I-081 80 90 I-082 80 90 I-083 80 90 I-084 80 100 I-085 80 80I-086 80 80 I-087 80 90 I-088 80 90 I-089 80 90 I-090 80 90 I-092 80 90I-093 80 80 I-094 80 90 I-096 80 90 I-097 80 80 I-098 80 90 I-099 80 80I-100 80 90 I-104 80 80 II-02 80 90 II-04 80 80 II-06 80 80 II-07 80 90II-08 80 90 II-10 80 90 II-11 80 90 II-12 80 90 II-18 80 80 II-20 80 80II-22 80 80 II-26 80 90 II-27 80 90 II-28 80 90 II-31 80 90 II-32 80 90II-33 80 80 II-34 80 90 II-35 80 90 II-37 80 90 III-02 80 80 III-04 8080 III-06 80 90 III-07 80 90 III-08 80 90 III-09 80 90 III-10 80 90III-12 80 80 III-13 80 90 III-16 80 80 III-17 80 90 IV-04 80 80 IV-06 8080 IV-07 80 90 V-01 80 90 V-04 80 90

TABLE 5.12 Post-emergence herbicidal action against VIOTR in %Herbicidal action Example Application against [%] number rate [g/ha]VIOTR I-012 80 80 I-013 80 80 I-014 80 90 I-015 80 90 I-016 80 80 I-01780 80 I-019 80 80 I-020 80 100 I-022 80 80 I-023 80 80 I-024 80 80 I-02780 80 I-028 80 80 I-029 80 80 I-032 80 80 I-036 80 90 I-037 80 90 I-03880 80 I-052 80 80 I-055 80 90 I-057 80 80 I-058 80 90 I-060 80 80 I-06180 80 I-062 80 80 I-063 80 80 I-064 80 80 I-065 80 90 I-067 80 80 I-06880 90 I-071 80 80 I-072 80 80 I-075 80 90 I-076 80 80 I-077 80 80 I-08080 80 I-082 80 90 I-083 80 90 I-084 80 90 I-085 80 80 I-087 80 90 I-08880 90 I-089 80 90 I-090 80 90 I-092 80 80 I-093 80 80 I-094 80 90 I-09680 90 I-097 80 80 I-098 80 80 I-099 80 80 I-100 80 80 II-07 80 80 II-1080 90 II-11 80 90 II-14 80 90 II-31 80 90 II-33 80 90 II-34 80 90 II-3580 90 II-36 80 90 II-37 80 90 II-38 80 80 III-07 80 90 III-08 80 80III-09 80 90 III-10 80 90 III-12 80 90 III-16 80 90 III-17 80 80 IV-0480 80 IV-06 80 90 IV-07 80 80 V-01 80 90 V-04 80 80

TABLE 5.13 Post-emergence herbicidal action against VERPE in %Herbicidal action Example Application against [%] number rate [g/ha]VERPE I-007 80 90 I-008 80 90 I-009 80 90 I-010 80 90 I-011 80 80 I-01280 80 I-013 80 80 I-014 80 90 I-015 80 90 I-016 80 90 I-017 80 90 I-01880 90 I-019 80 90 I-020 80 90 I-021 80 80 I-022 80 80 I-023 80 90 I-02480 80 I-026 80 80 I-027 80 80 I-028 80 80 I-029 80 90 I-030 80 80 I-03180 80 I-032 80 80 I-033 80 80 I-034 80 90 I-035 80 80 I-036 80 80 I-03780 90 I-038 80 90 I-039 80 80 I-040 80 80 I-042 80 80 I-043 80 80 I-04680 80 I-048 80 80 I-049 80 80 I-051 80 80 I-052 80 80 I-053 80 80 I-05480 90 I-055 80 80 I-056 80 80 I-057 80 80 I-058 80 80 I-059 80 80 I-06180 90 I-062 80 90 I-063 80 80 I-064 80 80 I-065 80 80 I-066 80 80 I-06780 80 I-068 80 80 I-069 80 80 I-070 80 80 I-071 80 80 I-072 80 80 I-07380 80 I-075 80 90 I-076 80 80 I-077 80 90 I-079 80 90 I-080 80 90 I-08180 80 I-082 80 90 I-083 80 90 I-084 80 90 I-085 80 90 I-086 80 90 I-08780 90 I-088 80 90 I-089 80 90 I-090 80 90 I-092 80 90 I-093 80 80 I-09480 90 I-095 80 80 I-096 80 90 I-097 80 80 I-098 80 80 I-099 80 80 I-10080 90 I-104 80 80 II-06 80 80 II-07 80 80 II-08 80 80 II-10 80 80 II-1180 90 II-12 80 80 II-14 80 90 II-18 80 80 II-22 80 80 II-24 80 80 II-2680 80 II-27 80 90 II-28 80 90 II-29 80 80 II-30 80 80 II-31 80 90 II-3280 80 II-33 80 80 II-34 80 90 II-35 80 90 II-36 80 80 II-37 80 90 II-3980 80 III-02 80 80 III-07 80 90 III-08 80 90 III-09 80 90 III-10 80 90III-12 80 90 III-13 80 80 III-16 80 80 III-17 80 90 IV-07 80 80 V-01 8080 V-04 80 80

TABLE 5.14 Post-emergence herbicidal action against HORMU in %Herbicidal action Example Application against [%] number rate [g/ha]HORMU I-006 80 80 I-007 80 90 I-008 80 90 I-009 80 90 I-010 80 90 I-01180 80 I-012 80 100 I-013 80 90 I-014 80 80 I-015 80 100 I-016 80 90I-017 80 100 I-018 80 90 I-019 80 90 I-020 80 80 I-021 80 90 I-022 80 80I-023 80 80 I-024 80 80 I-025 80 80 I-026 80 90 I-027 80 80 I-028 80 80I-029 80 80 I-030 80 90 I-031 80 90 I-032 80 80 I-033 80 80 I-034 80 90I-035 80 90 I-036 80 80 I-037 80 90 I-038 80 80 I-039 80 80 I-040 80 90I-041 80 90 I-042 80 90 I-043 80 80 I-044 80 100 I-045 80 90 I-046 80100 I-048 80 90 I-049 80 90 I-050 80 90 I-051 80 90 I-052 80 100 I-05480 90 I-055 80 90 I-056 80 80 I-057 80 80 I-058 80 100 I-059 80 90 I-06080 90 I-061 80 90 I-062 80 100 I-063 80 90 I-064 80 90 I-065 80 90 I-06680 90 I-067 80 90 I-068 80 90 I-069 80 90 I-070 80 90 I-071 80 90 I-07280 90 I-073 80 90 I-075 80 100 I-076 80 80 I-077 80 90 I-079 80 100I-080 80 90 I-081 80 100 I-082 80 100 I-083 80 100 I-084 80 100 I-085 80100 I-086 80 100 I-087 80 100 I-088 80 90 I-089 80 100 I-090 80 100I-092 80 100 I-093 80 100 I-094 80 90 I-096 80 100 I-097 80 90 I-098 8090 I-099 80 80 I-100 80 90 I-104 80 90 II-06 80 80 II-11 80 90 II-14 8090 II-18 80 90 II-22 80 90 II-25 80 100 II-26 80 100 II-27 80 80 II-2880 80 II-29 80 80 II-31 80 80 II-32 80 90 II-33 80 90 II-34 80 80 II-3580 80 II-36 80 80 II-37 80 90 II-39 80 80 III-02 80 100 III-03 80 90III-04 80 100 III-05 80 90 III-06 80 90 III-07 80 80 III-08 80 100III-09 80 100 III-10 80 100 III-12 80 100 III-13 80 90 III-16 80 90III-17 80 90 IV-04 80 90 IV-06 80 90 IV-07 80 90 IV-10 80 90 V-01 80 90V-04 80 90

As shown by the results, compounds according to the invention such as,for example, the compounds No. I-002 and other compounds from the tables(I-004, I-006, I-007, I-008, I-009, I-010, I-011, I-012, I-013, I-014,I-015, I-016, I-017, I-018, I-019, I-020, I-021, I-022, I-023, I-024,I-025, I-026, I-027, I-028, I-029, I-030, I-031, I-032, I-033, I-034,I-035, I-036, I-037, I-038, I-039, I-040, I-041, I-042, I-043, I-044,I-045, I-046, I-047, I-048, I-049, I-050, I-051, I-052, I-053, I-054,I-055, I-056, I-057, I-058, I-059, I-060, I-061, I-062, I-063, I-064,I-065, I-066, I-067, I-068, I-069, I-070, I-071, I-072, I-073, I-074,I-075, I-076, I-077, I-078, I-079, I-080, I-081, I-082, I-083, I-084,I-085, I-086, I-087, I-088, I-089, I-090, I-091, I-092, I-093, I-094,I-095, I-096, I-097, I-098, I-099, I-100, I-104 II-02, II-04, II-06,II-07, II-08, II-09, II-10, II-11, II-12, II-14, II-15, II-16, II-18,II-22, II-25, II-26, II-27, II-28, II-29, II-30, II-31, II-32, II-33,II-34, II-35, II-36, II-37, II-39, III-02, III-06, III-07, III-08,III-09, III-10, III-12, III-13, III-16, III-17, IV-02, IV-04, IV-06,IV-07, IV-10, V-01, V-04) have, when used for post-emergence treatment,very good activity (80% to 100% herbicidal action) against harmfulplants such as Abufilon theophrasfi, Alopecurus myosuroides, Avenafatua, Echinochloa crus-galli, Hordeum murinum, Lolium rigidum,Pharbitis purpurea, Polygonum convolvulus, Setaria viridis, Stellariamedia, Veronica persica and Viola tricolor at an application rate of0.08 kg of active substance or less per hectare.

1. 3-Phenylisoxazoline-5-carboxamides and -5-thioamides of formula (I)

And/or agrochemically acceptable salt thereof, in which G represents agroup of formula OR⁴ or NR¹¹R¹²; R¹ and R² independently of one anotherrepresent hydrogen, halogen or cyano, or represent (C₁-C₄)-alkyl or(C₁-C₄)-alkoxy, each of which is substituted by m radicals from thegroup consisting of halogen and cyano; R³ represents cyano or fluorine,or represents (C₁-C₅)-alkyl, (C₃-C₆)-cycloalkyl, (C₂-C₅)-alkenyl,(C₂-C₅)-alkynyl or (C₁-C₅)-alkoxy, each of which is substituted by mradicals from the group consisting of halogen, cyano, (C₁-C₅)-alkoxy andhydroxy; R⁴ represents hydrogen, or represents (C₁-C₁₂)-alkyl,(C₃-C₇)-cycloalkyl, (C₃-C₇)-cycloalkyl-(C₁-C₈)-alkyl, (C₂-C₈)-alkenyl,(C₅-C₆)-cycloalkenyl or (C₂-C₈)-alkynyl, each of which is substituted bym radicals from the group consisting of halogen, cyano, (C₁-C₆)-alkoxy,hydroxy and aryl; Y represents oxygen or sulfur; W represents oxygen orsulfur; Z represents a monounsaturated cyclopentane ring which issubstituted by k radicals from group R¹⁰,

where the arrow in each case denotes a bond to the group C═W of formula(I); R¹⁰ represents halogen, cyano or CO₂R⁷, or represents (C₁-C₂)-alkylor (C₁-C₂)-alkoxy, each of which is substituted by m radicals from thegroup consisting of fluorine and chlorine; R¹¹, R¹² independently of oneanother each represent hydrogen, cyano, OR⁷, S(O)_(n)R⁵, SO₂NR⁶R⁷,CO₂R⁸, CONR⁶R⁸, COR⁶, NR⁶R⁸, NR⁶COR⁸, NR⁶CONR⁸R⁸, NR⁶CO₂R⁸, NR⁶SO₂R⁸,NR⁶SO₂NR⁶R⁸, C(R⁶)═NOR⁸, optionally substituted aryl, optionallysubstituted heteroaryl or optionally substituted heterocyclyl, orrepresent (C₁-C₁₂)-alkyl, (C₃-C₈)-cycloalkyl,(C₃-C₇)-cycloalkyl-(C₁-C₇)-alkyl, (C₂-C₁₂)-alkenyl, (C₅-C₇)-cycloalkenylor (C₂-C₁₂)-alkynyl, each of which is substituted by m radicals from thegroup consisting of halogen, cyano, nitro, OR⁷, S(O)_(n)R⁵, SO₂NR⁶R⁷,CO₂R⁸, CONR⁶R⁸, COR⁶, NR⁶R⁸, NR⁶COR⁸, NR⁶CONR⁸R⁸, NR⁶CO₂R⁸, NR⁶SO₂R⁸,NR⁶SO₂NR⁶R⁸, C(R⁶)═NOR⁸, optionally substituted aryl, optionallysubstituted heteroaryl and optionally substituted heterocyclyl, or R¹¹and R¹² together with the nitrogen atom to which they are attached forma saturated, partially or fully unsaturated five-, six- orseven-membered ring which is optionally mono- to hexasubstituted byradicals from the group consisting of halogen, cyano, nitro,(C₁-C₆)-alkyl, halo-(C₁-C₆)-alkyl, oxo, OR⁷, S(O)_(n)R⁵, SO₂NR⁶R⁷,CO₂R⁸, CONR⁶R⁸, COR⁶, NR⁶R⁸, NR⁶COR⁸, NR⁶CONR⁸R⁸, NR⁶CO₂R⁸, NR⁶SO₂R⁸,NR⁶SO₂NR⁶R⁸ and C(R⁶)═NOR⁸ and which, in addition to this nitrogen atom,contains r carbon atoms, o oxygen atoms, p sulfur atoms and q elementsfrom the group consisting of NR′ and NCOR⁷ as ring atoms; X², X⁴ and X⁶independently of one another each represent hydrogen, halogen or cyano,or represent (C₁-C₂)-alkyl, in each case substituted by m radicals fromthe group consisting of fluorine, chlorine, bromine and (C₁-C₂)-alkoxy;X³ and X⁵ independently of one another each represent hydrogen,fluorine, chlorine, bromine, iodine, hydroxy, cyano, nitro, S(O)_(n)R⁶or CO₂R⁷, or represent (C₁-C₃)-alkyl, (C₁-C₃)-alkoxy,(C₃-C₄)-cycloalkyl, (C₂-C₃)-alkenyl or (C₂-C₃)-alkynyl, each of which issubstituted by m radicals from the group consisting of fluorine,chlorine and bromine; R⁵ represents (C₁-C₆)-alkyl, (C₃-C₆)-cycloalkyl oraryl, each of which is substituted by m radicals from the groupconsisting of halogen, cyano and hydroxy; R⁶ represents hydrogen or R⁵;R⁷ represents hydrogen, or represents (C₁-C₆)-alkyl, (C₃-C₆)-cycloalkyl,(C₃-C₄)-alkenyl or (C₃-C₄)-alkynyl, each of which is substituted by mradicals from the group consisting of halogen, cyano and (C₁-C₂)-alkoxy;R⁸ represents hydrogen, or represents (C₁-C₈)-alkyl, (C₃-C₆)-cycloalkyl,(C₃-C₈)-alkenyl or (C₃-C₈)-alkynyl, each of which is substituted by mradicals from the group consisting of halogen, cyano and (C₁-C₂)-alkoxy;k represents the running number 0, 1 or 2; where for k>1 R¹⁰independently of the others may be identical or different; m representsthe running number 0, 1, 2, 3, 4 or 5; n represents the running number0, 1 or 2; o represents the running number 0, 1 or 2; p represents therunning number 0 or 1; q represents the running number 0 or 1; and rrepresents the running number 3, 4, 5 or
 6. 2. Compound according toclaim 1, where R¹ and R² independently of one another each representhydrogen, fluorine, chlorine or cyano, or represent (C₁-C₃)-alkyl or(C₁-C₃)-alkoxy which are in each case substituted by m radicals from thegroup consisting of fluorine, chlorine, bromine and cyano.
 3. Compoundaccording to claim 1, where R³ represents (C₁-C₄)-alkyl,(C₃-C₅)-cycloalkyl, (C₂-C₄)-alkenyl, (C₂-C₄)-alkynyl or (C₁-C₄)-alkoxy,each of which is substituted by m radicals from the group consisting offluorine, chlorine, bromine, cyano, (C₁-C₄)-alkoxy and hydroxy. 4.Compound of the general formula (I) according to claim 1, where R⁴represents hydrogen, or represents (C₁-C₆)-alkyl, (C₃-C₆)-cycloalkyl,(C₃-C₆)-cycloalkyl-(C₁-C₆)-alkyl, (C₂-C₆)-alkenyl, (C₅-C₆)-cycloalkenylor (C₂-C₆)-alkynyl, each of which is substituted by m radicals from thegroup consisting of fluorine, chlorine, bromine, cyano, (C₁-C₄)-,hydroxy and aryl.
 5. Compound according to claim 1, where Y representsoxygen.
 6. Compound according to claim 1, where W represents oxygen. 7.Compound of the general formula (I) according to claim 1, where Zrepresents a group Z-1 to Z-22, where Z-1 to Z-22 have the followingmeaning:

where the arrow in each case denotes a bond to the group C═W of formula(I).
 8. Compound according to claim 1, where R¹⁰ represents fluorine,chlorine, cyano, CO₂H, CO₂CH₃ or CO₂CH₂CH₃, or represents (C₁-C₂)-alkylor (C₁-C₂)-alkoxy, each of which is substituted by m radicals from thegroup consisting of fluorine and chlorine.
 9. Compound according toclaim 1, where R¹¹ represents hydrogen, or represents (C₁-C₃)-alkyl or(C₃-C₆)-cycloalkyl, each of which is substituted by m radicals from thegroup consisting of fluorine and chlorine.
 10. Compound according toclaim 1, where R¹² represents hydrogen, cyano or hydroxy, or representsOR⁷, S(O)_(n)R⁵, NR⁶R⁸, NR⁶CO₂R⁸, (C₁-C₆)-alkyl, (C₃-C₆)-cycloalkyl,(C₂-C₃)-alkenyl or (C₂-C₃)-alkynyl, each of which is substituted by mradicals from the group consisting of fluorine, chlorine, bromine, cyanoand hydroxy.
 11. Compound according to claim 1, where R¹¹ and R¹²together with the nitrogen atom to which they are attached form asaturated, partially or fully unsaturated five-, six- or seven-memberedring which is optionally mono- to hexasubstituted by radicals from thegroup consisting of halogen, cyano, nitro, (C₁-C₆)-alkyl,halo-(C₁-C₆)-alkyl, oxo, OR⁷, CO₂R⁸ and NR⁶SO₂R⁸ and which, in additionto this nitrogen atom, contains r carbon atoms, o oxygen atoms, p sulfuratoms and q elements from the group consisting of NR′ and NCOR⁷ as ringatoms.
 12. Compound according to claim 1, where X², X⁴ and X⁶independently of one another each represent hydrogen, fluorine,chlorine, bromine or cyano, or represent methyl or methoxy, each ofwhich is substituted by m radicals from the group consisting of fluorineand chlorine.
 13. Compound according to claim 1, where X³ and X⁵independently of one another represent hydrogen, fluorine, chlorine,bromine, hydroxy or cyano, or represent (C₁-C₃)-alkyl, (C₁-C₃)-alkoxy,(C₃-C₄)-cycloalkyl, (C₂-C₃)-alkenyl or (C₂-C₃)-alkynyl, each of which issubstituted by m radicals from the group consisting of fluorine,chlorine and bromine.
 14. Compound according to claim 1, where R⁵represents (C₁-C₆)-alkyl or (C₃-C₆)-cycloalkyl, each of which issubstituted by m radicals from the group consisting of fluorine andchlorine.
 15. Compound according to claim 1, where R⁷ representshydrogen, or represents (C₁-C₆)-alkyl or (C₃-C₆)-cycloalkyl, each ofwhich is substituted by m radicals from the group consisting offluorine, chlorine and (C₁-C₂)-alkoxy.
 16. Compound according to claim1, where R⁸ represents hydrogen, or represents (C₁-C₆)-alkyl or(C₃-C₆)-cycloalkyl, each of which is substituted by m radicals from thegroup consisting of fluorine, chlorine and (C₁-C₂)-alkoxy.
 17. Compoundaccording to claim 1, where the running number m is 0, 1, 2 or
 3. 18.Compound according to claim 1, in which G represents a group of formulaOR⁴; R¹ and R² each represent hydrogen; R³ represents (C₁-C₃)-alkyl,(C₃-C₄)-cycloalkyl, (C₂-C₃)-alkenyl or (C₁-C₃)-alkoxy, each of which issubstituted by m radicals from the group consisting of fluorine,chlorine and (C₁-C₂)-alkoxy; R⁴ represents hydrogen, or represents(C₁-C₆)-alkyl, (C₃-C₆)-cycloalkyl, (C₃-C₆)-cycloalkyl-(C₁-C₆)-alkyl,(C₂-C₆)-alkenyl, (C₅-C₆)-cycloalkenyl or (C₂-C₆)-alkynyl, each of whichis substituted by m radicals from the group consisting of fluorine,chlorine, bromine, cyano, (C₁-C₄)-alkoxy, hydroxy and aryl; Y representsoxygen; W represents oxygen; Z represents a group Z-1, Z-4 or Z-6:

where the arrow in each case denotes a bond to the group C═W of formula(I); X², X⁴ and X⁶ independently of one another each represent hydrogenor fluorine; X³ and X⁵ independently of one another each representhydrogen, fluorine, chlorine, CF₃, CHF₂ or methyl; and m represents therunning number 0, 1, 2 or
 3. 19. Compound according to claim 1, in whichG represents a group of formula NR¹¹R¹²; R¹ and R² each representhydrogen; R³ represents (C₁-C₃)-alkyl, (C₃-C₄)-cycloalkyl,(C₂-C₃)-alkenyl or (C₁-C₃)-alkoxy, each of which is substituted by mradicals from the group consisting of fluorine, chlorine and(C₁-C₂)-alkoxy; Y represents oxygen; W represents oxygen; Z represents agroup Z-1, Z-4 or Z-6:

where the arrow in each case denotes a bond to the group C═W of formula(I); X², X⁴ and X⁶ independently of one another each represent hydrogenor fluorine; X³ and X⁵ independently of one another each representhydrogen, fluorine, chlorine, CF₃, CHF₂ or methyl; R⁵ represents(C₁-C₆)-alkyl or (C₃-C₆)-cycloalkyl, each of which is substituted by mradicals from the group consisting of fluorine and chlorine; R⁶represents hydrogen or R⁵; R⁷ represents hydrogen, or represents(C₁-C₆)-alkyl or (C₃-C₆)-cycloalkyl, each of which is substituted by mradicals from the group consisting of fluorine, chlorine and(C₁-C₂)-alkoxy; R⁸ represents hydrogen, or represents (C₁-C₆)-alkyl or(C₃-C₆)-cycloalkyl, each of which is substituted by m radicals from thegroup consisting of fluorine, chlorine and (C₁-C₂)-alkoxy; R¹¹represents hydrogen, or represents (C₁-C₃)-alkyl or (C₃-C₆)-cycloalkyl,each of which is substituted by m radicals from the group consisting offluorine and chlorine; R¹² represents hydrogen, cyano, OR⁷, S(O)_(n)R⁵,SO₂NR⁶R⁷, COR⁶, NR⁶R⁸, NR⁶COR⁸ or NR⁶SO₂R⁸, or represents (C₁-C₆)-alkyl,(C₃-C₆)-cycloalkyl, (C₂-C₃)-alkenyl or (C₂-C₃)-alkynyl, each of which issubstituted by m radicals from the group consisting of fluorine,chlorine, bromine, cyano, OR⁷, S(O)_(n)R⁵, NR⁶R⁸ and NR⁶CO₂R⁸; or R¹¹and R¹² together with the nitrogen atom to which they are attached forma saturated, partially or fully unsaturated five-, six- orseven-membered ring which is optionally mono- to hexasubstituted byradicals from the group consisting of halogen, (C₁-C₆)-alkyl,halo-(C₁-C₆)-alkyl and oxo and which, in addition to this nitrogen atom,contains r carbon atoms, o oxygen atoms, p sulfur atoms and q elementsfrom the group consisting of NR⁷ and NCOR⁷ as ring atoms; m representsthe running number 0, 1, 2 or 3; n represents the running number 0, 1 or2; o represents the running number 0, 1 or 2; p represents the runningnumber 0 or 1; q represents the running number 0 or 1; and r representsthe running number 3, 4 or
 5. 20. Herbicidal composition or plantgrowth-regulating composition, comprising one or more compounds offormula (I) or salts thereof according to claim
 1. 21. Herbicidalcomposition or plant growth-regulating composition according to claim20, further comprising a formulation auxiliary.
 22. Herbicidalcomposition or plant growth-regulating composition according to claim20, comprising at least one further active compound from the group ofinsecticides, acaricides, herbicides, fungicides, safeners and/or growthregulators.
 23. Herbicidal composition or plant growth-regulatingcomposition according to claim 20, comprising a safener.
 24. Herbicidalcomposition or plant growth-regulating composition according to claim23, in which the safener is selected from the group consisting ofmefenpyr-diethyl, cyprosulfamide, isoxadifen-ethyl, cloquintocet-mexyl,benoxacor and dichlormid.
 25. Method of controlling one or more unwantedplants, comprisinq applying an effective amount of at least one compoundof claim 1 or of a composition thereof to the plants and/or to a site ofunwanted vegetation.
 26. The compound according to claim 1 compositionthereof for controlling one or more unwanted plants.
 27. The compound orcomposition according to claim 26, wherein the compound is used forcontrolling one or more unwanted plants in one or more crops of usefulplants.
 28. The compound or composition according to claim 27, whereinthe useful plants are transgenic useful plants.